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Search Results (1,021)

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Keywords = shape–memory alloy

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20 pages, 3216 KB  
Review
Stapes Prostheses in Otosclerosis Surgery: Materials, Design Innovations, and Future Perspectives
by Luana-Maria Gherasie, Viorel Zainea, Razvan Hainarosie, Andreea Rusescu, Irina-Gabriela Ionita, Ruxandra-Oana Alius and Catalina Voiosu
Actuators 2025, 14(10), 502; https://doi.org/10.3390/act14100502 - 17 Oct 2025
Abstract
Background: Stapes prostheses represent one of the earliest and most widely applied “biomedical actuators” designed to restore hearing in patients with otosclerosis. Unlike conventional actuators, which convert energy into motion, stapes prostheses function as passive or smart micro-actuators, transmitting and modulating acoustic [...] Read more.
Background: Stapes prostheses represent one of the earliest and most widely applied “biomedical actuators” designed to restore hearing in patients with otosclerosis. Unlike conventional actuators, which convert energy into motion, stapes prostheses function as passive or smart micro-actuators, transmitting and modulating acoustic energy through the ossicular chain. Objective: This paper provides a comprehensive analysis of stapes prostheses from an engineering and biomedical perspective, emphasizing design principles, materials science, and recent innovations in smart actuators based on shape-memory alloys combined with surgical applicability. Methods: A narrative review of the evolution of stapes prostheses was consolidated by institutional surgical experience. Comparative evaluation focused on materials (Teflon, Fluoroplastic, Titanium, Nitinol) and design solutions (manual crimping, clip-on, heat-activated prostheses). Special attention was given to endoscopic stapes surgery, which highlights the ergonomic and functional requirements of new device designs. Results: Traditional fluoroplastic and titanium pistons provide reliable sound conduction but require manual crimping, with a higher risk of incus necrosis and displacement. Innovative prostheses, particularly those manufactured from nitinol, act as self-crimping actuators activated by heat, improving coupling precision and reducing surgical trauma. Emerging designs, including bucket-handle and malleus pistons, expand applicability to complex or revision cases. Advances in additive manufacturing and middle ear cement fixation offer opportunities for customized, patient-specific actuators. Conclusions: Stapes prostheses have evolved from simple passive pistons to innovative biomedical actuators exploiting shape-memory and biocompatible materials. Future developments in stapes prosthesis design are closely linked to 3D printing technologies. These developments have the potential to enhance acoustic performance, durability, and patient outcomes, thereby bridging the gap between otologic surgery and biomedical engineering. Full article
(This article belongs to the Section Actuators for Medical Instruments)
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10 pages, 2359 KB  
Article
Magnetic Field Suppression of the Martensitic Transformation in Mn-Based MnNi(Fe)Sn Metamagnetic Shape Memory Heusler Alloys
by Patricia Lázpita, Natalia Ahiova Río-López, David Mérida, Emily (Leonie Quinlyn Nowalaja) Ammerlaan, Uli Zeitler, Volodymyr Chernenko and Jon Gutiérrez
Magnetism 2025, 5(4), 25; https://doi.org/10.3390/magnetism5040025 - 16 Oct 2025
Abstract
Heusler-type metamagnetic shape memory alloys (MMSMAs) exhibit a large functional response associated with a first-order martensitic transformation (MT). The strong magneto-structural coupling combined with the presence of mixed magnetic interactions enables controlling this MT by means of a magnetic field, resulting in different [...] Read more.
Heusler-type metamagnetic shape memory alloys (MMSMAs) exhibit a large functional response associated with a first-order martensitic transformation (MT). The strong magneto-structural coupling combined with the presence of mixed magnetic interactions enables controlling this MT by means of a magnetic field, resulting in different multifunctional properties, among them giant magnetoresistance, metamagnetic shape memory effect (MMSM), or inverse magnetocaloric effect (MCE). Not only the shift rate of MT as a function of the magnetic field but also its eventual suppression are key parameters in order to develop these effects. Here we present our findings concerning a detailed study of the magnetic field-induced MT and its suppression in MnNi(Fe)Sn MMSMAs, by applying strong steady magnetic fields up to 33 T. These measurements will lead to the creation of the T-μ0H phase diagrams of the MT. Moreover, we will also give light to the effect of Fe—content and, as a direct consequence, the magnetic coupling on the suppression of the magnetostructural transformation. Full article
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19 pages, 7895 KB  
Article
SpiKon-E: Hybrid Soft Artificial Muscle Control Using Hardware Spiking Neural Network
by Florian-Alexandru Brașoveanu, Mircea Hulea and Adrian Burlacu
Biomimetics 2025, 10(10), 697; https://doi.org/10.3390/biomimetics10100697 - 15 Oct 2025
Viewed by 28
Abstract
Artificial muscles play a key role in the future of humanoid robotics and medical devices, with research on wire-driven joints leading the field. While electric servo motors were once at the forefront, the focus has shifted toward materials that react to changes in [...] Read more.
Artificial muscles play a key role in the future of humanoid robotics and medical devices, with research on wire-driven joints leading the field. While electric servo motors were once at the forefront, the focus has shifted toward materials that react to changes in the environment (smart materials), including pneumatic silicone actuators and temperature-reactive metallic alloys, aiming to replicate human muscle actuation for improved performance. Initially designed for rigid actuators, control strategies were adapted to address the unique dynamics of artificial muscles. Although current controllers offer satisfactory performance, further optimization is necessary to mimic natural muscle control more rigorously. This study details the design and implementation of a novel system that mimics biological muscle. This system is designed to replicate the full range of motion and control functionalities, which can be utilized in various applications. This research has three significant contributions in the field of sustainable soft robotics. First, a novel shape memory alloy-based linear actuator is introduced, which achieves significantly higher displacements compared to traditional SMA wire-driven systems through a guiding mechanism. Second, this linear actuator is integrated into a hybrid soft actuation structure, which features a silicone PneuNet as the end effector and a force sensor for real-time pressure feedback. Lastly, a hardware Spiking Neural Network (HW-SNN) is utilized to control the exhibited force at the actuator’s endpoint. Experimental results showed that the displacement with the control system is significantly higher than that of the traditional control-based shape memory alloy systems. The system evaluation demonstrates good performance, thus advancing actuation and control in humanoid robotics. Full article
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15 pages, 5296 KB  
Article
Boosting Caloric Performances of Ni-Co-Mn-Ti Shape Memory Alloy for Multi-Scenario Refrigeration by Spark Plasma Sintering
by Hongyuan Tang, Ziqi Guan, Yanze Wu, Zhenzhuang Li, Jiaqi Liu and Xing Lu
Materials 2025, 18(20), 4691; https://doi.org/10.3390/ma18204691 - 13 Oct 2025
Viewed by 319
Abstract
In this study, Ni37Co13Mn33.5+xTi16.5–x alloys with different particle sizes (75–150 μm, 50–75 μm, 0–50 μm) were successfully fabricated using spark plasma sintering under different processing conditions. By adjusting the composition of alloy and particle [...] Read more.
In this study, Ni37Co13Mn33.5+xTi16.5–x alloys with different particle sizes (75–150 μm, 50–75 μm, 0–50 μm) were successfully fabricated using spark plasma sintering under different processing conditions. By adjusting the composition of alloy and particle size, a significant transformation entropy change and the generation of a suitable amount of second phases along the grain boundaries were achieved in the SPS Ni37Co13Mn34.5Ti15.5 alloy with a particle size range of 0–50 μm. The mechanical properties of this optimized alloy were excellent, exhibiting a compressive strength of 2005 MPa and a fracture strain of 27%. Furthermore, under a loading rate of 0.28 s−1, the alloy demonstrated an adiabatic temperature change of up to 34.2 K. In addition, the alloy also exhibited a barocaloric effect under low-pressure conditions, achieving a substantial entropy change of 16.1 J·kg−1·K−1 and an estimated adiabatic temperature change of 11.2 K under 100 MPa pressure. Through these results, SPS Ni37Co13Mn34.5Ti15.5 alloy is proved to be a potential candidate for solid-state refrigeration applications. Full article
(This article belongs to the Special Issue Magnetic Shape Memory Alloys: Fundamentals and Applications)
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25 pages, 7130 KB  
Article
Shock Absorption Control of Sand-Layer Isolation Liquid Storage Structure with Soft Steel
by Hulin Zhang, Yiting Mu, Kai Ding and Xuansheng Cheng
Appl. Sci. 2025, 15(20), 10966; https://doi.org/10.3390/app152010966 - 13 Oct 2025
Viewed by 188
Abstract
Wall plate rupture in liquid storage structures (LSSs) induced by earthquakes is a prevalent issue. To mitigate the impacts of seismic hazards on plate–shell composite concrete liquid storage structures (CLSSs), in this study, we propose an investigation into X-type mild steel–Shape Memory Alloy [...] Read more.
Wall plate rupture in liquid storage structures (LSSs) induced by earthquakes is a prevalent issue. To mitigate the impacts of seismic hazards on plate–shell composite concrete liquid storage structures (CLSSs), in this study, we propose an investigation into X-type mild steel–Shape Memory Alloy (SMA) seismic mitigation control for plate–shell composite CLSSs with sand-layer seismic isolation. Via finite element parametric analysis, this study examines the effects of two key parameters—the sand-layer friction coefficient and the spring-damping ratio of X-type mild steel–SMA seismic mitigation elements—on the dynamic response of CLSSs. The results indicate the following: under unidirectional seismic excitation, the proposed mitigation method achieves a favorable control effect on the maximum principal stress of the structure; under bidirectional seismic excitation, the optimal control effect on the maximum principal stress is achieved when the spring-damping ratio of the mitigation elements is 0.3 and the friction coefficient of the seismic isolation sand layer is 0.4. Additionally, under both unidirectional and bidirectional seismic excitation, this method exhibits a noticeable control effect on the peak liquid sloshing height. Full article
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20 pages, 6904 KB  
Article
In Vitro Corrosion Resistance and Mechanical Properties of Ag-SiO2-TiO2 Coatings Electrophoretically Deposited on NiTi Alloy
by Bożena Łosiewicz, Julian Kubisztal, Adrian Barylski and Karolina Dudek
Coatings 2025, 15(10), 1176; https://doi.org/10.3390/coatings15101176 - 8 Oct 2025
Viewed by 300
Abstract
NiTi alloys are widely used in biomedical applications due to their shape memory and superelastic properties. However, their surface reactivity requires protective, biofunctional coatings. To enhance NiTi performance, its surface was modified with an Ag-SiO2-TiO2 nanocoating containing small amounts of [...] Read more.
NiTi alloys are widely used in biomedical applications due to their shape memory and superelastic properties. However, their surface reactivity requires protective, biofunctional coatings. To enhance NiTi performance, its surface was modified with an Ag-SiO2-TiO2 nanocoating containing small amounts of silica and silver. The coating’s primary phase was rutile with structural defects and a silver solid solution. It showed good adhesion, high scratch resistance, and improved corrosion behavior in Ringer’s solution, as demonstrated by EIS and cyclic polarization. EIS revealed high low-frequency impedance and two time constants, suggesting both barrier protection and slower electrochemical processes. Despite low breakdown and repassivation potentials, the coating effectively limited uniform corrosion. SEM/EDS confirmed localized degradation and partial substrate exposure, while elemental mapping showed well-dispersed silica and silver in a TiO2-rich matrix. The proposed pitting mechanism involves chloride-induced depassivation and galvanic effects. Surface potential mapping indicated electrostatic heterogeneity, mitigated by silica. The coating offers a balanced combination of corrosion protection and biofunctionality, supporting its potential for implant use. Full article
(This article belongs to the Special Issue Recent Advances in Surface Functionalisation, 2nd Edition)
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18 pages, 7510 KB  
Article
Effects of the Addition of Iron and Chromium on the Structure and Properties of the Ni-Co-Mn-In Alloy
by Edyta Matyja and Krystian Prusik
Materials 2025, 18(19), 4597; https://doi.org/10.3390/ma18194597 - 3 Oct 2025
Viewed by 276
Abstract
In this work, small amounts of Fe or Cr were added to Ni47Co3Mn36.5In13.5 alloy (x = 0) to produce five-component alloys with nominal compositions of Ni47Co3Mn35.5In13.5Fe1, [...] Read more.
In this work, small amounts of Fe or Cr were added to Ni47Co3Mn36.5In13.5 alloy (x = 0) to produce five-component alloys with nominal compositions of Ni47Co3Mn35.5In13.5Fe1, Ni47Co3Mn33.5In13.5Fe3, Ni47Co3Mn35.5In13.5Cr1, and Ni47Co3Mn33.5In13.5Cr3, which are denoted as Ni47Co3Mn36.5−xIn13.5Fex/Crx (x = 1, 3 at.% Cr/Fe) series or as Mn-series (due to the addition of alloying elements instead of Mn), and Ni47Co3Mn36.5In12.5Fe1, Ni47Co3Mn36.5In10.5Fe3, Ni47Co3Mn36.5In12.5Cr1, and Ni47Co3Mn36.5In10.5Cr3, denoted as Ni47Co3Mn36.5In13.5−x (x = 1, 3 at.% Cr/Fe) series or In-series (due to the addition of alloying elements instead of In). The polycrystalline alloys were produced using the vacuum arc melting technique. The as-received alloys were characterized in structure, homogeneity, phase composition, martensitic transformation, and microhardness. The results showed that the addition of 1 at.% of Cr or Fe positively impacted the microstructure of the alloys. The quaternary alloy exhibited a single-phase coarse-grained structure. The addition of Fe and Cr (1 at.%) caused microstructure refinement with small Fe/Cr- and Co-rich γ particles appropriately distributed in the matrix, while the addition of 3% Fe or Cr resulted in γ formation in a dendritic form distributed more randomly. The addition of 1 at.% and 3 at.% of Cr or Fe significantly influenced the martensitic transformation temperatures. The microhardness increased by 21% in the Ni47Co3Mn33.5In13.5Fe3 alloy compared to the quaternary alloy. Full article
(This article belongs to the Special Issue Processing of Metals and Alloys)
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15 pages, 14339 KB  
Article
Origami Fresnel Zone Plate Lens Reflector Antennas for Satellite Applications
by Massimo Donelli, Sreedevi Menon, Viviana Mulloni, Giada Marchi and Irene Dal Chiele
Electronics 2025, 14(19), 3892; https://doi.org/10.3390/electronics14193892 - 30 Sep 2025
Viewed by 208
Abstract
This work presents a methodology for designing deployable reflector antennas that combine origami structures and the Fresnel zone plate lens to obtain a compact antenna structure. In particular, Miura and Yoshimura’s origami patterns have been considered for the design of the Fresnel reflector [...] Read more.
This work presents a methodology for designing deployable reflector antennas that combine origami structures and the Fresnel zone plate lens to obtain a compact antenna structure. In particular, Miura and Yoshimura’s origami patterns have been considered for the design of the Fresnel reflector mirror and the conical horn antenna feeder, respectively. A set of memory-form alloy (MFA) actuators have been used to deploy the antenna. The MFA actuators are activated by a direct current aimed at increasing the temperature and activating the memorized shape. The combination of these techniques provides light, inexpensive, and very compact antennas, particularly suitable for satellite applications. A numerical and experimental assessment campaign has been carried out on antenna prototypes operating in the Ku band at 15 GHz. The obtained experimental results are quite promising. Full article
(This article belongs to the Special Issue Theory, Methods and Applications of Electromagnetic Scattering)
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12 pages, 2029 KB  
Article
An Assessment of TiN Formation on NiTi Alloy and the Corrosion Resistance of TiN/NiTi Alloy Using First-Principles Calculation
by Yunfei Wang, Haodong He, Huan Yang, Weijian Li, Zhiyong Gao, Haizhen Wang and Xiaoyang Yi
Metals 2025, 15(10), 1089; https://doi.org/10.3390/met15101089 - 29 Sep 2025
Viewed by 188
Abstract
In this paper, the interfacial bonding properties between (110)NiTi and (200)TiN interfaces, as well as the adsorption capacity of Cl on the surfaces of (110)NiTi and (200)TiN, were investigated using the first-principles computational method based on density [...] Read more.
In this paper, the interfacial bonding properties between (110)NiTi and (200)TiN interfaces, as well as the adsorption capacity of Cl on the surfaces of (110)NiTi and (200)TiN, were investigated using the first-principles computational method based on density functional theory (DFT). Four types of interfacial models between (110)NiTi and (200)TiN were developed. It was found that the interfacial bonding energies of the four interface models are greater than zero, indicating stable interface bonding between (110)NiTi and (200)TiN. For comparison, model III (N of (200)TiN is located at the bridge size between Ti and Ni in (110)NiTi) has the largest Wad value of 9.773 J/m2, which is attributed to stronger N-Ti bonding at the interface. Based on interface model III, an interfacial model of Cl at three different adsorption locations (top, bridge, and hole) on the (110)NiTi and (200)TiN surfaces, respectively, was constructed. The results reveal that the adsorption energies of Cl on the surface of (110)NiTi are significantly less than those of the Cl on the surface of (200)TiN. This suggests that (110)NiTi is more likely to react with Cl. Hence, the introduction of a TiN layer on the surface of NiTi alloy can effectively improve its corrosion resistance. Full article
(This article belongs to the Special Issue Advances in Shape Memory Alloys: Theory, Experiment and Calculation)
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27 pages, 2979 KB  
Review
Review of EDM-Based Machining of Nickel–Titanium Shape Memory Alloys
by Sujeet Kumar Chaubey and Kapil Gupta
Quantum Beam Sci. 2025, 9(4), 28; https://doi.org/10.3390/qubs9040028 - 26 Sep 2025
Viewed by 402
Abstract
Shape memory alloy (SMA) materials are valued for their shape memory effect, superelasticity, and biocompatibility, making them an ideal choice for applications in biomedical, aerospace, and actuator fields. Nickel–titanium (NiTi) SMA is a promising biomedical material. It is widely used in the manufacture [...] Read more.
Shape memory alloy (SMA) materials are valued for their shape memory effect, superelasticity, and biocompatibility, making them an ideal choice for applications in biomedical, aerospace, and actuator fields. Nickel–titanium (NiTi) SMA is a promising biomedical material. It is widely used in the manufacture of biomedical instruments, devices, implants, and surgical tools. However, its complex thermo-mechanical behavior and poor machinability pose challenges for conventional machining. To manufacture high-quality nitinol parts, traditional machining processes are being replaced by advanced machining technologies. Electric discharge machining (EDM) is an advanced machining technique whose mechanism of material removal involves erosion caused by plasma formation and spark generation. It has proven effective for processing difficult-to-machine materials. This review summarizes EDM and its variants, including hybrid EDM, with a focus on machining NiTi-SMA materials for biomedical, aerospace, microelectromechanical systems, and automotive applications, and systematically explores key factors such as process parameters, material removal mechanisms, surface integrity, tool wear, and optimization strategies. This review begins with an introduction to nitinol (i.e., NiTi-SMA) and its variants, followed by an in-depth discussion of plasma formation, spark generation mechanisms, and other key aspects of EDM. It then provides a detailed analysis of notable past research on the machining of NiTi SMA materials using EDM and its variants. This paper concludes with insights into future research directions, aiming to advance EDM-based machining of SMA materials and serve as a valuable resource for researchers and engineers in the field. Full article
(This article belongs to the Section Engineering and Structural Materials)
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38 pages, 2674 KB  
Review
Incorporation of Nitinol (NiTi) Shape Memory Alloy (SMA) in Concrete: A Review
by Muhammed Turkmen, Anas Issa, Omar Awayssa and Hilal El-Hassan
Materials 2025, 18(19), 4458; https://doi.org/10.3390/ma18194458 - 24 Sep 2025
Viewed by 636
Abstract
Incorporating Nitinol (NiTi) shape memory alloy (SMA) into concrete structures has gained significant attention in recent years due to its ability to enhance the properties of concrete. This review paper illustrates the history of NiTi SMA and its use in various civil engineering [...] Read more.
Incorporating Nitinol (NiTi) shape memory alloy (SMA) into concrete structures has gained significant attention in recent years due to its ability to enhance the properties of concrete. This review paper illustrates the history of NiTi SMA and its use in various civil engineering structural applications. A detailed analysis of the existing literature and case studies offers perspectives on the possible applications, benefits, and prospects of utilizing NiTi SMA to reinforce and strengthen elements in concrete structures. The study examined publications on the internal usage of NiTi SMA in concrete and cement-based matrices as an embedded element, including fibers, bars, cables, wires, powder, and strands. In addition, superelastic and shape memory forms of NiTi were considered. It was concluded that the superelasticity of NiTi aided in energy dissipation from impact or seismic events. It also improved the re-centering performance and deformation capacity and reduced residual stresses, strains, and cracks. Conversely, the SMA effect of NiTi helped bridge cracks, recover the original shape, and induced prestressing forces under thermal activation. Full article
(This article belongs to the Special Issue Advanced Concrete Formulations: Nanotechnology and Hybrid Materials)
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21 pages, 32435 KB  
Article
Structure and Magnetic Properties of Vanadium-Doped Heusler Ni-Mn-In Alloys
by Dmitry Kuznetsov, Elena Kuznetsova, Alexey Mashirov, Alexander Kamantsev, Denis Danilov, Georgy Shandryuk, Sergey Taskaev, Irek Musabirov, Ruslan Gaifullin, Maxim Kolkov, Victor Koledov and Pnina Ari-Gur
Nanomaterials 2025, 15(19), 1466; https://doi.org/10.3390/nano15191466 - 24 Sep 2025
Viewed by 385
Abstract
The crystal structure, texture, martensitic transformation, and magnetic properties of magnetic shape-memory Heusler alloys of Ni51−xMn33.4In15.6Vx (x = 0; 0.1; 0.3; 0.5; 1) were investigated. Experimental studies of the magnetic properties and meta-magnetostructural transition (martensitic transition—MT) [...] Read more.
The crystal structure, texture, martensitic transformation, and magnetic properties of magnetic shape-memory Heusler alloys of Ni51−xMn33.4In15.6Vx (x = 0; 0.1; 0.3; 0.5; 1) were investigated. Experimental studies of the magnetic properties and meta-magnetostructural transition (martensitic transition—MT) confirm the main sensitivity of the martensitic transition temperature to vanadium doping and to an applied magnetic field. This makes this family of shape-memory alloys promising for use in numerous applications, such as magnetocaloric cooling and MEMS technology. Diffuse electron scattering was analyzed, and the structures of the austenite and martensite were determined, including the use of TEM in situ experiments during heating and cooling for an alloy with a 0.3 at.% concentration of V. In the austenitic state, the alloys are characterized by a high-temperature-ordered phase of the L21 type. The images show nanodomain structures in the form of tweed contrast and contrast from antiphase domains and antiphase boundaries. The alloy microstructure in the temperature range from the martensitic finish to 113 K consists of a six-layer modulated martensite, with 10 M and 14 M modulation observed in local zones. The morphology of the double structure of the modulated martensite structure inherits the morphology of the nanodomain structure in the parent phase. This suggests that it is possible to control the structure of the high-temperature austenite phase and the temperature of the martensitic transition by alloying and/or rapidly quenching from the high-temperature phase. In addition, attention is paid to maintaining fine interface structures. High-resolution transmission electron microscopy showed good coherence along the austenite–martensite boundary. Full article
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32 pages, 8677 KB  
Review
Advances in Dealloying of Ti and Ti-Based Alloys for Biomedical Applications
by Kirti Tiwari, Deepti Raj, Paola Rizzi and Federico Scaglione
Materials 2025, 18(18), 4424; https://doi.org/10.3390/ma18184424 - 22 Sep 2025
Viewed by 293
Abstract
Dealloying technique has been used for centuries as an attractive method for producing porous surfaces by removing one or more undesirable elements from the surface. Since early 2000s, the technique has been further developed for understanding the dealloying mechanism and tailoring it to [...] Read more.
Dealloying technique has been used for centuries as an attractive method for producing porous surfaces by removing one or more undesirable elements from the surface. Since early 2000s, the technique has been further developed for understanding the dealloying mechanism and tailoring it to produce chemically homogeneous materials with nanoporous (np) morphology. Dealloying has found numerous applications such as sensors, catalysts, as well as in the biomedical field, which is fairly recent and has attracted great attention on this topic. This review investigates the dealloying technique for preparing nanoporous materials and nanoporous surfaces by using different modification routes on various types of Ti-based alloys for biomedical implant application. There has been significant growth in studying dealloying of crystalline, amorphous, shape memory, and composites-based Ti alloys. This review aims to summarise the findings from literature and discuss the scope of this technique and challenges involved for future aspects. Full article
(This article belongs to the Special Issue Advances in Implant Materials and Biocompatibility)
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14 pages, 2938 KB  
Article
Influence of Beryllium Addition on the Microstructure, Corrosion, and Wear Properties of Cu-Al-Ni Shape Memory Alloys
by Luis Olmos, Omar Jimenez, Ivon Alanis, Francisco Alvarado-Hernández, Jorge Chavez, Bertha Alejandra Olmos, Max Flores-Jiménez, David Israel Bravo-Bárcenas and Martín Flores
Coatings 2025, 15(9), 1103; https://doi.org/10.3390/coatings15091103 - 20 Sep 2025
Viewed by 330
Abstract
Cu–Al–Ni shape memory alloys (SMAs) are attractive for structural and functional applications due to their cost-effectiveness and shape memory behavior. This study systematically investigated the effect of beryllium (Be) addition on the phase stability, microstructure, transformation temperatures, mechanical hardness, corrosion resistance, and wear [...] Read more.
Cu–Al–Ni shape memory alloys (SMAs) are attractive for structural and functional applications due to their cost-effectiveness and shape memory behavior. This study systematically investigated the effect of beryllium (Be) addition on the phase stability, microstructure, transformation temperatures, mechanical hardness, corrosion resistance, and wear behavior of Cu–Al–Ni alloys. Alloys with Be contents ranging from 0 to 1.5 wt.% were fabricated via arc melting and subjected to thermal treatment. Characterization techniques included dilatometry, X-ray diffraction (XRD), microhardness testing, potentiodynamic polarization, and pin-on-flat wear testing. The results showed that Be additions ≤ 0.4 wt.% stabilized the martensitic β′ phase, while higher concentrations favored the formation of austenitic β phase with a BCC structure. Hardness increased with Be content, especially in austenitic samples. Corrosion tests revealed that while the 0.2 wt.% Be alloy exhibited the most positive corrosion potential (Ecorr), it also had a higher corrosion rate. Overall, corrosion resistance declined with Be concentrations ≥ 0.6 wt.%. Wear tests demonstrated improved resistance in martensitic alloys, attributed to pseudoplastic deformation. These findings highlight the dual role of Be in modifying phase stability and functional properties, offering useful guidance for designing Cu-based SMAs with tailored performance. Full article
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28 pages, 3589 KB  
Article
Broadband Low-Frequency Sound Absorption Enabled by a Rubber-Based Ni50Ti50 Alloy Multilayer Acoustic Coating
by Yizhe Huang, Ziyi Liu, Qiyuan Fan, Huizhen Zhang, Bin Huang, Qibai Huang and Zhifu Zhang
J. Mar. Sci. Eng. 2025, 13(9), 1756; https://doi.org/10.3390/jmse13091756 - 11 Sep 2025
Viewed by 474
Abstract
Acoustic coatings play a vital role in enhancing the acoustic stealth of underwater structures across the full depth range and, especially, in the low-frequency band. However, existing small-scale acoustic coatings struggle to achieve low-frequency broadband sound absorption, which limits further performance improvements. Ni [...] Read more.
Acoustic coatings play a vital role in enhancing the acoustic stealth of underwater structures across the full depth range and, especially, in the low-frequency band. However, existing small-scale acoustic coatings struggle to achieve low-frequency broadband sound absorption, which limits further performance improvements. Ni50Ti50 alloy, with their shape memory effect, hyper elasticity, and high damping properties, offer promising applications in vibration and noise control. In this study, a rubber-based Ni50Ti50 alloy multilayer acoustic coating is proposed, based on the sound absorption mechanism of rubber and the vibration and noise reduction mechanism of Ni50Ti50 alloy. The sound absorption characteristics of the proposed composite coating were obtained through analytical derivations, numerical simulations, and experimental investigations. The objective was to combine the high-frequency absorption capability of rubber and the low-frequency absorption characteristics of Ni50Ti50 alloy without increasing material dimensions, thereby introducing a novel approach for the design of the next generation of underwater acoustic coatings. Full article
(This article belongs to the Section Ocean Engineering)
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