Search Results (1,193)

The presence of secondary electromagnetic waves (EMWs) results in EMW pollution and a large need for EMW-shielding materials. Therefore, new, lightweight, flexible, chemically resistant, and durable EMW shielding materials are demanded, while graphene and its derivatives meet the above-mentioned requirements. Among graphene derivatives, N-doped graphene exhibits promising electrical properties for shielding applications, although achieving sufficient N-incorporation in the graphene sheets remains a challenge. Herein, we produced graphene oxide using the modified Hummers’ method (GO) and the electrochemical exfoliation of highly ordered pyrolytic graphite. These two GO samples were thermally treated at 500 °C and 800 °C under a pure NH₃ gas for 1 h. UV-Vis, infrared, and Raman spectroscopies and X-ray diffraction, elemental, and thermogravimetric analyses were used to investigate the structural properties of modified GO. One of the highest levels of N-doping of GO was measured (11.25 ± 0.08 at%). The modification under a NH₃ atmosphere leads to simultaneous N-doping and reduction of graphene, resulting in the formation of electrically conductive and EMW shielding materials. Density functional theory (DFT) revealed the effect of heteroatoms on the energy band gap of GO. The cluster corresponding to N-doped rGO had a reduced bandgap of 0.77 eV. Full article

Highly efficient shielding materials, transparent in the visible and IR ranges are becoming important in practice. This stimulates the development of cheap methods for creating transparent conductors with low sheet resistance and high optical transparency. This work presents a complex approach based on preliminary modeling of the shielding characteristics of two-layer sandwich structures based on irregular aluminum mesh (IAM) formed by the cracked template method. Experimentally measured spectral dependences of the transmission coefficient of single-layer IAM are used as a reference point for modeling. According to the simulation results, two types of sandwich structures were designed using IAM, with varying filling factors and a fixed PMMA layer thickness of 4 mm. The experimentally measured shielding characteristics of the sandwich structures in the range of 0.01–7 GHz are in good agreement with the calculated data. The obtained structures demonstrate a shielding efficiency of 55.96 dB and 65.55 dB at a frequency of 3.5 GHz (the average range of 5G communications). At the same time, their optical transparency at a wavelength of 550 nm are 84.07% and 75.78%, respectively. Our sandwich structures show electromagnetic shielding performance and uniform diffraction pattern. It gives them an advantage over structures based on regular meshes. The obtained results highlight the prospect of the proposed comprehensive approach for obtaining highly efficient, low-cost optically transparent shielding structures. Such materials are needed for modern wireless communication systems and metrology applications. Full article

Over the last few decades, polymer composites have been rapidly making inroads in critical applications of electrical storage devices such as batteries and supercapacitors. Structural supercapacitor composites (SSCs) have emerged as multifunctional materials capable of storing energy while bearing mechanical loads, offering lightweight and compact solutions for energy systems. This study investigates the functionalization of Bisphenol A-based thermosetting polymers with ionic liquids, aiming to synthesize dual-functional structural electrolytes for SSC fabrication. A multifunctional sandwich structure was subsequently fabricated, in which the fabricated SSC served as the core layer, bonded between two structurally robust outer skins. The core layer was fabricated using carbon fibre layers coated with 10% graphene nanoplatelets (GNPs), while the skin layers contained 0.25% GNPs dispersed in the resin matrix. The developed device demonstrated stable operation up to 85 °C, achieving a specific capacitance of 57.28 mFcm⁻² and an energy density of 179 mWhm⁻² at room temperature. The performance doubled at 85 °C, maintaining excellent capacitance retentions across all experimented temperatures. The flexural strength of the developed sandwich SSC at elevated temperature (at 85 °C) was 71 MPa, which exceeds the minimum requirement for roofing sheets as specified in Australian building standard AS 4040.1 (Methods of testing sheet roof and wall cladding, Method 1: Resistance to concentrated loads). Finite element analysis (FEA) was performed using Abaqus CAE to evaluate structural integrity under mechanical loading and predict damage initiation zones under service conditions. The simulation was based on Hashin’s failure criteria and demonstrated reasonable accuracy. This research highlights the potential of multifunctional polymer composite systems in renewable energy infrastructure, offering a robust and energy-efficient material solution aligned with circular economy and sustainability goals. Full article

Accurately simulating fuses is challenging because the fuse behavior is affected by a variety of thermal and electrical factors. This paper presents a SPICE fuse model and its parameterization procedure. The model mimics the physical behavior of the time–current characteristic including the transition region. For the parameterization only, the time–current characteristic of the fuse, its resistance at room temperature and the melting temperature of the conducting material are needed. The novelty of this SPICE fuse model is the mathematical derivation of a physically based correction factor that considers the temperature dependence of the electrical fuse conductivity. The correction factor is applied to the inverted time–current characteristic. A third-order Foster thermal equivalent network is fitted to the adapted fuse characteristic using a least square algorithm. After a Foster–Cauer transformation, the thermal equivalent network is integrated into the SPICE model. Exemplary LTSpice is used to show and validate the model’s wiring diagram. Comparisons show a very good agreement with data sheet characteristics for a variety of fuse types and current ratings. In the adiabatic and transition region—i.e., at low tripping times—the maximum relative error between the data sheet characteristic and the simulated characteristic was consistently below 15% and thus within the production parameter spread. Full article

This paper investigates the influence of airfoil parameters on the cavitation performance of water jet propulsion pumps through numerical simulation methods. The effects of a varying inlet pressure and different airfoil structures on the critical net positive suction head (NPSH), head, and efficiency were systematically studied. Subsequently, the impact pattern of the airfoil structure on the cavitation performance was analyzed. The results demonstrate that the NACA0009-16_0004-16 airfoil exhibited the lowest required NPSH and superior cavitation resistance relative to the other tested airfoils. Nevertheless, the NACA0009-13_0004-13 airfoil demonstrated an optimal comprehensive performance, balancing the efficiency, head, and cavitation resistance. By extracting a water velocity isosurface of 23.6 m/s, we further investigated the flow characteristics of the suction surfaces of different airfoils at different cavitation conditions and found that the cavitation mainly includes TIP cavitation and sheet cavitation. With an increasing cavitation intensity, the sheet cavitation region progressively develops axially from the blade tip towards the blade outlet, extends radially from the shroud to the hub, and eventually nearly extends over the entire blade surface. The area of the TIP cavitation also expands, spreading downward in the same direction as the impeller rotation. The velocity vector exhibits a significantly higher density near the shroud and blade tips, suggesting potential flow separation and complex vortex structures in these regions. Near the blade leading edge, the water velocity isosurface area contracts, whereas near the trailing edge, it expands. These alterations indicate that the cavitation development modifies the flow field velocity distribution and adversely affects the impeller performance. This study establishes a theoretical foundation and offers practical guidelines for the multi-objective collaborative design of water jet propulsion pumps. Full article

Tantalum nitride (TaN) is a typical transition metal nitride characterized by a wide range of tunable resistivity. Low-resistance TaN even exhibits a resistivity similar to that of metals. Given that electrical resistance influences secondary electron emission (SEE) behavior, this study investigates the relationship between TaN film resistivity and SEE characteristics. Five TaN films were deposited by varying the N₂ gas flow rate during sputtering. Morphological analyses revealed that the film thicknesses ranged from approximately 197 to 281 nm. X-ray photoelectron spectroscopy (XPS) results indicated that the Ta:N atomic ratio of the films ranged from approximately 0.53 to 0.87. Furthermore, XPS detected non-adsorbed oxygen on the surfaces of the TaN films, and more detailed XPS analysis revealed the formation of TaON compounds on the surfaces due to oxygen exposure. X-ray diffraction patterns confirmed that the TaN films contained two crystal phases: Ta₂N (002) and TaN (200). Sheet resistivity tests showed that the resistivity of the TaN films ranged from 5.67 × 10⁻³ to 2.43 Ω·cm. Furthermore, the lower the Ta:N atomic ratio was, the lower the electrical resistivity of the films became. SEE coefficient (SEEC) showed a clear positive correlation with the films’ electrical resistivity. Specifically, films with lower resistivity exhibited reduced SEEC values. When the N₂ gas flow rate was 16 sccm (N₂:Ar = 16:0), the film exhibited the smallest SEEC (maximum ~1.88); when the N₂ flow rate was 0 sccm (N₂:Ar = 0:16), the film showed the largest SEEC (maximum ~2.25). This research provides valuable references for expanding the application of TaN films in engineering scenarios involving electrical resistivity adjustment and SEE applications. Full article

The integration of microstructured current collectors offers a potential pathway to enhance interface properties in solid-state battery architectures. In this work, we investigate the influence of surface morphology on the electrochemical performance of Zn/Na_2.99Ba_0.005OCl/Cu electrodeless pouch cells by fabricating copper thin films on microstructured parylene-C substrates using a combination of colloidal lithography and reactive ion etching. O₂ plasma etching times ranging from 0 to 15 min were used to tune the surface topography, resulting in a systematic increase in root-mean-square roughness and a surface area enhancement of up to ~30% for the longest etching duration, measured via AFM. Kelvin probe force microscopy-analyzed surface potential showed maximum differences of 270 mV between non-etched and 12-minute-etched Cu collectors. The results revealed that the chemical potential is the property that relates the surface of the Cu current collector/electrode with the cell’s ionic transport performance, including the bulk ionic conductivity, while four-point sheet resistance measurements confirmed that the copper layers’ resistivity maintained values close to those of bulk copper (1.96–4.5 µΩ.cm), which are in agreement with electronic mobilities (−6 and −18 cm²V⁻¹s⁻¹). Conversely, the charge carrier concentrations (−1.6 to −2.6 × 10²³ cm⁻³) are indirectly correlated with the performance of the cell, with the samples with lower CCC_bulk (fewer free electrons) performing better and showing higher maximum discharge currents, interfacial capacitance, and first-cycle discharge plateau voltage and capacity. The data were further consolidated with Scanning Electron Microscopy and X-ray Photoelectron Spectroscopy analyses. These results highlight that the correlation between the surface morphology and the cell is not straightforward, with the microstructured current collectors’ surface chemical potential and the charge carriers’ concentration being determinant in the performance of all-solid-state electrodeless sodium battery systems. Full article

Direct fusion welding of aluminum (Al) to magnesium (Mg) results in the formation of brittle intermetallic compounds (IMCs) that significantly restrict the application of these joints in structural applications. In this study, cold spray, a promising solid-state coating deposition technology, was employed to introduce a nickel (Ni) interlayer to facilitate joining of Al to Mg sheets by means of resistance spot welding (RSW). The ability of cold spraying to deposit metallic powder on the substrate without melting proves beneficial in mitigating the formation of the Al-Mg IMCs. The Ni-coated coupons were subsequently welded via resistance spot welding at optimized parameters: 27 kA for 15 cycles in two pulses with a 5-cycle inter-pulse delay. Scanning electron microscopy confirmed metallurgical bonding between the Al, Mg, and Ni coatings in the fusion zone. It is shown that the bonding between the three elements inhibits the formation of deleterious IMCs. Tensile shear testing showed joint strength exceeding 4.2 kN, highlighting the potential of the proposed cold spray RSW approach for dissimilar joining in structural applications. Full article

The use of weld bond (WB) joints in automotive manufacturing is gaining popularity for joining similar and dissimilar materials. This study investigated the effect of Sikaflex-252 (Sika Australia Pty Ltd, Perth, Australia) adhesive in DP600 similar steel joints and DP600 and AISI 316 stainless steel dissimilar steel joints. An increase in welding current from 7 kA to 10 kA increased the weld diameter and tensile shear strength in the RSW joints and the WB joints. WB joints had bigger weld diameters of 5.39 mm and 4.84 mm, higher tensile shear strengths of 12.3 kN and 6.85 kN, and higher energy absorption before failure of 32.6 J and 24.6 J at 10 kA compared to joints at 7 kA for similar and dissimilar joints, respectively. The use of adhesive increased heat generation at 10 kA welding current, due to the increase in dynamic resistance. At 7 kA welding current, the adhesive could not produce sufficient heat for spot weld development. The use of adhesive narrowed the weldability lobe in dissimilar RSW and WB joints and showed changes in failure mode. In similar RSW joints and WB joints, weldability lobe changes were not observed, and RSW and WB joints had the same fracture mode for the same welding current. WB welds have reduced stress distribution across the weld nugget compared to RSW welds because of the bigger weld diameter of 5.39 mm and lesser sheet bending of 1.13 mm. WB joint failure comprises the adhesive failure at the start and later the spot weld failure, while RSW joint failure is purely due to spot weld failure. Full article

This study presents a high-performance external strengthening strategy for reinforced concrete (RC) beam–column joints, integrating near-surface mounted (NSM) Carbon Fiber Reinforced Polymer (C-FRP) ropes with externally bonded C-FRP sheets. The X-shaped ropes, anchored diagonally on both principal joint faces and complemented by vertical ropes at column corners, provide enhanced core confinement and shear reinforcement. C-FRP sheets applied to the beam’s plastic hinge region further increase flexural strength and delay localized failure. Three full-scale, shear-deficient RC joints were subjected to cyclic lateral loading. The unstrengthened specimen (JB0V) exhibited rapid stiffness deterioration, premature joint shear cracking, and unstable hysteretic behavior. In contrast, the specimen strengthened solely with X-shaped C-FRP ropes (JB0VF2X2c) displayed a markedly slower rate of stiffness degradation, delayed crack development, and improved energy dissipation stability. The fully retrofitted specimen (JB0VF2X2c + C-FRP) demonstrated the most pronounced gains, with peak load capacity increased by 65%, equivalent viscous damping enhanced by 55%, and joint shear deformations reduced by more than 40%. Even at 4% drift, it retained over 90% of its peak strength, while localizing damage away from the joint core—a performance unattainable by the unstrengthened configuration. These results clearly establish that the combined C-FRP rope–sheet system transforms the seismic response of deficient RC joints, offering a lightweight, non-invasive, and rapidly deployable retrofit solution. By simultaneously boosting shear resistance, ductility, and energy dissipation while controlling damage localization, the technique provides a robust pathway to extend service life and significantly enhance post-earthquake functionality in critical structural connections. Full article

Background: Maintaining long-term exercise adherence in occupational settings remains a challenge, particularly in remote or unsupervised environments. This study aimed to investigate the effect of individualized feedback on exercise adherence, body composition, and physical function during a remote home-based training intervention utilizing the video-based exercise system “SUKUBARA^®”. Methods: In total, 66 care facility workers were randomly categorized into either a feedback (FB) group or a non-feedback (NF) group. Both groups performed a combined exercise program comprising low-load resistance training (slow squats) and balance exercises (one-leg standing time of closed eye) for approximately 15 min, thrice weekly over 12 weeks. The FB group received individualized feedback sheets visualizing total video play time (TT), exercise frequency, and interruptions, alongside reminder emails. The primary outcome was TT. Secondary outcomes included body composition measures (body weight, fat-free mass, and body fat mass rate) and one-leg standing time of opened eye. Results: The FB group demonstrated significantly greater TT, approximately 1.5 times that of the NF group, indicating enhanced exercise adherence. Moreover, significant improvements in fat-free mass and body fat mass rate were observed in the FB group. A significant correlation was identified between changes in TT and body composition parameters, suggesting TT as a valid proxy for exercise engagement. Conclusions: Individualized feedback within a remote monitoring home exercise program effectively improved exercise adherence and body composition among care workers. The “SUKUBARA^®” system shows promise as a tool to support exercise continuity in occupational health and long-term care settings. Full article

Seepage erosion around sheet pile walls represents a critical failure mechanism in geotechnical engineering, yet the underlying mechanisms governing the onset of erosion remain poorly understood. This study presents a comprehensive multi-scale investigation employing a coupled computational fluid dynamics (CFD)-discrete element method (DEM) to elucidate the onset mechanisms of seepage erosion in gap-graded soils with varying the fines content under different hydraulic gradients. The results demonstrate that increasing the fines content enhances the overall erosion resistance, as evidenced by reduced particle mobilization and eroded mass ratio. Particle tracking analysis reveals that the fines content fundamentally influences the spatial distribution of the erosion. Specimens with low fines content exhibit distributed erosion throughout the domain, while specimens with higher fines content show concentrated erosion around the sheet pile wall and downstream regions. Micromechanical analysis of local contact fabric and contact forces indicates that this spatial heterogeneity stems from the mechanical coordination number and mechanical redundancy, characterized by the reduced magnitudes of these parameters for the region with lower erosion resistance. These findings establish that the fines content governs both global erosion resistance and spatial erosion patterns, providing essential insights for optimizing soil gradation design and advancing fundamental understanding of seepage erosion mechanisms. Full article

In the present study, the reflection and transmission of radiation in submicron indium tin oxide (ITO) films deposited on a borosilicate glass substrate are experimentally investigated for a wide spectral range, including ultraviolet, visible, infrared and terahertz regions. Theoretical modeling of the spectra is performed using the transfer matrix method. The interaction of electromagnetic radiation with ITO is considered in the framework of the Drude model. The simulated spectra are in good agreement with the experimental ones. New non-destructive methods for determining the ITO film parameters (sheet resistivity, thickness, electron concentration and mobility) have been developed. They are based on a fitting procedure for reflectivity and/or transmittance spectra. Full article

The electric energy metering box serves as a crucial node in power grid operations, offering essential protection for key components in the distribution network, such as smart meters, data acquisition terminals, and circuit breakers, thereby ensuring their safe and reliable operation. However, the non-metallic housings of these boxes are susceptible to aging under environmental stress, which can result in diminished flame-retardant properties and an increased risk of fire. Currently, there is a lack of rapid and accurate methods for assessing the fire resistance of non-metallic metering box enclosures. In this study, laser-induced breakdown spectroscopy (LIBS), which enables fast, multi-element, and non-contact analysis, was utilized to develop an effective assessment approach. Thermal aging experiments were conducted to systematically investigate the degradation patterns and mechanisms underlying the reduced flame-retardant performance of sheet molding compound (SMC), a representative non-metallic material used in metering box enclosures. The results showed that the intensity ratio of aluminum ionic spectral lines is highly correlated with the flame-retardant grade, serving as an effective performance indicator. On this basis, a one-dimensional convolutional neural network (1D-CNN) model was developed utilizing LIBS data, which achieved over 92% prediction accuracy for different flame-retardant grades on the test set and demonstrated high recognition accuracy for previously unseen samples. This method offers significant potential for rapid, on-site evaluation of flame-retardant grades of non-metallic electric energy metering boxes, thereby supporting the safe and reliable operation of power systems. Full article

In this work, a sol–gel spin coating method was applied to obtain ZnO and ZnO:Ga thin films on a glass and ITO-coated glass substrate. Their structural, optical, and electrical properties were investigated with respect to their dependence on the different substrates, the number of layers (two and four), and the annealing temperature (300 and 400 °C). X-ray diffraction (XRD) patterns showed a hexagonal structure corresponding to the wurtzite phase for ZnO and ZnO:Ga films. ZnO films, deposited on a glass substrate, reveal greater crystallite sizes compared with ZnO films obtained from an ITO substrate. A Ga dopant worsened film crystallization. X-Ray photoelectron spectroscopy (XPS) proves the presence of Ga in a ZnO structure. ZnO films show lower transparency and haze values up to 44.12 (glass substrate) and 33.73 (ITO substrate) at a wavelength of 550 nm. The significant enhancement of ZnO film transparency is observed with Ga doping (with average transmittance in the visible spectral range above 85%, independent of the substrate used). Sheet resistance values are lower for ZnO:Ga films, and the figure of merit values are better compared with those of undoped ZnO films. Work function is studied for ZnO and ZnO:Ga films, deposited on Si, ITO, and glass substrates. Full article