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Keywords = mechanism and theories

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20 pages, 2758 KB  
Article
Optimal Energy Sharing Strategy in Multi-Integrated Energy Systems Considering Asymmetric Nash Bargaining
by Na Li, Guanxiong Wang, Dongxu Guo and Chongchao Pan
Energies 2025, 18(21), 5729; https://doi.org/10.3390/en18215729 (registering DOI) - 30 Oct 2025
Abstract
Integrated energy systems (IESs) are increasingly being deployed and expanded, which integrate various energy infrastructures to enable flexible conversion and utilization among different energy forms. To facilitate collaboration among operators of varying scales and fully leverage the economic and environmental benefits of multi-integrated [...] Read more.
Integrated energy systems (IESs) are increasingly being deployed and expanded, which integrate various energy infrastructures to enable flexible conversion and utilization among different energy forms. To facilitate collaboration among operators of varying scales and fully leverage the economic and environmental benefits of multi-integrated energy systems (MIESs), this study develops a peer-to-peer (P2P) energy sharing framework for MIES based on asymmetric Nash bargaining. First, an IoT-based P2P energy sharing architecture for MIES is proposed, which incorporates coordinated electricity–heat–gas multi-energy synergy within IES models. Carbon capture systems (CCS) and power-to-gas (P2G) units are integrated with carbon trading mechanisms to reduce carbon emissions. Then, an MIES energy sharing operational model is established using Nash bargaining theory, subsequently decoupled into two subproblems: alliance benefit maximization and individual IES benefit distribution optimization. For subproblem 2, an asymmetric bargaining method employing natural exponential functions quantifies participant contributions, enabling fair distribution of cooperative benefits. Finally, the alternating direction method of multipliers (ADMM) is employed to solve both subproblems distributively, effectively preserving participant privacy. The effectiveness of the proposed method is verified by case simulation, demonstrating reduced operational costs across all IESs alongside equitable benefit allocation proportional to energy-sharing contributions. Carbon emission amounts are simultaneously reduced. Full article
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21 pages, 5613 KB  
Article
Food Traceability System Design Incorporating AI Chatbots: Promoting Consumer Engagement with Prepared Foods
by Bingjie Lu, Decheng Wen, Han Li and Xiao Chen
Foods 2025, 14(21), 3731; https://doi.org/10.3390/foods14213731 (registering DOI) - 30 Oct 2025
Abstract
Industrialized processing has increased the complexity of the food supply chain. Concerns about food-related risks have increased consumer interest in food traceability. Traceability systems are regarded as effective tools for mitigating information asymmetry and enhancing food quality and safety. However, the design of [...] Read more.
Industrialized processing has increased the complexity of the food supply chain. Concerns about food-related risks have increased consumer interest in food traceability. Traceability systems are regarded as effective tools for mitigating information asymmetry and enhancing food quality and safety. However, the design of traditional food traceability systems overlooks the risk of information overload. Based on information overload theory, this study designs an artificial intelligence (AI) traceability assistant as an innovative tool to optimize traditional food traceability systems and examines its positive effects. This study focuses on prepared foods as the research objects, selecting three types of prepared foods (Kung Pao chicken, fish-flavored shredded pork, and pickled fish) and three food traceability tasks (preservatives, sweeteners, and drug residues) as experimental stimuli. Through three online scenario experiments, 747 valid responses were collected. This study explores the impact of AI traceability assistant design on positive consumer engagement behaviors and its underlying mechanism. The results reveal that the AI traceability assistant significantly promotes positive consumer engagement behaviors. This positive effect is mediated by perceived system ease of use. Furthermore, perceived product risk positively moderates the impact of the AI traceability assistant on perceived system ease of use. Perceived product risk strengthens the mediating effect of perceived system ease of use. This study contributes a novel theoretical perspective for research on food traceability systems and reveals the underlying mechanism through which the AI traceability assistant exerts its positive effect. In practice, it provides actionable guidance for food producers implementing digital traceability solutions. Full article
(This article belongs to the Special Issue Food Design for Enhancing Quality and Sensory Attributes)
18 pages, 1722 KB  
Perspective
Nanoscale Lattice Heterostructure in High-Tc Superconductors
by Annette Bussmann-Holder, Jürgen Haase, Hugo Keller, Reinhard K. Kremer, Sergei I. Mukhin, Alexey P. Menushenkov, Andrei Ivanov, Alexey Kuznetsov, Victor Velasco, Steven D. Conradson, Gaetano Campi and Antonio Bianconi
Condens. Matter 2025, 10(4), 56; https://doi.org/10.3390/condmat10040056 (registering DOI) - 30 Oct 2025
Abstract
Low-temperature superconductivity has been known since 1957 to be described by BCS theory for effective single-band metals controlled by the density of states at the Fermi level, very far from band edges, the electron–phonon coupling constant l, and the energy of the boson [...] Read more.
Low-temperature superconductivity has been known since 1957 to be described by BCS theory for effective single-band metals controlled by the density of states at the Fermi level, very far from band edges, the electron–phonon coupling constant l, and the energy of the boson in the pairing interaction w0, but BCS has failed to predict high-temperature superconductivity in different materials above about 23 K. High-temperature superconductivity above 35 K, since 1986, has been a matter of materials science, where manipulating the lattice complexity of high-temperature superconducting ceramic oxides (HTSCs) has driven materials scientists to grow new HTSC quantum materials up to 138 K in HgBa2Ca2Cu3O8 (Hg1223) at ambient pressure and near room temperature in pressurized hydrides. This perspective covers the major results of materials scientists over the last 39 years in terms of investigating the role of lattice inhomogeneity detected in these new quantum complex materials. We highlight the nanoscale heterogeneity in these complex materials and elucidate their special role played in the physics of HTSCs. Especially, it is highlighted that the geometry of lattice and charge complex heterogeneity at the nanoscale is essential and intrinsic in the mechanism of rising quantum coherence at high temperatures. Full article
(This article belongs to the Special Issue Superstripes Physics, 4th Edition)
21 pages, 1635 KB  
Article
Research on Regional Resilience After Flood-Waterlogging Disasters Under the Concept of Urban Resilience Based on DEMATEL-TOPSIS-AISM
by Hong Zhang, Jiahui Luo and Wenlong Li
Sustainability 2025, 17(21), 9677; https://doi.org/10.3390/su17219677 (registering DOI) - 30 Oct 2025
Abstract
Under the dual pressures of global climate change and accelerated urbanization, the impacts of flood disasters on urban systems are becoming increasingly pronounced. Enhancing regional resilience has emerged as a critical factor in achieving sustainable urban development. Compared with existing methods such as [...] Read more.
Under the dual pressures of global climate change and accelerated urbanization, the impacts of flood disasters on urban systems are becoming increasingly pronounced. Enhancing regional resilience has emerged as a critical factor in achieving sustainable urban development. Compared with existing methods such as CRITIC–Entropy, PCA–AHP, or SWMM-based resilience evaluations, grounded in urban resilience theory, this study takes Fangshan District in Beijing as empirical research to construct a post-flood disaster resilience evaluation index system spanning five dimensions (ecological, social, engineering, economic, and institutional) and leverages the integrated DEMATEL-TOPSIS-AISM model to synergistically identify key drivers, evaluate performance, and uncover internal hierarchies, thereby overcoming the limitations of existing research approaches. The findings indicate that the DEMATEL analysis identified the frequency of heavy rainfall (a12 = 0.889) and the proportion of flood disaster information databases (c51 = 1.153) as key driving factors. The TOPSIS assessment reveals that Fangshan District exhibits the strongest resilience in the economic dimension (Relative Closeness C = 0.21200), while the institutional dimension is the weakest (C = 0.00000), the AISM model constructs a hierarchical topology from a cause–effect priority perspective, elucidating the causal relationships and transmission mechanisms among factors across different dimensions. This study pioneers a novel perspective for urban resilience assessment, thereby establishing a theoretical foundation and practical references for enhancing flood resilience and advancing resilient city development. Full article
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19 pages, 17886 KB  
Article
Mechanism and Simulation Analysis of Acoustic Wave Excitation by Partial Discharge
by Ziqi Li, Xianmei Wu, Tao Leng, Bingwen An and Wei Dong
Appl. Sci. 2025, 15(21), 11611; https://doi.org/10.3390/app152111611 (registering DOI) - 30 Oct 2025
Abstract
Partial discharge serves as a typical indicator of insulation defects in high-voltage electrical equipment and is often accompanied by acoustic emission. The online monitoring of partial discharge via acoustic signals makes it essential to investigate the underlying mechanism of acoustic wave excitation by [...] Read more.
Partial discharge serves as a typical indicator of insulation defects in high-voltage electrical equipment and is often accompanied by acoustic emission. The online monitoring of partial discharge via acoustic signals makes it essential to investigate the underlying mechanism of acoustic wave excitation by partial discharge. However, experimental investigation is often prohibitively expensive and struggles to capture key discharge parameters. Numerical simulation thus provides a valuable alternative for microscopic analysis. In this study, a typical needle-plane corona discharge model is employed. Based on the theory that acoustic waves are generated by gas disturbances caused by collisions between charged and neutral particles in weakly ionized gases, a numerical model for acoustic wave excitation by positive corona discharge is developed. Simulations and analyses are performed on the acoustic source characteristics and the acoustic field distribution. The results demonstrate that the spatiotemporal evolution of electron density plays a dominant role in the generation of acoustic waves during positive DC corona discharge. The characteristics of the simulated acoustic field agree well with experimental results from relevant studies, validating the effectiveness of the proposed electroacoustic coupling numerical model and providing a new tool for further research into the acoustic features of partial discharge. Full article
(This article belongs to the Section Applied Physics General)
28 pages, 2855 KB  
Article
Electrochemical and Computational Analyses of Thiocolchicoside as a New Corrosion Inhibitor for Biomedical Ti6Al4V Alloy in Saline Solution: DFT, NBO, and MD Approaches
by Inam M. A. Omar, Ibrahim H. Elshamy, Shimaa Abdel Halim and Magdy A. M. Ibrahim
Surfaces 2025, 8(4), 77; https://doi.org/10.3390/surfaces8040077 (registering DOI) - 30 Oct 2025
Abstract
The Ti6Al4V alloy is considered the most beneficial of the titanium alloys for use in biomedical applications. However, it corrodes when exposed to various biocompatible fluids. This investigation aims to evaluate the corrosion inhibition performance of the Ti6Al4V in a saline solution (SS) [...] Read more.
The Ti6Al4V alloy is considered the most beneficial of the titanium alloys for use in biomedical applications. However, it corrodes when exposed to various biocompatible fluids. This investigation aims to evaluate the corrosion inhibition performance of the Ti6Al4V in a saline solution (SS) using thiocolchicoside (TCC) drug as an environmentally acceptable corrosion inhibitor. The corrosion assessments were conducted using potentiodynamic polarization curves (PPCs), open-circuit potential (OCP), and electrochemical impedance spectroscopy (EIS) methodologies, supplemented by scanning electron microscopy (SEM), energy-dispersive X-ray (EDS) analysis, atomic force microscopy (AFM), and contact angle (CA) measurements. The outcomes indicated that the inhibitory efficacy improved with higher TCC concentrations (achieving 92.40% at 200 mg/L of TCC) and diminished with an increase in solution temperature. TCC’s physical adsorption onto the surface of the Ti6A14V, which adheres to the Langmuir adsorption isotherm, explains its mitigating power. The TCC acts as a mixed-type inhibitor. The adsorption and inhibitory impact of TCC were examined at various temperatures using PPC and EIS. When TCC is present, the corrosion’s apparent activation energy is higher (35.79 kJ mol−1) than when it is absent (14.46 kJ mol−1). In addition, the correlation between the structural properties of thiocolchicoside (TCC) and its corrosion inhibition performance was systematically analyzed. Density Functional Theory (DFT) calculations were utilized to characterize the adsorption mechanism, supported by Natural Bond Orbital (NBO) analysis and Molecular Dynamics (MD) simulations. The combined computational and electrochemical findings confirm that TCC provides effective and enhanced corrosion protection for the Ti6Al4V alloy in a saline environment. These characteristics provide compelling evidence for the suitability of these pharmaceutical compounds as promising corrosion inhibitors. Full article
37 pages, 5698 KB  
Article
Design and Optimization of Self-Powered Photodetector Using Lead-Free Halide Perovskite Ba3SbI3: Insights from DFT and SCAPS-1D
by Salah Abdo, Ambali Alade Odebowale, Amer Abdulghani, Khalil As’ham, Yacine Djalab, Nicholas Kanizaj and Andrey E. Miroshnichenko
Nanomaterials 2025, 15(21), 1656; https://doi.org/10.3390/nano15211656 (registering DOI) - 30 Oct 2025
Abstract
All-inorganic halide perovskites have attracted significant interest in photodetector applications due to their remarkable photoresponse properties. However, the toxicity and instability of lead-based perovskites hinder their commercialization. In this work, we propose cubic Ba3SbI3 as a promising, environmentally friendly, lead-free [...] Read more.
All-inorganic halide perovskites have attracted significant interest in photodetector applications due to their remarkable photoresponse properties. However, the toxicity and instability of lead-based perovskites hinder their commercialization. In this work, we propose cubic Ba3SbI3 as a promising, environmentally friendly, lead-free material for next-generation photodetector applications. Ba3SbI3 shows good light absorption, low effective masses, and favorable elemental abundance and cost, making it a promising candidate compound for device applications. Its structural, mechanical, electronic, and optical properties were systematically investigated using density functional theory (DFT) with the Perdew–Burke–Ernzerhof (PBE) and hybrid HSE06 functionals. The material was found to be dynamically and mechanically stable, with a direct bandgap of 0.78 eV (PBE) and 1.602 eV (HSE06). Photodetector performance was then simulated in an Al/FTO/In2S3/Ba3SbI3/Sb2S3/Ni configuration using SCAPS-1D. To optimize device efficiency, the width, dopant level, and bulk concentration for each layer of the gadgets were systematically modified, while the effects of interface defects, operating temperature, and series and shunt resistances were also evaluated. The optimized device achieved an open-circuit voltage (Voc) of 1.047 V, short-circuit current density (Jsc) of 31.65 mA/cm2, responsivity of 0.605 A W−1, and detectivity of 1.05 × 1017 Jones. In contrast, in the absence of the Sb2S3 layer, the performance was reduced to a Voc of 0.83 V, Jsc of 26.8 mA/cm2, responsivity of 0.51 A W−1, and detectivity of 1.5 × 1015 Jones. These results highlight Ba3SbI3 as a promising platform for high-performance, cost-effective, and environmentally benign photodetectors. Full article
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17 pages, 2511 KB  
Article
In Vitro Antibacterial Activity Evaluation and Mechanism of Morphology-Controlled Synthesis of Cerium Dioxide Nanoparticles
by Ziting Gao, Mi Liu, Zhen Wang, Meina Zhang, Genli Shen, Yan Gong, Kaijie Zheng, Min Yang and Qi Wang
Int. J. Mol. Sci. 2025, 26(21), 10587; https://doi.org/10.3390/ijms262110587 (registering DOI) - 30 Oct 2025
Abstract
Cerium dioxide (CeO2) nanoparticles with distinct morphologies, including rods, cubes, and octahedrons, were synthesized via a straightforward hydrothermal method. The microstructure and morphology of the as-prepared samples were systematically characterized. The antibacterial activity of the samples against Escherichia coli was evaluated [...] Read more.
Cerium dioxide (CeO2) nanoparticles with distinct morphologies, including rods, cubes, and octahedrons, were synthesized via a straightforward hydrothermal method. The microstructure and morphology of the as-prepared samples were systematically characterized. The antibacterial activity of the samples against Escherichia coli was evaluated using the plate counting method. The antibacterial experiments revealed that the antibacterial properties of the samples were arranged in the following order: rod > cube > octahedron. Data analysis indicated that the superior antibacterial performance of the CeO2 nanorod was attributed to the higher concentration of oxygen vacancies and adsorption of reactive oxygen species (ROS) on the surface, with ROS playing a critical role in the antibacterial mechanism of CeO2. Additionally, density functional theory (DFT) calculations were employed to simulate the oxygen vacancy environments of CeO2 with different morphologies and provided indirect insights into ROS behavior. Combining experimental and computational results, a mechanistic framework was proposed to elucidate the dependence relationship between morphology and antibacterial activity of CeO2. Full article
(This article belongs to the Special Issue Antimicrobial Materials: Molecular Developments and Applications)
28 pages, 877 KB  
Article
Does ESG Washing Increase Abnormal Audit Fees? Research Based on the Chain Mediating Effects
by Xiaoyan Sun, Yuan Yao and Jie Han
Sustainability 2025, 17(21), 9668; https://doi.org/10.3390/su17219668 (registering DOI) - 30 Oct 2025
Abstract
ESG washing, as an organizational decoupling behavior, refers to enterprises strategically disclosing environmental information to obscure their actual ESG performance, which not only elevates audit risks but also increases uncertainty in audit pricing. Based on a sample of Chinese listed companies from 2014 [...] Read more.
ESG washing, as an organizational decoupling behavior, refers to enterprises strategically disclosing environmental information to obscure their actual ESG performance, which not only elevates audit risks but also increases uncertainty in audit pricing. Based on a sample of Chinese listed companies from 2014 to 2023, this study introduces excess executive compensation and executive myopia as mediators to investigate the mechanisms through which ESG washing influences abnormal audit fees via chain mediating effects. Additionally, market structure is considered a moderating variable to examine its moderating role within the model. The empirical results demonstrate that ESG washing in listed companies significantly increases abnormal audit fees. Both excess executive compensation and executive myopia exert positive individual mediating effects as well as a chain mediating effect. Furthermore, the moderating effect of market structure attenuates the mediating role of excess executive compensation but amplifies that of executive myopia. This research proposes an integrated framework combining organizational decoupling theory and transaction cost theory, thereby clarifying the underlying pathways through which ESG washing influences abnormal audit fees. The study offers policy implications for government authorities to strengthen ESG regulations, enhance supervisory mechanisms, and promote a more sustainable business environment. In addition, it provides guidance for enterprises in mitigating ESG washing, optimizing audit-related costs, and enhancing their capacity to address ESG challenges, improve corporate governance, and strengthen competitiveness. Full article
(This article belongs to the Section Economic and Business Aspects of Sustainability)
25 pages, 453 KB  
Article
Research on the Value Co-Creation Mechanism of Digital Intelligence Empowerment in Shared Manufacturing Ecosystems: Taking Zhiyun Tiangong as an Example
by Yanlei Pan and Hao Zhang
Systems 2025, 13(11), 969; https://doi.org/10.3390/systems13110969 (registering DOI) - 30 Oct 2025
Abstract
At present, the construction of China’s shared manufacturing platform is developing rapidly. However, it is still in the stage of practical exploration, facing numerous challenges, such as difficulties in resource integration, immature business models, and a weak digital foundation. This paper takes Changzhou [...] Read more.
At present, the construction of China’s shared manufacturing platform is developing rapidly. However, it is still in the stage of practical exploration, facing numerous challenges, such as difficulties in resource integration, immature business models, and a weak digital foundation. This paper takes Changzhou Zhiyun Tiangong’s “Super Virtual Factory” as an example, utilizing the grounded theory to conduct a case study on this shared manufacturing platform. Using a ‘condition-action-result’ framework, this paper explores the value co-creation (VCC) mechanism in a shared manufacturing ecosystem. We analyze how digital intelligence convergence (DIC) and supply chain collaboration (SCC) facilitate the digital intelligence transformation of consumption, production capacity, and products. The study finds that consumer insight, technological drive, government support, enterprise challenges, and the Changzhou home appliance industry cluster are the internal driving forces for the shared manufacturing ecosystem to carry out industrial ecological VCC; DIC and SCC are the two key elements for digital intelligence technology empowerment. Digital intelligence technology is empowered from three aspects—technology, resources, and structure—enabling organizational members with capability and authority while achieving “decentralization” of industrial chains. Finally, digital intelligence empowerment enables the shared manufacturing ecosystem to achieve VCC of the industrial ecosystem, thereby establishing a VCC model for the digital intelligence empowerment shared manufacturing ecosystem. The results of the study not only help enrich the theory of VCC in shared manufacturing platforms but also provide practical insights for the digital intelligence transformation of traditional manufacturing enterprises. Full article
26 pages, 487 KB  
Article
Types of Knowledge Transferred Within International Interfirm Alliances in the Nigerian Oil Industry and the Potential to Develop Partners’ Innovation Capacity
by Okechukwu C. Okonkwo
Adm. Sci. 2025, 15(11), 423; https://doi.org/10.3390/admsci15110423 (registering DOI) - 30 Oct 2025
Abstract
This study focuses on exploring the nature of inter-organizational learning and the types of knowledge that are transferred/shared between foreign multinational companies (MNCs) and their local partner firms within international interfirm alliances in developing countries, particularly those operating in the Nigerian oil industry. [...] Read more.
This study focuses on exploring the nature of inter-organizational learning and the types of knowledge that are transferred/shared between foreign multinational companies (MNCs) and their local partner firms within international interfirm alliances in developing countries, particularly those operating in the Nigerian oil industry. The aim is to identify/examine the types/quality of knowledge transfer and the viability of interfirm knowledge transfer for boosting the knowledge base and innovation capacity of the alliance partner firms, particularly of the local partner firms, in such a distinctive type of international alliances. Using a qualitative case study research method, four cases of international interfirm collaborative arrangements between foreign and local companies in the Nigerian oil industry were studied. The findings of this study show that the local partner firms in the alliances were able to access and acquire mainly technological and international market knowledge through the collaborations, but not managerial knowledge. Contrary to the extant theory/literature, the foreign partner firms did not seek to acquire local market knowledge from the local firms but clearly demonstrated “knowledge transfer willingness” that facilitated the acquisition of knowledge by the local firms in the alliances. However, the technological and international market knowledge acquired by local firms were limited to mainly the explicit dimension of the knowledge. In effect, the local partners in this study mainly acquired explicit technological and international market knowledge with limited tacit knowledge. A key implication of this finding can be a reduced ability to develop innovation capacity through alliances. This paper, therefore, highlights the necessity for an increased focus on tacit knowledge acquisition by local partner firms and the importance of utilizing appropriate learning mechanisms to achieving tacit knowledge acquisition through the collaborations. Full article
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45 pages, 2491 KB  
Review
Metaverse Business Models and Framework: A Systematic Search with Narrative Synthesis
by Katarina Kostelić and Darko Etinger
Systems 2025, 13(11), 968; https://doi.org/10.3390/systems13110968 (registering DOI) - 30 Oct 2025
Abstract
This systematic search with narrative synthesis examines metaverse business models and their shift toward immersive virtual ecosystems. Following the PRISMA flow for identification and screening to structure transparency, we review 91 publications to map the shift from classical and digital models to metaverse [...] Read more.
This systematic search with narrative synthesis examines metaverse business models and their shift toward immersive virtual ecosystems. Following the PRISMA flow for identification and screening to structure transparency, we review 91 publications to map the shift from classical and digital models to metaverse models, highlighting new value propositions, revenue mechanisms, and the integration of VR, AR, and blockchain across the value chain. Our contributions are threefold: we articulate the transition patterns from classical and digital to metaverse business models; we propose a structured metaverse business framework with evaluation dimensions; and we compile a candidate metric set to support comparative analysis. Interpreting the evidence through a socio-technical systems lens, the synthesis indicates an emergent shift in how value is created, delivered, and captured. We identify five core dimensions for assessing metaverse business models: scalability, technological adaptability, user engagement and retention, ethical and sustainability practices, and economic viability as critical dimensions for future comparative analysis of metaverse business models. Building on these findings, we propose a metaverse business framework and a set of candidate KPIs to enable comparative evaluation and guide investment, design, and governance. The paper advances digital transformation theory and outlines a research agenda on dynamic capabilities and the long-term sustainability of metaverse business models. Full article
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39 pages, 1564 KB  
Article
The Role of Green Finance in Investing in Environmentally Friendly Technologies: Risks and Returns
by Aylin Erdoğdu, Faruk Dayi, Adem Özbek, Farshad Ganji and Ayhan Benek
Sustainability 2025, 17(21), 9652; https://doi.org/10.3390/su17219652 (registering DOI) - 30 Oct 2025
Abstract
This study offers a comprehensive analysis of the performance and systemic dynamics of green finance investments in environmentally sustainable technologies from 2000 to 2025, complemented by scenario-based projections extending to 2050. Empirical results indicate a consistent increase in portfolio returns—from 5.2% in 2000 [...] Read more.
This study offers a comprehensive analysis of the performance and systemic dynamics of green finance investments in environmentally sustainable technologies from 2000 to 2025, complemented by scenario-based projections extending to 2050. Empirical results indicate a consistent increase in portfolio returns—from 5.2% in 2000 to 11.8% in 2025—accompanied by a significant reduction in annualized volatility, declining from 8.1% to 3.0%. Concurrently, the portfolio’s sustainability score improved from 0.45 to a full alignment score of 1.00, reflecting a strategic shift towards high-impact green assets. Building on these observed trends, this study introduces the Eco-Financial Resonance Theory (EFRT), an original conceptual framework that interprets sustainable transitions as emergent phenomena arising from resonant interactions among four interdependent domains: financial flows, technological innovation, policy and regulation, and environmental outcomes. Scenario analyses highlight the pivotal roles of policy ambition and innovation pathways in shaping long-term risk-return profiles, with optimistic forecasts projecting returns exceeding 40% by 2050, alongside markedly reduced risks. Regional analysis reveals persistent disparities, underscoring the necessity for context-specific strategies to enhance systemic coherence. Beyond its theoretical contributions, EFRT offers actionable insights for investors and policymakers aiming to align profitability with ecological sustainability. Collectively, these findings position green finance not merely as a niche or ancillary activity but as a transformative mechanism for enabling scalable and resilient sustainability transitions amid accelerating global environmental challenges. Full article
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15 pages, 2918 KB  
Article
Fouling Mitigation of PVDF Membrane Induced by Sodium Dodecyl Sulfate (SDS)-TiO2 Micelles
by Jie Zhang, Shiying Bo, Chunhua Wang, Zicong Jian, Yuehuan Chu, Si Qiu, Hongyan Chen, Qiancheng Xiong, Xiaofang Yang, Zicheng Xiao and Guocong Liu
Membranes 2025, 15(11), 330; https://doi.org/10.3390/membranes15110330 (registering DOI) - 30 Oct 2025
Abstract
As a favorable hydrophilic additive for antifouling modification of polyvinylidene fluoride (PVDF) membrane, titanium dioxide (TiO2) nanoparticles have been applied for years. Sodium dodecyl sulfonate (SDS), a representative anionic surfactant, has been proven to benefit the dispersion of nano-TiO2 via [...] Read more.
As a favorable hydrophilic additive for antifouling modification of polyvinylidene fluoride (PVDF) membrane, titanium dioxide (TiO2) nanoparticles have been applied for years. Sodium dodecyl sulfonate (SDS), a representative anionic surfactant, has been proven to benefit the dispersion of nano-TiO2 via an electro-spatial stabilizing mechanism. In this study, various proportionally SDS-functionalized TiO2 nanoparticles were adopted to modify PVDF membrane. Dispersion and stability of SDS-functionalized TiO2 nanoparticles in casting solutions were evaluated by multiple light scattering technology. The properties and antifouling performance of PVDF/SDS-TiO2 composite membranes were assessed. The uniformity of surface pores as well as structures on cross-section morphologies was modified. The finger-like structure of PVDF/SDS-TiO2 composite membrane was adequately developed at the SDS/TiO2 mass ratio of 1:1. The improved antifouling performance was corroborated by the increasing free energy of cohesion and adhesion as well as the interaction energy barrier between membrane surfaces and approaching foulants assessed by classic extended Derjaguin–Landau–Verwey–Overbeek (XDLVO) theory, the low flux decline during bovine serum albumin (BSA) solution filtration process, and the high critical flux (38 L/(m2·h·kPa)) in membrane bioreactor. This study exploits a promising way to modify PVDF membrane applicable to the wastewater treatment field. Full article
(This article belongs to the Special Issue Membrane Fouling Control: Mechanism, Properties, and Applications)
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21 pages, 3149 KB  
Article
Digital Media Discourse and the Secularization of Germany: A Textual Analysis of News Reporting in 2020–2024
by Jing Zhang and Wenlong Song
Journal. Media 2025, 6(4), 186; https://doi.org/10.3390/journalmedia6040186 (registering DOI) - 30 Oct 2025
Abstract
This article examines how digital media discourse mediated Germany’s secularization between 2020 and 2024. Drawing on a corpus from Der Spiegel, Die Zeit, and other outlets, this study combines text mining, sentiment profiling, and frame analysis. Mentions of “faith” and “religion” rose sharply, [...] Read more.
This article examines how digital media discourse mediated Germany’s secularization between 2020 and 2024. Drawing on a corpus from Der Spiegel, Die Zeit, and other outlets, this study combines text mining, sentiment profiling, and frame analysis. Mentions of “faith” and “religion” rose sharply, while reporting stabilized around a neutral tone with a slight positive drift. Coverage centered on public order and institutional roles, relocating religion from moral authority to a civic function. Time-series evidence shows that peaks in discourse preceded increases in non-affiliation by about two months, suggesting a spiral relation in which media both mirror and accelerate secularization. The analysis identifies a three-stage mediating mechanism: communicative reconfiguration, which decentralizes religious narration; cognitive shaping, where neutral framing encourages functional evaluation; and feedback reinforcement, where expanding secular discourse normalizes non-religion. Generational and regional contrasts sharpen this process. Nearly 60% of Germans aged 18–30 identify as unaffiliated, and Eastern regions display both higher secularization and more critical frames than the West. This study contributes empirical evidence for how digital discourse structures belief change in a high-penetration society and extends secularization and mediatization theories by showing how discursive circulation links structural transformation with individual cognition in the digital age. Full article
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