Search Results (1,978)

Glaciers, often regarded as “frozen reservoirs”, play a crucial role in replenishing numerous rivers in arid regions, contributing to ecological balance and managing river flow. Recently, the rapid shrinkage of the glaciers in the East Tianshan Mountains has affected the water quantity in the Karez system. However, studies on glacier changes in this region are limited, and recent data are scarce. This study utilizes annual Landsat composite images from 1990 to 2022 obtained via the Google Earth Engine (GEE). It utilizes a ratio threshold approach in conjunction with visual analysis to gather the glacier dataset specific to the Turpan–Hami region. The Open Global Glacier Model (OGGM) is used to model the flowlines and mass balance of around 300 glaciers. The study analyzes the glacier change trends, distribution characteristics, and responses to climate factors in the Turpan–Hami region over the past 30 years. Additionally, future glacier changes through the end of the century are projected using CMIP6 climate data. The findings indicate that the following: (1) From 1990 to 2022, glaciers in the research area underwent considerable retreat. The total glacier area decreased from 204.04 ± 0.887 km² to 133.52 ± 0.742 km², a reduction of 70.52 km², representing a retreat rate of 34.56%. The number of glaciers also decreased from 304 in 1990 to 236 in 2022. The glacier length decreased by an average of 7.54 m·a⁻¹, with the average mass balance at −0.34 m w.e.·a⁻¹, indicating a long-term loss of glacier mass. (2) Future projections to 2100 indicate that under three climate scenarios, the area covered by glaciers could diminish by 89%, or 99%, or even vanish entirely. In the SSP585 scenario, glaciers are projected to nearly disappear by 2057. (3) Rising temperatures and solar radiation are the primary factors driving glacier retreat in the Turpan–Hami area. Especially under high emission scenarios, climate warming will accelerate the glacier retreat process. Full article

The accelerated urbanisation that is occurring in many regions of the world is resulting in a corresponding increase in the volume of sewage sludge. This sludge is then stored in specialised landfills, the area of which is increasing annually. One of the methods of utilising this sludge is through its combustion in power plants, where it serves to generate heat. However, due to the low calorific value of sewage sludge, it is recommended to combust it in conjunction with high-calorific fuel. To improve energy efficiency of sewage residue biomass utilisation by co-combustion with coal, it is necessary to determine the main combustion parameters and mass fraction in the mixture. The objective of this study is to estimate the primary parameters of combustion of sewage sludge and coal by employing the synchronous thermal analysis method, in addition to determining the concentrations of gaseous substances formed during the combustion process. A comprehensive technical and elemental analysis of the fuels was conducted, and their thermal properties were thoroughly determined. The inorganic residue from sewage sludge combustion was analysed by scanning electron microscopy for the content of trace elements and basic oxides. Thermogravimetric analysis (TGA) of fuels was conducted in an oxidising medium, utilising a 6 mg suspension with a heating rate of 20 °C/min. The profiles of TG, DTG, and DSC curves were then utilised to determine the ignition and burnout temperatures, maximum mass loss rate, combustion index, and synergistic effects. The mixture of coal with 25% sewage sludge was found to have the most energy-efficient performance compared to other mixtures, with a 3% reduction in ignition temperature compared to coal. Concentrations of carbon dioxide, carbon monoxide, nitrogen oxides, and sulphur oxides were also determined. Full article

This article presents an investigation into the use of nanoscale phononic crystals (PnCs) as reflectors for surface acoustic wave (SAW) resonators, with a focus on pillar-based PnCs. Finite element analysis was employed to simulate the phononic dispersion characteristics and to study the effects of the pillar shape, material and geometric dimensions on achievable acoustic bandgap. To validate our concept, we fabricated SAW resonators and filters incorporating the proposed pillar-based PnC reflectors. The PnC-based reflector shows promising performance, even with smaller number of PnC arrays. In this regard, with a PnC array reflector consisting of 20 lattice periods, the SAW resonator exhibits a maximum bode-Q of about 1600, which can be considered to be a reasonably high value for SAW resonators on bulk 42° Y-X lithium tantalate (42° Y-X LiTaO₃) substrate. Furthermore, we implemented SAW filters using pillar-based PnC reflectors, resulting in a minimum insertion loss of less than 3 dB and out-of-band attenuation exceeding 35 dB. The authors believe that there is still a long way to go in making it fit for mass production, especially due to issues related with the accuracy of fabrication. But, upon its successful implementation, this approach of using PnCs as SAW reflectors could lead to reducing the foot-print of SAW devices, particularly for SAW-based sensors and filters. Full article

To address the low resource utilization of copper tailings and high environmental impact of conventional river sand, this study innovatively integrates Box–Behnken design (BBD) with fractal theory to systematically investigate the performance optimization mechanisms of cement mortar incorporating copper tailings sand. A three-factor interaction model was developed through BBD experimental design, considering water–cement ratio (0.38–0.48), replacement ratio (10–30%), and binder–sand ratio (0.3–0.4), to elucidate the macroscopic performance evolution under multiparameter coupling effects. Fractal dimension analysis was employed to quantitatively characterize microstructural evolution. Experimental results demonstrate that the optimal parameters (water–cement ratio: 0.43, replacement ratio: 20%, binder–sand ratio: 0.35) yield superior performance, with 28-day compressive/flexural strengths reaching 61.88/7.14 MPa (12.3%/9.8% enhancement over the control group), and sulfate attack resistance showing 0.74% mass loss after 30 cycles. Microstructural analysis reveals reduced fractal dimension (D = 2.31) in copper tailings-modified specimens, indicating improved pore structure homogeneity. The enhanced performance is attributed to synergistic effects of micro-aggregate filling and pozzolanic reaction-driven C-S-H gel densification. This research establishes a novel multiscale methodology overcoming the limitations of conventional single-factor analysis, providing theoretical and technical support for high-value utilization of industrial solid wastes in construction materials. Full article

Natural sand and high OPC utilization in the concrete industry have affected our environment and caused climate change. This study developed a novel methodology to prepare modified sand by adding (50% R-Sand + 50% M-Sand) to replace 100% natural sand. The two SCMs (5–20% of FA) and 10% of optimized SF were added to the four newly developed concrete mixes. The developed sustainable design mix concrete achieved the design and target strength after a curing period of 28 days. The findings for flexural strength showed comparable trends. Significant strength improvement was also seen at later curing ages, till 182 days. The water absorption and sulfuric acid attacks of the design mix concrete at the hardened stage were also measured. The analysis reveals that water absorption percentages tend to decline as the curing age progresses. The developed mixes show better resistance against sulfuric acid attacks than the reference mix NAC*. A mass loss of around 5% was discovered, much closer to the published studies. The developed mix 15FASFRSC showed consistent results when the modified sand (50% R-Sand + 50% M-Sand) was combined with the SCMs of (15% FA + 10% SF). Hence, the mix 15FASFRSC is the best sustainable mix for the concrete industry. Full article

Battery thermal runaway (TR) is usually accompanied by a large amount of heat release, as well as a jet of flame. This not only causes harm to the surrounding environment but even exacerbates thermal runaway propagation (TRP). At this stage, many types of materials are used to suppress TRP, and people tend to focus on improving one characteristic of the material while ignoring other properties of the material. This may leave potential pitfalls for TRP suppression, suggesting the need to study multiple properties of multiple materials. In order to better weigh the advantages and disadvantages of different types of materials when suppressing TRP, we compared three typical materials for suppressing TRP behavior in lithium-ion batteries (LIBs). These materials are phase change materials (PCM), ceramic fibers, and glass fibers. They are all available in two different thicknesses, 2 mm and 3 mm. The experiments started with a comparative analysis of the TR experimental phenomena in the presence of the different materials. Then, the temperature and mass loss of the battery module during TR were analyzed separately and comparatively. The 3 mm glass fiber showed the best inhibition effect, which extended the TR interval between cells 1 and 2 to 894 s and successfully inhibited the TR of cell 3. Compared with the blank group, the total mass loss decreased from 194.3 g to 182.2 g, which is a 6.2% reduction. Subsequently, we comprehensively analyzed the performance of the three materials in suppressing TRP by combining their suppressing mechanisms. The experimental results show that glass fiber has the best effect in suppressing TRP due to its excellent thermal insulation and mechanical properties. This study may provide new insights into how to trade-off material properties for TRP suppression in the future. Full article

Untreated olive oil mill wastewater (OOMW) from conventionally farmed olives was used in bread production to create a new functional product. Two types of bread were developed with 50% OOMW (EXP-1) and 100% OOMW (EXP-2) replacing water. Two leavening processes were tested: sourdough inoculum (S) vs. biga-like inoculum (B), with controls (CTR) without OOMW addition. The doughs were monitored throughout the acidification process by measuring pH, total titratable acidity, and the development of key fermentative microorganisms. To assess the hygienic quality during fermentation, plate count techniques were employed. After baking, the breads were evaluated for various quality parameters, including weight loss, specific volume, crumb and crust colors, image analysis, and the presence of spore-forming bacteria. Volatile compounds released from the breads were identified using solid-phase microextraction coupled with gas chromatography–mass spectrometry (SPME-GC/MS). Polyphenolic compounds were analyzed via liquid chromatography–mass spectrometry (LC-MS). To assess the functional properties of the final products, the breads were homogenized with synthetic human saliva and subjected to in vitro digestion. OOMW did not significantly affect the growth of yeasts and lactic acid bacteria (LAB) or the acidification process. However, in terms of the specific volume and alveolation, breads from the S process and OOMW had poor quality, while those from the B process had better quality. Experimental breads (EXP_B-1 and EXP_B-2) contained higher levels of alcohols (especially ethanol and isobutyl alcohol), carbonyl compounds (like benzaldehyde), esters (such as ethyl caproate and ethyl caprylate), and terpenes. OOMW introduced phenolic compounds like hydroxytyrosol, coumaric acid, caffeic acid, and trans-hydroxycinnamic acid, which were absent in CTR_B breads. Functionalization of EXP_B-1 and EXP_B-2 breads was demonstrated by a 2.4- and 3.9-fold increase in Trolox equivalents, respectively. However, OOMW did not reduce post-prandial hyper-glycemia, as starch digestibility was similar between CTR_B and EXP_B breads. The sensory analysis, which focused solely on the visual, structural, and olfactory characteristics of the breads, excluding taste testing to prevent potential health risks from residual pesticides, showed a high appreciation for EXP_B-1 and EXP_B-2 breads, scoring higher than CTR_B in the overall assessment. Full article

Tangerine peel, rich in moisture (75–90%) and medicinal value, requires drying to prevent spoilage and extend shelf life. Traditional heat pump drying often causes uneven airflow, leading to inconsistent drying and nutrient loss, compromising product quality and storage stability. In this study, a prediction model of drying moisture ratio of tangerine peel based on Kolmogorov–Arnold network bidirectional long short-term memory (KAN-BiLSTM) and multimodal feature fusion is proposed. A pre-trained visual geometry group U-shaped network (VGG-UNet) is employed to segment tangerine peel images and extract color, contour, and texture features, while airflow distribution is simulated using finite element analysis (FEA) to obtain spatial location information. These multimodal features are fused and input into a KAN-BiLSTM model, where the KAN layer enhances nonlinear feature representation and a multi-head attention (MHA) mechanism highlights critical temporal and spatial features to improve prediction accuracy. Experimental validation was conducted on a dataset comprising 432 tangerine peel samples collected across six drying batches over a 480 min period, with image acquisition and mass measurement performed every 20 min. The results showed that the pre-trained VGG-UNet achieved a mean intersection over union (MIoU) of 93.58%, outperforming the untrained model by 9.41%. Incorporating spatial features improved the coefficient of determination (R²) of the time series model by 0.08 ± 0.04. The proposed KAN-BiLSTM model achieved a mean absolute error (MAE) of 0.024 and R² of 0.9908, significantly surpassing baseline models such as BiLSTM (R² = 0.9049, MAE = 0.0476) and LSTM (R² = 0.8306, MAE = 0.0766), demonstrating superior performance in moisture ratio prediction. Full article

To compare the differences in meat quality between obese-type Chinese pig breeds and lean-type foreign pig breeds, we selected Taoyuan Black (TB) pigs and Duroc pigs at 180 and 210 days of age and analyzed their meat quality, chemical composition, and flavor compounds using an electronic tongue, chromatographic techniques, and two-dimensional gas chromatography-time-of-flight-mass-spectrometry (GC×GC-TOF-MS). A total of 16 main fatty acids, 18 main free amino acids, and 249 flavor compounds were identified. The results showed that TB pigs exhibited redder meat color, higher intramuscular fat, and lower shear force than Duroc pigs (p < 0.05). TB pigs displayed higher levels of flavor nucleotides, free amino acids, and monounsaturated fatty acids (p < 0.05). Furthermore, pigs at 180 days exhibited lower dripping loss and more flavor compounds than those at 210 days (p < 0.05). Electronic tongue analysis revealed higher umami values in TB pigs at 180 days of age. Among the flavor compounds in pork, the four compounds that contributed most significantly to flavor across all species were 2-nonenal, 2-octenal, heptanal, 2,3-butanedione, and 2-pentylfuran. These findings provide fundamental data and insight into pig production. Full article

In the age of widespread renewable energy integration, coal-fired power plants are transitioning from a primary baseload role to a more flexible peak-shaving capacity. Under frequent load changes, the thermal efficiency will significantly decrease. In order to achieve efficient dynamic operation, this study proposes a comprehensive mechanical model of a 300 MW drum-type boiler. Based on the Modelica/DYMOLA platform, the multi-domain equations describing energy and mass balance are programmed and solved. A comprehensive evaluation of the energy transformation within the boiler’s heat exchange components was performed. Utilizing the principles of exergy analysis, this study investigates how fluctuating operational conditions impact the energy dynamics and exergy losses in the drum and heating surfaces. Steady-state simulation reveals that the evaporator and superheater units account for 81.3% of total exergy destruction. Dynamic process analysis shows that the thermal inertia induced by the drum wall results in a significant delay in heat transfer quantity, with a dynamic period of up to 5000 s. The water wall exhibits the highest total dynamic exergy destruction at 9.5 GJ, with a destruction rate of 7.9–8.5 times higher than other components. Full article

In the present work, meso-tetrakis(2,4,6-trimethylphenyl) porphyrinato)zinc(II): ([Zn(TMP)] (1), meso-tetrakis-(tetraphenyl)porphyrin iron(III))chloride): [Fe(TPP)Cl] (2), and meso-tetrakis(phenyl)porphyrin manganese(III) chloride): [Mn(TPP)Cl] (3) were synthesized. Then, the three prepared porphyrinic complexes (1–3) were functionalized with branched polyethyleneimine (PEI). The prepared complexes were thoroughly analyzed using several analytical techniques, including ¹H NMR, FT-IR, UV-vis, XRD, XRF, TGA-DTA, SEM, and EDX. The presence of sharp main peaks at 2θ between 10° and 80°, in XRD analysis, for all studied compounds suggested the crystalline nature of the porphyrinic complexes. The morphological properties of the porphyrininc complexes were significantly affected by the chemical modification with polyethyleneimine. EDX result confirmed the complexation of zinc, iron, and manganese metals with the porphyrinic core. The increase in carbon and nitrogen contents after the addition of polyethyleneimine to the complexes (1–3) was noticeable. After thermal decomposition, the total mass loss was equal to 92.97%, 66.77%, and 26.78% for complexes (1), (2), and (3), respectively. However, for the complex (1)-PEI, complex (2)-PEI, and complex (3)-PEI, the total mass losses were 83.12%, 81.88%, and 35.78%, respectively. The synthetic compounds were additionally utilized for the adsorption of Naphthol blue black B from water. At optimum adsorption conditions (T = 20 °C, time = 60 min, pH = 5), the highest adsorption capacities were 154 mg/g, 139 mg/g, and 119 mg/g for complex (3)-PEI, complex (2)-PEI, and complex (1)-PEI, respectively. The adsorption mechanism followed the pseudo second order, the Freundlich, and the Temkin models. The results indicated that the adsorption process is reliant on chemical interactions. It was also governed by intraparticular diffusion and other kinetic phenomena. Full article

Food contact polymers require thermochromic pigments to provide temperature-sensitive visual cues for consumer safety and product integrity. However, their susceptibility to ultraviolet (UV) degradation limits long-term application. This study investigates the UV resistance of food-grade thermochromic polypropylene blends under simulated indoor and outdoor UV exposure for 500 and 1000 h. Visual properties, colorimetric (CIE L*a*b*) measurements, mechanical testing (tensile and impact), and mass variation analysis were performed to assess photostability and material integrity. Exposure to UV led to progressive discoloration (ΔE*_ab up to 34.07) and significant mechanical deterioration. Tensile strain at break decreased by 48.67%, and notched impact strength dropped by 44.15% after 1000 h of UV exposure. No measurable mass loss occurred, indicating degradation was confined to surface-level oxidation rather than bulk material erosion or leaching. These findings highlight the need for optimal pigment loading and UV stabilization to extend the shelf life of thermochromic food packaging materials in light-exposed storage and retail environments. The study offers a framework for improving the long-term reliability of smart packaging in the food industry. This work uniquely integrates optical, mechanical, and mass loss analyses to evaluate thermochromic packaging degradation under extended UVA exposure. Full article

The objective of the present study was to investigate the potential effects of biofillers derived from fruit waste, a byproduct of the food-processing industry, on the degradation of ethylene–norbornene (EN) copolymers under the controlled conditions of laboratory composting. This manuscript provides a comprehensive analysis of the influence of waste biofillers on the biological degradation of EN-based materials, thereby filling a gap in the existing literature on the subject. The concept of this work encompasses the enhancement of the degradability of synthetic EN through the incorporation of bioadditives. Waste apple and chokeberry pomace were added to EN as biofillers in amounts of 5, 10, and 15 phr (parts per hundred rubber). The polymeric materials were composted for 3 and 6 months under laboratory conditions. We assessed the susceptibility of the samples to the growth of microorganisms, as well as the mass loss of the polymeric materials after composting. The findings indicated that the bioadditives increased the compostability of the materials, as evidenced by the elevated carbonyl indices observed for the samples containing biofillers. Furthermore, the elevated polar component of the surface energy exhibited by the samples containing biofillers suggested a heightened susceptibility to composting processes, attributable to their augmented hydrophilicity, in comparison to the reference EN. Fruit pomace is a promising additive for increasing the compostability of synthetic polymeric materials. Full article

This study systematically investigates the effects of repeated Kurome treatment—a physical modification method combining mechanical stirring and oxidative regulation—on the processing characteristics and film properties of Chinese lacquer (urushi). By subjecting raw lacquer to 1–4 cycles of hydration–dehydration (KL1–KL4), the researchers observed a significant increase in viscosity (from 12,688 to 16,468 mPa·s) and a dramatic reduction in curing time (from 74 h to just 3.6 h), driven by deep oxidation of urushiol and quinone-mediated crosslinking, as confirmed by FTIR spectroscopy. The Kurome treatment enabled controlled darkening (L* value decreased from 29.31 to 26.89) while maintaining stable hue and gloss (88.96–90.96 GU), with no adverse effects on abrasion resistance (mass loss of 0.126–0.150 g/100 r) or adhesion (9.58–9.75 MPa). The reduced transparency of the KL3/KL4 films is associated with a densified polymer network, a feature that may benefit protective coatings. Scanning electron microscopy (SEM) analysis confirmed the formation of uniform, defect-free surfaces across all treatment groups. Among them, the KL2 group (viscosity of 14,630 mPa·s, curing time of 9.2 h) exhibited the most favorable balance for industrial applications. This study establishes Kurome technology as a low-carbon, additive-free strategy that enhances the processability of Chinese lacquer while preserving its traditional craftsmanship standards, offering scientific support for its sustainable use in modern coatings and cultural heritage conservation. Full article

Alkali-activated-slag cementitious material (AASCM) is distinguished by minimal energy consumption, reduced pollution, and superior mechanical properties; however, it is prone to issues such as susceptibility to cracking and inadequate frost resistance. To facilitate its application in cold region construction, research on AASCM modifications was conducted following freeze-thaw cycle and chloride ion corrosion coupling tests. The test results show that the AASCM made of recycled rubber and coal ash does not change much in shape or appearance after 100 freeze-thaw cycles, with a mass loss rate of less than 5% and a compressive strength loss rate of less than 25%. Furthermore, the AASCM containing recycled rubber, coal ash, and straw fiber demonstrates an effective resistance to freeze-thaw and chloride ion coupling, maintaining its appearance and shape without notable changes and exhibiting a mass loss rate of less than 25% following 100 such tests. Following 100 tests for freeze-thaw and chloride ion coupling, the appearance and morphology of AASCM exhibited no significant alterations, with a mass loss rate below 5% and a compressive strength loss rate under 25%; microscopic analysis revealed that the C-A-S-H gel maintained a relatively dense and stable structure. Adding recycled rubber to the AASCM matrix can slow the spread of cracks, make the material more flexible, and make it more resistant to frost. Straw fibers can stop cracks from getting bigger, and adding coal ash helps make more C-A-S-H gel, which improves the AASCM’s mechanical properties. Full article