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Keywords = optimization of bitumen–mineral composition

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26 pages, 7020 KB  
Article
Increasing the Adhesion of Bitumen to the Surface of Mineral Fillers through Modification with a Recycled Polymer and Surfactant Obtained from Oil Refining Waste
by Antonina Dyuryagina, Yuliya Byzova, Kirill Ostrovnoy, Alexandr Demyanenko, Aida Lutsenko and Tatyana Shirina
Polymers 2024, 16(5), 714; https://doi.org/10.3390/polym16050714 - 5 Mar 2024
Cited by 4 | Viewed by 2256
Abstract
The purpose of this study was to optimize the processes of wetting fillers by varying the content of such additives as a surfactant and polymer in bitumen–mineral compositions in order to achieve optimal performance. The cosine of the contact angle was used as [...] Read more.
The purpose of this study was to optimize the processes of wetting fillers by varying the content of such additives as a surfactant and polymer in bitumen–mineral compositions in order to achieve optimal performance. The cosine of the contact angle was used as a criterion for assessing the adhesion of the bitumen binder to the surface of crushed stone. The effect of the additives’ concentration on surface tension and adhesive efficiency in binary and ternary bitumen compositions was studied. The following chemicals were used as additives: the original product AS-1, industrial additive AMDOR-10, and used sealant AG-4I, a product based on polyisobutylene and petroleum oils. AS-1 was obtained from the oil refining waste in the laboratory of M. Kozybayev North Kazakhstan University. The ternary “bitumen–AG-4I–AS-1” composition provided a maximum decrease in the contact angle by 15.96° (gray crushed stone) and by 14.06° (red crushed stone) relative to original bitumen, providing better wettability of the mineral filler particles with the bitumen, and as a result, maximum adhesion between the bitumen and crushed stone. The optimal performance of the bitumen–mineral composition was recorded with the joint presence of additives in the bitumen: AS-1 at a level of 1.0 g/dm3 and AG-4I at a level of 1.0 g/dm3. Full article
(This article belongs to the Section Polymer Applications)
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16 pages, 1956 KB  
Article
Correlation Dependence between Hydrophobicity of Modified Bitumen and Water Saturation of Asphalt Concrete
by Antonina Dyuryagina, Yuliya Byzova, Kirill Ostrovnoy and Aida Lutsenko
Appl. Sci. 2023, 13(19), 10946; https://doi.org/10.3390/app131910946 - 3 Oct 2023
Cited by 2 | Viewed by 1754
Abstract
Improving the durability of asphalt concrete road surfaces by increasing their moisture resistance is an urgent task. Modified bituminous binders should be compacted into coatings with the lowest possible water saturation. The purpose of this study was to establish the effect of modifiers [...] Read more.
Improving the durability of asphalt concrete road surfaces by increasing their moisture resistance is an urgent task. Modified bituminous binders should be compacted into coatings with the lowest possible water saturation. The purpose of this study was to establish the effect of modifiers on the hydrophobicity of bituminous films in order to achieve minimum water saturation and to build a mathematical model of the wetting process with water. As modifiers, we used a product of amination of distillation residues of petrochemistry, waste sealing liquid (a solution of high molecular weight polyisobutylene in mineral oil), and a condensation product of polyamines and higher fatty acids. The water-repellent effect of modifiers was studied by measuring the contact angle of bituminous film with a water drop. The water saturation of asphalt concrete samples was determined by the amount of water absorbed by asphalt concrete at 20 °C. A close correlation was revealed between the hydrophobicity of modified bitumen and the water saturation of asphalt concrete. Generalized equations and a graphical representation of a function of several variables allowed for optimizing compositions by the content of modifiers to achieve the required performance properties of asphalt concrete coatings. Full article
(This article belongs to the Special Issue Validation and Measurement in Analytical Chemistry: Practical Aspects)
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23 pages, 10230 KB  
Article
Physical, Mechanical and Structural Characteristics of Sulfur Concrete with Bitumen Modified Sulfur and Fly Ash
by Sergey A. Stel’makh, Evgenii M. Shcherban’, Alexey N. Beskopylny, Levon R. Mailyan, Besarion Meskhi, Alexandr A. Shilov, Alexandr Evtushenko, Andrei Chernil’nik, Diana El’shaeva, Memduh Karalar, Yasin Onuralp Özkılıç and Ceyhun Aksoylu
J. Compos. Sci. 2023, 7(9), 356; https://doi.org/10.3390/jcs7090356 - 25 Aug 2023
Cited by 18 | Viewed by 3116
Abstract
Industrial waste usage in the technology of construction materials is currently in a relevant and promising direction. Materials made of industrial waste have a lower cost and are highly environmentally friendly. The objective of this study is to develop effective compositions of sulfur [...] Read more.
Industrial waste usage in the technology of construction materials is currently in a relevant and promising direction. Materials made of industrial waste have a lower cost and are highly environmentally friendly. The objective of this study is to develop effective compositions of sulfur concrete based on the maximum possible number of various wastes of the local industry for this and to investigate the characteristics of this composite. Test samples of sulfur concrete were made from sulfur, fly ash, mineral aggregates and bitumen additive. The dosages of fly ash, sand and bitumen varied, while the content of sulfur and crushed stone remained constant. The following main characteristics of sulfur concrete were determined: density; compressive strength; and water absorption. Tests of sulfur concrete were carried out after 1 day and 28 days of hardening. The best values of compressive strength (24.8 MPa) and water absorption (0.9%) were recorded for the composition of sulfur concrete at the age of 28 days with the following content of components: sulfur—25%, modified with 4% bitumen of its mass; fly ash—10%; crushed stone—40%; and sand—25%. The optimal composition of modified sulfur concrete showed compressive strength up to 78% more and water absorption up to 53% less than the control composition. The characteristics of the sulfur concrete samples after 28 days of hardening differ slightly from the values after 1 day of hardening (up to 1.8%). An analysis of the structure confirmed the effectiveness of the developed composition of sulfur concrete in comparison with the control. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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