Search Results (24)

This study investigates the effects of air pressure, glue pressure, and viscosity on atomization characteristics through experimental and simulation methods, aiming to reveal gas–liquid interaction mechanisms and optimize process parameters. The rheological parameters of aqueous polyurethane adhesives with varying viscosities were characterized. Spray characteristics, including spray angle, cured film diameter, and thickness, were quantitatively measured under different operating conditions. The internal flow field and droplet dynamics were numerically analyzed. The results indicate the following: Increasing the air pressure (from 0.3 to 0.7 MPa) enlarges the spray angle and film diameter while reducing the film thickness. In contrast, increasing the glue pressure enlarges all three parameters: spray angle, film diameter, and film thickness. Furthermore, increasing the viscosity within the test range reduces the spray angle, film diameter, and film thickness. These effects stem from enhanced gas kinetic energy and shear intensity (promoting liquid film fragmentation), an increased fluid flow rate with glue pressure, and strengthened droplet resistance to breakup with suppressed spreading at higher viscosities. This research provides useful criteria for nozzle design and the optimization of industrial atomization processes involving non-Newtonian adhesives. Full article

Surgical adhesives and glues have gained significant attention in the medical field due to their potential to replace traditional sutures and staples in various surgical applications. This review explores the evolution of biocompatible adhesives, focusing on their chemical composition, mechanical properties, and biocompatibility. We discuss the key challenges in developing these materials, including their adhesive strength, degradation rate, and tissue compatibility. The article also delves into regulatory frameworks governing their use in clinical settings and highlights the ongoing innovations aimed at enhancing their performance and safety. Finally, the review examines the current trends in the development of next-generation surgical adhesives, with an emphasis on environmentally friendly and bioresorbable options. The importance of multidisciplinary collaboration in advancing these materials for clinical use is also underscored. Full article

The seismic response of confined masonry (CM) walls, built from innovative hollow clay blocks featuring large thermal insulation cavities and bonded with polyurethane glue instead of thin-layer mortar, was investigated. A 3D micro-model was subsequently developed in Abaqus and validated against results from cyclic shear tests on full-scale CM wall specimens. Once validated, the model was utilized in an extensive parametric study to investigate the effects of openings on the walls. This parametric study considered the size of the opening, its position, the aspect ratio of the walls, and different sizes of tie-columns. The results showed that the size and placement of openings substantially and negatively affected seismic response, and that the detrimental effects can be alleviated by placing strong tie-columns next to the openings. Full article

This paper explores the effect of waste rubber grain size on the porosity, modulus of elasticity, thermal properties, and soundproofing performance of polymer composites with different thicknesses (10, 15, and 20 mm). All properties were tested in accordance with European standards, with the exception of porosity, which was measured using Archimedes’ principle. The findings indicate that with a consistent amount of polyurethane glue, finer rubber grains result in composites with higher porosity, leading to a lower modulus of elasticity but enhanced thermal and sound insulation. In contrast, coarser rubber grains produced composites with lower porosity and a higher modulus of elasticity, though with slightly reduced thermal insulation and significantly worse soundproofing. A combination of fine and coarse rubber grains provided a balanced performance, offering both good thermal and sound insulation while maintaining a high modulus of elasticity. Among the thicknesses tested, 15 mm was identified as optimal, combining a relatively high modulus of elasticity, low thermal conductivity, and better airborne sound insulation index. Future research will focus on applying this composite in concrete building products that meet noise protection and energy efficiency standards. Full article

Eucalyptus-based glued laminated timber (glulam) was produced to determine the feasibility of a non-destructive method (drilling resistance) to predict the properties of structural elements and add value to lower-quality hardwood species. Glulam was manufactured with formaldehyde (Resorcinol), reference condition, and bio-based (Castor oil-based) adhesives in two assembly schemes, the core composed either of two continuous lamellae each 105 cm long, or of two formed by the juxtaposition of shorter boards (35 and 55 cm). The shear strength of the glue line (f_v0), modulus of elasticity (E_c90), and strength (f_c90) in compression perpendicular to the grain; delamination (DL); and main and extended glue line thicknesses were evaluated. The Resistograph equipment was used to perform the perforation perpendicular to the glue line (samples extracted from the glulam elements) to correlate the properties. The results of this research demonstrate that the scheme of the boards had little effect on the physical and mechanical properties evaluated (except the main glue line and delamination), and the drilling resistance (DR) presents a significant correlation with practically all properties evaluated (variations in density values and other properties are explained by variations in DR values), making it possible to estimate E_c90 and f_c90 with desired precision (R²_adj ≈ 80%). This highlights the feasibility of using this methodology in the quality control of glulam elements. It is concluded that regardless of the adhesive, elements comprising a 105 cm-length core and external lamellae (T1 and control) are indicated for external use, presenting low delamination. Short-length central lamellae adhesively glued with PUR (T2) are not recommended for external applications due to their susceptibility to delamination. However, T2 is indicated for internal environments due to its low production cost. This study also proved the efficiency of using models based on drilling resistance to estimate wood density and its resistance to compression perpendicular to the fiber. Full article

The current level of packaging consumption imposes a need to fabricate single-use food packaging with renewable and compostable materials, such as bio-polyesters (e.g., polylactic acid, PLA and polybutylene succinate, PBS) or cellulose, but their use is still problematic. Fabrication of bio-compostable composites can specifically address impeding challenges, and adhesive lamination, achieved with compostable glue, is becoming more and more popular with respect to the less versatile hot lamination. In this context, plasma activation, a chemical-free oxidation technique of a material’s surface, is used to increase the affinity of three different biomaterials (cellulose, PLA and PBS) toward a compostable polyurethane adhesive to decrease its amount by gluing bio-polyesters to cellulose. Optical Microscopy reveals activation conditions that do not affect the integrity of the materials, while Water Contact Analyses confirm the activation of the surfaces, with contact angles decreased to roughly 50 deg in all cases. Unexpectedly, ζ-potential analyses and subtractive infrared spectroscopy highlight how the activation performed superficially etches cellulose, while for both PLA and PBS, a general decrease in surface potential and an increase in superficial hydroxyl group populations confirm the achievement of the desired oxidation. Thus, we rationalize continuous activation conditions to treat PLA and PBS and to glue them to neat cellulose. While no beneficial effect is observed with activated PLA, bi-laminate composites fabricated with activated PBS fulfill the benchmark for adhesion strength using less than before, while oxygen permeation analyses exclude plasma-induced etching even at a nanoscale. Full article

The evolution toward small-diameter and fast-growing plantation timbers such as the Pinus elliotti var. elliottii (Engelm) × Pinus caribaea var. hondurensis (Sénéclauze) (PEE×PCH) hybrids around the world is producing large volumes of core wood that are falling short of structural sawn timber grading requirements. Engineered timber products such as cross-laminated timber (CLT) and glue-laminated (glulam) offer potential solutions to value-adding this resource, but the bond performance of this feedstock and the extent to which current standards and guides address its common characteristics for bond performance need to be understood. This study investigated the bond quality and performance of clear defect-free, low stiffness out-of-grade PEE×PCH and evaluated this performance using the pass/fail criteria of the CLT bond performance requirements of three national CLT standards. 5-layer CLT delamination samples and shear block test samples were glued using one-component polyurethane (PUR). This process was repeated for common occurring characteristics in this resource of resin, knots, and pith to understand their impact and inform an evaluation on the need to restrict their inclusion. Clear samples had an average glue line delamination of 2.9% and an average glue line wood failure of 96.7%. Resin achieved 9.3% and 92.6%, respectively. While knots had the lowest performance at 24.4% and 77.4%, respectively. When pith was at or adjacent to the glue line, wood failure occurred through the pith and its immediate surrounding fiber. Shear strength and wood failure tests were carried out on glulam and CLT-oriented samples. CLT knot samples were tested in two load orientations. Glulam-oriented samples in clear, resin, pith, and knots achieved an average shear strength of 8.5 MPa, 8.2 MPa, 7.9 MPa, and 8.2 MPa, respectively, and wood failure of 86%, 85%, 90%, and 69%, respectively. CLT-oriented samples in clear and resin both achieved average shear strengths of 4.0 MPa; 0°-loaded and 90°-loaded pith samples achieved 3.6 MPa and 2.4 MPa, while 0°-loaded and 90°-loaded knot samples achieved 4.2 MPa and 4.7 MPa respectively. Average wood failures were 90%, 89%, 96%, 96%, 83%, and 51%, respectively. PRG320 was found to be the most restrictive standard. Resin, knots, and pith were not addressed in the evaluation of delamination or shear strength in any standard, and PRG320 was the only standard to restrict these characteristics over and above structural grading rules. The amount and type of characteristics present vary considerably in structurally graded wood, and even more so for this out-of-grade resource. It was determined that the negative impact that resin, knots, and pith have on bond quality and bond performance calls for some restriction of their inclusion in order to achieve the author’s interpretation of the intended bond performance requirements of the CLT standards, which currently do not address these characteristics well or at all. A proposed modification to the PRG320 effective bond area was presented as a proactive solution. Full article

Wood industries use thermal and thermomechanical treatments as ecological approaches to increase the durability of wood products, avoiding the need for chemical additives. In this regard, the aim of this study was to compare the physical and mechanical properties of plywood made from veneers treated at different temperatures using thermal and thermomechanical processes, with untreated panels serving as a control. The treatment process involved Pinus taeda veneers submitted to treatment in a hot press at 1.0 MPa in a laboratory oven at temperatures of 160 °C, 180 °C, and 200 °C for 30 min. For bonding the veneers, a vegetable-based polyurethane resin derived from castor oil with a grammage of 395 g/m² was used, applying pressing conditions at 90 °C, 0.6 MPa, and 10 min. Our results indicate that temperature significantly influences plywood properties, playing a key role in the choice of equipment for the treatment process. Regardless of the method employed, the treatment resulted in an improvement in the hydrophobicity of the veneers due to the decrease in hemicellulose content. Notably, the reduction in strength and stiffness caused by the loss of cell wall polymers was not statistically significant. The treatment was successful in softening the wood material, reducing roughness, and increasing wettability. Despite a minimum of 20% reduction in glue line tension, the samples still surpassed the 1 MPa mark, showing satisfactory results. This demonstrates the feasibility of adjusting treatment variables to ensure the proper use of this adhesive. Full article

In this study, the modulus of elasticity and flexural strength properties of laminated wood elements reinforced with steel mesh with different mesh openings were determined. In accordance with the purpose of the study, three- and five-layer laminated elements were produced from scotch pine (Pinus sylvestris L.) wood material, which is widely used in the wood construction industry in Türkiye. The 50, 70, and 90 mesh steel used as the support layer was placed between each lamella and pressed with polyvinylacetate (PVAc-D₄) and polyurethane (PUR-D₄) adhesives. Afterward, the prepared test samples were kept for 3 weeks at 20 °C temperature and 65 ± 5% relative humidity for 3 weeks. The flexural strength and modulus of elasticity in flexural of the prepared test samples were determined according to the TS EN 408: 2010+A1 standard by the Zwick universal tester. Multiple analysis of variance (MANOVA) was carried out using MSTAT-C 1.2 software to determine the effect of the modulus of elasticity and flexural strength on the obtained flexural properties, the mesh opening of the support layer, and the adhesive type. When the differences within or between groups were significant with a margin of error of 0.05, achievement rankings were made using the Duncan test on the basis of the least significant difference. According to the results of the research, the highest bending strength (120.3 N/mm²) was obtained in three-layer samples reinforced with 50 mesh steel wire and bonded with Pol-D4 glue, and the highest modulus of elasticity (8969.3 N/mm²) was obtained in three-layer samples reinforced with 50 mesh steel wire and bonded with Pol-D4 glue. As a result, the reinforcement of the laminated wood material with steel wire had an increasing effect on the strength. Accordingly, the use of 50 mesh steel wire can be recommended to increase mechanical properties. Full article

To give full play to the advantages of polyurethane as a binder, such as mixing at room temperature, short curing time, and high curing strength, polyurethane was used as the binder of a waste asphalt mixture, and the pavement performance of PCRM (Polyurethane Cold-Recycled Mixture) was analyzed. Firstly, the adhesion performance of polyurethane binder with new and old aggregates was evaluated using the adhesion test. Then, the mix proportion was designed according to the material characteristics, and the reasonable molding process, maintenance conditions, design indexes, and the optimal binder ratio were proposed. Secondly, the high-temperature stability, low-temperature crack resistance, water stability, and compressive resilient modulus of the mixture were evaluated through laboratory tests. Finally, the pore structure and microscopic morphology of polyurethane cold-recycled mixture were analyzed by industrial CT (Computerized Tomography) scanning, and the failure mechanism of polyurethane cold-recycled mixture was revealed. The test results show that the adhesion between polyurethane and RAP (Reclaimed Asphalt Pavement) is good, and the splitting strength of the mixture increases greatly when the ratio of glue to stone reaches 9%. Polyurethane binder has low sensitivity to temperature and poor water stability. With the increase of RAP content, the high-temperature stability, low-temperature crack resistance, and compressive resilient modulus of PCRM showed a decreasing trend. When the RAP content was less than 40%, the freeze–thaw splitting strength ratio of the mixture was improved. After the incorporation of RAP, the interface was more complex and there were many micron-scale holes, cracks, and other defects; after high-temperature immersion, the polyurethane binder appeared to show a certain degree of peeling at the holes of the RAP surface. After freeze–thaw, the polyurethane binder on the surface of the mixture produced many cracks. The study of polyurethane cold-recycled mixture is of great significance to realize green construction. Full article

The aim of this work was to verify the behavior of hybrid hardwood glue-laminated beams and the possibility of replacing Norway spruce (Picea abies) construction elements, especially in roof and ceiling structures. The samples were six lamellae homogeneous beech (Fagus sylvatica) beams and six-lamellae hybrid beech-poplar (Fagus sylvatica–Poplar spp.) beams; each beam had a cross-section of 60 × 120 mm and was glued with polyurethane adhesive. The samples were loaded using destructive four-point bending tests according to EN 408; the obtained bending strength and modulus of elasticity were statistically evaluated and compared to each other in both types of samples. The results showed that the examined properties of the hybrid beams (with a 16% weight reduction) are comparable to the properties of homogeneous beech glue-laminated beams. Based on the obtained data, the timber elements that are currently used can be successfully replaced by hardwood glue-laminated elements. Based on their higher load-bearing capacity, the cross-section depth can be reduced compared to a larger cross-section depth in spruce beams; this means that hardwood could be suitable in building renovations. Full article

This study aims to investigate the thermo-acoustic and hygrothermal properties of innovative panels made of leather waste produced by a bag factory from a circular economy perspective. Their performance was compared with other residual-based insulation panels. The leather scraps were chipped and three boards were fabricated by means of a mold with different compositions, adding adhesive glue. In order to improve the sustainability aspects, a sample was assembled by using a water-based polyurethane glue, in addition to the two panels with vinyl glue. Panels were tested for thermal, acoustic, and hygrothermal performance. Thermal conductivity values in the range of 0.064–0.078 W/mK at 10 °C were measured depending on the composition and the adhesive. A slight thermal performance deterioration occurs when using the natural water-based glue. The samples were characterized by good performance both in terms of sound absorption coefficient (Noise Reduction Coefficient NRC = 0.21–0.28) and Transmission Loss, up to 59 dB values. Water vapor resistance factor values in the 35–48 range were obtained, close to the values of standard materials, such as expanded polystyrene and polyurethane. Full article

Glued laminated (glulam) beams are used in the roofs, ceilings and walls of buildings as well as in bridges and towers. At present, with the limitation of tree harvesting, the production of glulam beams from recycled wood sources is implemented with the proviso that their mechanical properties and resistance to pests, fire and weathering will not be aggravated. This work deals with the primary effect of aging Norway spruce wood (Picea abies Karst. L.) lamellas on the moduli of rupture (MOR) and elasticity (MOE) in bending of three-layer glulam beams composed of sound and aged lamellas and polyurethane (PUR) glue. Three methods of lamella aging were used: (A) natural, lasting 60 years in the form of roof trusses with a greater or lesser degree of bio-attack by woodworm (Anobium punctatum De Geer); (B) artificial, caused by increased temperatures from 160 to 220 °C for 4 h; (C) artificial, caused by 2% water solutions of inorganic preservatives, namely, CuSO₄ × 5H₂O, ZnCl₂, H₃BO₃ or (NH₄)₂SO₄, for 28 days. The lowest MOR values were determined for glulam beams in which all three lamellas or two surface lamellas had a greater degree of bio-attack (60.5 MPa, a decrease of 25.9%) or were exposed to primary aging at 220 °C (62.6 MPa, a decrease of 23.3%). On the contrary, the exposure of lamellas to 160 or 180 °C did not significantly influence the MOR of beams (76.0–82.7 MPa, an average decrease of 1.6%). The MOE of glulam beams ranged from 7540 to 10,432 MPa without an obvious influence of the method of lamella aging or their location in the beams. Linear correlations between the MOR or MOE of glulam beams and the shear strength (σ) of glued joints, if both composite types consisted of similarly aged lamellas, were only slightly significant or insignificant. Full article

This study deals with the scanning electron microscopy (SEM) analyses of the phase interfaces in the glued joints between Norway spruce wood elements thermally modified at 160, 180, 200, and 220 °C/4 h and polyurethane (PUR) and polyvinyl acetate (PVAc) glues with the aim of evaluating various anatomical influences of wood on the quality of joints. Due to cracked regions created in the surface of spruce wood at severe thermal modifications, the penetration depth of glues doubled from 140 to 241 μm for PUR glue, and from 100 to 200 μm for PVAc glue. The thickness of glue lines in joints was apparently higher for PVAc glue, mainly in earlywood regions; however, in joints from thermally modified (TM) woods it increased more apparently for PUR glue from 16.6 to 44.4 μm, probably in connection with formation of micro-bubbles in its structure. The SEM analyses corresponded well with the previous knowledge about lower shear strength of glued joints formed from the more intensively TM spruce elements and mentioned types of glues. Full article

Plywood is widely used in civil construction. Due to the importance of preservation and gluing in bio-composites, this study compares the influence of a chemical treatment with CCA (chromated-copper-arsenate) on Pinus taeda L. wood veneers to produce two plywood types using phenol-formaldehyde (PF) and castor oil-based polyurethane (PU). Four different treatments were performed to analyze both varieties’ physical and mechanical properties. As a result, an improvement in the properties of the treated panels was observed. Lower moisture contents and better interactions caused by less thickness swelling and water absorption were identified in the PU-based plywoods. The treatment with CCA was efficient, improving these properties when they were compared to the reference panels. Most treatments evidenced increases in the modulus of elasticity and modulus of rupture for both adhesives when the CCA treatment was applied to the veneers. Comparing the resins, the PF showed the best values of modulus of elasticity. All treatments met the requirements defined by the Brazilian standard document for the glue line shear. Full article