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Keywords = material extrusion of metals (MEX/M)

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17 pages, 9545 KB  
Article
Comparative Study of Micro-Detail Replication in SAE H13 Tool Steel: Powder Hot Embossing vs. Material Extrusion Additive Manufacturing
by Elsa Wellenkamp Sequeiros, Fernando Ye Lin, Manuel Fernando Vieira and José Manuel Costa
Appl. Sci. 2026, 16(12), 6275; https://doi.org/10.3390/app16126275 (registering DOI) - 22 Jun 2026
Viewed by 109
Abstract
Micro-structured SAE H13 tool steel inserts for polymer injection molding require accurate replication of sub-millimeter features while retaining adequate densification and heat-treatment response. This study compared two powder-based routes on the same hemispherical insert containing pyramidal features of approximately 0.145 mm base width: [...] Read more.
Micro-structured SAE H13 tool steel inserts for polymer injection molding require accurate replication of sub-millimeter features while retaining adequate densification and heat-treatment response. This study compared two powder-based routes on the same hemispherical insert containing pyramidal features of approximately 0.145 mm base width: hot embossing (HE) of water-atomized SAE H13 powder (supplier d50 = 5.7 µm, irregular morphology) compounded with a commercial M1 binder, and material extrusion (MEX) of a commercial gas-atomized SAE H13 filament processed on a Markforged Metal X. Rheological screening selected a 57:43 vol% powder-to-binder ratio for the in-house HE feedstock, and DSC/TGA measurements defined two-step debinding windows. The best HE conditions were 220 °C, 8 MPa, and 45 min for the in-house mixture, and 210 °C, 8 MPa, and 30 min for the granulated commercial filament; the latter showed a 0.15% linear deviation from the silicone replica diameter among the best-rated samples. Under the tested commercial MEX configuration, the pyramidal features were not resolved because the 0.40 mm deposition line width exceeded the target feature base width, causing the slicer to omit the sub-line-width geometry. The defect populations differed qualitatively: HE specimens showed porosity and local cracking associated with powder morphology and pressureless sintering, whereas MEX specimens showed build-direction-aligned inter-raster voids associated with the toolpath. Microhardness and tensile data are therefore interpreted as process-history-specific results rather than as a direct route ranking, because sintering conditions were not uniform across all specimens. The study defines an experimentally bound process-selection limit for SAE H13 micro-tooling: HE remains preferable for sub-nozzle surface features, whereas MEX remains attractive for macro-scale geometric freedom, if resolution, densification, and post-sintering consolidation are addressed. Full article
(This article belongs to the Section Materials Science and Engineering)
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13 pages, 3845 KB  
Article
Investigation of Sintering Parameters for Low-Cost 3D-Printed Cast Iron Using Material Extrusion
by Matthew Drummond, Gillian MacLean, Abdelkrem Eltaggaz and Ibrahim Deiab
Machines 2026, 14(2), 166; https://doi.org/10.3390/machines14020166 - 2 Feb 2026
Viewed by 638
Abstract
Metal Material Extrusion (MEX/M) provides a rapid, low-cost additive manufacturing option for individual and batch productions; however, cast materials are not typically available in the material pool. White cast iron is subject to long casting lead times and high foundry costsThis research details [...] Read more.
Metal Material Extrusion (MEX/M) provides a rapid, low-cost additive manufacturing option for individual and batch productions; however, cast materials are not typically available in the material pool. White cast iron is subject to long casting lead times and high foundry costsThis research details a comparative sintering process study for MEX/M printed white cast iron, a novel addition to the metal additive manufacturing field. A mechanical properties and microscopic evaluation on MEX/M white cast iron samples was completed to compare the influence of three sintering parameters: peak sintering temperature, dwell time, and cooling process. It was observed that increasing the peak sintering temperature increased the sintered density by 23.2% and the volumetric shrinkage by 14.25%. A longer dwell time increased the sintered density by 30.1% and the volumetric shrinkage by 9.42% but decreased the microhardness of the sample. A change in the cooling process of the sample had no effect on the mechanical properties or the microstructure of the sample. The samples achieved a 79.9% increased average density after sintering to 5.75 g/cc, with 57.82% volumetric shrinkage and a 23.3% mass loss. Overall, the samples were 85.8% less dense than casted white cast iron but showed features of a white cast iron microstructure. Full article
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20 pages, 6442 KB  
Review
Enhancing the Performance of Metal Additive Manufacturing Parts: A Review of Post-Treatment Processes for Extrusion and Sinter-Based Technology
by Alessandro Pellegrini, Maria Grazia Guerra, Roberto Spina and Fulvio Lavecchia
J. Manuf. Mater. Process. 2025, 9(11), 357; https://doi.org/10.3390/jmmp9110357 - 31 Oct 2025
Cited by 1 | Viewed by 1801
Abstract
Material Extrusion for Metals (MEX/M) has emerged as a cost-effective and versatile Additive Manufacturing technology (AM) for producing complex metal components. Despite its potential, parts realized via MEX/M suffer from significant limitations, primarily poor surface quality due to the intrinsic layer-wise effect from [...] Read more.
Material Extrusion for Metals (MEX/M) has emerged as a cost-effective and versatile Additive Manufacturing technology (AM) for producing complex metal components. Despite its potential, parts realized via MEX/M suffer from significant limitations, primarily poor surface quality due to the intrinsic layer-wise effect from the printing deposition and selected printing conditions. Furthermore, the multi-step nature of the MEX/M process, particularly the sintering stage, can exacerbate roughness along with the printing orientation, thereby affecting part performance and limiting potential applications. In addition to surface defects, MEX parts are characterized by a high content of porosity when compared to other metal AM technologies like Powder Bed Fusion laser-based (PBF-LB) and Directed Energy Deposition laser-based (DED-LB). These defects, both on the surface and within the parts, can compromise the mechanical properties and overall quality of the final parts. In this context, the scientific community has increasingly recognized post-treatment processes as essential for simultaneously improving surface quality and enhancing bulk material properties. This review according to the PRISMA 2020 guidelines provides a comprehensive analysis of the most critical post-treatment processes applied to MEX/M parts. By critically reviewing the state of the art, this paper discusses how these treatments can effectively mitigate outer and inner defects, reduce porosity, and significantly improve mechanical performance, ultimately enabling the broader industrial adoption of MEX/M technology. Full article
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25 pages, 9856 KB  
Article
Design Guidelines for Material Extrusion of Metals (MEX/M)
by Karim Asami, Mehar Prakash Reddy Medapati, Titus Rakow, Tim Röver and Claus Emmelmann
J. Exp. Theor. Anal. 2025, 3(2), 15; https://doi.org/10.3390/jeta3020015 - 28 May 2025
Cited by 3 | Viewed by 2723
Abstract
This study introduced a systematic framework to develop practical design guidelines specifically for filament-based material extrusion of metals (MEX/M), an additive manufacturing (AM) process defined by ISO/ASTM 52900. MEX/M provides a cost-efficient alternative to conventional manufacturing methods, which is particularly valuable for rapid [...] Read more.
This study introduced a systematic framework to develop practical design guidelines specifically for filament-based material extrusion of metals (MEX/M), an additive manufacturing (AM) process defined by ISO/ASTM 52900. MEX/M provides a cost-efficient alternative to conventional manufacturing methods, which is particularly valuable for rapid prototyping. Although AM offers significant design flexibility, the MEX/M process imposes distinct geometric and process constraints requiring targeted optimization. The research formulates and validates design guidelines tailored for the MEX/M using an austenitic steel 316L (1.4404) alloy filament. The feedstock consists of a uniform blend of 316L stainless steel powder and polymeric binder embedded within a thermoplastic matrix, extruded and deposited layer by layer. Benchmark parts were fabricated to examine geometric feasibility, such as minimum printable wall thickness, feature inclination angles, borehole precision, overhang stability, and achievable resolution of horizontal and vertical gaps. After fabrication, the as-built (green-state) components undergo a two-step thermal post-processing treatment involving binder removal (debinding), followed by sintering at elevated temperatures to reach densification. Geometric accuracy was quantitatively assessed through a 3D scan by comparing the manufactured parts to their original CAD models, allowing the identification of deformation patterns and shrinkage rates. Finally, the practical utility of the developed guidelines was demonstrated by successfully manufacturing an impeller designed according to the established geometric constraints. These design guidelines apply specifically to the machine and filament type utilized in this study. Full article
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25 pages, 3819 KB  
Article
Application of Machine Learning in Predicting Quality Parameters in Metal Material Extrusion (MEX/M)
by Karim Asami, Maxim Kuehne, Tim Röver and Claus Emmelmann
Metals 2025, 15(5), 505; https://doi.org/10.3390/met15050505 - 30 Apr 2025
Cited by 2 | Viewed by 1366
Abstract
Additive manufacturing processes such as the material extrusion of metals (MEX/M) enable the production of complex and functional parts that are not feasible to create through traditional manufacturing methods. However, achieving high-quality MEX/M parts requires significant experimental and financial investments for suitable parameter [...] Read more.
Additive manufacturing processes such as the material extrusion of metals (MEX/M) enable the production of complex and functional parts that are not feasible to create through traditional manufacturing methods. However, achieving high-quality MEX/M parts requires significant experimental and financial investments for suitable parameter development. In response, this study explores the application of machine learning (ML) to predict the surface roughness and density in MEX/M components. The various models are trained with experimental data using input parameters such as layer thickness, print velocity, infill, overhang angle, and sinter profile enabling precise predictions of surface roughness and density. The various ML models demonstrate an accuracy of up to 97% after training. In conclusion, this research showcases the potential of ML in enhancing the efficiency in control over component quality during the design phase, addressing challenges in metallic additive manufacturing, and facilitating exact control and optimization of the MEX/M process, especially for complex geometrical structures. Full article
(This article belongs to the Special Issue Machine Learning in Metal Additive Manufacturing)
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17 pages, 11207 KB  
Article
Metallic Bipolar Plate Production Through Additive Manufacturing: Contrasting MEX/M and PBF-LB/M Approaches
by Karim Asami, Sebastian Roth, Jan Hünting, Tim Röver and Claus Emmelmann
J. Exp. Theor. Anal. 2025, 3(2), 12; https://doi.org/10.3390/jeta3020012 - 14 Apr 2025
Viewed by 2204
Abstract
Additive manufacturing (AM) technologies have witnessed remarkable advancements, offering opportunities to produce complex components across various industries. This paper explores the potential of AM for fabricating bipolar plates (BPPs) in fuel cell or electrolysis cell applications. BPPs play a critical role in the [...] Read more.
Additive manufacturing (AM) technologies have witnessed remarkable advancements, offering opportunities to produce complex components across various industries. This paper explores the potential of AM for fabricating bipolar plates (BPPs) in fuel cell or electrolysis cell applications. BPPs play a critical role in the performance and efficiency of such cells, and conventional manufacturing methods often face limitations, particularly concerning the complexity and customization of geometries. The focus here lies in two specific AM methods: the laser powder bed fusion of metals (PBF-LB/M) and material extrusion of metals (MEX/M). PBF-LB/M, tailored for high-performance applications, enables the creation of highly complex geometries, albeit at increased costs. On the other hand, MEX/M excels in rapid prototyping, facilitating the swift production of diverse geometries for real-world testing. This approach can facilitate the evaluation of geometries suitable for mass production via sinter-based manufacturing processes. The geometric deviations of different BPPs were identified by evaluating 3D scans. The PBF-LB/M method is more suitable for small features, while the MEX/M method has lower deviations for geometrically less complex BPPs. Through this investigation, the limits of the capabilities of these AM methods became clear, knowledge that can potentially enhance the design and production of BPPs, revolutionizing the energy conversion and storage landscape and contributing to the design of additive manufacturing technologies. Full article
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15 pages, 8573 KB  
Article
17-4 PH Steel Parts Obtained through MEX and PBF-LB/M Technologies: Comparison of the Structural Properties
by Katarzyna Jasik, Lucjan Śnieżek, Janusz Kluczyński, Jakub Łuszczek, Krzysztof Grzelak, Bartłomiej Sarzyński and Ireneusz Szachogłuchowicz
Materials 2024, 17(12), 2801; https://doi.org/10.3390/ma17122801 - 7 Jun 2024
Cited by 6 | Viewed by 1975
Abstract
The material extrusion (MEX) method utilizing highly filled metal filament presents an alternative to advanced additive metal manufacturing technologies. This process enables the production of metal objects through deposition and sintering, which is particularly attractive compared to powder bed fusion (PBF) technologies employing [...] Read more.
The material extrusion (MEX) method utilizing highly filled metal filament presents an alternative to advanced additive metal manufacturing technologies. This process enables the production of metal objects through deposition and sintering, which is particularly attractive compared to powder bed fusion (PBF) technologies employing lasers or high-power electron beams. PBF requires costly maintenance, skilled operators, and controlled process conditions, whereas MEX does not impose such requirements. This study compares research on 17-4 PH steel manufactured using two different commercially available techniques: MEX and powder bed fusion with laser beam melting (PBF-LB/M). This research included assessing the density of printed samples, analyzing surface roughness in two printing planes, examining microstructure including porosity and density determination, and measuring hardness. The conducted research aimed to determine the durability and quality of the obtained samples and to evaluate their strength. The research results indicated that samples produced using the PBF-LB/M technology exhibited better density and a more homogeneous structure. However, MEX samples exhibited better strength properties (hardness). Full article
(This article belongs to the Special Issue The Additive Manufacturing of Metallic Alloys)
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15 pages, 7703 KB  
Article
A Comparative Investigation of Properties of Metallic Parts Additively Manufactured through MEX and PBF-LB/M Technologies
by Janusz Kluczyński, Katarzyna Jasik, Jakub Łuszczek, Bartłomiej Sarzyński, Krzysztof Grzelak, Tomáš Dražan, Zdeněk Joska, Ireneusz Szachogłuchowicz, Paweł Płatek and Marcin Małek
Materials 2023, 16(14), 5200; https://doi.org/10.3390/ma16145200 - 24 Jul 2023
Cited by 17 | Viewed by 2717
Abstract
In this study, the research on 316L steel manufactured additively using two commercially available techniques, Material Extrusion (MEX) and Laser Powder Bed Fusion of Metals (PBF-LB/M), were compared. The additive manufacturing (AM) process based on powder bed synthesis is of great interest in [...] Read more.
In this study, the research on 316L steel manufactured additively using two commercially available techniques, Material Extrusion (MEX) and Laser Powder Bed Fusion of Metals (PBF-LB/M), were compared. The additive manufacturing (AM) process based on powder bed synthesis is of great interest in the production of metal parts. One of the most interesting alternatives to PBF-LB/M, are techniques based on material extrusion due to the significant initial cost reduction. Therefore, the paper compares these two different methods of AM technologies for metals. The investigations involved determining the density of the printed samples, assessing their surface roughness in two printing planes, examining their microstructures including determining their porosity and density, and measuring their hardness. The tests carried out make it possible to determine the durability, and quality of the obtained sample parts, as well as to assess their strength. The conducted research revealed that samples fabricated using the PBF-LB/M technology exhibited approximately 3% lower porosity compared to those produced using the MEX technology. Additionally, it was observed that the hardness of PBF-LB/M samples was more than twice as high as that of the samples manufactured using the MEX technology. Full article
(This article belongs to the Special Issue 3D Printing Technology with Metal Materials)
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