Search Results (69)

The driving force behind protein translocation across the cell membrane is not yet fully understood. In bacteria, there is an electrochemical potential across the cell membrane, which can interact with charged residues in the translocation substrate. In this study, the protonation states of lysine and glutamate, serving as test residues in a peptide translocating across the bacterial channel SecYEG, are investigated by applying Poisson–Boltzmann continuum electrostatic free energy calculations and Monte Carlo titrations to snapshots of molecular dynamics (MD) simulations. A clear shift in protonation probability towards the uncharged state is found for both test residues as they move deeper into the channel. Thus, charge neutralization occurs irrespective of whether the original charge of the test residue is positive (lysine) or negative (glutamate). Electrostatic interactions of acidic and basic residues of SecYEG with the peptide cancel out. The main determinants of the test residue’s protonation state are the dielectric properties of its surroundings and interactions with non-titrating charges in the channel. Crucially, the membrane protein—including its water-filled pore—is assigned a low dielectric constant. The results are discussed in the context of the limitations inherent to continuum electrostatics and MD simulations with fixed protonation states. Full article

Bisphenol A (BPA) is an industrial chemical used primarily in the manufacture of polycarbonate plastics and epoxy resins. BPA is considered an endocrine-disrupting chemical (EDC) because it interferes with hormonal systems. Over the decades, several techniques have been proposed for BPA removal in wastewaters. This study discusses recent advancements and progress of effective techniques for BPA removal, including membrane, adsorption, advanced oxidation process (AOPs), and biodegradation. The mechanisms of BPA adsorption on modified adsorbents include pore-filling, hydrophobic interactions, hydrogen bonding, and electrostatic interactions. Among the various agricultural waste adsorbents, Argan nut shell-microporous carbon (ANS@H20–120) exhibited the highest efficiency in removing BPA. Furthermore, the performance of magnetic treatment for activated carbon (AC) regeneration is introduced. According to the present study, researchers should prioritize agricultural waste-based adsorbents such as ACs, highly microporous carbons, nanoparticles, and polymers for the removal of BPA. In particular, the combination of adsorption and AOPs (advanced oxidations) is regarded as an efficient method for BPA removal. A series of relevant studies should be conducted at laboratory, pilot, and industrial scales for optimizing the application of agricultural waste-based AC to reduce BPA or other refractory pollutants from an aqueous environment. Full article

Due to the high formation temperature of high-temperature reservoirs, ordinary polyacrylamide microspheres cannot meet the requirements for temperature resistance. To address the challenge of deep profile control in high-temperature reservoirs, we prepared AM/PF polymer microspheres with excellent temperature resistance through the copolymerization of water-soluble phenolic resin (PF) and acrylamide (AM). The swelling properties of AM/PF polymer microspheres were examined using a visible light microscope, SEM, and laser diffraction. The plugging and migration characteristics of the microspheres were evaluated using membrane filtration tests and sand-filled tube displacement tests. The results indicate that the average particle size of AM/PF microspheres prepared via inverse suspension polymerization is approximately 30 μm, and the swelling process is relatively slow. The microspheres take approximately 15 days to fully swell, with a volume swelling ratio of roughly 34.25. At high temperatures, the swollen microsphere dispersion system can effectively block microporous membranes with specific pore sizes. As the concentration of microspheres increases, their plugging effect gradually enhances; however, this effect diminishes as permeability increases. The AM/PF polymer microspheres exhibit excellent temperature stability along with favorable plugging and migration characteristics at specific permeabilities. Full article

This study investigates the development of pore-filling anion-exchange membranes (PFAEMs) for water-electrolysis applications. Ionomers using two different cross-linking monomers, namely hydrophilic C10 and hydrophobic C11, along with a common electrolyte monomer, E3, were compared in terms of through-plane ion conductivity, hydrogen permeability, mechanical and chemical stability, I-V polarization, and water-electrolysis durability. The results revealed that the E3-C10 PFAEM exhibited 40% higher OH⁻ conductivity (98.7 ± 7.0 mS cm⁻¹) than the E3-C11 PFAEM with a similar ion-exchange capacity. This improvement was attributed to improved separation of hydrophobic and hydrophilic domains, creating well-connected ion channels by the hydrophilic C10. Alkaline stability tests demonstrated that the E3-C10 retained higher ion conductivity compared to E3-C11, due to the absence of ether linkages and increased resistance to nucleophilic attack. During water-electrolysis operations, the E3-C10 PFAEMs showed 10% better durability and 87% lower hydrogen permeability, confirming their suitability for anion-exchange-membrane water electrolysis (AEMWE). Despite the higher ion conductivity of the E3-C10 PFAEM, performance was limited by interfacial resistance. It is suggested that ionomer-coated electrodes could further enhance AEMWE performance by leveraging the higher ion conductivity of the E3-C10. Overall, this study provides valuable guidance on strategies for utilizing pore-filling membranes in water electrolysis. Full article

We report the discovery of a novel free-living marine nematode, Dracognomus elongatus sp. nov., from the genus Dracognomus Allen & Noffsinger, 1978 (Nematoda: Draconematidae), collected from geniculate coralline algal assemblages in the intertidal zone along the eastern coast of Korea in the Northwest Pacific Ocean. Dracognomus elongatus sp. nov. is distinguished from its congeners by several key features: a relatively long body length (522 µm), densely developed minute spine-like ornamentation along the margins of body annules, small pore-shaped amphids (2 µm) with membranous tubes filled with corpus gelatum extending to the fifth body annule, twelve modified cephalic adhesion tubes located posterior to the rostrum, eight pairs of modified adhesion tubes in the mid-body region, an arrangement of both normal and modified subventral adhesion tubes (three pairs of each), disc-shaped tips on sublateral adhesion tubes, absence of copulatory thorns in males, and the presence of three pairs of short setae with no protuberances on the non-annulated tail end. Morphological details and illustrations were obtained using differential interference contrast microscopy. We also provide information on the geographic distribution and comparative characteristics of species within the genus Dracognomus, along with a schematic ventral view of a congener illustrating the arrangement of posterior adhesion tubes and copulatory thorns. Additionally, we present a species-level pictorial dichotomous key. Dracognomus elongatus sp. nov. is the eighth described species of this rare genus and marks the first record of Dracognomus in the Northwest Pacific Ocean. Full article

Four distinct pore-filling anion exchange membranes (PFAEMs) were prepared, and their mechanical properties, ion conductivity, and performance in anion exchange membrane water electrolysis (AEMWE) were evaluated. The fabricated PFAEMs demonstrated exceptional tensile strength, which was approximately 14 times higher than that of the commercial membrane, despite being nearly half as thin. Ion conductivity measurements revealed that acrylamide-based membranes outperformed benzyl-based ones, exhibiting 25% and 41% higher conductivity when using crosslinkers with two and three crosslinking sites, respectively. The AEMWE performance directly correlated with the hydrophilicity and ion exchange capacity (IEC) of the membranes. Specifically, AE_3C achieved the highest performance, supported by its superior IEC and ionic conductivity. Durability tests showed that AE_3C outlasted the commercial membrane, with a delayed voltage increase corresponding to its higher IEC, confirming the importance of increased ion-exchange functional groups in ensuring longevity. These results highlight the critical role of hydrophilic monomers and crosslinker structure in optimizing PFAEMs for enhanced performance and durability in AEMWE applications. Full article

This study examines the effect of the structural characteristics of anion-conducting monomers within pore-filling anion exchange membranes on the performance and durability of anion exchange membrane water electrolysis. Analysis reveals that acrylamide- and acrylate-based membranes show optimal performance without methyl groups, with acrylamide-based membranes outperforming their acrylate counterparts in current density, particularly at 1.8 V. The AC-AA and AC-MAA monomers demonstrate durability, with AC-MAA showing enhanced alkaline stability, likely due to the presence of a methyl group, resulting in an increase rate of 746.6 μV/h compared to AC-AA’s 1150 μV/h. This study also shows that a commercial membrane exhibits a decrease rate of 3116 μV/h, underscoring the pore-filling membrane’s superior durability. Furthermore, the findings highlight that pore-filling membrane technology enables better durability and performance in electrolysis environments compared to the commercial homogeneous membrane, particularly when alkaline conditions are present. This research provides a foundation for designing high-performance, durable membranes for efficient hydrogen production, particularly under water electrolysis conditions. Full article

Polymer-based membranes represent an irreplaceable group of materials that can be applied in a wide range of key industrial areas, from packaging to high-end technologies. Increased selectivity to transport properties or the possibility of controlling membrane permeability by external stimuli represents a key issue in current material research. In this work, we present an unconventional approach with the introduction of silver nanoparticles (AgNPs) into membrane pores, by immobilising them onto the surface of polyethyleneterephthalate (PET) foil with subsequent physical modification by means of laser and plasma radiation prior to membrane preparation. Our results showed that the surface characteristics of AgNP-decorated PET (surface morphology, AgNP content, and depth profile) affected the distribution and concentration of AgNPs in subsequent ion-track membranes. We believe that the presented approach affecting the redistribution of AgNPs in the polymer volume may open up new possibilities for the preparation of metal nanoparticle-filled polymeric membranes. The presence of AgNPs on the pore walls can facilitate the grafting of stimuli-responsive molecules onto these active sites and may contribute to the development of intelligent membranes with controllable transport properties. Full article

Non-aqueous redox flow batteries (NARFBs) have been attracting much attention because they can significantly increase power and energy density compared to conventional RFBs. In this study, novel pore-filled anion-exchange membranes (PFAEMs) for application to a NAPFB employing metal polypyridyl complexes (i.e., Fe(bpy)₃²⁺/Fe(bpy)₃³⁺ and Co(bpy)₃²⁺/Co(bpy)₃³⁺) as the redox species are successfully developed. A porous polyethylene support with excellent solvent resistance and mechanical strength is used for membrane fabrication. The PFAEMs are prepared by filling an ionic liquid monomer containing an imidazolium group and a crosslinking agent into the pores of the support film and then performing in situ photopolymerization. As a result, the prepared membranes exhibit excellent mechanical strength and stability in a non-aqueous medium as well as high ion conductivity. In addition, a low crossover rate for redox ion species is observed for the prepared membranes because they have relatively low swelling characteristics in non-aqueous electrolyte solutions and low affinity for the metal-complex redox species compared to a commercial membrane. Consequently, the PFAEM is revealed to possess superior battery performance than a commercial membrane in the NARFB tests, showing high energy efficiency of about 85% and stable operation for 100 cycles. Full article

The present study demonstrates the synthesis of phase pure hematite (α-Fe₂O₃) nanoparticles (NPs) using collagen protein and calcium carbonate extracted from eggshell membranes and eggshells, respectively, as organic additives. To test the influence of organic additives on the quality of the resulting NPs, the amount of eggshell powder was varied between 1 to 5 g in aqueous iron nitrate solution. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and RAMAN analysis confirmed the formation of hematite NPs without any impurities. FTIR spectra revealed the presence of polyphenolic constituents on the surface of the resulting NPs as stabilizers, which may potentially be responsible for the observed antioxidant and antibacterial properties. Furthermore, the stable phase and the presence of low defects divulged the high hardness value (~983 HV) and fracture toughness (8.59 MPa m^1/2), which can be exploited for bone implantation. The FE-SEM results demonstrate the formation of spherical particles, which are well-separated NPs. The results of a biodegradation study which was carried out in phosphate-buffered saline (PBS) revealed that the as-prepared NPs retained their hardness even after 72 h of soaking. These prepared NPs showed 95% radical scavenging activity (RSA) and were good carriers against S. aureus bacteria. Moreover, the SEM images of the mineralization of iron oxide NPs confirmed the formation of new bone. After 5 weeks, all pores were filled, and the minerals were deposited on the surfaces of the scaffolds. Full article

In this study, novel pore-filled anion-exchange membranes (PFAEMs) modified with polypyrrole (PPy) and reduced graphene oxide (rGO) were developed to improve the energy harvesting performance of reverse electrodialysis (RED). The surface-modified PFAEMs were fabricated by varying the contents of PPy and rGO through simple spin coating and chemical/thermal treatments. It was confirmed that the PPy and PPy/rGO layers introduced on the membrane surface did not significantly increase the electrical resistance of the membrane and could effectively control surface characteristics, such as structural tightness, hydrophilicity, and electrostatic repulsion. The PPy/rGO-modified PFAEM showed excellent monovalent ion selectivity, more than four times higher than that of the commercial membrane (AMX, Astom Corp., Tokyo, Japan). This means that the PPy/rGO layer can effectively reduce the permeation of multivalent ions with a high charge intensity and a relatively large hydration radius compared to monovalent ions. The results of evaluating the performance of the surface-modified PFAEMs by applying them to a RED cell revealed that the decrease in potential difference occurring in the membrane was reduced by effectively suppressing the uphill transport of multivalent ions. Consequently, the PPy/rGO-modified membrane exhibited a 5.43% higher power density than the AMX membrane. Full article

Traumatic nerve defects result in dysfunctions of sensory and motor nerves and are usually accompanied by pain. Nerve guidance conduits (NGCs) are widely applied to bridge large-gap nerve defects. However, few NGCs can truly replace autologous nerve grafts to achieve comprehensive neural regeneration and function recovery. Herein, a three-dimensional (3D) sponge-filled nanofibrous NGC (sf@NGC) resembling the structure of native peripheral nerves was developed. The conduit was fabricated by electrospinning a poly(L-lactide-co-glycolide) (PLGA) membrane, whereas the intraluminal filler was obtained by freeze-drying a collagen-based matrix (ColM) resembling the extracellular matrix. The effects of the electrospinning process and of the composition of ColM on the physicochemical performance of sf@NGC were investigated in detail. Furthermore, the biocompatibility of the PLGA sheath and ColM were evaluated. The continuous and homogeneous PLGA nanofiber membrane had high porosity and tensile strength. ColM was shown to exhibit an ECM-like architecture characterized by a multistage pore structure and a high porosity level of over 70%. The PLGA sheath and ColM were shown to possess stagewise degradability and good biocompatibility. In conclusion, sf@NGC may have a favorable potential for the treatment of nerve reconstruction. Full article

In this review, the state of the art of modified membranes developed and applied for the improved performance of redox flow batteries (RFBs) is presented and critically discussed. The review begins with an introduction to the energy-storing chemical principles and the potential of using RFBs in the energy transition in industrial and transport-related sectors. Commonly used membrane modification techniques are briefly presented and compared next. The recent progress in applying modified membranes in different RFB chemistries is then critically discussed. The relationship between a given membrane modification strategy, corresponding ex situ properties and their impact on battery performance are outlined. It has been demonstrated that further dedicated studies are necessary in order to develop an optimal modification technique, since a modification generally reduces the crossover of redox-active species but, at the same time, leads to an increase in membrane electrical resistance. The feasibility of using alternative advanced modification methods, similar to those employed in water purification applications, needs yet to be evaluated. Additionally, the long-term stability and durability of the modified membranes during cycling in RFBs still must be investigated. The remaining challenges and potential solutions, as well as promising future perspectives, are finally highlighted. Full article

Flood season embankment due to long-term high water immersion environment creates situations where its soil properties will deteriorate, quickly triggering bank slope instability and other dangerous situations. In order to study embankment slope soil in the disintegration and permeability characteristics under the long-term water immersion process, disintegration tests and variable head infiltration tests were carried out on embankment-disturbed clays in Jiangxinzhou, Nanjing, Jiangsu Province, China. The results showed that the disintegration rate decreased with increasing dry density. Moreover, the samples gained weight quickly when the water content was low. Moreover, there is a threshold water content of around 20%, and it is assumed that the disintegration pattern of the soil may be significantly different depending on the optimum moisture content. The effect of moisture content on the disintegration of the samples was more significant. There were three main typical disintegration modes of the samples. The primary influencing factors resulting in the various disintegration patterns are the soil matrix suction, the change in consistency following water immersion, and the water membrane on the surface of the clay particles. The coefficient of permeability decreases with increasing dry density, and the variation of the coefficient of permeability with dry density coincides with the exponential function relationship. Long-term immersion conditions will change the permeability of the soil. An electron microscope test of immersed and unimmersed samples shows that the internal structure change is an essential factor affecting the permeability. After water immersion, with the dissolution of cementing material between soil particles, the particles move to fill the intergranular pore space so that the permeability coefficient decreases. Full article

This study investigated the performance of photocatalytic titanium dioxide microfiltration membranes with an average pore size of approximately 180 nm and ultrafiltration membranes with an average pore size of around 40 nm fabricated with the suspension plasma spray process. The membranes were evaluated for their filtration performance using SiO₂ particles of different sizes and polyethylene oxide with molecular weights of 20 kDa to 1000 kDa, and the fouling parameters were characterized. The rejection rate was enhanced by increasing the thickness of the membranes. This effect was more pronounced with the ultrafiltration membranes. The rejection rate of the ultrafiltration membrane was improved significantly after filling the larger pores on the surface with agglomerates of titanium dioxide nanoparticles. The self-cleaning performance of the membranes was assessed under visible light. Both ultrafiltration and microfiltration membranes showed a flux recovery under visible light illumination due to the photocatalytic activity of titanium dioxide. The membranes also show a flux recovery of more than 90%. Full article