Search Results (229)

To promote the development of long-distance high-speed underwater optical wireless communication (UWOC) based on visible light, this study proposes a high-bandwidth UWOC system based on micro-light-emitting-diodes (micro-LEDs) adopting the Non-Return-to-Zero On-Off Keying (NRZ-OOK) modulation. The numerical simulations reveal that optimizing the structural parameters of gallium nitride (GaN)-based micro-LED through dimensional scaling and quantum well layer reduction may significantly enhance optoelectronic performance, including modulation bandwidth and luminous efficiency. Moreover, experimental validation demonstrated maximum real-time data rates of 420 Mbps, 290 Mbps, and 250 Mbps at underwater distances of 2.3 m, 6.9 m, and 11.5 m, respectively. Furthermore, the underwater audio communication was successfully implemented at an 11.5 m UWOC distance at an ultra-low level of incoming optical power (12.5 µW) at the photodetector (PD) site. The channel characterization yielded a micro-LED-specific attenuation coefficient of 0.56 dB/m, while parametric analysis revealed wavelength-dependent degradation patterns, exhibiting positive correlations between both attenuation coefficient and bit error rate (BER) with operational wavelength. This study provides valuable insights for optimizing underwater optical systems to enhance real-time environmental monitoring capabilities and strengthen security protocols for subaquatic military communications in the future. Full article

Vanadium nitride (VN) ceramic layers were deposited on 304L stainless steel specimens by direct current (DC) magnetron sputtering in an Ar/N₂ gas mixture at substrate temperatures of 250 °C, 300 °C, and 350 °C. The obtained films were evaluated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). The results showed the existence of VN and V₂N phases in the as-deposited coatings. It was found that the surface roughness parameter (Ra = 10 nm) decreased with increasing substrate temperatures up to 350 °C. The highest hardness (10.6 GPa) was achieved in the layer produced at 300 °C. The low values of plastic and elastic deformation, as well as a low friction coefficient (0.38), led to an enhancement in the coatings’ tribological properties. The film’s thickness increased with increasing temperature due to the presence of nucleation centers in the films. The highest thickness (557 nm) was achieved in the layer deposited at 350 °C. The electrochemical tests exhibited reliable protection against corrosion in strongly aggressive electrolytes. It has been proven that the temperature significantly affects the ceramic coatings’ structural, morphological, tribological, and corrosion properties. Full article

The electrical properties of contacts to p-type nitride semiconductor devices, based on gallium nitride, were simulated by ab initio and drift-diffusion calculations. The electrical properties of the contact are shown to be dominated by the electron-transfer process from the metal to GaN, which is related to the Fermi-level difference, as determined by both ab initio and model calculations. The results indicate a high potential barrier for holes, leading to the non-Ohmic character of the contact. The electrical nature of the Ni–Au contact formed by annealing in an oxygen atmosphere was elucidated. The influence of doping on the potential profile of p-type GaN was calculated using the drift-diffusion model. The energy-barrier height and width for hole transport were determined. Based on these results, a new type of contact is proposed. The contact is created by employing multiple-layer implantation of deep acceptors. The implementation of such a design promises to attain superior characteristics (resistance) compared with other contacts used in bipolar nitride semiconductor devices. The development of such contacts will remove one of the main obstacles in the development of highly efficient nitride optoelectronic devices, both LEDs and LDs: energy loss and excessive heat production close to the multiple-quantum-well system. Full article

Chromium–aluminum nitride (CrAlN) coatings were deposited on polished H13 tool steel substrates using direct current (DC) magnetron sputtering. The Cr/Al composition in the target was varied by inserting either four or eight chromium (Cr) plugs into cavities machined into an aluminum (Al) plate target. Nitrogen was introduced as a reactive gas to facilitate the formation of the nitride phase. Coatings were deposited at substrate bias voltages of −30 V, −50 V, and −60 V to study the combined effects of composition and ion energy on coating properties. Compositional analysis of coatings deposited at a −50 V bias revealed Cr/Al ratios of approximately 0.8 and 1.7 for the 4- and 8-plug configurations, respectively. This increase in the Cr/Al ratio led to a 2.6-fold improvement in coating hardness. Coatings produced using the eight-Cr-plug target exhibited a nearly linear increase in hardness with increasing substrate bias voltage. Cross-sectional scanning electron microscopy revealed a uniform bilayer structure consisting of an approximately 0.5 µm metal interlayer beneath a 2–3 µm CrAlN coating. Surface morphology analysis indicated the presence of coarse microdroplets in coatings with the lower Cr/Al ratio. These microdroplets were significantly suppressed in coatings with higher Cr/Al content, especially at increased bias voltages. This suppression is likely due to enhanced ion bombardment associated with the increased Cr content, attributed to Cr’s relatively higher atomic mass compared to Al. Coatings with lower hardness exhibited greater scratch resistance, likely due to the influence of residual compressive stresses. The findings highlight the critical role of both Cr/Al content and substrate bias in tailoring the tribo-mechanical performance of PVD CrAlN coatings for wear-resistant applications. Full article

During the last few years, the requirements for highly efficient, sustainable, and versatile materials in modern biomedicine, aircraft and aerospace industries, automotive production, and electronic and electrical engineering applications have increased. This has led to the development of new and innovative methods for material modification and optimization. This can be achieved in many different ways, but one such approach is the application of surface thin films. They can be conductive (metallic), semi-conductive (metal-ceramic), or isolating (polymeric). Special emphasis is placed on applying semi-conductive thin films due to their unique properties, be it electrical, chemical, mechanical, or other. The particular thin films of interest are composite ones of the type of transition metal oxide (TMO) and transition metal nitride (TMN), due to their widespread configurations and applications. Regardless of the countless number of studies regarding the application of such films in the aforementioned industrial fields, some further possible investigations are necessary to find optimal solutions for modern problems in this topic. One such problem is the possibility of characterization of the applied thin films, not via textbook approaches, but through a simple, modern solution using their electrical properties. This can be achieved on the basis of measuring the films’ electrical impedance, since all different semi-conductive materials have different impedance values. However, this is a huge practical work that necessitates the collection of a large pool of data and needs to be based on well-established methods for both characterization and formation of the films. A thorough review on the topic of applying thin films using physical vapor deposition techniques (PVD) in the field of different modern applications, and the current results of such investigations are presented. Furthermore, current research regarding the possible methods for applying such films, and the specifics behind them, need to be summarized. Due to this, in the present work, the specifics of applying thin films using PVD methods and their expected structure and properties were evaluated. Special emphasis was paid to the electrical impedance spectroscopy (EIS) method, which is typically used for the investigation and characterization of electrical systems. This method has increased in popularity over the last few years, and its applicability in the characterization of electrical systems that include thin films formed using PVD methods was proven many times over. However, a still lingering question is the applicability of this method for backwards engineering of thin films. Currently, the EIS method is used in combination with traditional techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDX), and others. There is, however, a potential to predict the structure and properties of thin films using purely a combination of EIS measurements and complex theoretical models. The current progress in the development of the EIS measurement method was described in the present work, and the trend is such that new theoretical models and new practical testing knowledge was obtained that help implement the method in the field of thin films characterization. Regardless of this progress, much more future work was found to be necessary, in particular, practical measurements (real data) of a large variety of films, in order to build the composition–structure–properties relationship. Full article

Silicon nitride (Si₃N₄) ceramic is widely used in the production of structural components. The surface wettability is closely related to the service life of materials. Laser surface texturing is considered an effective method for controlling surface wettability by processing specific patterns. This research focused on the laser surface texturing of a Si₃N₄ ceramic, employing rectangular patterns instead of the typical dimple designs, as these had promising applications in heat transfer and hydrodynamic lubrication. The effects of scanning speed and number of scans on the change of the morphologies and dimensions of the grooves were investigated. The results indicated that the higher scanning speed and fewer number of scans resulted in less damage to the textured surface. As the scanning speed increased, the width and depth of the grooves decreased significantly first, and then fluctuated. Conversely, increasing the number of scans led to an increase in the width and depth of the grooves, eventually stabilizing. The analysis of the elemental composition of different areas on the textured surface presented a notable increase in oxygen content at the grooves, while Si and N levels decreased. It was mainly caused by the chemical reaction between Si₃N₄ ceramic and oxygen during laser surface texturing in an air environment. This study also assessed the wettability of the textured surface, finding that the contact angle of the water droplet was significantly affected by the groove dimensions. After laser surface texturing, the contact angle increased from 35.51 ± 0.33° to 57.52 ± 1.83°. Improved wettability was associated with smaller groove volume, indicating better hydrophilicity at lower scanning speed and enhanced hydrophobicity with a fewer number of scans. Full article

To improve the performance of superhard ceramic composites, this study aims to develop a dense, phase-pure, and uniform TiN coating on cubic boron nitride (cBN) particles with a target thickness of at least 150 nm. TiN coatings were applied using atomic layer deposition (ALD) alone, as well as a combined ALD/chemical vapor deposition (CVD) process. While ALD produced uniform and dense coatings, the thickness remained below 50 nm. The combined ALD/CVD approach achieved greater thicknesses up to 500 nm, though coating homogeneity remained a challenge. Optimization efforts, including increased ALD cycles and reduced CVD pressure, led to improved coating uniformity, with 25%–30% of particles coated to thicknesses ≥ 80 nm. Structural analysis confirmed dense, pore-free TiN_1−x layers for all synthesized powders. In contrast, the commercial reference powder showed a non-uniform, multiphase coating (α − Ti, Ti₂N, and TiN_0.53) with defects. While the ALD/CVD powders exhibited better phase purity than the commercial sample, further optimization is needed to achieve consistent coatings above 150 nm. These results suggest the ALD/CVD route is promising for producing coatings suitable for use in ceramic matrix composites. Full article

A variational formulation and variationally consistent boundary conditions were derived for a coupled system of two boron nitride nanotubes (BNNTs), with the piezoelectric and surface effects taken into account in the formulation. The coupling between the nanotubes was defined in terms of Winkler and Pasternak interlayers. The equations governing the vibrations of the coupled system were expressed as a system of four partial differential equations based on nonlocal elastic theory. After deriving the variational principle for the double BNNT system, Hamilton’s principle was expressed in terms of potential and kinetic energies. Next, the differential equations for the free vibration case were presented and the variational form for this case was derived. The Rayleigh quotient was formulated for the vibration frequency, which indicated that piezoelectric and surface effects led to higher vibration frequencies. Next, the variationally consistent boundary conditions were formulated in terms of moment and shear force expressions. It was observed that the presence of the Pasternak interlayer between the nanotubes led to coupled boundary conditions when a shear force and/or a moment was specified at the boundaries. Full article

This study explored advancements in photovoltaic technologies by enhancing the electronic quality of multicrystalline silicon (mc-Si) through silicon nitride (SiN_x) and hydrogen (H₂) plasma deposition via plasma-enhanced chemical vapor deposition (PECVD). This innovative approach replaced toxic chemical wet processes with H₂ plasma and SiN_x. The key parameters of silicon solar cells, including the effective lifetime (τ_eff), diffusion length (L_diff), and iron concentration ([Fe]), were analyzed before and after this sustainable solution. The results show significant improvements, particularly in the edge region, which initially exhibited a low τ_eff and a high iron concentration. After the treatment, the τ_eff and L_diff increased to 7 μs and 210 μm, respectively, compared to 2 μs and 70 μm for the untreated mc-Si. Additionally, the [Fe] decreased significantly after the process, dropping from 60 ppt to 10 ppt in most regions. Furthermore, the treatment led to a significant decrease in reflectivity, from 25% to 8% at a wavelength of 500 nm. These findings highlight the effectiveness of the PECVD-SiN_x and H₂ plasma treatments for improving the optoelectronic performance of mc-Si, making them promising options for high-efficiency photovoltaic devices. Full article

The development of photothermal-assisted photocatalytic systems with broad-spectrum solar utilization and high charge separation efficiency remains a critical challenge for antibiotic degradation. Herein, we report novel black g-C₃N₄ (BCN) materials synthesized via a one-step thermal copolymerization strategy using C/N precursors and tetrachlorofluorescein. After the introduction of tetrachlorofluorescein, the color of the sample changes, which gives BCN enhanced light absorption and a significant photothermal effect for poorly heating-assisted photocatalysis. The synergistic coupling of photothermal and photocatalytic processes enabled the optimal BCN-U sample to achieve exceptional degradation efficiency (89% within 120 min) for a typical antibiotic (e.g., tetracycline) under an LED lamp as the visible light source, outperforming conventional yellow g-C₃N₄ (YCN-U) by a factor of 1.37. Mechanistic studies revealed that the photothermal effect facilitates carrier separation via thermal-driven electron excitation while accelerating reactive oxygen species (•OH and •O₂⁻) generation. The synergistic interplay between photocatalysis and photothermal effects, which improved mass transfer, ensures robust stability, which provides new insights into designing dual-functional carbon nitride-based materials for sustainable environmental remediation. Full article

A novel Ti-N-O composite was prepared by powder nitriding/oxynitriding combined with the spark plasma sintering (SPS) method. The effects of N/O on the microstructure and mechanical properties of the Ti-N-O alloy were systematically studied. The results showed that the addition of N/O elements significantly improved the mechanical properties of commercially pure titanium (cp-Ti). The hardness reached 298.8 HV0.1 while the yield strength can reach 666 MPa. And, the O element played a leading role in regulating the microstructure and morphology of the Ti-N-O alloy. With the addition of the O element, the microstructure showed an equiaxed structure, and the characterization showed that this region is an O-enriched region, and that a small amount of nano-TiO₂ particles appeared in the alloy, which together led to the change in the microstructure. At the same time, more large-angle grain boundaries were generated in the Ti-N-O alloy. This study investigated a new method for the preparation of titanium materials and provides new ideas for researching medical titanium materials. Full article

This study investigates the influence of hexagonal boron nitride (h-BN) particle size and concentration on the tribological performance of lithium and calcium greases. Formulations containing h-BN nanoparticles and microparticles at 1%, 3%, 5%, and 10% by weight were evaluated in ball-on-flat reciprocating tests under three load conditions. The tests were conducted using a steel ball and a steel plate. The most favorable results were obtained for greases with 3% h-BN, characterized by an average particle size of 130 nm and the highest nanoparticle content. In lithium grease, this formulation reduced friction by up to 9.7% and wear by up to 69.2% compared to the base grease. In calcium grease, the same additive concentration led to reductions of up to 18.2% in friction and 70.2% in wear. Tribological performance was significantly influenced by the type of base grease, which affected the dispersion of the additive and its ability to form protective surface layers. SEM/EDS analysis of the surfaces after testing revealed that the dominant lubrication mechanisms included shearing-sliding and surface-mending effects. This study confirms that h-BN—especially in nanoparticle form—is an effective additive for improving the performance of greases. Full article

Integrated light-emitting diodes (LEDs) with waveguides play an important role in applications such as augmented reality (AR) displays, particularly regarding coupling efficiency optimization. Quantum dot light-emitting diodes (QLEDs), an emerging high-performance optoelectronic device, demonstrate substantial potential for next-generation display technologies. This study investigates the influence of microcavity modulation on the output of QLEDs coupled with a silicon nitride (SiNx) waveguide by simulating a white light QLED (W-QLED) with a broad spectrum and mixed RGB QDs (RGB-QLED) with a comparatively narrower spectrum. The microcavity converts both W-QLED and RGB-QLED emissions from broadband white-light emissions into narrowband single-wavelength outputs. Specifically, both of them have demonstrated wavelength tuning and full-width at half-maximum (FWHM) narrowing across the visible spectrum from 400 nm to 750 nm due to the microcavity modulation. The resulting RGB-QLED achieves a FWHM of 11.24 nm and reaches 110.76% of the National Television System Committee 1953 (NTSC 1953) standard color gamut, which is a 20.95% improvement over W-QLED. Meanwhile, due to the Purcell effect of the microcavity, the output efficiency of the QLED coupled with a SiNx waveguide is also significantly improved by optimizing the thickness of the Ag anode and introducing a tilted reflective mirror into the SiNx waveguide. Moreover, the optimal output efficiency of RGB-QLED with the tilted Ag mirror is 10.13%, representing a tenfold increase compared to the sample without the tilted Ag mirror. This design demonstrates an efficient and compact approach for the near-eye full-color display technology. Full article

This work studied the effect of self-protective paste nitriding (SPN) and ion plasma nitriding (IPN) on the surface chemistry, microstructure, and nanohardness of AISI 304 and 316L stainless steels, with both treated at 440 °C for 5 h. Surface modifications analyzed using SEM and nanoindentation revealed distinct outcomes. SPN induced an oxynitriding effect due to the oxidation properties of the pastes, forming Fe₃O₄ and Fe_xC phases, while IPN produced an expanded austenite layer. Both methods enhanced surface nanohardness, but SPN showed superior results. For 316L SS, SPN increased nanohardness by 367.81% (6.83 GPa) compared to a 133.5% increase (3.41 GPa) with IPN. For 304 SS, SPN improved nanohardness by 26% (2.23 GPa), whereas IPN reduced it by 48% (0.92 GPa). These findings highlight SPN’s potential as an effective anti-wear treatment, particularly for 316L SS. The SPN process utilized a eutectic mixture of sodium cyanate and sodium carbonate, while IPN employed a N₂:H₂ (1:1) gas mixture. SEM analyses confirmed the formation of γ-Fe(N) phases, indicating dispersed iron nitrides (FeN, Fe₃N, Fe₄N). SPN’s simultaneous oxidation and nitrocarburization led to an oxide layer above the nitride diffusion layer, enhancing mechanical properties through iron oxides (Fe₃O₄) and carbides (Fe_xC). Comparative analysis showed that AISI 316L exhibited better performance than AISI 304, underscoring SPN’s effectiveness for surface modification. Full article

The growing global demand for sustainable energy solutions has led to increased interest in kinetic energy harvesting as a viable alternative to traditional power sources. High-foot-traffic environments, such as public spaces and religious sites, generate significant mechanical energy that often remains untapped. This study explores energy-harvesting technologies applicable to public areas with heavy foot traffic, focusing on Al-Haram Mosque in Saudi Arabia—one of the most densely populated religious sites in the world. The research investigates the potential of piezoelectric, triboelectric, and hybrid systems to convert pedestrian foot traffic into electrical energy, addressing challenges such as efficiency, durability, scalability, and integration with existing infrastructure. Piezoelectric materials, including PVDF and BaTiO₃, effectively convert mechanical stress from footsteps into electricity, while triboelectric nanogenerators (TENGs) utilize contact electrification for lightweight, flexible energy capture. In addition, this study examines material innovations such as 3D-printed biomimetic structures, MXene-based composites (MXene is a two-dimensional material made from transition metal carbides, nitrides, and carbonitrides), and hybrid nanogenerators to improve the longevity and scalability of energy-harvesting systems in high-density footfall environments. Proposed applications for Al-Haram Mosque include energy-harvesting mats embedded with piezoelectric and triboelectric elements to power IoT devices, LED lighting, and environmental sensors. While challenges remain in material degradation, scalability, and cost, emerging hybrid systems and advanced composites present a promising pathway toward sustainable, self-powered infrastructure in large-scale, high-foot-traffic settings. These findings offer a transformative approach to energy sustainability, reducing reliance on traditional energy sources and contributing to Saudi Arabia’s Vision 2030 for renewable energy adoption. Full article