Search Results (117)

This LCA study addresses the research gap concerning the comprehensive environmental implications of using paving block aggregates (PBA), derived from crushed waste concrete paving blocks (CPB), as a sustainable replacement for natural aggregates in cementitious materials. While the concrete industry faces twin challenges—high CO₂ emissions from cement and the massive ecological toll of extracting 20 Gt/year of natural aggregates—a systematic life cycle assessment of this specific waste stream was necessary, especially one that considered potential material interaction trade-offs. The study’s conclusions offer critical insight into achieving genuine sustainability. Consistently, cement production was identified as the overwhelming environmental hotspot, contributing over 90% of the global warming potential (GWP) across all scenarios. This finding indicates that even substantial changes in aggregate sourcing can only deliver limited GWP reductions unless accompanied by strategies targeting cement-related emissions. While substituting natural aggregates with PBA generally provided environmental benefits, a crucial trade-off was identified: the significantly higher dosage of superplasticizer required to maintain the workability of the PBA mixes. For mortar, the burden from the increased plasticizer became a major secondary hotspot, occasionally offsetting the gains from aggregate replacement. In these scenarios, the contribution of admixtures to the total GWP was sufficiently high to reduce or negate the environmental benefits achieved through aggregate substitution. In contrast, aggregate replacement proved more favorable in concrete than in mortar, as the concrete scenarios showed a weaker correlation between environmental impact and plasticizer use. The authors conclude that future strategies must prioritize reducing cement content and, critically, systematically consider the necessary use of admixtures to ensure that the intended environmental improvements are genuine and not counteracted by the side effects of material substitution. The quantified LCA results demonstrate that cement reduction offers the highest mitigation potential, while admixture optimization is essential to prevent secondary environmental hotspots, particularly in mortar applications. Full article

The implementation of Australia’s 2024 waste export ban has increased pressure on domestic recycling systems, resulting in an additional 650,000 tonnes of waste annually. This emphasises the urgent need for high volume landfill waste material recovery, especially in sustainable construction materials such as geopolymer concrete (GPC). Geopolymer concrete is recognised as a sustainable construction material; however, the scientific understanding of the compatibility between landfill waste and the geopolymer matrix, particularly under harsh environments, remains unknown. This paper presents an experimental investigation on five types of geopolymer concrete (GPC) mixes. The study included a control mix with natural stone chips and four additional mixes in which stone chips were 100% replaced with waste materials including shredded plastic, cardboard, crushed glass, and granular crumb rubber as fine aggregates. The mechanical performance, durability behaviour and stress-strain characteristics of these mixes were evaluated. Concrete samples were exposed to normal air, a saline environment with 10% salinity, and a hygrothermal environment at 60 °C and 98% humidity for four months to assess durability performance. The results demonstrate that GPC is compatible with landfill waste aggregates and enables the production of a workable mixture. As a result of saline environments, waste aggregate-based geopolymer concrete reduces compressive strength by 15%, while natural stone chips-based geopolymer concrete decreases strength by 45% during the same period, indicating that waste aggregates are more appropriate than natural aggregates in marine environments. Although the inclusion of waste aggregates reduces the strength and stiffness of the GPC, the materials continue to meet the mechanical property requirements for non-structural applications. A theoretical model considering the elastic modulus, ultimate strength and corresponding strain has been developed to predict compressive stress–strain behaviour of waste-based GPC. High modulus aggregates, typically ranging from approximately 10.0 GPa to 85.0 GPa such as stone chips and glass sand demonstrate parabolic stress–strain behaviour. In contrast low modulus aggregates, generally ranging from 1.0 GPa to 5.0 GPa including plastic, cardboard, and crumb rubber, exhibit a bilinear stress–strain response. Full article

To enhance the rheological properties and engineering applicability of fully solid waste filling slurry, this study uses iron tailings sand as aggregate and slag, steel slag, and desulfurization ash as cementing materials. Through a central composite design experiment, the synergistic regulatory effects of steel slag (10~30%) and desulfurization ash (10~30%) on the slurry’s rheological and strength properties were systematically investigated. The yield stress and plastic viscosity of the slurry were quantified based on the Bingham fluid model, using expansion tests and L-tube models, while isothermal calorimetry analysis and microscopic image processing revealed the underlying micro-mechanisms. The results show that when both steel slag and desulfurization ash contents are 20%, the cured specimen prepared from the slurry achieves an optimal 28-day uniaxial compressive strength of 5.90 MPa at 28 days, with yield stress and plastic viscosity of 146.71 Pa and 3.04 Pa·s, respectively. Micro-mechanistic analysis revealed that desulfurization ash effectively reduced the yield stress by up to 38% (from 196.04 Pa to 90.01 Pa) and increased the fractal dimension of flocculated structures to 1.906, thereby optimizing initial flowability. Conversely, steel slag increased the yield stress but decreased plastic viscosity, enhancing structural stability, and regulating the later hydration process. The loop tests confirmed the good transport performance and engineering adaptability of the optimized mix, achieving a cost reduction of up to 65% compared to cement-based systems. Full article

The increasing amount of recycled plastic waste and the extensive use of construction materials both contribute significantly to CO₂ emissions, a major global concern. This study investigates the use of recycled plastic waste (PW) as a partial replacement for natural 4/10 mm coarse aggregates in concrete mix design, aiming to promote sustainable construction practices. Concrete mixes were prepared with varying levels of plastic replacement—0%, 15%, 30%, 45%, and 60% by volume—and evaluated for workability, compressive strength, tensile strength, water absorption, and microstructural properties. Results indicated that replacing aggregates with PW increased slump values, suggesting improved workability, particularly at 30–45% replacement. However, both compressive and tensile strengths exhibited a declining trend as the replacement level increased. The standard strength was maintained only at 15% replacement, achieving 35.3 MPa at 56 days compared to 37.3 MPa for the control mix. Durability tests showed reduced water absorption at low replacement levels but significant porosity and microcracking at higher percentages. Scanning Electron Microscopy (SEM) revealed weak interfacial transition zones (ITZs) between plastic waste and cement paste, with bonding weakening and micro voids increasing as replacement levels rose. A simplified life cycle assessment (LCA) suggests that while CO₂ emissions remain largely unchanged due to cement dominance, incorporating recycled plastic waste provides sustainability benefits through resource conservation and waste diversion rather than direct carbon reduction. These findings highlight that limited aggregate replacement with plastic waste can be practical, cost-efficient, and environmentally advantageous. This research underscores the potential of recycled plastics in sustainable construction, contributing to waste management and reducing reliance on natural aggregates. Full article

This novel study provides new experimental evidence and a detailed comparative analysis of how various types of plastic materials influence concrete performance. Six widely used plastic materials were examined for their impact on the flexural strength of reinforced concrete (RC) beams, as well as the compressive strength, elastic modulus, and durability of concrete specimens. In the experimental program, 10% of the natural fine aggregate was replaced with particles of polyethylene terephthalate (PET), high-density polyethylene (HDPE), polyvinyl chloride (PVC), low-density polyethylene (LDPE), polypropylene (PP), and polystyrene (PS). A simplified life cycle assessment (LCA) model was included to compare the greenhouse gas emissions (measured as CO₂-e) from managing plastic waste. The new experimental data indicate that, overall, incorporation of plastic waste materials into concrete has modest adverse effects, suggesting the viability of the resulting product as a sustainable material alternative. Flexural tests on RC beams showed that the addition of plastic particles has no adverse effects on flexural behavior under the specific test conditions. Furthermore, durability assessments using ultrasonic pulse velocity and electrical resistivity tests confirmed that plastic-modified concrete performs comparably to conventional mixes. LCA revealed that, with strategic improvements in recycling technology and logistics, using plastic waste in concrete can become an environmentally friendly option, helping to reduce the carbon footprint. Full article

This paper focuses on mixed seeds of Vicia villosa and Avena sativa, with their discrete element model and contact parameters being systematically calibrated and validated to provide reliable theoretical support for the structural design and parameter optimization of the air-assisted seed delivery system. The physical properties of both seed types, including triaxial dimensions, density, moisture content, Poisson’s ratio, and shear modulus, were first measured. The Hertz–Mindlin (no slip) contact model and the multi-sphere aggregation method were employed to construct the discrete element models of Vicia villosa and Avena sativa, with preliminary calibration of the intrinsic model parameters. Poisson’s ratio, elastic modulus, collision restitution coefficient, static friction coefficient, and rolling friction coefficient between the seeds and PLA plastic plate were determined through uniaxial compression, free fall, inclined sliding, and inclined rolling tests. Each test was repeated five times, and the calibration criterion for contact parameters was based on minimizing the relative error between simulation and experimental results. Based on this, experiments on the packing angle of mixed seeds, steepest slope, and a three-factor quadratic rotational orthogonal combination were conducted. The inter-seed collision restitution coefficient, static friction coefficient, and rolling friction coefficient were set as the experimental factors. A total of 23 treatments were designed with repetitions at the center point, and a regression model was established for the relative error of the packing angle with respect to each factor. Based on the measured packing angle of 28.01° for the mixed seeds, the optimal contact parameter combination for the mixed seed pile was determined to be: inter-seed collision restitution coefficient of 0.312, static friction coefficient of 0.328, and rolling friction coefficient of 0.032. The relative error between the simulated packing angle and the measured value was 1.32%. The calibrated inter-seed contact parameters were further coupled into the EDEM–Fluent gas–solid two-phase flow model. Simulations and bench verification tests were carried out under nine treatment combinations, corresponding to three fan speeds (20, 25, and 30 m·s⁻¹) and three total transport efficiencies (12.5, 17.5, and 22.5 g·s⁻¹), with the consistency coefficient of seed distribution in each row being the main evaluation variable. The results showed that the deviation in the consistency coefficient of seed distribution between the simulation and experimental measurements ranged from 1.24% to 3.94%. This indicates that the calibrated discrete element model for mixed seeds and the EDEM–Fluent coupled simulation can effectively reproduce the air-assisted seed delivery process under the conditions of Vicia villosa and Avena sativa mixed sowing, providing reliable parameters and methodological support for the structural design of seeders and DEM-CFD coupled simulations in legume–grass mixed sowing systems. Full article

The increasing global production of plastic (P) waste presents a critical environmental challenge, while the construction industry’s demand for sustainable materials continues to grow. The building industry’s reliance on natural aggregates, a contributor to environmental degradation, requires sustainable alternatives. Utilizing plastic waste as a partial aggregate substitute in concrete offers dual advantages: preserving limited resources and redirecting waste from landfills. This research uses advanced machine learning (ML) to forecast the mechanical properties of P waste concrete. Random Forest (RF) and eXtreme Gradient Boosting (XGBoost) models with particle swarm optimization (PSO) were developed to predict compressive and tensile strengths of P waste concrete. A comprehensive dataset comprising 196 datapoints for compressive strength (CS) and 100 datapoints for tensile strength (TS) of P waste concrete was collected from the literature. The input parameters encompassed the plastic (P), cement (C), water-to-cement ratio (W/C), coarse aggregate (CA), fine aggregate (FA), and curing age (Age), while the outputs were CS and TS of P waste concrete. The constructed models were assessed utilizing various statistical metrics. The findings indicate that coefficient of determination of both XGBoost (CS, R² = 0.9911, and TS, R² = 0.9947) and RF (CS, R² = 0.9757, and TS, R² = 0.9737) models performed well, with XGBoost indicating better performance with fewer prediction errors. SHAP analysis emphasizes the substantial effect of P waste on concrete strength properties followed by C and Age. Furthermore, GUIs for predicting TS and CS of concrete containing P waste utilizing both RF and XGBoost models were developed. Overall, this study not only achieves superior accuracy through hybrid PSO-ML models but also contributes to sustainable construction materials and computational material science, offering a data-driven framework for optimizing mix designs that incorporate plastic waste, which can accelerate its adoption in eco-friendly engineering applications. Full article

This study examines the effectiveness of pervious concrete pavements as a sustainable and cost-effective stormwater management technique, particularly by incorporating locally sourced recycled materials into their design. It evaluates the stormwater treatment potential of three pervious concrete pavement types incorporating recycled plastic, glass, and crushed concrete aggregates, with six design variations produced using 25% and 50% replacements of coarse aggregates from these materials. The key properties of pervious concrete, namely compressive strength, porosity, unit weight, and infiltration, and key water quality indicators, namely pH, electrical conductivity (EC), total suspended solids (TSS), colour, turbidity, chemical oxygen demand (COD), nitrate (NO₃⁻), and orthophosphate (PO₄³⁻), were analysed. Results indicated an overall improvement in the quality of the stormwater runoff passed through all pervious concrete pavements irrespective of composition. Notable reductions in turbidity, TSS, colour, COD, PO₄³⁻, and NO₃⁻ underscored the effectiveness of pervious concrete containing waste materials in the treatment of stormwater runoff. Pervious concrete pavements with 25% recycled concrete exhibited optimal performance in reducing TSS, COD, and PO₄³⁻ levels, while the 50% recycled concrete variant excelled in diminishing turbidity. However, the study found that the use of recycled materials in pervious concrete pavements affects properties like compressive strength and infiltration rate differently. While incorporating 25% and 50% recycled concrete aggregates did not significantly reduce compressive strength, the effectiveness of stormwater treatment varied based on the mix design and type of recycled material used. Thus, this study highlights the potential of utilizing recycled waste materials in pervious concrete pavements for sustainable stormwater management. Full article

Waste valorization in construction materials offers a promising pathway to reducing environmental burdens while promoting circular resource strategies in the built environment. This study develops a novel composite mortar formulated with sustainable materials and alternative aggregates, namely polyethylene terephthalate (PET) particles recovered from post-consumer plastic waste and bottom ash from thermal power generation. Natural pumice was incorporated to improve the lightness and the thermal insulation, with cement serving as the binder. The mix design was systematically optimized using the Taguchi method to enhance performance while minimizing carbon emissions. The resulting mortar, produced at both laboratory and small-scale commercial levels, demonstrated favorable technical properties: dry density of 1.3 g/cm³, compressive strength of 5.96 MPa, thermal conductivity of 0.27 W/(m*K), and water absorption of 16.1%. After exposure to 600 °C, it retained 60.6% of its strength and exhibited only a 10.1% mass loss. These findings suggest its suitability for non-load-bearing urban components where sustainability, thermal resistance, and durability are essential. The study contributes to global sustainability goals, particularly Sustainable Development Goal (SDG) 11, 12, and 13, by illustrating how waste valorization can foster resilient construction while reducing the environmental footprint of cities. Full article

This study evaluates the performance of asphalt concrete incorporating steel slag aggregates coated with recycled polyethylene terephthalate (PET). The aim was to enhance adhesion between aggregate and binder while addressing environmental concerns related to waste management. Laboratory testing was carried out to assess Marshall stability, indirect tensile strength, and tensile strength ratio, which are commonly used indicators of strength and moisture resistance in asphalt mixtures. The results showed that PET coating enhanced binder-aggregate bonding, resulting in higher stability, which indicates an improved resistance to plastic deformation and moisture damage compared to uncoated slag mixtures. Among the tested combinations, the mixes containing 20% slag with 10% PET and 30% slag with 15% PET demonstrated the most balanced performance. These mixes achieved greater durability while maintaining satisfactory strength values, indicating that PET-coated slag can serve as an effective partial replacement for natural aggregates in asphalt concrete. The study also highlights that the approach can help reduce reliance on natural stone, lower construction costs, and promote recycling of industrial byproducts and plastic waste. This contributes to more sustainable pavement practices while addressing issues of waste disposal and environmental degradation. The findings suggest that PET-coated steel slag can be considered a practical and resource-efficient material for asphalt mixtures. The research not only adds technical evidence to the growing interest in waste-based construction materials but also provides guidance for adopting such methods in developing countries, where cost and sustainability are critical factors. Full article

Accurate information on waste composition is essential for strategic planning in waste management and developing environmental technologies. However, detailed analyses of individual waste containers are both time- and cost-intensive, resulting in a limited number of available samples. Therefore, it is crucial to apply statistical methods that enable reliable estimation of average waste composition and its variability, while accounting for territorial differences. This study presents a statistical approach based on territorial stratification, aggregating data from individual waste container analyses to higher geographic units. The methodology was applied in a case study conducted in the Czech Republic, where 19.4 tons of mixed municipal waste (MMW) were manually analyzed in selected representative municipalities. The method considers regional heterogeneity, monitors the precision of partial estimates, and supports reliable aggregation across stratified regions. Three alternative approaches for constructing interval estimates of individual waste components are presented. Each interval estimate addresses variability from the random selection of waste containers and the selection of strata representatives at multiple levels. The proposed statistical framework is particularly suited to situations where the number of samples is small, a common scenario in waste composition analysis. The approach provides a practical tool for generating statistically sound insights under limited data conditions. The main fractions of MMW identified in the Czech Republic were as follows: paper 6.7%, plastic 7.3%, glass 3.6%, bio-waste 28.4%, metal 2.1%, and textile 3.0%. The methodology is transferable to other regions with similar waste management systems. Full article

This study explored the functionalization of sodium caseinate (NaCas) using environmentally friendly approaches to improve the mechanical and structural properties of the derived films. NaCas functionalization was achieved through casein crosslinking using two approaches: (i) thermal treatment at an alkaline pH to induce the formation of lysinoalanine (LAL) and (ii) riboflavin-mediated photo-oxidation to induce the formation of di-tyrosine (di-Tyr). Starting from NaCas (not functionalized, control) obtained from pasteurized milk, three functionalized NaCas samples were prepared: one sample crosslinked by LAL, and two samples crosslinked by di-Tyr formed under LED light either with or without riboflavin. The amount of crosslinking was evaluated in the acid hydrolysates through HPLC methods using either fluorescence (di-Tyr) or MS (LAL) detection. Heat treatment at pH 9 induced the formation of up to 3540 µg of LAL/g casein, whereas LED light exposure in the presence of riboflavin promoted the formation of up to 500 µg of di-Tyr/g casein. The formation of crosslinks at the intermolecular level, which resulted in protein aggregation, was detected by SDS-PAGE. Films were obtained by mixing the water solutions of the four NaCas samples with glycerol as the plasticizer and casting them. The FTIR spectra revealed that the formation of crosslinks also induced changes in the secondary structure of NaCas, which were conserved in the derived films. Mechanical testing demonstrated that di-Tyr crosslinks enhanced film ductility, while LAL crosslinks increased tensile strength and stiffness. Full article

The growing disposal of used tyres and plastic waste in landfills poses a significant environmental challenge. This study investigates the potential of utilizing used tyre rubber and macro-synthetic fibres (MSFs) made from recycled plastics in fibre-reinforced rubberized concrete (RuFRC). Various percentages of tyre rubber shreds were used to replace coarse aggregates, calculated as 10%, 20%, and 30% of the volume of fine aggregates; fibre dosages (0%, 0.25%, 0.5%, 0.75%, and 1% by volume) were incorporated into the mix, and a series of physical, mechanical, and durability properties were evaluated. The results show that, as the fibre and rubber content increased, the slump of RuFRC decreased, with the lowest value obtained for concrete with 1% fibre and 30% rubber. The density of RuFRC decreases as the rubber percentage increases due to air voids and increased porosity caused by the rubber. The strength properties of RuFRC were found to decline with the increase in the rubber content, with mixes containing 30% rubber exhibiting reductions of about 60% in compressive strength, 27% in tensile strength, and 13% in flexural strength compared to the control specimen. Durability testing revealed that an increased rubber content led to higher water absorption, water penetration, and chloride ion permeability, with 30% rubber showing the highest values. However, lower rubber content (10%) and higher fibre dosages improved the durability characteristics, with water absorption reduced by up to 5% and shrinkage strains lowered by about 7%, indicating better compaction and bonding. These results indicate that RuFRC with moderate rubber and higher fibre content offers a promising balance between sustainability and performance. Full article

Heparan sulfate proteoglycans (HSPGs) within the neuronal niche are expressed during brain development, contributing to multiple aspects of neurogenesis, yet their roles in glial lineage commitment remain elusive. This study utilised three human cell models expanded under basal culture conditions followed by media-induced lineage induction to identify a reproducible and robust model of gliogenesis. SH-SY5Y human neuroblastoma cells (neuronal control), ReNcell CX human neural progenitor cells (astrocyte inductive) and ReNcell VM human neural progenitor (mixed neural induction) models were examined. The cultures were characterised during basal and inductive states via Q-PCR, Western Blotting, immunocytochemistry (ICC) and calcium signalling activity analyses. While the ReNcell lines did not produce fully mature or homogeneous astrocyte cultures, the ReNcell CX cultures most closely resembled an astrocytic phenotype with ReNcell VM cells treated with platelet-derived growth factor (PDGF) biased toward an oligodendrocyte lineage. The glycated variant of surface-bound glypican-2 (GPC2) was found to be associated with lineage commitment, with GPC6 and 6-O HS sulfation upregulated in astrocyte lineage cultures. Syndecan-3 (SDC3) emerged as a lineage-sensitive proteoglycan, with its cytoplasmic domain enriched in progenitor-like states and lost upon differentiation, supporting a role in maintaining neural plasticity. Conversely, the persistence of transmembrane-bound SDC3 in astrocyte cultures suggest continued involvement in extracellular signalling and proteoglycan secretion, demonstrated by increased membrane-bound HS aggregates. This data supports HSPGs and HS GAGs as human neural lineage differentiation and specification markers that may enable better isolation of human neural lineage-specific cell populations and improve our understanding of human neurogenesis. Full article

Recycling plastics waste into concrete represents one of the possible approaches for its valorization, offering both economic and environmental benefits. Although numerous studies have explored the mechanical properties of concrete with plastics waste, its durability performance remains largely unexplored. In this context, this study aims to assess the electrochemical behavior of rebars embedded in reinforced concrete modified by partially replacing natural aggregates with recycled plastics, comparing their behavior to that of conventional concrete. The corrosion of reinforcing steel bars was evaluated by wet and dry cycles (w/d) in calcium chloride solutions, monitoring corrosion potential and potentiostatic polarization resistance, and recording electrochemical impedance spectroscopy (EIS) and polarization curves. In addition, the chloride diffusion tendency and the mechanical performances were assessed in unreinforced samples. The findings indicate that in environments with lower chloride concentrations, concrete with plastic granules provides good protection against rebar corrosion. Although the mechanical results of the studied mixes confirmed that incorporating plastic granules as aggregates in the concrete matrix causes a reduction in compressive strength, as known in the literature, the modified concrete also exhibits improved post-cracking behavior, resulting in enhanced ductility and fracture toughness. Full article