Search Results (477)

Natural gas hydrates are regarded as a vital strategic energy resource for the future owing to their high energy density and clean combustion characteristics. To facilitate research into the physical and mechanical properties of pressure-maintained hydrate samples, this paper presents an integrated multi-parameter online analysis system capable of rapidly measuring the P-wave velocity, electrical resistivity, thermal conductivity, and shear strength of core samples under pressure-maintaining conditions. The system comprises hardware acquisition boards based on ZYNQ and ARM platforms, specialized measurement probes, and comprehensive data acquisition and analysis software. To mitigate the susceptibility of P-wave signals to noise interference, an improved denoising algorithm combining Empirical Mode Decomposition (EMD) and wavelet thresholding is proposed. By employing autocorrelation function analysis, the algorithm identifies the transition boundary between noise-dominated and signal-dominated Intrinsic Mode Functions (IMFs), subsequently applying wavelet soft-thresholding to the noise-dominant components. Experimental results demonstrate that the proposed algorithm achieves a superior signal-to-noise ratio (SNR) compared to traditional EMD methods, particularly under low SNR conditions. System validation indicates measurement accuracies of 3.2% for P-wave velocity at 20 °C, 1.76% for electrical resistivity at 25 °C, and within 7% for both thermal conductivity and shear strength. Furthermore, sea trials conducted aboard the “HAIYANG SHIYOU 708” drilling vessel confirm that the system operates stably and effectively fulfills the requirements for deep-sea core parameter characterization. Full article

As a finite strategic resource, helium is extracted from natural gas (NG). The concentration of helium in NG is very low, which makes helium hard to separate. The hydrate-based gas separation (HBGS) was proposed as a promising method for the separation of the NG with low helium content in this work. This work systematically investigated the HBGS of helium from simulated NG. The thermodynamic analysis reveals that the existence of 5.00 mol% tetrahydrofuran (THF) in the liquid phase decreased the gas–liquid–hydrate equilibrium pressure by 92.11%, compared to the deionized water system. The single-stage HBGS experimental results show that high THF concentration, low temperature, and high pressure benefited the gas processing capacity and helium purification, but they led to a low helium recovery rate. The best HBGS performance was limited by the “hydrate shell effect”. The decrease in gas–liquid ratio led to an increase in helium concentration without losing the gas processing capacity, but it caused a decrease in the helium recovery rate. Through three-stage HBGS optimization, the helium concentration was increased from 0.54 mol% to 13.54 mol% (a 25.07-fold enrichment), and a total helium recovery of 87.34% was achieved. The mathematical model proposed in this work accurately predicts the performance of HGBS with 2.09% average relative error compared to the experimental data. Full article

Hybrid gas separation technologies combining different physicochemical mechanisms represent a promising approach for the efficient treatment of complex natural gas mixtures. In this work, a hybrid process integrating gas hydrate crystallization and membrane gas separation was investigated for the upgrading of multicomponent natural gas-containing hydrocarbons (C₁–C₄), acid gases (CO₂ and H₂S), and inert components. Polysulfone hollow-fiber membranes were fabricated, and their gas transport properties were experimentally determined using an eight-component quasi-real natural gas mixture under elevated pressure conditions. The obtained mixed-gas permeance values were used as input parameters for the development of a detailed mathematical model of a hollow-fiber membrane module implemented in the Aspen Custom Modeler. The model was applied to simulate membrane separation of both gas- and hydrate-derived streams produced by the gas hydrate crystallizer. Simulation results were analyzed in terms of hydrocarbon composition, acid gas removal efficiency, and hydrocarbon recovery as a function of the stage-cut. The modeling predictions were validated experimentally using a laboratory membrane module integrated with the gas hydrate crystallization unit. Good agreement between the experimental data and simulation results was observed for all major components. The deviation between modeled and experimental concentrations remained small, while the discrepancy in hydrocarbon recovery was higher and reached approximately 10–20%, which is attributed to the cumulative uncertainty of flow rate and composition measurements. These results confirm the adequacy of the developed model. The hybrid process demonstrates strong complementarity between the thermodynamic selectivity of hydrate formation and the transport selectivity of membrane separation, enabling efficient removal of acid gases while maintaining acceptable hydrocarbon recovery. The results indicate that the proposed gas hydrate–membrane hybrid process is a promising strategy for advanced natural gas purification and upgrading. Full article

The natural gas hydrate production riser is the main passage for offshore hydrate production and transport. Its safe operation directly affects the production process. However, current hydrate production methods cannot avoid hydrate decomposition and formation inside the pipe. Hydrate phase change causes internal multiphase flow. Together with the external ocean current, it leads to more complex nonlinear vibration of the riser. Based on China’s gas hydrate trial production in the Shenhu area of the South China Sea, this study establishes a dynamic model of a production riser. The model considers hydrate phase change inside the pipe and vortex-induced vibration. It is solved using the Newmark-β method, and its validity is confirmed by CFD simulations. The results show that, under the combined action of ocean currents and internal multiphase flow, the riser exhibits a clear multi-frequency response in vortex-induced vibration. Its spatial trajectory is highly irregular. Specifically, hydrate phase change increases internal gas content and gas slippage, elevating fluid velocity. This reduces the riser’s structural stiffness and effective tension, altering the VIV response. In addition, lower top tension and higher slurry density, flow rate, and outlet backpressure delay hydrate decomposition. These factors also reduce the effective tension along the riser and increase its in-line deformation. Full article

With natural gas demand growing rapidly in this century, solidified natural gas technology holds great potential for strengthening energy resilience and delivering secure global gas supply. However, this technology is still impeded by insufficient gas uptake capacity and sluggish hydrate formation rate. Environmentally benign peptides have recently emerged as a novel class of green hydrate promoters. Different from single amino acids, peptides exhibit significant structural diversity owing to their varying sequences and combinations of their constituent amino acid monomers, showing great potential in hydrate-based applications. In this work, a unique tripeptide promoter, L-glutathione reduced (GSH), was employed, and the thermodynamic influence factors in methane hydrate formation were systematically investigated. Furthermore, as a highly hydrophilic amino acid, L-arginine was chosen for a comparative kinetic investigation with extremely hydrophilic GSH. The results revealed that experimental pressure showed a strong effect on the methane uptake rate, while it presented little influence on final methane storage capacity. The initial temperature greatly affected the average induction time, the rate of hydrate growth, and the yields of hydrates promoted by GSH. Increasing temperature resulted in a significant reduction in both the hydrate formation rate and methane uptake at 3 h. Therefore, in the GSH-promoted hydrate formation process, suitable pressure and temperature should be carefully chosen for desirable hydrate performance. Furthermore, the initial 15 min hydrate formation rate of 0.3 wt% L-arginine is 52.4% lower than that of 0.3 wt% GSH. The final methane uptake of 0.3 wt% arginine is substantially smaller than that of 0.3 wt% GSH. Although both GSH and arginine exhibit strong hydrophilic properties, the tripeptide GSH is more effective than the amino acid arginine in enhancing methane hydrate formation. The insights gained from this work offer a theoretical foundation for the application of peptide-based promoters in solidified natural gas technology. Full article

Hydrogen is a key energy carrier for the transition to renewable energy, but its storage remains a major challenge, mainly due to the energy requirements for its production and to its low volumetric energy density under ambient conditions. Clathrate hydrates have recently emerged as a promising medium for gas storage, yet their potential for hydrogen storage is still underexplored. This study presents a comprehensive bibliometric analysis of hydrogen storage research, focusing on clathrate hydrates. The analysis, based on publications indexed in Scopus over the past decades, reveals that research on gas hydrates is mature and interdisciplinary, encompassing hydrate formation, thermodynamics, and production from natural reservoirs. In contrast, hydrogen hydrates remain a marginal and emerging research area, characterized by limited scientific output and weak connections to dominant storage strategies such as metal hydrides, metal–organic frameworks, and adsorptive materials. The results highlight key research gaps, including a limited understanding of formation kinetics, thermodynamic stability under practical conditions, and challenges related to scalability and system integration. These findings suggest that targeted research efforts addressing these bottlenecks could support the development of hydrate-based systems as complementary solutions within the broader hydrogen storage landscape. Full article

Natural gas hydrate is a clean energy resource critical for global energy security and low-carbon transition. Understanding its geological accumulation mechanisms is essential for exploration and development. However, the current research on NGH geological accumulation lacks a systematic and quantitative analysis of its global research evolution, hotspots, and frontiers. To fill this gap, this study conducts a bibliometric analysis of 5891 articles (1999–2025) from the Web of Science Core Collection using CiteSpace and VOSviewer to map research trends, contributions, and frontiers. The results show that annual publications followed a three-stage trajectory: slow initiation, rapid growth, and stable development, with key boosts from production tests in Japan (2013) and China (2017). Marine and Petroleum Geology emerged as the most cited journal. China, the United States, and Germany lead research output, with the Chinese Academy of Sciences serving as the central hub (centrality: 0.46). Core researchers such as Jinqiang Liang have established foundational knowledge through highly cited studies on accumulation theory and resource–environment interactions. Research focus has shifted from early resource assessment to controlling factors, and recently toward production technologies and parameter optimization, highlighting a transition from basic to applied research with strong interdisciplinary integration. While bibliometrics reveals structural evolution and hotspots, limitations in data sources and analytical scope remain. Future efforts should integrate multi-source data and deepen content analysis to address unresolved challenges in NGH geological accumulation. Full article

Permeability evolution in hydrate-bearing porous media is a key factor controlling gas production efficiency during natural gas hydrate exploitation. In this study, laboratory experiments were conducted using sand-packed tubes filled with quartz sand and glass beads to systematically investigate the variation of liquid-phase permeability with hydrate saturation. The effects of pore structure, particle size, and initial gas injection pressure on hydrate formation and permeability reduction were analyzed. Furthermore, experimental results were compared with four commonly used permeability models, including the Kozeny model, the Dai model, the Masuda model, and the parallel capillary model. The results show that permeability decreases continuously with increasing hydrate saturation in both porous media, and the most rapid decline occurs at low saturation levels between 0 and 9%. Under the same conditions of 20–40 mesh and an initial pressure of 6.0 MPa, the pressure drop rate in the quartz-sand-packed tube reaches 1.062 kPa per minute, which is about 2.35 times higher than the 0.451 kPa per minute observed in the glass-bead-packed tube, indicating a faster hydrate formation rate and stronger permeability reduction in quartz sand. In addition, both increasing particle mesh size and raising the initial gas injection pressure significantly promote methane consumption and hydrate formation. Model comparison results demonstrate that permeability reduction is strongly dependent on pore structure. The Kozeny pore-filling model, the Dai model (M = 3), and the Masuda model (N = 8) show good agreement with the glass-bead data, whereas the Dai model (M = 8), the Masuda model (N = 15), and the pore-center form of the parallel capillary model better describe the quartz-sand system. In contrast, models based on particle-surface coating show poor agreement in both media. These findings indicate that permeability reduction is primarily controlled by pore-space occupation and flow-path restriction rather than uniform surface coverage. The results suggest that hydrate growth is more likely to occur in pore centers and critical pore-throat regions, although this conclusion is based on macroscopic model comparison and requires further validation by pore-scale observations. This study provides a quantitative basis for model selection and improves the understanding of permeability evolution in hydrate-bearing porous media. Full article

The development of all-concrete liquefied natural gas (LNG) storage tanks is hindered by the susceptibility of conventional concrete to ultra-low temperature (ULT) cycling down to −70 °C. While redispersible polymer powder (RPP) and polypropylene (PP) fibers individually enhance performance, their combined effect in various mineral admixture systems remains unclear. This study investigates the synergy and selective compatibility in hybrid-modified concrete containing fly ash (FA), silica fume (SF), or slag (SG). Comprehensive assessments after 50 ULT cycles reveal that the efficacy of hybrid modification is intrinsically governed by the mineral admixture. Among all systems, the silica fume-based hybrid system (EPSF) exhibits the highest residual compressive strength (57.5 MPa), the lowest strength loss (6.7%), and the most balanced durability. Microstructural analysis reveals that this synergy arises from a dense matrix, continuous polymer network, and effective fiber bridging—achieved only when the mineral admixture enables uniform RPP distribution. In contrast, the FA system exhibits a strength–durability trade-off, with RPP localized at interfaces, while the SG system shows a polymer-activated hydration mechanism. Microstructural and nano-mechanical analyses confirm that RPP acts as a pore filler in cement, an interfacial modifier in FA, a cohesive network former in SF, and a hydration activator in SG. This work establishes that superior ULT resilience requires not merely additive modifications but a matrix-enabled synergy, providing a scientific basis for the rational design of cryogenic concrete. Full article

Water-based drill cuttings generated during onshore natural gas development are complex solid wastes that may pose environmental risks if improperly managed. This study evaluates the feasibility of reutilizing water-based drill cuttings as pavement base materials after stabilization using a novel composite stabilizer composed of cement, stabilizer liquid agent, and water-reducing powder (CLP stabilizer). Mix proportion optimization was conducted through compaction and 7-day unconfined compressive strength tests, followed by evaluation of road performance, including strength, compressive rebound modulus, water stability, and temperature shrinkage, with stabilized powder stabilized soil as a control. Microstructural characteristics were analyzed using X-ray diffraction and scanning electron microscopy, and environmental safety was assessed through heavy metal leaching tests and background soil investigation. The results show that the optimal mixture ratio of curing agent (5% cement + 2% liquid stabilizer + 8% superplasticizer powder) satisfies the strength requirement for pre-drilling road bases, exhibiting superior performance compared to the control group. When the stabilizer dosage reaches 9%, the 7-day unconfined compressive strength achieves a maximum of 3.38 MPa, representing a 51% increase over the control group. At a stabilizer dosage of 12%, the splitting tensile strength reaches a peak value of 0.901 MPa, showing a 60.3% improvement. These results indicate enhanced deformation resistance, water stability, and reduced temperature shrinkage rates. Microstructural analysis indicates that the formation of calcium silicate hydrate (C-S-H) gel and ettringite (AFt phase) leads to a denser structure and enhanced durability. Heavy metal concentrations comply with relevant standards, demonstrating controllable environmental risks and supporting sustainable pavement base application. Full article

Natural gas hydrates, as an abundant potential energy resource, are widely present in marine sediments. In this paper, a novel method using color recognition technology is proposed for reconstructing marine hydrate reservoirs. By identifying the red, green, and blue values of image colors within the study area’s grid, numerical values are assigned and translated into geological parameters. These parameters are then input into the Computer Modeling Group software to establish heterogeneous reservoirs, and numerical simulations are conducted. The results indicate that this method successfully establishes a correspondence between color features and geological parameters. The reconstructed model images exhibit a high degree of consistency with the original images, allowing for precise parameter readings. The method was applied to hydrate reservoirs in the second trial production area of the South China Sea, the Shenhu SH2 area, and the Nankai Trough. The cumulative gas production obtained through numerical simulation of the reconstructed models closely matched the known production data, with discrepancies of 3.5%, 0.9%, and 7.6%, respectively. These findings confirm the reliability of the model, providing valuable insights for future studies on heterogeneous hydrate reservoirs and extending its application prospects to heterogeneous oil and gas reservoir research. Full article

Dynamic phase transition of natural gas hydrates confined within complex pore–throat structures is a key factor impacting the safe and efficient development of hydrate-bearing deposits. In this work, hydrate-bearing samples with varying saturation were first reconstructed with the proposed ice-seeding method using actual marine soil in hydrate-bearing sediments from the South China Sea. Dynamic evolution characteristics of hydrate formation in evolving porous media under different temperature and pressure conditions were analyzed in detail. Combined with high-resolution CT scanning, image processing, pore network extraction, and statistical analysis, the typical microscopic pore–throat structures of hydrate-bearing sediments were revealed, and the presence of nanopores was identified. Furthermore, highly controllable heterogeneous pore–throat structures were constructed for microfluidic chips by integrating stochastic modeling, equivalent modeling, and machine learning approaches. On this basis, a novel microfluidic testing method was developed for investigating the dynamic formation, dissociation, and phase transition characteristics of natural gas hydrates in complex pore structures by controlling the temperature. This study provides reliable data support and theoretical guidance for the productivity prediction of marine hydrate-bearing deposits. Full article

Permeability is a critical parameter for evaluating the production potential of natural gas hydrate reservoirs, and its accurate prediction is essential for enhanced oil recovery (EOR). However, existing permeability models often assume a uniform particle distribution, neglecting the inherent heterogeneity of natural sediments, and rarely fully couple the effects of effective stress and temperature variations induced by EOR operations. To address that gap, this study develops a novel non-empirical fractal permeability model that incorporates particle heterogeneity through an offset angle (θ) and an aspect ratio (m), and couples these with thermoelastic theory to describe the evolution of the pore structure under coupled thermo-mechanical conditions. The model accounts for two hydrate growth habits (grain-coating and pore-filling) and allows for their coexistence via weighting coefficients. Using this model, we systematically investigate the individual and combined effects of effective stress, temperature, particle heterogeneity, and hydrate saturation on permeability. Model predictions are validated against independent experimental data from multiple sources, showing good agreement. The results reveal that permeability decreases with increasing effective stress and temperature, with stress playing a more dominant role; moreover, the transition between hydrate growth habits under stress is captured. The proposed model provides a theoretical tool to understand permeability evolution in heterogeneous hydrate reservoirs under varying thermo-mechanical conditions, thereby supporting EOR strategy optimization. Full article

Natural gas hydrate (NGH) deposits represent a vast and clean energy source. However, sustainable gas production from these resources remains an unsolved technical problem due to potential geohazards and climate challenges. A critical issue in this regard is the difficulty of obtaining in situ samples, which are essential for detailed laboratory studies of NGH’s geomechanical and chemical behavior for safe and green gas production after hydrate dissociation. Currently, the retrieval of representative samples from NGH reservoirs is hindered by significant technological limitations and high costs. Consequently, laboratory-synthesized gas hydrate-bearing sediment (HBS) samples are crucial for controlled research purposes and validating numerical simulation models and are used in the majority of research studies. With this in mind and considering the complexity of synthesizing HBS samples, this study comprehensively reviews different methods of synthesizing gas hydrates in porous media, including excess-gas, excess-water, dissolved-gas, spray, bubble injection, and hybrid techniques. Each method produces distinct hydrate morphologies (e.g., pore-filling, cementing, grain-coating, etc.) and saturation levels, with trade-offs in speed, uniformity, reproducibility, and ease of control. Furthermore, the current review details the synergic application of non-invasive characterization techniques, i.e., X-ray Computed Tomography (CT) and Nuclear Magnetic Resonance (NMR), in studying gas hydrates. CT provides high-resolution three-dimensional (3D) structural images of pore geometry and hydrate distribution, while NMR/MRI (Magnetic Resonance Imaging) quantifies fluid saturations and tracks hydrate formation/dissociation dynamics in real time. The synergistic use of CT and NMR offers a powerful multimodal approach, overcoming individual limitations such as CT’s poor hydrate–water contrast detection and NMR’s indirect hydrate inference, which could help in the sustainable synthesis of particular hydrate morphologies. Finally, the critical analysis of current technological challenges or gaps and also the emerging trends and future directions in the study of HBS, including advanced imaging techniques, AI-assisted analysis, and standardization efforts, etc., are discussed. It was found that the selection of the most appropriate method for natural gas hydrate synthesis is mostly task-specific, and the emerging technologies have facilitated the synthesis of HBS samples with more precise control of morphology, saturation, etc. This review provides the required insights for sustainable synthesis and characterization of hydrate-bearing sediments samples and serves sustainable gas production from natural gas hydrate reservoirs. Full article

Investigations into the production of gas hydrates from marine sediments have demonstrated that commercial viability necessitates a daily gas production rate of 130,000 to 200,000 m³. However, the second-round trial production in the South China Sea yielded only 28,700 m³/day, falling short of the rule-of-thumb for economic feasibility. Given the coexistence of natural gas hydrates (NGHs) and shallow gas in the subsurface reservoirs of the South China Sea, a co-production strategy (simultaneously exploiting NGHs and shallow gas) was proposed to reduce costs and enhance production efficiency. In this study, a large-scale, three-dimensional, multi-phase, and multi-component model was established based on the NGHs–shallow gas symbiotic system in the Qiongdongnan Basin. A dual horizontal well configuration was designed to extract NGHs from the hydrate-bearing layer and natural gas from the underlying shallow gas layer. Co-production via dual horizontal wells expanded the hydrate dissociation zone from the near-wellbore region to deeper strata, particularly enhanced the dissociation of NGHs in the region between the two horizontal wells. By the 10th year of simulation, the peak and cumulative volume rate of CH₄ released from hydrate dissociation increased to 3.52 and 1.45 times under the co-production scenario, resulting in a 2.4-fold improvement in NGH recovery efficiency. Sensitivity analyses of bottom hole pressure and length of the horizontal intervals revealed that reducing bottom hole pressure significantly improved the daily and accumulative gas production from hydrate-bearing reservoirs. The length of horizontal intervals emerged as a critical factor influencing the dissociation of NGHs, whereas it had negligible impact on gas production from shallow gas reservoir with satisfied permeability. This study provides insights into optimizing the development of marine hydrate resources via integrated exploitation strategies. Full article