Search Results (5,159)

Chlorpyrifos CPF (O,O-diethyl O-(3,5,6-trichloro-2-pyridyl) phosphorothioate), known also as Chlorpyrifos-ethyl, is one of the most utilized organophosphorus pesticides worldwide. Additionally, CPF could be used as a chemical warfare agent surrogate. Although its acute toxicity is not high, it is responsible for both a large number of intoxications and chronic, delayed neurological effects. In this work, it is reported for the first time the qualitative and quantitative response produced by CPF vapors, using a pocket-held Time-of-Flight Ion Mobility Spectrometer (ToF IMS) with a non-radioactive ionization source and ammonia doping, model LCD-3.2E (Smiths Detection Ltd.), operated near ambient temperature (below 30 °C). Spectra of CPF in positive ion mode included two distinct product ion peaks; thus, identification of CPF vapors by IMS relies on these peaks—the monomer M·NH₄⁺ with reduced ion mobility K₀ = ca. 1.76 cm²V⁻¹s⁻¹ and the dimer M₂·NH₄⁺ with K₀ = ca. 1.47 cm²V⁻¹s⁻¹ (where M may be assignable to CPF molecule)—and positive reactant ions (Pos RIP) have K₀ = ca. 2.25 cm²V⁻¹s⁻¹. Excellent sensitivity, with a limit of detection LOD of 0.72 ppb_v (10.5 μg m⁻³) and a limit of quantification LOQ of 2.41 ppb_v (35.1 μg m⁻³), has been noticed; linear response was up to 100 ppb_v, while saturation occurs over ca. 1000 ppb_v (14.6 mg m⁻³). Our results demonstrate that this method provides a robust tool for both off-site and on-site detecting and quantifying CPF vapors at trace levels, which has strong implications for either industrial hygiene or forensic investigations concerning the pesticide Chlorpyrifos, as well as for monitoring of environmental contamination by organophosphorus pesticides. Full article

Armed conflicts continue to severely impact human populations and essential infrastructure, particularly water supply systems. This study examines the Yechilla area, a high-intensity battle corridor during the Tigray (between 12°15′26″ 14°57′49″ N latitude; and 36°20′57″–39°58′54″ E longitude) war (2020–2022). Using Cochran’s formula, a representative sample of 89 water schemes was selected for onsite assessment. Additional data on damages to water offices, personnel, equipment, and related infrastructure were gathered through face-to-face interviews with local officials and water professionals, onsite visits, and reviews of governmental and non-governmental archives, and previous studies. The findings reveal that 48.3% of water schemes in the study area are non-functional (does not deliver water), which is a significant increase from pre-war non-functionality rates of approximately 7.1% regionally and 21.1% nationally. Despite the Pretoria peace agreement, non-functionality levels remain critically high two years after conflict. Damage includes partial impairments, lack of technical and spare part support, complete destruction, and looting of water scheme components. The widespread destruction of civilian water infrastructure during the Tigray conflict underscores the insufficiency of existing international legal frameworks, such as the International Humanitarian Law and International Water Law, which are inadequately protecting civilians and their property. Understanding the broader consequences of armed conflicts requires examining the indirect effects and the complex interactions within and between social, economic, and environmental systems. These interconnected impacts are essential to fully grasp how conflict affects livelihoods and human security on a wider scale. Full article

The exponential increase in environmental pollutants due to industrialization, urbanization, and agricultural intensification has underscored the urgent need for sensitive, selective, and real-time monitoring technologies. Among emerging analytical tools, organic fluorescent sensors have demonstrated exceptional potential for detecting a wide range of pollutants in water, air, and soil, with a limit of detection (LOD) in the pM–µM range. This review critically examines recent advances in organic fluorescent sensors, focusing on their photophysical properties, molecular structures, sensing mechanisms, and environmental applications. Key categories of organic sensors, including small molecules, polymeric materials, and nanoparticle-based systems, are discussed, highlighting their advantages, such as biocompatibility, tunability, and cost-effectiveness. Comparative insights into inorganic fluorescent sensors, including quantum dots, are also provided, emphasizing their superior photostability and wide operating range (in some cases from pg/mL up to mg/mL) but limited biodegradability and higher toxicity. The integration of nanomaterials and microfluidic systems is presented as a promising route for developing portable, on-site sensing platforms. Finally, the review outlines current challenges and future perspectives, suggesting that fluorescent sensors, particularly organic ones, represent a crucial strategy toward sustainable environmental monitoring and pollutant management. Full article

A surface molecularly imprinted ratiometric fluorescent sensor (Eu/CDs@SiO₂@IIPs) was constructed for the selective and visual detection of Cu²⁺. The sensor integrates blue-emitting carbon dots as an internal reference and a custom-designed Eu(III) complex, Eu(MAA)₂(2,9-phen), as both the functional and fluorescent monomer within a surface-imprinted polymer layer, enabling efficient ratiometric fluorescence response. This structural design ensured that all fluorescent monomers were located at the recognition sites, thereby reducing background fluorescence interference and enhancing the accuracy of signal changes. Under optimized conditions, the sensor exhibited a detection limit of 2.79 nM, a wide linear range of 10–100 nM, and a rapid response time of 3.0 min. Moreover, the uncoordinated nitrogen atoms in the phenanthroline ligand improved resistance to interference from competing ions, significantly enhancing selectivity. Practical applicability was validated by spiked recovery tests in deionized and river water, with results showing good agreement with ICP-MS analysis. These findings highlight the potential of Eu/CDs@SiO₂@IIPs as a sensitive, selective, and portable sensing platform for on-site monitoring of Cu²⁺ in complex water environments. Full article

The recent growing adversarial activity against critical systems, such as the power grid, has raised attention on the necessity of appropriate measures to manage the related risks. In this setting, our research focuses on developing tools for early detection of adversarial activities, taking into account the specificities of the energy sector. We developed a framework to design and deploy AI-based detection models, and since one cannot risk disrupting regular operation with on-site tests, we also included a testbed for evaluation and fine-tuning. In the test environment, adversarial activity that produces realistic artifacts can be injected and monitored, and evidence analyzed by the detection models. In this paper we concentrate on the emulation of attacks inside our framework: A tool called SecuriDN is used to define, through a graphical interface, the network in terms of devices, applications, and protection mechanisms. Using this information, SecuriDN produces sequences of attack steps (based on the MITRE ATT&CK project) that are interpreted and executed by software called Netsploit. A case study related to Distributed Energy Resources is presented in order to show the process stages, highlight the possibilities given by our framework, and discuss possible limitations and future improvements. Full article

To explore the coupling between agricultural farming models and surface water environmental in central China’s irrigation districts, this study focuses on the Four Lakes Basin within Jianghan Plain, a key grain-producing and ecological protection area. Integrating remote sensing images, statistical yearbooks, and on-site monitoring data, the study analyzed the phased characteristics of the basin’s agricultural pattern transformation, the changes in non-point source nitrogen and phosphorus loads, and the responses of water quality in main canals and Honghu Lake to agricultural adjustments during the period 2010~2023. The results showed that the basin underwent a significant transformation in agricultural patterns from 2016 to 2023: the area of rice-crayfish increased by 14%, while the areas of dryland crops and freshwater aquaculture decreased by 11% and 4%, respectively. Correspondingly, the non-point source nitrogen and phosphorus loads in the Four Lakes Basin decreased by 11~13%, and the nitrogen and phosphorus concentrations in main canals decreased slightly by approximately 2 mg/L and 0.04 mg/L, respectively; however, the water quality of Honghu Lake continued to deteriorate, with nitrogen and phosphorus concentrations increasing by approximately 0.46 mg/L and 0.06 mg/L, respectively. This indicated that the adjustment of agricultural farming models was beneficial to improving the water quality of main canals, but it did not bring about a substantial improvement in the sustainable development of Honghu Lake. This may be related to various factors that undermine the sustainability of the lake’s aquatic ecological environment, such as climate change, natural disasters, internal nutrient release from sediments, and the decline in water environment carrying capacity. Therefore, to advance sustainability in this basin and similar irrigation districts, future efforts should continue optimizing agricultural models to reduce nitrogen/phosphorus inputs, while further mitigating internal nutrient release and climate disaster risks, restoring aquatic vegetation, and enhancing water environment carrying capacity. Full article

This study addresses the issue of coordinated development of coal, oil, and gas resources in the Yulin-Shenmu Coalfield. Taking the 132,201 working face of the Xiaobaodang No. 1 Coal Mine as a case study, the study combines FLAC^3D numerical simulation with on-site monitoring to analyze the impact of mining activities on the stability of gas well casings. Simulation results indicate that mining activities cause stress redistribution in the surrounding rock, with a maximum shear stress of 5.8 MPa, which is far below the shear strength of the casing. The maximum horizontal displacement of the wellbore is only 23 mm, with uniform overall deformation and no shear failure. On-site monitoring showed that the airtightness was intact, and the wellbore diameter test did not detect any destructive damage such as deformation or cracks. Concurrently, fiber optic strain monitoring of the inner and outer casings aligns with simulation results, confirming no significant instability caused by mining activities. The conclusion is that mining activities have a negligible impact on the stability of the gas well casing-concrete composite structure. The dual casing-cement ring structure effectively coordinates deformation to ensure safety. This finding provides a reliable technical basis for the coordinated exploitation of coal, oil and gas resources at the Xiaobaodang No. 1 Coal Mine and similar mines. Full article

Urban school environments often face significant thermal discomfort due to extensive paved surfaces, limited vegetation, and outdated building designs. This study examines how green spaces can mitigate temperature extremes and improve thermal comfort at two secondary schools in Coimbra, Portugal: Escola Secundária José Falcão (ESJF) and Escola Secundária D. Dinis (ESDD). Using a mixed-methods approach that combined school community surveys with on-site microclimatic measurements, we integrated user feedback on comfort with data on temperature and humidity variations across different indoor and outdoor spaces. Results revealed that tree-shaded areas consistently maintained lower air temperatures and higher relative humidity than unshaded zones, which experienced intense heat accumulation—up to a 5 °C difference. At ESJF, the older infrastructure and large asphalt surfaces led to severe heat retention, with east-facing classrooms recording the highest indoor temperatures. ESDD’s pavilion-style layout and existing green spaces provided comparatively better thermal conditions, although insufficient vegetation maintenance and limited shade reduced their effectiveness. The findings demonstrate a clear correspondence between the school community’s perceptions of thermal comfort and the measured microclimatic data. Vegetation—particularly deciduous trees—plays a critical role in cooling the school microclimate through shading and evapotranspiration. Strategic interventions such as expanding tree cover in high-exposure areas, installing green roofs and walls, and carefully selecting species can significantly reduce temperature extremes and improve outdoor usability. In addition, fostering environmental education and participatory co-design programs can encourage sustainable behaviors within the school community, underlining the importance of inclusive, nature-based solutions for climate adaptation. This research highlights that integrating green infrastructure in school design and management is a cost-effective strategy for thermal regulation. Green spaces, when co-designed with community involvement, not only enhance climate resilience and student well-being but also contribute to broader sustainable urban development goals. Full article

With the continuous progress and innovation of petroleum engineering technology, the development of new oilfield additives with superior environmental benefits has attracted widespread attention. Konjac glucomannan (KGM) is a natural resource characterized by abundant availability, low cost, biodegradability, and environmental compatibility. Konjac gum easily forms a weak gel network in water, but its water solubility and thermal stability are poor, and it is easily degraded at high temperatures. Therefore, its application in drilling fluid and fracturing fluid is limited. In this paper, a method of carboxymethyl modification of KGM was developed, and a carboxymethyl group was introduced to adjust KGM’s hydrogel forming ability and stability. Carboxymethylated Konjac glucomannan (CMKG) is a water-soluble anionic polysaccharide derived from natural Konjac glucomannan. By introducing carboxymethyl groups, CMKG overcomes the limitations of the native polymer, such as poor solubility and instability, while retaining its safe and biocompatible nature, making it an effective natural polymer additive for oilfield applications. The results show that when used as a drilling fluid additive, CMKG can form a stable three-dimensional gel network through molecular chain cross-linking, significantly improving the rheological properties of the mud. Its unique gel structure can enhance the encapsulation of clay particles and inhibit clay hydration expansion. When used as a fracturing fluid thickener, the viscosity of the gel system formed by CMKG at 0.6% (w/v) is superior to that of the weak gel system of KGM. The heat resistance/shear resistance tests confirm that the gel structure remains intact under high-temperature and high-shear conditions, meeting the sand-carrying capacity requirements for fracturing operations. The gel-breaking experiment shows that the system can achieve controlled degradation within 300 min, in line with on-site gel-breaking specifications. This modification process not only improves the rheological properties and water solubility of the CMKG gel but also optimizes the gel stability and controlled degradation through molecular structure adjustment. Full article

Red bricks serve as an important material for load-bearing or enclosing structures in traditional architecture and are widely used in construction projects both domestically and internationally. Fujian red bricks, due to geographical, trade, and immigration-related factors, have spread to Taiwan and various regions in Southeast Asia, giving rise to distinctive red brick architectural complexes. To further investigate the types of damage, such as cracking and missing bricks, that occur in traditional red brick buildings due to multiple factors, including climate and human activities, this study takes Fujian red brick buildings as its research subject. It employs the YOLOv12 rapid detection method to conduct technical support research on structural assessment, type detection, and damage localization of surface damage in red brick building materials. The experimental model was conducted through the following procedures: on-site photo collection, slice marking, creation of an image training set, establishment of an iterative model training, accuracy analysis, and experimental result verification. Based on this, the causes of damage types and corresponding countermeasures were analyzed. The objective of this study is to attempt to utilize computer vision image recognition technology to provide practical, automated detection and efficient identification methods for damage types in red brick building brick structures, particularly those involving physical and mechanical structural damage that severely threaten the overall structural safety of the building. This research model will reduce the complex manual processes typically involved, thereby improving work efficiency. This enables the development of customized intervention strategies with minimal impact and enhanced timeliness for the maintenance, repair, and preservation of red brick buildings, further advancing the practical application of intelligent protection for architectural heritage. Full article

Monitoring contamination in soil and food systems remains vital for ensuring environmental and public health, particularly in agriculture-intensive regions. Existing laboratory-based techniques are often time-consuming, equipment-dependent, and impractical for rapid on-site screening. In this study, we present a portable, non-faradaic electrochemical impedance-based sensing platform capable of simultaneously detecting Salmonella Typhimurium (S. Typhi) and Aflatoxin B1 in spiked soil run-off samples. The system employs ZnO-coated electrodes functionalized with crosslinker for covalent antibody immobilization, facilitating selective, label-free detection using just 5 µL of sample. The platform achieves a detection limit of 1 CFU/mL for S. Typhi over a linear range of 10–10⁵ CFU/mL and 0.001 ng/mL for Aflatoxin B1 across a dynamic range of 0.01–40.96 ng/mL. Impedance measurements captured with a handheld potentiostat were strongly correlated with benchtop results (R² > 0.95), validating its reliability in field settings. The duplex sensor demonstrates high precision with recovery rates above 80% and coefficient of variation below 15% in spiked samples. Furthermore, machine learning classification of safe versus contaminated samples yielded an ROC-AUC > 0.8, enhancing its decision-making capability. This duplex sensing platform offers a robust, user-friendly solution for real-time environmental and food safety surveillance. Full article

This study explores the evolving role of architecture centers in the digital age by analyzing the case of Casa da Arquitectura (CdA) in Porto, Portugal, a hybrid institution that functions as both archive and museum. Positioned within the broader context of museum digitization and liminality theory, the research investigates how CdA navigates the spatial, social, and procedural shifts inherent in digital transformation. Drawing on qualitative methods, including in-depth interviews with key personnel and on-site observations, the study examines the institution’s strategies in acquisition, curation, and exhibition design. The findings highlight CdA’s innovative approach to archival visibility, the creation of a multipurpose digital platform (“edifício digital”), and the integration of archival acquisitions with exhibition practices. These practices illustrate a condition of triple liminality of the digital museum concerning its process, position, and place. The study also discusses how digitization reconfigures the museum’s organizational model in terms of accessibility and curatorial complexity. By analyzing CdA’s operational and curatorial choices, the paper discusses how digital museums can act as speculative, process-oriented spaces that challenge traditional boundaries between archive and exhibition, physical and virtual, institutional and public. Full article

Quantifying deep soil (10–100 cm) and non-growing-season soil respiration (SR) is crucial for refining carbon (C) cycle models, yet the regulatory mechanisms governing these processes remain unclear. The novelty of this study lies in its focus on deep soils and non-growing seasons to elucidate how soil properties regulate SR under these special conditions. We conducted an on-site field experiment in the Caragana korshinskii plantation, measuring SR at soil depths of 0–10 cm, 10–50 cm, and 50–100 cm during the non-growing season and growing. The results suggested that the annual cumulative soil CO₂ fluxes reached 510.1 (0–10 cm), 131.5 (10–50 cm), and 45.3 g CO₂·m⁻² (50–100 cm). These emissions during the non-growing season accounted for 33%, 31%, and 32%, respectively. The soil physical properties (temperature, moisture, bulk density) explained the greatest variation in SR during growing and non-growing periods, followed by the biological properties (α-diversity, root biomass) and chemical properties (soil organic C, ammonium nitrogen, total C/nitrogen ratio). Depth-specific analysis demonstrated that soil physical properties explained the most SR variance at three depths with independent contributions of 78.9% (0–10 cm), 89.7% (10–50 cm), and 76.9% (50–100 cm). These values exceeded the independent contributions of chemical properties (70.3%, 70.9%, 60.0%) and biological properties (54.9%, 45.1%, 41.6%) at the corresponding depths. Overall, deep soil and non-growing season SR represent important C emission sources; excluding them may therefore substantially overestimate net C sequestration potential. Full article

Hakka traditional vernacular dwellings embody regionally specific climatic adaptation strategies. This study takes the Meizhou Guangludi enclosed house as a case study to evaluate its climate adaptability with longevity and passive survivability factors of the Hakka three-hall enclosed house under subtropical climatic conditions. A mixed research method is employed, integrating visualized parametric modeling analysis and on-site measurement comparisons to quantify wind, temperature, solar radiation/illuminance, and humidity, along with human comfort zone limits and building environment. The results reveal that nature erosion in the Guangludi enclosed house is the most pronounced during winter and spring, particularly on exterior walls below 2.8 m. Key issues include bulging, spalling, molding, and fractured purlins caused by wind-driven rain, exacerbated by low wind speeds and limited solar exposure, especially at test spots like the E8–E10 and N1–N16 southeast and southern walls below 1.5 m. Fungal growth and plant intrusion are severe where surrounding trees and fengshui forests restrict wind flow and lighting. In terms of passive survivability, the Guangludi enclosed house has strong thermal insulation and buffering, aided by the Huatai mound; however, humidity and day illuminance deficiencies persist in the interstitial spaces between lateral rooms and the central hall. To address these issues, this study proposes strategies such as adding ventilation shafts and flexible partitions, optimizing patio dimensions and window-to-wall ratios, retaining the spatial layout and Fengshui pond to enhance wind airflow, and reinforcing the identified easily eroded spots with waterproofing, antimicrobial coatings, and extended eaves. Through parametric simulation and empirical validation, this study presents a climate-responsive retrofit framework that supports the sustainability and conservation of the subtropical Hakka enclosed house. Full article

Filter wash water (FWW) from public swimming pools is a recoverable resource, yet full-scale evidence on safe on-site reuse with documented economics is scarce. We evaluated a full-scale integrated recovery unit (SOWA) installed at an indoor public pool. The SOWA system—sedimentation, granular filtration operated at a hydraulic loading rate (HLR) of 7.5–10 m³ m⁻² h⁻¹, ultrafiltration, and chlorine-dioxide (ClO₂) disinfection—was monitored for physicochemical and microbiological performance. Turbidity decreased from 23.1 nephelometric turbidity units (NTU) to 0.25 NTU; chemical oxygen demand, reported as the permanganate index (COD_Mn), fell from 10.4 to 1.6 mg O₂ L⁻¹; and total microbial count declined from 1.6 × 10⁴ to 30 colony-forming units per millilitre (CFU mL⁻¹). Indicator organisms (Escherichia coli, Intestinal enterococci and Pseudomonas aeruginosa) were not detected, and all quality criteria complied with national standards. At the Olender facility, monthly freshwater use dropped from 1700 to 1000 m³ after 24/7 SOWA operation, while combined chlorine was maintained at 0.12 mg Cl₂/L and no issues with chloroform were observed. The unit recovered 4.7 m³ h⁻¹ of FWW for non-potable uses. According to manufacturer catalogue data, the recovery process can reach up to 96%, enabling annual savings up to ~EUR 9000 and a payback of ~2 years under favourable tariffs and loads. Our outcomes are consistent with independent full-scale reuse trains (e.g., ultrafiltration/reverse osmosis) and with disinfection-by-product control strategies reported in the literature, and they align with international guidance for swimming-pool water reuse. This study provides a rare, end-to-end implementation at full scale, documenting continuous operation, verified microbial safety, regulatory compliance, quantified water and cost savings, and site-specific economics for a compact, multi-barrier FBW recovery system that can be directly transferred to similar facilities. Full article