Search Results (618)

Although substantial knowledge exists regarding the use of ceramic powders as pozzolanic supplementary cementitious materials, a notable gap remains in the literature concerning the durability properties of cement with ceramics. This research aims to address this gap by evaluating the effects of ceramic powders on mortar durability, specifically focusing on resistance to freeze–thaw, high temperatures, and 1% sulphuric acid. The study also investigates the use of recycled ceramic demolition waste as a replacement for calcined clay in limestone calcined clay (LC3) formulations. This research demonstrates the potential of using ceramic waste to enhance mortar durability. The results show significant improvements in freeze–thaw resistance, with strength losses of 1.91% to 2.61% for modified mortars, compared to 6.31% for the reference mortar. Fire resistance also improves, with strength gains of up to 13.9% at 200 °C for LC3 mortars with ceramic powder. At 500 °C, strength losses ranged from 2.8% to 31.9%, with ceramic-containing mortars showing better performance than the reference. At 900 °C, substantial strength losses occurred across all mixes (72.0% to 90.0%), with mortars containing ultrafine ceramic powder showing the best resistance. Resistance to 1% sulphuric acid is enhanced, with strength losses decreasing from 9.37% in the reference mortar to 1.38% in LC3 mortar with ceramic powder. Full article

In this study, the synergistic effects of a combination of nano additives (nano-clay (NC) and nano-silica (NS)) on the compressive strength (CS) of concrete exposed to temperatures ranging between 25 °C and 800 °C were modeled with two machine learning (ML) techniques: extreme gradient boosting (XGB) and random forest (RF) algorithms. A dataset comprising 169 compressive strength results (using four input parameters: NC dose, NS dose, temperature, and duration) was utilized for the raw data for the prediction models. The results indicated the superior performance of the XGB model in terms of the high accuracy attained in the prediction and the few errors present. Furthermore, SHAP analysis demonstrated that temperature has the highest negative impact on the prediction of the CS of nano-modified concrete. The individual conditional expectation (ICE) with partial dependence plots (PDPs) demonstrated that the optimum doses of NS and NC, leading to maximum compressive strength, were (2~3%) and (5~6%) by weight of cement. The developed models can be used as tools for optimizing mix designs to enhance fire resistance, thereby contributing to more durable and sustainable concrete construction and reducing the need for costly experimental trials. Full article

To improve the engineering properties of red clay, sodium polyacrylate (PAAS) and locust bean gum (LBG) were used as modifiers, either singly or in combination. The modified soils were subjected to variable head permeability tests, triaxial compression tests, and scanning electron microscopy (SEM) tests to analyze the effects of different modifiers on the permeability and shear strength of the red clay and systematically explore the modification mechanism. The results showed that both PAAS and LBG significantly reduced the permeability of the red clay, with PAAS having a more pronounced effect. This mechanism is attributed to PAAS swelling upon water absorption, forming a hydrogel network that fills micropores and forms ionic bonds with clay particles. LBG, on the other hand, encapsulates the particles in a highly viscous colloid, enhancing their aggregation. Regarding shear strength, both PAAS and LBG improved soil cohesion, with PAAS exhibiting a superior combined improvement in cohesion and internal friction angle compared to LBG. The PAAS-LBG composite modification exhibits a significant synergistic effect: PAAS forms a continuous hydrogel network as the primary skeletal structure of the soil, while LBG supplements the pores and increases bonding, resulting in a denser soil structure. Microscopic analysis further confirms that the PAAS-LBG composite modification significantly reduces porosity and enhances interparticle interlocking, thereby simultaneously improving both the impermeability and shear strength of the red clay. This research can provide a reference for sustainable development and red clay modification in red clay regions. Full article

In the mining industry, key unit operations such as grinding, flotation, thickening, and tailings transport are negatively affected by the presence of clay minerals, which impart complex rheological behaviors to mineral suspensions by increasing their rheological properties. This deterioration arises from specific physicochemical characteristics of clay minerals such as fine particle size, anisotropic character, laminar morphology, and swelling capacity. This work reviews the effects of various rheology-modifying reagents on clay suspensions including kaolinite, illite, and montmorillonite. The reviewed reagents include inorganic salts, pH modifiers, polymers, surfactants, and nanoparticles. Their mechanisms of interaction with solid particles are analyzed, highlighting their influence on the degree of dispersion or aggregation. Furthermore, this review proposes research opportunities focused on the formulation of hybrid reagents, modified biopolymers, and the development of reagents effective under adverse conditions such as high salinity or elevated temperatures. This review provides a comprehensive basis for optimizing the use of rheological additives through more efficient and sustainable strategies for managing clay-rich suspensions in the mining industry. Full article

The combined effects of soil properties, zinc (Zn), and chloride ion (Cl⁻) concentrations on Zn distribution across soil fractions are poorly understood, even though zinc chloride (ZnCl₂) contamination in industrial soils is a major source of mobile Zn and poses significant environmental risks. This study aimed to (1) assess how the soil type, physicochemical properties, and Zn concentration affect Zn distribution in Community Bureau of Reference (BCR)-extracted fractions; (2) evaluate the impact of Cl⁻ on Zn mobility; and (3) develop predictive models for mobile and stable Zn fractions based on soil characteristics. Zn mobility was analyzed in 18 soils differing in Zn and Cl⁻, pH, specific surface area (SSA), organic matter (OM), and texture (sand, silt, clay (CLY)), using a modified BCR method. Zn fractions were measured by atomic absorption spectroscopy (AAS). Analysis of Covariance was used to assess Zn distribution across soil types, while Zn fractions were modeled using non-linear regression (NLR). The results showed that mobile Zn increased with the total Zn, and that the soil type and Zn levels influenced Zn distribution in soils contaminated with ZnCl₂ (Zn 304–2136 mg·kg⁻¹ d.m.; Cl⁻ 567–2552 mg·kg⁻¹; pH 3.5–7.5; CLY 11–22%; SSA 96–196 m²·g⁻¹; OM 0–4.8%). Although Cl⁻ enhanced Zn mobility, its effect was weaker than that of Zn. Predictive models based on the total Zn, SSA, and CLY accurately estimated Zn in mobile and stable fractions (R > 0.92), whereas the effects of the pH and OM, although noticeable, were not statistically significant. Full article

Rice cultivation has the ability to ameliorate saline soils, but this monoculture pattern can lead to negative plant–soil feedback. In a previous study, we investigated the effects of long-term rice cultivation on saline soil chemistry, salt ions, root characteristics, and agglomerate formation, and concluded that the optimal rice planting period is 5 years. However, we do not know which crop rotation is most effective in improving this negative soil feedback and enhancing soil quality. In this study, we carried out an experiment on saline land planted with rice over 5 years and set up four different rotations, including rice–Hunan Jizi, rice–maize, rice–sweet sorghum, and rice–soybean, with perennial rice planting as CK, to analyze soil texture under different treatments. Physicochemical properties and enzyme activities were also analyzed under different treatments, and the soil quality index (SQI) was constructed using principal component analysis and correlation analysis for comprehensive evaluation of each treatment. The results showed that (1) the saline-alkali soil texture of perennial rice planting in the Yinbei Plain was silty soil, and different rice drought rotation methods changed the soil texture from silty to silty loam, which improved the fractal dimension of the soil. The fractal dimension of saline-alkali soil was significantly positively correlated with the clay volume content, negatively correlated with silt volume content, and negatively correlated with sand volume content. (2) There was no risk of structural degradation (SI > 9%) in saline-alkali soil planted in perennial rice, and it appeared that RS (rice–soybean) could improve the stability coefficient of soil structure in the 0~40 cm soil layer. (3) Different rice and drought rotation methods could significantly affect the physical and chemical properties and enzyme activities of soil, and the quality of soil in the 0~40 cm soil layer was evaluated; RS (rice–soybean) and RC (rice–maize) were suitable for rice drought rotation in the Yinbei area. The structural equation model showed that salinity and soil nutrients were the key factors restricting the improvement of saline-alkali soil quality in Yinbei. These results will deepen the current understanding of bio-modified saline soils. Full article

Water pollution by organic dyes poses serious environmental and health challenges, demanding efficient and selective remediation methods. In this study, we engineered tailored organo-clay nanocomposites by modifying montmorillonite with hexadecyltrimethylammonium bromide (HTAB) and intercalating polyethylene glycol (PEG) chains of two distinct molecular weights (PEG200 and PEG4000). Comprehensive characterization techniques (XRD, FTIR, SEM, zeta potential, and TGA) confirmed the successful modification of the composites. Notably, PEG4000 promoted significant interlayer expansion, as evidenced by the shift of the (00l) reflection corresponding to the basal spacing d, indicating an increase in basal spacing. This expansion contributed to the formation of a well-ordered porous framework with uniformly distributed pores. In contrast, PEG200 produced smaller pores with a more uniform distribution but induced less pronounced interlayer expansion. Adsorption tests demonstrated rapid kinetics, achieving equilibrium in under 15 min, and impressive capacities: 420 mg/g of methylene blue (MB) adsorbed on PEG200/MMT@HTAB, and 385 mg/g of Congo red (CR) on PEG4000/MMT@HTAB. The crucial role of PEG chain length in adsorption selectivity was assessed, showing that shorter PEG chains favored methylene blue adsorption by producing narrower pores and faster kinetics, while longer PEG chains enhanced CR uptake via a stable, interconnected pore network that facilitates diffusion of larger dye molecules. Thermodynamic and Dubinin–Radushkevich analyses confirmed that the adsorption was spontaneous, exothermic, and predominantly driven by physical adsorption mechanisms involving weak van der Waals and dipole interactions. These findings highlight the potential of PEG-modified montmorillonite nanocomposites as cost-effective, efficient, and tunable adsorbents for rapid and selective removal of organic dyes in wastewater treatment. Full article

Soil thermal conductivity (λ) is a critical parameter governing heat transfer in geothermal exploitation, nuclear waste disposal, and landfill engineering. This study explores the thermal conductivity characteristics of silty clay and develops a prediction model using the actively heated fiber-optic method based on fiber Bragg grating technology. Tests analyze the effects of particle content (silt and sand), dry density, moisture content, organic matter (sodium humate and potassium humate), and salt content on λ. Results show λ decreases with increasing silt, sand, and organic matter content, while it increases exponentially with dry density. The critical moisture content is 50%, beyond which λ declines, and λ first rises then falls with salt content exceeding 2%. Sensitivity analysis reveals dry density is the most influential factor, followed by sodium humate and silt content. A modified Johansen model, incorporating shape factors correlated with influencing variables, improves prediction accuracy. The root mean squared error decreases to 0.087, and coefficient of determination increases to 0.866. The study provides an accurate method for measuring thermal conductivity and enhances understanding of the heat-transfer mechanism in silty clay. Full article

This research presents the results of studies on the physical and mechanical properties of the soil–polymer composites developed by the Scientific and Production Company “Special Polymer Technologies” SPT^® by injecting polyurethane material into clay soils to strengthen the foundations of erected structures. A novel method is proposed to determine the strain characteristics of these composites, embracing the preparation of model specimens in cylindrical containers with subsequent static and dynamic load testing. The results of static tests showed a significant increase in the strain modulus in comparison to that of the soil, resulting in soil stabilization due to a decrease in the initial content of moisture squeezed out of the modified soil. A coefficient of increase in the deformation modulus (K_E) is introduced to quantitatively assess the soil stabilization efficiency. An original technique is also proposed for assessing composite durability, and it is based on analyzing the mass loss after cyclic wetting and drying. The proposed soil stabilization approach promotes and improves digital construction technologies such as Building Information Modeling (BIM) by enabling the accurate simulation and prediction of the behavior of loaded soil in foundation systems. The introduced quantifiable metrics can be integrated into Digital Twin- or BIM-based project planning tools, contributing to sustainability, safety, and reliability in modern construction practices. Full article

Polymers derived from renewable polysaccharides offer promising avenues for the development of high-temperature, environmentally friendly drilling fluids. However, their industrial application remains limited by inadequate thermal stability and poor colloidal compatibility in complex mud systems. In this study, we report the rational design and synthesis of epichlorohydrin-crosslinked carboxymethyl xylan (ECX), developed through a synergistic strategy combining covalent crosslinking with hydrophilic functionalization. When incorporated into water-based drilling fluid base slurries, ECX facilitates the formation of a robust gel suspension. Comprehensive structural analyses (FT-IR, XRD, TGA/DSC) reveal that dual carboxymethylation and ether crosslinking impart a 10 °C increase in glass transition temperature and a 15% boost in crystallinity, forming a rigid–flexible three-dimensional network. ECX-modified drilling fluids demonstrate excellent colloidal stability, as evidenced by an enhancement in zeta potential from −25 mV to −52 mV, which significantly improves dispersion and interparticle electrostatic repulsion. In practical formulation (1.0 wt%), ECX achieves a 620% rise in yield point and a 71.6% reduction in fluid loss at room temperature, maintaining 70% of rheological performance and 57.5% of filtration control following dynamic aging at 150 °C. Tribological tests show friction reduction up to 68.2%, efficiently retained after thermal treatment. SEM analysis further confirms the formation of dense and uniform polymer–clay composite filter cakes, elucidating the mechanism behind its high-temperature resilience and effective sealing performance. Furthermore, ECX demonstrates high biodegradability (BOD₅/COD = 21.3%) and low aquatic toxicity (EC₅₀ = 14 mg/L), aligning with sustainable development goals. This work elucidates the correlation between molecular engineering, gel microstructure, and macroscopic function, underscoring the great potential of eco-friendly polysaccharide-based crosslinked polymers for industrial gel-based fluid design in harsh environments. Full article

This study introduces an innovative deflection-controlled design method (DCM) for evaluating the bearing capacity of offshore mono-bucket foundations (MBFs) in clay, integrating advanced numerical simulations using FLAC3D with the modified cam clay (MCC) soil model. Departing from conventional ultimate bearing capacity approaches, the proposed method prioritizes serviceability limits by constraining foundation deflections to ensure optimal structural performance and turbine efficiency. A systematic investigation revealed that the MBF performance is predominantly governed by eccentricity ratios and soil–structure interaction, with vertical loads exhibiting a minimal impact in a serviceability limit state. Key findings include the following: (1) the rotation center (RC) stabilizes at approximately 0.8 times the skirt length (L) under loading; (2) thin, deep MBFs (aspect ratio > 1.0) exhibit up to a 30% higher bearing capacity compared to wide, shallow configurations; (3) increasing eccentricity ratios (ε = 0.31–1.54) enhance the moment capacity but reduce the allowable horizontal force by 15–20%; (4) compressive vertical loads (υ = −0.30) slightly reduce the normalized bending moments (ω) by 5–10% at low eccentricities (ε < 0.5). The numerical framework was rigorously validated against centrifuge test data, demonstrating high accuracy (error < 3%) in predicting foundation behavior. By bridging geotechnical mechanics with practical engineering requirements, this study provides a robust and efficient design framework for MBFs, offering significant improvements in reliability and cost-effectiveness for offshore wind turbine applications. The proposed DCM successfully guided the design of an MBF in southeastern China, demonstrating its efficacy for use with homogeneous clay. Full article

To address the critical challenges of severe fragmentation in cuttings, persistent cuttings bed accumulation, and abrupt friction torque increases during horizontal well drilling of Jurassic continental shale oil formations in J Block, Sichuan Basin—rooted in the unique high clay content that induces colloidal stability of fine cuttings and resistance to conventional cleaning—this study innovatively proposes a coupled prevention–removal hole-cleaning technology. The core methodology integrates three synergistic components: (1) orthogonal numerical simulations to optimize drilling parameters, reducing the cuttings input rate by 43.48% through “hydraulic carrying + mechanical agitation” synergy; (2) a modified Moore model with horizontal section correction factors to quantify slip velocity of cuttings, lowering the prediction error from ±20% to ±5%; and (3) a helical groove cutting removal sub with 60 m optimal spacing, enhancing local turbulence intensity by 42% to disrupt residual cuttings bed. Field validation in Well J110-8-1H demonstrated remarkable improvements: a 50% reduction in sliding friction, a 25% decrease in rotational torque, and 40% shortening of the drilling cycle. This integrated technology fills the gap in addressing the “fragmentation–colloidal stability” dilemma in shale with high clay contents, providing a quantifiable solution for safe and efficient drilling in similar continental formations. Full article

This study explores the adsorption and catalytic degradation of 2,4,6-trinitrotoluene (TNT) from aqueous solutions, using montmorillonite-based catalysts. Commercially, montmorillonite K10 was modified through aluminum pillaring (K10-Al-PILC), followed by vanadium intercalation (K10-Al-PILC-V) and ozone activation. A novel aspect of this work is the use of naturally contaminated water as the TNT source. The selected sample, collected from the Plaiul Arșiței–Cireșu–Leșunț region (Oituz, Bacau, Romania), originated from an area historically exposed to explosive residues, where TNT traces were previously identified. The adsorption performance of the materials was evaluated by varying adsorbent dosage, contact time, and solution pH. Catalytic ozonation experiments were conducted under different catalyst masses, ozone concentrations, and reaction times to assess degradation efficiency. The results demonstrated that aluminum pillaring significantly enhanced the adsorption capacity of the clay, while vanadium incorporation further improved both adsorption and catalytic activity. The vanadium-modified material exhibited superior performance in TNT removal, both through adsorption and oxidative degradation. Additionally, the catalytic ozonation process led to the formation of degradation products with reduced toxicity, confirming the potential of these materials for environmental remediation of nitroaromatic pollutants in real water systems. Full article

Surface functionalization is a key enabler that imparts solid materials with excellent chemoselectivity. With this aim, halloysite and sepiolite clay particles were functionalized with carboxyethylsilanetriol sodium salt (CES) and 3-aminopropyltriethoxysilane (APTES), affording carboxy-terminated and amino-terminated clay, respectively. In the case of halloysite, the grafting occurs at Al-OH groups of the lumen surface (tube inner surface) and Al-OH and Si-OH groups at the edges and external surface defects of the nanotubes. For sepiolite, silanol groups located on the edges of the structural channels were at the origin of a chemical reaction between this fibrous clay and the terminal alkoxysilane. The resulting modified clays were examined for removal of Congo red (CR) and malachite green (MG) as anionic and cationic dyes, respectively. Clay bearing only carboxylic groups display more affinity towards cationic dye (MG), recording 926 mg·g⁻¹ and 387 mg·g⁻¹ for HNT-CES and SEP-CES, respectively, while amino-functionalized clays show very high adsorption for anionic dye (CR), reaching 1232 and 1228 mg·g⁻¹ for HNT-APTES and SEP-APTES, respectively. Simultaneous grafting of the two silyl coupling reagents was also attempted through one-pot and sequential grafting method, with the latter being more appropriate to access amphoteric clay featuring both carboxylic and amino groups. The behavior of the bifunctional adsorbents was investigated with respect to pristine and monofunctional clay. The obtained results provide insights to fulfill the requirement for handling complex water effluent containing both anionic and cationic pollutants, towards more sustainable development. Full article

Alexandrium spp. blooms and paralytic shellfish poisoning pose serious economic threats to coastal communities and aquaculture. This study evaluated the removal efficiency of two Alexandrium minutum strains using natural kaolinite clay (KNAC) and kaolinite with polyaluminum chloride (KPAC) at three concentrations (0.1, 0.25, and 0.3 g L⁻¹), two pH levels (7 and 8), and two cell densities (1.0 and 2.0 × 10⁷ cells L⁻¹) in seawater. PAC significantly enhanced removal, achieving up to 100% efficiency within two hours. Zeta potential analysis showed that PAC imparted positive surface charges to the clay, promoting electrostatic interactions with negatively charged algal cells and enhancing flocculation through Van der Waals attractions. In addition, the study conducted a cost estimate analysis and found that treating one hectare at 0.1 g L⁻¹ would cost approximately USD 31.75. The low KPAC application rate also suggests minimal environmental impact on benthic habitats. Full article