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21 pages, 18550 KB  
Article
Aeromagnetic Anomaly Characteristics and Prospecting Direction in the Jiaduoling Area, Northern Segment of the Southwest Sanjiang Metallogenic Belt
by Jianchun Xu, Yanxu Liu, Baodi Wang, Xuanjie Zhang, Yanan Zhang and Xin Wang
Appl. Sci. 2026, 16(13), 6356; https://doi.org/10.3390/app16136356 - 25 Jun 2026
Viewed by 310
Abstract
The Jiaduoling area is located in the northern segment of the Southwest Sanjiang Metallogenic Belt, a region characterized by complex geological structures and abundant mineral resources. This study systematically identifies the spatial correlation between subsurface magnetic bodies and tectonic structures by utilizing 1:50,000 [...] Read more.
The Jiaduoling area is located in the northern segment of the Southwest Sanjiang Metallogenic Belt, a region characterized by complex geological structures and abundant mineral resources. This study systematically identifies the spatial correlation between subsurface magnetic bodies and tectonic structures by utilizing 1:50,000 high-precision aeromagnetic data. Advanced processing techniques—including upward continuation, vertical derivatives, total gradient modulus, and Euler deconvolution—were integrated to refine the structural framework and clarify the mechanisms of fault-controlled mineralization. The results indicate that the aeromagnetic anomaly pattern is predominantly governed by NW-trending faults. Specifically, the deep-seated major fault F1 (with a calculated depth exceeding 3 km) served as the primary migration channel for ore-forming fluids, while secondary faults created localized ore-hosting spaces. Physical property analysis reveals a significant magnetic contrast, where Mesozoic intermediate-acid magmatic rocks act as the essential source for mineralization, providing both material and thermal energy for the formation of porphyrite-type iron deposits. Based on these findings, a three-dimensional “aeromagnetic anomaly-structural framework-mineralization” correlation model was established. Finally, two high-potential metallogenic prospective zones (P1 and P2) were delineated, providing precise geophysical evidence and strategic guidance for regional mineral exploration and the targeting of concealed ore bodies. Full article
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17 pages, 7760 KB  
Article
Terahertz Time-Domain Spectroscopy in Molybdenum Exploration: A Case Study of the Dengshang Deposit, North China Craton
by Xiao-Xia Li, Shan-Shan Li, Murat Tamer, Zhuo-Er Teng, Qun-Feng Miao, Jia-Hui Zhou, Cheng-Xun Li, Ze-Hai Peng, Hao-Chong Huang, Zhi-Yuan Zheng and Kun-Feng Qiu
Geosciences 2026, 16(5), 187; https://doi.org/10.3390/geosciences16050187 - 7 May 2026
Viewed by 469
Abstract
Porphyry-type deposits are characterized by well-developed alteration zoning, among which potassic alteration is closely associated with mineralization and represents a key target for prospecting and exploration. The Dengshang molybdenum deposit is a porphyry-type deposit within the Yanliao molybdenum metallogenic belt. Characterized by deep [...] Read more.
Porphyry-type deposits are characterized by well-developed alteration zoning, among which potassic alteration is closely associated with mineralization and represents a key target for prospecting and exploration. The Dengshang molybdenum deposit is a porphyry-type deposit within the Yanliao molybdenum metallogenic belt. Characterized by deep burial and unclear alteration zoning, it presents challenges for prospecting and exploration. This study integrates field surveys, petrographic analysis, and terahertz time-domain spectroscopy (THz-TDS) to characterize the altered wall rocks and molybdenite ores, aiming to support deep prospecting. The main findings reveal a clear spatial gradient from potassic to propylitic alteration zones within and around the rhyolite porphyry intrusion. THz-TDS reveals that the THz spectral characteristics of potassic-altered wall rocks are closely related to the structure of minerals and the intensity of hydrothermal alteration. Propylitically altered wall rocks exhibit distinctive spectral signatures in the terahertz band. For molybdenite ores, the molybdenite content shows a negative correlation with THz amplitude and a positive correlation with both the absorption coefficient and refractive index. This study proposes that the lower refractive index and absorption coefficient of potassic wall rocks, coupled with the higher values in ores, reflect the spatial position of the ore body. Additionally, the characteristic THz spectral curve of propylitically altered rocks can aid in delineating ore body boundaries. These findings hold practical guiding significance for prospecting and exploration. Full article
(This article belongs to the Special Issue Isotope Geochemistry: New Techniques and Applications)
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23 pages, 41162 KB  
Article
Characteristics of Fluid Inclusions in the Super-Large Wollastonite Deposit in Shizhushan, Western Jiangxi Province
by Yan Huo, Feng Ding, Yuzhu Luo, Yuhang Fan and Junyi Yao
Minerals 2026, 16(5), 488; https://doi.org/10.3390/min16050488 - 7 May 2026
Viewed by 396
Abstract
The Shizhushan super-large wollastonite deposit, situated in the western segment of the Pingle Depression within the Qin–Hang metallogenic belt, represents the largest known wollastonite deposit in the world. The deposit formed mainly through contact metamorphism, followed by contact metasomatism. The ore bodies are [...] Read more.
The Shizhushan super-large wollastonite deposit, situated in the western segment of the Pingle Depression within the Qin–Hang metallogenic belt, represents the largest known wollastonite deposit in the world. The deposit formed mainly through contact metamorphism, followed by contact metasomatism. The ore bodies are hosted in the carbonate rocks of the Middle Permian Maokou Formation. The deposit consists of 12 ore bodies, which are controlled by the strata and occur as layered and lenticular bodies. The mineralization process is divided into an early contact metamorphism period (wollastonite–calcite and wollastonite–calcite–quartz stages) and later hydrothermal metasomatism period (wollastonite–garnet stage). This study examined the fluid inclusions in the contact metamorphic wollastonite ore bodies in this deposit. The results show that the types of inclusions are mainly liquid-rich two-phase inclusions, pure liquid-phase inclusions, and pure vapor-phase inclusions, with a small number of CO2-H2O three-phase inclusions. The homogenization temperature ranges of the different stages are 409.50~260.10 °C for the wollastonite–calcite stage and 283.60~132.40 °C for the wollastonite–calcite–quartz stage. The temperature and salinity of ore-forming fluids show an evolution from medium–high temperature and medium–low salinity to low temperature and low salinity. The minimum ore-forming depth of the deposit is 0.79~4.74 km, indicating a shallow, low-pressure environment. Based on the macrogeological characteristics, the tectonic fractures formed during the contact metamorphic period triggered decompression boiling of the ore-forming fluids, which led to the precipitation of mineralization materials and the subsequent mineralization. Based on a comprehensive analysis of the metallogenic geological setting, material sources, metallogenic process, and structural control factors, a trinity metallogenic model of the “carbonate rock + pluton + semi-open structural system” is established for the Shizhushan wollastonite deposit. Full article
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22 pages, 7911 KB  
Article
Genesis of the Wuyi Pb Deposit, SW China: Constraints from Fluid Inclusions and C-H-O-S-Pb Isotopes
by Jimin Cai, Jiahui Li, Wenbin Cheng, Wenli Xu, Bo Li, Xinghai Lang, Cuihua Chen, Yiwei Peng and Lei Peng
Minerals 2026, 16(5), 487; https://doi.org/10.3390/min16050487 - 6 May 2026
Viewed by 399
Abstract
The Sichuan–Yunnan–Guizhou (SYG) metallogenic belt hosts numerous carbonate-hosted Pb-Zn deposits, yet the genesis of lead-dominated deposits remains poorly understood. This study investigates the Wuyi Pb deposit, a representative lead-dominated deposit in the SYG belt, through an integrated approach including field geology, fluid inclusion [...] Read more.
The Sichuan–Yunnan–Guizhou (SYG) metallogenic belt hosts numerous carbonate-hosted Pb-Zn deposits, yet the genesis of lead-dominated deposits remains poorly understood. This study investigates the Wuyi Pb deposit, a representative lead-dominated deposit in the SYG belt, through an integrated approach including field geology, fluid inclusion microthermometry, and C-H-O-S-Pb isotope geochemistry. The ore bodies occur as stratoid and lenticular lenses within the dolomitic limestone of the Ordovician Dajing Formation, controlled by both lithology and the Wuyi composite fold structure. Mineralization is divided into two stages: (I) pyrite–sphalerite–dolomite–calcite, and (II) galena–calcite–quartz–anhydrite. Fluid inclusion studies reveal that the ore-forming fluids are of the NaCl-H2O system, characterized by moderate-low temperatures (Stage II, average 201 °C) and moderate-low salinities (Stage II, average 5.35 wt% NaCl eq.). Hydrogen and oxygen isotopes (δD = −100.97 to −76.33‰; δ18Ofluid = 7.09 to 12.10‰) indicate that the ore-forming fluids were predominantly meteoric in origin. Carbon isotopes (δ13C = −4.45 to 0.75‰) suggest that carbon was derived mainly from dissolution of the host carbonate rocks. Sulfur isotopes show a significant shift from Stage I (δ34S = −12.40 to −3.00‰) to Stage II (δ34S = −8.20 to −0.10‰ for sulfides; 25.00–29.40‰ for sulfates), indicating a transition from bacterial sulfate reduction (BSR) to thermochemical sulfate reduction (TSR) as the dominant sulfur reduction mechanism, with sulfur derived from Ordovician seawater sulfate. Lead isotopes (206Pb/204Pb = 18.10–25.37, 207Pb/204Pb = 15.50–21.72, 208Pb/204Pb = 38.29–53.90; μ = 9.30–21.05) demonstrate that metals were sourced predominantly from the Proterozoic basement rocks (Kunyang and Huili groups). Integration of geological, geochemical, and isotopic evidence indicates that the Wuyi Pb deposit formed during the Indosinian post-collisional intracontinental orogeny (ca. 230–200 Ma), when topography-driven meteoric water circulation extracted metals from the Precambrian basement and sulfur from Ordovician strata. Metal precipitation under the reduced sulfur model is caused by decreases in temperature and pressure and the water–rock reaction. This study establishes the Wuyi deposit as an MVT Pb deposit and provides a genetic model for lead-dominated mineralization in the SYG belt. Full article
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16 pages, 4029 KB  
Article
Identification of Deep Iron-Rich Intrusions from Gravity and Magnetic Data and Their Natural Hydrogen Responses in the Liaohe Basin, China
by Xingfu Le, Wenna Zhou, Hui Ma, Bo Li, Gang Tao, Yongkang Chan, Bohu Xu and Sihati A
Minerals 2026, 16(4), 393; https://doi.org/10.3390/min16040393 - 10 Apr 2026
Viewed by 806
Abstract
Natural hydrogen is regarded as a potential resource for the global energy transition, and its accumulation is closely linked to water–rock reactions involving Fe2+ bearing minerals and effective sealing conditions. The Liaohe Basin, located on the northeastern margin of the North China [...] Read more.
Natural hydrogen is regarded as a potential resource for the global energy transition, and its accumulation is closely linked to water–rock reactions involving Fe2+ bearing minerals and effective sealing conditions. The Liaohe Basin, located on the northeastern margin of the North China Craton within a key metallogenic belt, is surrounded by sedimentary-metamorphic iron deposits and is a potential area for natural hydrogen accumulation. In this study, aeromagnetic and satellite gravity data were integrated to estimate basement depth through gravity interface inversion, followed by three-dimensional magnetic susceptibility and density inversion and structural–mineralization correlation analysis. The results reveal strong basement heterogeneity. Iron-rich anomalous bodies show clustered and belt-like to dome-like distributions, mainly along the transitional zone between deep depressions and basement uplifts. Combined density–magnetic zonation suggests that high-density, high-magnetic units may correspond to iron-rich bodies, whereas high-magnetic, low-density units likely indicate fractured and altered fluid pathways. Based on the measured results of surface hydrogen concentration, it is inferred that the high magnetic anomaly in the uplift transition zone at the edge of the depression might be the coupling area of iron-rich rock bodies and channel zones, which is the priority response area of natural hydrogen in the Liaohe Basin, China. Full article
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19 pages, 4742 KB  
Article
Monazite U-Pb Chronology, Pyrite Rb-Sr Chronology and Isotope Geochemistry of the Xidouya Gold Deposit in the Jiaodong Peninsula, Eastern China: Constraints on the Timing and Process of Mineralization
by Faqiang Zhao, Zhimin Li, Peng Guo, Tongliang Tian, Bin Li, Jiabin Yu, Dongyue Li, Pengpeng Zhang and Jiepeng Tian
Minerals 2026, 16(3), 338; https://doi.org/10.3390/min16030338 - 23 Mar 2026
Viewed by 525
Abstract
The Jiaodong gold concentration area, one of the most important gold metallogenic belts in China, has long been the focus of contentious debates regarding the genetic mechanisms and timing of gold mineralization. This study presents the new monazite U-Pb and pyrite Rb-Sr isotopic [...] Read more.
The Jiaodong gold concentration area, one of the most important gold metallogenic belts in China, has long been the focus of contentious debates regarding the genetic mechanisms and timing of gold mineralization. This study presents the new monazite U-Pb and pyrite Rb-Sr isotopic chronology data for the No. I ore zone of the Xidouya gold deposit, integrated with H-O-S isotopic geochemical analyses, to systematically investigate the mineralization age, ore-forming fluid sources and material provenance of the deposit. The main mineralization age of the deposit is constrained to 117 Ma, which is highly consistent with the regional mineralization peak of 120 ± 5 Ma in the Jiaodong gold concentration area. The δD values of the fluids range from −88.0‰ to −75.0‰ (mean = −82.6‰), while the δ18OH2O values are calculated to be between 4.6‰ and 6.1‰. H-O isotopic data indicate that the ore-forming fluids of the Xidouya gold deposit originated from a mixed magmatic and meteoric source. As mineralization progressed from Stage I through Stage III, there was a detectable trend of increasing meteoric water involvement and a general decrease in δD and δ18OH2O values. This signature indicates that the initial mineralizing system was dominated by primary magmatic water which subsequently underwent significant water–rock interaction with Early Cretaceous granitic bodies and progressive dilution by meteoric fluids in an open tectonic environment. Furthermore, sulfur isotopes (average δ34S = +7.43‰) and the initial strontium isotope ratio (87Sr/86Sr = 0.71012) support a mixed-source model for the ore-forming materials, likely dominated by the anatexis of ancient crust with potential minor mantle-derived contributions. During the Early Cretaceous, lithospheric thinning and extension in the North China Craton (NCC) triggered large-scale magmatism and mineralization. The Xidouya gold deposit is a direct product of these regional tectono-magmatic-mineralizing events. This study provides new high-precision isotopic dating data for the Xidouya gold deposit, clarifies the evolutionary history of ore-forming fluids and the supply mechanism of ore-forming materials, and provides important theoretical insights and practical references for gold prospecting and exploration in the eastern part of the Jiaodong gold concentration area. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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23 pages, 4551 KB  
Article
Provenance Tracing of Uranium-Bearing Sandstone of Saihan Formation in Naomugeng Sag, Erlian Basin, China
by Caili Zhang, Zhao Li, Hu Peng, Yue Wu, Ning Luo, Kang Pang, Zhiwei Qiu, Xiaolin Yu, Haiqi Quan, Miao Wang, Qi Li, Yongjiu Liu, Yinan Zhuang and Chengyuan Jin
Minerals 2026, 16(1), 76; https://doi.org/10.3390/min16010076 - 13 Jan 2026
Cited by 1 | Viewed by 830
Abstract
The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad [...] Read more.
The northern part of the Naomugeng Sag in the Erlian Basin shows favorable sandstone-type uranium mineralization in the lower member of the Saihan Formation. The sandstone thickness ranges from 39.67 to 140.36 m, with an average sand content ratio of 76.33%, indicating broad prospecting potential. This study focuses on samples from uranium ore holes and uranium-mineralized holes in the area, conducting grain-size analysis of uranium-bearing sandstones, heavy mineral assemblage analysis, and detrital zircon U-Pb dating to systematically investigate provenance characteristics. The results indicate that the uranium-bearing sandstones in the lower member of the Saihan Formation were primarily transported by rolling and suspension, characteristic of braided river channel deposits. The heavy mineral assemblage is dominated by zircon + limonite + garnet + ilmenite, suggesting that the sedimentary provenance is mainly composed of intermediate-acid magmatic rocks with minor metamorphic components. Detrital zircon U-Pb ages are mainly concentrated in the ranges of 294–217 Ma (Early Permian to Late Triassic), 146–112 Ma (Middle Jurassic to Early Cretaceous), 434–304 Ma (Late Carboniferous to Early Permian), and 495–445 Ma (Middle–Late Ordovician to Early Silurian). Combined with comparisons of the ages of surrounding rock masses, the provenance of the uranium-bearing sandstones is mainly derived from intermediate-acid granites of the Early Permian–Late Triassic and Middle Jurassic–Early Cretaceous periods in the southern part of the Sonid Uplift, with minor contributions from metamorphic and volcanic rock fragments. The average zircon uranium content is 520.53 ppm, with a Th/U ratio of 0.73, indicating that the provenance not only supplied detrital materials but also provided uranium-rich rock bodies that contributed essential metallogenic materials for uranium mineralization. This study offers critical insights for regional prospecting and exploration deployment. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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40 pages, 3732 KB  
Review
Applications and Prospects of Muography in Strategic Deposits
by Xingwen Zhou, Juntao Liu, Baopeng Su, Kaiqiang Yao, Xinyu Cai, Rongqing Zhang, Ting Li, Hengliang Deng, Jiangkun Li, Shi Yan and Zhiyi Liu
Minerals 2025, 15(9), 945; https://doi.org/10.3390/min15090945 - 4 Sep 2025
Cited by 2 | Viewed by 4083
Abstract
With strategic mineral exploration extending to deep and complex geological settings, traditional methods increasingly struggle to dissect metallogenic systems and locate ore bodies precisely. This synthesis of current progress in muon imaging (a technology leveraging cosmic ray muons’ high penetration) aims to address [...] Read more.
With strategic mineral exploration extending to deep and complex geological settings, traditional methods increasingly struggle to dissect metallogenic systems and locate ore bodies precisely. This synthesis of current progress in muon imaging (a technology leveraging cosmic ray muons’ high penetration) aims to address these exploration challenges. Muon imaging operates by exploiting the energy attenuation of cosmic ray muons when penetrating earth media. It records muon transmission trajectories via high-precision detector arrays and constructs detailed subsurface density distribution images through advanced 3D inversion algorithms, enabling non-invasive detection of deep ore bodies. This review is organized into four thematic sections: (1) technical principles of muon imaging; (2) practical applications and advantages in ore exploration; (3) current challenges in deployment; (4) optimization strategies and future prospects. In practical applications, muon imaging has demonstrated unique advantages: it penetrates thick overburden and high-resistance rock masses to delineate blind ore bodies, with simultaneous gains in exploration efficiency and cost reduction. Optimized data acquisition and processing further allow it to capture dynamic changes in rock mass structure over hours to days, supporting proactive mine safety management. However, challenges remain, including complex muon event analysis, long data acquisition cycles, and limited distinguishability for low-density-contrast formations. It discusses solutions via multi-source geophysical data integration, optimized acquisition strategies, detector performance improvements, and intelligent data processing algorithms to enhance practicality and reliability. Future advancements in muon imaging are expected to drive breakthroughs in ultra-deep ore-forming system exploration, positioning it as a key force in innovating strategic mineral resource exploration technologies. Full article
(This article belongs to the Special Issue 3D Mineral Prospectivity Modeling Applied to Mineral Deposits)
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21 pages, 5158 KB  
Article
Genesis of the Erentaolegai Silver Deposit, Inner Mongolia, Northeast China: Evidence from Fluid Inclusion and H-O-S Isotopes
by Yushan Zuo, Xintong Dong, Zhengxi Gao, Liwen Wu, Zhao Liu, Jiaqi Xu, Shanming Zhang and Wentian Mi
Minerals 2025, 15(7), 748; https://doi.org/10.3390/min15070748 - 17 Jul 2025
Viewed by 1455
Abstract
The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization [...] Read more.
The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization process of the deposit is divided into three stages: Stage I: Pyrite–Quartz Stage; Stage II: Sulfide–Quartz Stage; Stage III: Quartz–Manganese Carbonate Stage. This paper discusses the ore-forming fluids, ore-forming materials, and deposit genesis of the Erentaolegai silver deposits using fluid inclusions microthermometry, laser Raman spectroscopy, and H-O-S isotope analyses. Fluid inclusion microthermometry and laser Raman spectroscopy analyses indicate that the Erentaolegai silver deposit contains exclusively fluid-rich two-phase fluid inclusions, all of which belong to the H2O-NaCl system. Homogenization temperatures of fluid inclusions in the three stages (from early to late) ranged from 257 to 311 °C, 228 to 280 °C, and 194 to 238 °C, corresponding to salinities of 1.91 to 7.86 wt%, 2.07 to 5.41 wt%, and 0.70–3.55 wt% NaCl equivalent, densities of 0.75 to 0.83 g/cm−3, 0.80 to 0.86 g/cm−3 and 0.85 to 0.89 g/cm−3. The mineralization pressure ranged from 12.2 to 29.5 MPa, and the mineralization depth was 0.41 to 0.98 km, indicating low-pressure and shallow-depth mineralization conditions. H-O isotope results indicate that the ore-forming fluid is a mixture of magmatic fluids and meteoric water, with meteoric contribution dominating in the late stage. The δ34S values of metallic sulfides ranged from −1.8 to +4.0‰, indicating that the metallogenic material of the Erentaolegai silver deposit was dominated by a deep magmatic source. This study concludes that meteoric water mixing and subsequent fluid cooling served as the primary mechanism for silver mineral precipitation. The Erentaolegai silver deposit is classified as a low-sulfidation epithermal silver deposit. Full article
(This article belongs to the Special Issue Recent Developments in Rare Metal Mineral Deposits)
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22 pages, 12129 KB  
Article
Metallogenic Age and Tectonic Setting of the Haigou Gold Deposit in Southeast Jilin Province, NE China: Constraints from Magmatic Chronology and Geochemistry
by Zhongjie Yang, Yuandong Zhao, Cangjiang Zhang, Chuantao Ren, Qun Yang and Long Zhang
Minerals 2025, 15(6), 582; https://doi.org/10.3390/min15060582 - 29 May 2025
Viewed by 1344
Abstract
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily [...] Read more.
Haigou deposit, located in Dunhua City, southeast Jilin Province, NE China, is a large-scale gold deposit. The gold ore body is categorized into two types: quartz-vein type and altered rock type, with the quartz-vein type being predominant. The vein gold ore body primarily occurs within the monzonite granite and monzonite rock mass in the Haigou area and is controlled by fault structures trending northeast, northwest, and near north-south. In order to constrain the age and tectonic setting of quartz vein-type gold mineralization, we conducted a detailed underground investigation and collected samples of monzonite granite and pyroxene diorite porphyrite veins related to quartz-vein-type gold mineralization for LA-ICP-MS zircon U-Pb dating and whole-rock main trace element data testing to confirm that monzonite granite is closely related to gold mineralization. Pyroxene diorite porphyry and gold mineralization were found in parallel veins. The zircon U-Pb weighted mean ages of monzonite and pyroxene diorite porphyrite veins are 317.1 ± 3.5 Ma and 308.8 ± 3.0 Ma, respectively, indicating that gold mineralization in monzonite, pyroxene diorite porphyrite veins, and quartz veins occurred in the Late Carboniferous. The monzonite granite and pyroxene diorite porphyrite veins associated with quartz vein-type gold mineralization have high SiO2, high K, and high Al2O3 and are all metaluminous high-potassium calc-alkaline rock series. Both of them are relatively enriched in light rare earth elements (LREE) and macroionic lithophile elements (LILE: Rb, Ba, K, etc.), but deficient in heavy rare earth elements (HREE) and high field strength elements (HFSE: Nb, Ta, P, Ti, etc.), the monzonitic granite Eu is a weak positive anomaly (δEu = 1.15–1.46), the pyroxene diorite porphyre dyke Eu is a weak positive anomaly (δEu = 1.09–1.13), and the Nb and Ta are negative anomalies. The Th/Nb values are 0.28–0.73 and 1.48–2.05, and La/Nb are 2.61–4.74 and 4.59–5.43, respectively, suggesting that diagenetic mineralization is the product of subduction in an active continental margin environment. In recent years, scholarly research on Sr, Nd, and Pb isotopes in Haigou rock masses has indicated that the magmatic source region in the Haigou mining areas is complex. It is neither a singular crustal source nor a mantle source but rather a mixed crust-mantle source, primarily resulting from the partial melting of lower crustal materials, with additional contributions from mantle-derived materials. In summary, the metallogenic characteristics, chronology data, geochemical characteristics, and regional tectonic interpretation indicate that at least one phase of magmatic-hydrothermal gold mineralization was established in the Late Carboniferous as a result of the subduction of the Paleo-Asian ocean plate at the northern margin of the North China Craton. Full article
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21 pages, 8878 KB  
Article
Significance of Adakitic Plutons for Mineralization in Wubaduolai Copper Deposit, Xizang: Evidence from Zircon U-Pb Age, Hf Isotope, and Geochemistry
by Ke Gao, Zhi Zhang, Linkui Zhang, Peiyan Xu, Yi Yang, Jianyang Wu, Yingxu Li, Miao Sun and Wenpeng Su
Minerals 2025, 15(5), 500; https://doi.org/10.3390/min15050500 - 8 May 2025
Cited by 3 | Viewed by 1143
Abstract
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and [...] Read more.
The Wubaduolai copper deposit, a newly discovered porphyry-type deposit located in the western section of the Gangdese metallogenic belt, shows great potential for mineralization. Investigating the ore-bearing potentiality of the adakitic granite in this area is crucial for identifying concealed ore bodies and assessing the metallogenic potential. This paper presents the zircon U-Pb dating, Hf isotope analysis, and whole-rock major and trace geochemical analysis of the plutons in the Wubaduolai mining area. The results indicate that the zircon U-Pb concordia age of the monzogranite is 15.7 ± 0.1 Ma, while the granodiorite porphyry has a concordia age of 15.9 ± 0.2 Ma, both corresponding to a Miocene diagenesis. The geochemical data show that both plutons belong to the high-K calc-alkaline series, characterized by a relative enrichment of large-ion lithophile elements (K, Rb, Ba, and Sr) and a depletion of high-field-strength elements (Nb, Ta, and Ti). Both plutons are characterized by low Y, low Yb, and high Sr/Y values, displaying the typical geochemical characteristics of adakites. Their mineral composition is similar to that of adakite. The εHf(t) values of the monzogranite and granodiorite porphyry range from −5.34 to −2.3 and −5.2 to −3.43, respectively, with two-stage model ages (TDM2) of 1246–1441 Ma and 1318–1432 Ma. Based on the regional data and this study, the plutons in the Wubaduolai mining area formed in a post-collision setting following the India–Asia continental collision. The magma source is identified as the partial melting of a thickened, newly formed lower crust. The above characteristics are consistent with the diagenetic and metallogenic ages, magma source, and dynamic backgrounds of the typical regional deposits. Full article
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17 pages, 9690 KB  
Article
Age and Source of the Jinjingzui Skarn-Type Gold Deposit in the Southeastern Hubei Province, China
by Yan Li, Chun Cheng, Yuan Yao and Qinghua Yan
Appl. Sci. 2025, 15(5), 2763; https://doi.org/10.3390/app15052763 - 4 Mar 2025
Viewed by 2068
Abstract
The Jinjingzui gold (Au) deposit is located in the central part of Edong, China. The theoretical gold reserves are large with significant potential for mining and future development. This deposit is the only Au-bearing deposit discovered in the Middle-Lower Yangtze River Valley Metallogenic [...] Read more.
The Jinjingzui gold (Au) deposit is located in the central part of Edong, China. The theoretical gold reserves are large with significant potential for mining and future development. This deposit is the only Au-bearing deposit discovered in the Middle-Lower Yangtze River Valley Metallogenic Belt, which has existing ore bodies that are mainly diorite. Re–Os dating of molybdenite from the Jinjingzui deposit confirm that the deposit formed in the Lower Cretaceous period, with an isochron age of 138.5 ± 2.7 Ma. The geochemical data of the rocks indicate that the diorite contains 54.75% to 56.66% SiO2, 5.68% to 8.94% Fe2O3, 2.05% to 2.19% MgO, and 1.06% to 1.08% TiO2, and with enrichment of large-ion lithophile elements (e.g., Rb and Ba). High-field-strength elements U-Nb–Ti displayed strong negative anomalies. Six pyrites from the Jinjingzui Au deposit δ34SV-PDB(‰) ranged from −2.4% to −8.4%, with an average value of −3.1%, and 206Pb~204Pb, 207Pb~204Pb, 208Pb~204Pb contents ranged from 17.77–18.58, 15.48–15.67 to 37.91–39.05, with average values of 18.14, 15.59 and 38.49, respectively. These values indicate that the metallic components originated from the upper mantle and lower crust. The Re concentrations in the molybdenites are significantly higher than those in other ores within the district (847.91~2018.58 × 10−6), suggesting a significant mantle component was involved in the mineralization process. Full article
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19 pages, 7052 KB  
Article
The Application of Sulfur–Metal Mass Ratios in Metal Sulfides in Assessing Prospects for Deep Metallogeny: A Case Study of the Tongshan Copper Deposit in Heilongjiang Province, Northeast China
by Ruixuan Lan, Lixin Zhu, Shixin Tang, Zhuang Duan, Yong Li and Shengming Ma
Minerals 2024, 14(11), 1069; https://doi.org/10.3390/min14111069 - 24 Oct 2024
Viewed by 1499
Abstract
Sulfur–metal mass ratios (SMMRs) between sulfur and metal elements (Cu, Pb, Zn, Ag, Fe, etc.) in metal sulfides are fixed in idealized compositions, so they should have a relatively fixed proportion in terms of mass without considering the presence of structural defects such [...] Read more.
Sulfur–metal mass ratios (SMMRs) between sulfur and metal elements (Cu, Pb, Zn, Ag, Fe, etc.) in metal sulfides are fixed in idealized compositions, so they should have a relatively fixed proportion in terms of mass without considering the presence of structural defects such as vacancies or substitution elements. Rock bodies with an SMMR of S far greater than the common metal sulfides may contain additional sulfides of other metals. We studied the Tongshan copper deposit in NE China and calculated the mass transfer of various elements in drill hole ZK611 samples. The data show a S influx of 7160 g/t, a Cu influx of 5469 g/t, and an Fe influx of 8796 g/t in the Cu ore body. Below the Cu ores, the average influx is 18,600 g/t of S, 650 g/t of Cu, and 5360 g/t of Fe, which provides an SMMR far above common mineral sulfide values. Further studies indicated that this rock unit contains fine-grained sphalerite and galenite, and when Zn and Pb are included in the rock SMMR calculations, values closer to the mineral sulfides emerge. These results imply that the coordinating balance relationship of S content with Fe and other ore-forming metals could provide direct information for assessing metallogenic prospects. Full article
(This article belongs to the Special Issue Geochemical Exploration for Critical Mineral Resources)
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28 pages, 35997 KB  
Article
Evaluation of Granite Fertility Utilizing Porphyry Indicator Minerals (Zircon, Apatite, and Titanite) and Geochemical Data: A Case Study from an Emerging Metallogenic Province in the Taimyr Peninsula, Siberian High Arctic
by Stepan V. Berzin, Dmitry L. Konopelko, Sergei V. Petrov, Vasiliy F. Proskurnin, Evgeny I. Berzon, Mikhail Yu. Kurapov, Tamara A. Golovina, Natalya Ya. Chernenko, Vasiliy S. Chervyakovskiy, Roman S. Palamarchuk and Elena M. Andreeva
Minerals 2024, 14(11), 1065; https://doi.org/10.3390/min14111065 - 23 Oct 2024
Cited by 2 | Viewed by 3286
Abstract
The Taimyr Peninsula in the Russian High Arctic comprises a late Paleozoic-early Mesozoic collisional belt where several porphyry-type mineralization occurrences were identified during the last decade, making this area a potential exploration target for Cu-Mo deposits. In order to further evaluate the metallogenic [...] Read more.
The Taimyr Peninsula in the Russian High Arctic comprises a late Paleozoic-early Mesozoic collisional belt where several porphyry-type mineralization occurrences were identified during the last decade, making this area a potential exploration target for Cu-Mo deposits. In order to further evaluate the metallogenic potential of the poorly outcropped northeastern part of Taimyr, samples from seven granitoid intrusions were investigated in this study aimed to evaluate the granite fertility based on petrography, geochemistry, and composition of porphyry indicator minerals (zircon, apatite, and titanite). The studied intrusions represent small to moderate-sized bodies (40–800 km2) composed of biotite (±amphibole) quartz monzonites, granodiorites, granites, and biotite leucogranites that formed in the course of late Paleozoic-early Mesozoic tectono-magmatic events at the Siberian margins. The late Carboniferous Tessemsky massif represents suprasubduction granitoid series, while the Pekinskiy, Shirokinskiy, Dorozhinskiy, Kristifensenskiy, and Yuzhno-Lodochnikovskiy massifs are correlated with the early Triassic Siberian Traps LIP. The rocks of intrusions comprise a relatively uniform geochemically, predominantly magnesian, slightly peraluminous, calc-alkaline high-K amphibole-bearing I-type granitoid series with adakitic affinity, where Triassic plume-related granitoids inherit geochemical signatures of Carboniferous supra-subduction granitoids, and all rock types are marked by enrichment in LILE and negative Ta, Nb, and Ti anomalies. It is suggested that the adakitic geochemical characteristics of the Taimyr granites are a result of derivation from a relatively homogeneous mafic lower crustal source that formed at the stage of Carboniferous continental subduction and continued to produce granitic melts in the course of the early Mesozoic magmatic evolution. Whole rock geochemistry and composition of porphyry mineral indicators (zircon, apatite, and titanite) indicate that the Taimyr granites crystallized from oxidized water-saturated magmas at moderate temperatures, with the majority of samples showing characteristics typical for porphyry-fertile granites worldwide (fO2 = ΔFMQ +1 to +3 with zircon Eu/Eu* > 0.4 and apatite SO3 > 0.2 wt.%). Data from Dorozhinskiy, Kristifensenskiy, Pekinskiy, and Tessemskiy intrusions fully match geochemical criteria for porphyry-fertile granitoids, and these massifs are considered the most prospective for Cu-Mo mineralization. Granites from Shirokinskiy and Yuzhno-Lodochnikovskiy intrusions only partially match compositional constraints for fertile melts and can be considered as second-tier exploration targets. Finally, available data for the Simsovsky massif preclude its classification as a porphyry-fertile body. These conclusions are in line with previously developed exploration criteria for the northeastern Taimyr, showing that geochemical indicators of granite-fertility can be used on a regional scale in parallel with other exploration methods. Full article
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24 pages, 13494 KB  
Article
Geology and Geochemistry of the Hongnipo Copper Deposit, Southwest China
by Wangdong Yang, Gongwen Wang and Yunchou Xu
Minerals 2024, 14(9), 936; https://doi.org/10.3390/min14090936 - 13 Sep 2024
Cited by 1 | Viewed by 2286
Abstract
The Hongnipo deposit, a newly discovered large copper deposit in the Kangdian Fe-Cu metallogenic belt of southwest China, is hosted in the Paleoproterozoic metavolcanic and metasedimentary rocks of the Hekou group. The deposit comprises five strata-bound ore bodies and is associated with sporadically [...] Read more.
The Hongnipo deposit, a newly discovered large copper deposit in the Kangdian Fe-Cu metallogenic belt of southwest China, is hosted in the Paleoproterozoic metavolcanic and metasedimentary rocks of the Hekou group. The deposit comprises five strata-bound ore bodies and is associated with sporadically distributed gabbroic intrusions. Four stages of mineralization and alteration have been identified: sodic alteration (I), banded sulfide (II), magnetite (III), and sulfide vein/stockwork (IV). Extensive sodic alteration of stage I is confirmed by the composition of feldspars. Trace element analysis of magnetite suggests a formation temperature of 400 ± 50 °C and has a characteristic of IOCG deposits, while high δ18O values (8.3–11.0‰) of fluids from stage III indicate a magmatic water origin. Sulfide δ34SVCDT values from stages II and IV range from −2.6 to 10.9‰ and −1.5 to 9.9‰, respectively, suggesting a mixed sulfur source from magmatic H2S and reduced seawater sulfate. Chalcopyrite from Hongnipo shows a narrow δ65Cu range of −0.135 to 0.587‰, indicating formation at high temperatures. The lack of correlation between δ65Cu and δ34SVCDT values suggests distinct geochemical behaviors in mineralization. In summary, the Hongnipo deposit is classified as a Cu-rich section of a typical IOCG deposit. Full article
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