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20 pages, 14676 KB  
Article
Optimal and Model Predictive Control of Single Phase Natural Circulation in a Rectangular Closed Loop
by Aitazaz Hassan, Guilherme Ozorio Cassol, Syed Abuzar Bacha and Stevan Dubljevic
Sustainability 2025, 17(19), 8807; https://doi.org/10.3390/su17198807 - 1 Oct 2025
Viewed by 344
Abstract
Pipeline systems are essential across various industries for transporting fluids over various ranges of distances. A notable application is natural circulation through thermo-syphoning, driven by temperature-induced density variations that generate fluid flow in closed loops. This passive mechanism is widely employed in sectors [...] Read more.
Pipeline systems are essential across various industries for transporting fluids over various ranges of distances. A notable application is natural circulation through thermo-syphoning, driven by temperature-induced density variations that generate fluid flow in closed loops. This passive mechanism is widely employed in sectors such as process engineering, oil and gas, geothermal energy, solar water heaters, fertilizers, etc. Natural Circulation Loops eliminate the need for mechanical pumps. While this passive mechanism reduces energy consumption and maintenance costs, maintaining stability and efficiency under varying operating conditions remains a challenge. This study investigates thermo-syphoning in a rectangular closed-loop system and develops optimal control strategies like using a Linear Quadratic Regulator (LQR) and Model Predictive Control (MPC) to ensure stable and efficient heat removal while explicitly addressing physical constraints. The results demonstrate that MPC improves system stability and reduces energy usage through optimized control actions by nearly one-third in the initial energy requirement. Compared to the LQR and unconstrained MPC, MPC with active constraints effectively manages input limitations, ensuring safer and more practical operation. With its predictive capability and adaptability, the proposed MPC framework offers a robust, scalable solution for real-time industrial applications, supporting the development of sustainable and adaptive natural circulation pipeline systems. Full article
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42 pages, 6823 KB  
Review
Biomimetic Daytime Radiative Cooling Technology: Prospects and Challenges for Practical Application
by Jiale Wang, Haiyang Chen, Xiaxiao Tian, Dongxiao Hu, Yufan Liu, Jiayue Li, Ke Zhang, Hongliang Huang, Jie Yan and Bin Li
Materials 2025, 18(19), 4556; https://doi.org/10.3390/ma18194556 - 30 Sep 2025
Viewed by 522
Abstract
Biomimetic structures inspired by evolutionary optimized biological systems offer promising solutions to overcome current limitations in passive daytime radiative cooling (PDRC) technology, which efficiently scatters solar radiation through atmospheric windows and radiates surface heat into space without additional energy consumption. While structural biomimicry [...] Read more.
Biomimetic structures inspired by evolutionary optimized biological systems offer promising solutions to overcome current limitations in passive daytime radiative cooling (PDRC) technology, which efficiently scatters solar radiation through atmospheric windows and radiates surface heat into space without additional energy consumption. While structural biomimicry provides excellent optical performance and feasibility, its complex manufacturing and high costs limit scalability due to micro–nano fabrication constraints. Material-based biomimicry, utilizing environmentally friendly and abundant raw materials, offers greater scalability but requires improvements in mechanical durability. Adaptive biomimicry enables intelligent regulation with high responsiveness but faces challenges in system complexity, stability, and large-scale integration. These biologically derived strategies provide valuable insights for advancing radiative cooling devices. This review systematically summarizes recent progress, elucidates mechanisms of key biological structures for photothermal regulation, and explores their application potential across various fields. It also discusses current challenges and future research directions, aiming to promote deeper investigation and breakthroughs in biomimetic radiative cooling technologies. Full article
(This article belongs to the Section Biomaterials)
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45 pages, 10473 KB  
Review
Strategies for Enhancing BiVO4 Photoanodes for PEC Water Splitting: A State-of-the-Art Review
by Binh Duc Nguyen, In-Hee Choi and Jae-Yup Kim
Nanomaterials 2025, 15(19), 1494; https://doi.org/10.3390/nano15191494 - 30 Sep 2025
Viewed by 193
Abstract
Bismuth vanadate (BiVO4) has attracted significant attention as a photoanode material for photoelectrochemical (PEC) water splitting due to its suitable bandgap (~2.4 eV), strong visible light absorption, chemical stability, and cost-effectiveness. Despite these advantages, its practical application remains constrained by intrinsic [...] Read more.
Bismuth vanadate (BiVO4) has attracted significant attention as a photoanode material for photoelectrochemical (PEC) water splitting due to its suitable bandgap (~2.4 eV), strong visible light absorption, chemical stability, and cost-effectiveness. Despite these advantages, its practical application remains constrained by intrinsic limitations, including poor charge carrier mobility, short diffusion length, and sluggish oxygen evolution reaction (OER) kinetics. This review critically summarizes recent advancements aimed at enhancing BiVO4 PEC performance, encompassing synthesis strategies, defect engineering, heterojunction formation, cocatalyst integration, light-harvesting optimization, and stability improvements. Key fabrication methods—such as solution-based, vapor-phase, and electrochemical approaches—along with targeted modifications, including metal/nonmetal doping, surface passivation, and incorporation of electron transport layers, are discussed. Emphasis is placed on strategies to improve light absorption, charge separation efficiency (ηsep), and charge transfer efficiency (ηtrans) through bandgap engineering, optical structure design, and catalytic interface optimization. Approaches to enhance stability via protective overlayers and electrolyte tuning are also reviewed, alongside emerging applications of BiVO4 in tandem PEC systems and selective solar-driven production of value-added chemicals, such as H2O2. Finally, critical challenges, including the scale-up of electrode fabrication and the elucidation of fundamental reaction mechanisms, are highlighted, providing perspectives for bridging the gap between laboratory performance and practical implementation. Full article
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23 pages, 3362 KB  
Review
Polymer Functional Layers for Perovskite Solar Cells
by Jinho Lee, Jaehyeok Kang, Jong-Hoon Lee and Soonil Hong
Polymers 2025, 17(19), 2607; https://doi.org/10.3390/polym17192607 - 26 Sep 2025
Viewed by 644
Abstract
Perovskite solar cells (PSCs) are next-generation solar cells; they are replacing silicon-based solar cells due to their higher efficiency, greater cost-effectiveness, and enhanced potential for various applications. Exceeding the efficiency of crystalline silicon-based solar cells, the commercialization of PSCs has driven not only [...] Read more.
Perovskite solar cells (PSCs) are next-generation solar cells; they are replacing silicon-based solar cells due to their higher efficiency, greater cost-effectiveness, and enhanced potential for various applications. Exceeding the efficiency of crystalline silicon-based solar cells, the commercialization of PSCs has driven not only the development of perovskite photoactive materials but also charge transport layer advancements, interfacial engineering, and processing technologies. PSCs were developed later than dye-sensitized solar cells and organic solar cells; the adoption of techniques previously employed in these technologies is significant to enhancing their performance. Among them, polymers are widely employed in perovskite solar cells to facilitate efficient charge transport, provide interfacial passivation, enhance mechanical flexibility, enable solution-based processing, and improve environmental stability. In this review, we highlight the roles of polymer materials as charge transport layers, interfacial layers, and other functional layers for highly efficient and stable PSCs. Full article
(This article belongs to the Special Issue Polymer Thin Films: Synthesis, Characterization and Applications)
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24 pages, 1518 KB  
Article
Smart Matter-Enabled Air Vents for Trombe Wall Automation and Control
by Gabriel Conceição, Tiago Coelho, Afonso Mota, Ana Briga-Sá and António Valente
Electronics 2025, 14(18), 3741; https://doi.org/10.3390/electronics14183741 - 22 Sep 2025
Viewed by 645
Abstract
Improving energy efficiency in buildings is critical for supporting sustainable growth in the construction sector. In this context, the implementation of passive solar solutions in the building envelope plays an important role. Trombe wall is a passive solar system that presents great potential [...] Read more.
Improving energy efficiency in buildings is critical for supporting sustainable growth in the construction sector. In this context, the implementation of passive solar solutions in the building envelope plays an important role. Trombe wall is a passive solar system that presents great potential for passive solar heating purposes. However, its performance can be enhanced when the Internet of Things is applied. This study employs a multi-domain smart system based on Matter-enabled IoT technology for maximizing Trombe wall functionality using appropriate 3D-printed ventilation grids. The system includes ESP32-C6 microcontrollers with temperature sensors and ventilation grids controlled by actuated servo motors. The system is automated with a Raspberry Pi 5 running Home Assistant OS with Matter Server. The integration of the Matter protocol provides end-to-end interoperability and secure communication, avoiding traditional systems based on MQTT. This work demonstrates the technical feasibility of implementing smart ventilation control for Trombe walls using a Matter-enabled infrastructure. The system proves to be capable of executing real-time vent management based on predefined temperature thresholds. This setup lays the foundation for scalable and interoperable thermal automation in passive solar systems, paving the way for future optimizations and addicional implementations, namely in order to improve indoor thermal comfort in smart and more efficient buildings. Full article
(This article belongs to the Special Issue Parallel and Distributed Computing for Emerging Applications)
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22 pages, 2805 KB  
Article
Enhancing PV Module Efficiency Through Fins-and-Tubes Cooling: An Outdoor Malaysian Case Study
by Ihsan Okta Harmailil, Sakhr M. Sultan, Ahmad Fudholi, Masita Mohammad and C. P. Tso
Processes 2025, 13(9), 2812; https://doi.org/10.3390/pr13092812 - 2 Sep 2025
Viewed by 618
Abstract
One of the most important applications of solar energy is electricity generation using photovoltaic (PV) panels. Yet, as the temperature of PV modules rises, both their efficiency and service life decline. A common approach to mitigate this issue is cooling with fins, a [...] Read more.
One of the most important applications of solar energy is electricity generation using photovoltaic (PV) panels. Yet, as the temperature of PV modules rises, both their efficiency and service life decline. A common approach to mitigate this issue is cooling with fins, a design that is now widely adopted. However, traditional fin-based cooling systems often fail to deliver adequate performance in hot regions with strong solar radiation. In particular, passive cooling alone shows limited effectiveness under conditions of high ambient temperatures and intense sunlight, such as those typical in Malaysia. To address this limitation, hybrid cooling strategies, especially those integrating both air and water, have emerged as promising solutions for enhancing PV performance. In this study, an experimental and economic investigations were carried out on a PV cooling system combining copper tubes and aluminium fins, tested under Malaysian climatic conditions. The economic feasibility was evaluated using the Simple Payback Period (SPP) method. An outdoor test was conducted over four consecutive days (10–13 June 2024), comparing a conventional PV module with one fitted with the hybrid cooling system (active and passive). The cooled module achieved noticeable surface temperature reductions of 2.56 °C, 2.15 °C, 2.08 °C, and 2.58 °C across the four days. The system also delivered a peak power gain of 66.85 W, corresponding to a 2.82% efficiency improvement. Economic analysis showed that the system’s payback period is 4.52 years, with the total energy value increasing by USD 477.88, representing about a 2.81% improvement compared to the reference panel. In summary, the hybrid cooling method demonstrates clear advantages in lowering panel temperature, enhancing electrical output, and ensuring favorable economic performance. Full article
(This article belongs to the Special Issue Solar Technologies and Photovoltaic Systems)
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32 pages, 8958 KB  
Review
An Overview of Natural Cooling and Ventilation in Vernacular Architectures
by Amineddin Salimi, Ayşegül Yurtyapan, Mahmoud Ouria, Zihni Turkan and Nuran K. Pilehvarian
Wind 2025, 5(3), 21; https://doi.org/10.3390/wind5030021 - 29 Aug 2025
Cited by 1 | Viewed by 1326
Abstract
Natural cooling and ventilation have been fundamental principles in vernacular architecture for millennia, shaping sustainable building practices across diverse climatic regions. This paper examines the historical evolution, technological advancements, environmental benefits, and prospects of passive cooling strategies, with a particular focus on wind [...] Read more.
Natural cooling and ventilation have been fundamental principles in vernacular architecture for millennia, shaping sustainable building practices across diverse climatic regions. This paper examines the historical evolution, technological advancements, environmental benefits, and prospects of passive cooling strategies, with a particular focus on wind catchers. Originating in Mesopotamian, Egyptian, Caucasia, and Iranian architectural traditions, these structures have adapted over centuries to maximize air circulation, thermal regulation, and humidity control, ensuring comfortable indoor environments without reliance on mechanical ventilation. This study analyzes traditional wind catcher designs, highlighting their geometric configurations, airflow optimization, and integration with architectural elements such as courtyards and solar chimneys. Through a comparative assessment, this paper contrasts passive cooling systems with modern HVAC technologies, emphasizing their energy neutrality, low-carbon footprint, and long-term sustainability benefits. A SWOT analysis evaluates their strengths, limitations, opportunities for technological integration, and challenges posed by urbanization and regulatory constraints. This study adopts a comparative analytical method, integrating a literature-based approach with qualitative assessments and a SWOT analysis framework to evaluate passive cooling strategies against modern HVAC systems. Methodologically, the research combines historical review, typological classification, and sustainability-driven performance comparisons to derive actionable insights for climate-responsive design. The research is grounded in a comparative assessment of traditional and modern cooling strategies, supported by typological analysis and evaluative frameworks. Looking toward the future, the research explores hybrid adaptations incorporating solar energy, AI-driven airflow control, and retrofitting strategies for smart cities, reinforcing the enduring relevance of vernacular cooling techniques in contemporary architecture. By bridging historical knowledge with innovative solutions, this paper contributes to ongoing discussions on climate-responsive urban planning and sustainable architectural development. Full article
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26 pages, 4512 KB  
Article
Adapting Energy Conservation Building Code-2023 for the Diverse Climates of Pakistan: A Path to Affordable Energy Efficiency and Sustainable Living
by Tahir Mehmood, Tanzeel ur Rashid, Muhammad Usman, Muzaffar Ali, Daud Mustafa Minhas and Georg Frey
Buildings 2025, 15(17), 3053; https://doi.org/10.3390/buildings15173053 - 26 Aug 2025
Viewed by 691
Abstract
In Pakistan and most other developing nations, the residential building sector is one of the highest energy-consuming domains. The residential sector has the highest share of 50% of final electricity use of the country. Though Energy Conservation Building Codes (ECBC-2023) provide structured energy [...] Read more.
In Pakistan and most other developing nations, the residential building sector is one of the highest energy-consuming domains. The residential sector has the highest share of 50% of final electricity use of the country. Though Energy Conservation Building Codes (ECBC-2023) provide structured energy guidelines, no work has been performed to quantify the actual energy-saving potential of code-compliant retrofits in residential buildings. This study investigates the performance of ECBC-compliant retrofitting strategies for residential buildings under Pakistan’s diverse climatic conditions. The Passive House Planning Package (PHPP), a validated simulation tool, was used to assess energy performance improvements through building envelope interventions such as thermal insulation, solar shading, window glazing, and optimal orientation. Field data were collected from three representative cities, Multan (hot desert), Taxila (humid subtropical), and Quetta (cold semi-arid), to simulate both conventional and energy-efficient building scenarios. The results showed substantial seasonal energy savings in all three climates. During the heating period, energy savings were 48%, 50%, and 60% for Taxila, Multan, and Quetta, respectively. Similarly, energy savings during the cooling season were 44%, 33%, and 16%. Life cycle economic analysis revealed that these retrofits yielded Net Present Values (NPVs) of USD 752 (Taxila), USD 1226 (Multan), and USD 1670 (Quetta) over a 30-year period, with discounted payback periods ranging from 6 to 10 years. Furthermore, a life cycle assessment demonstrated that retrofitted buildings yielded up to 26% reduction in overall carbon emissions, combining both embodied and operational sources. The findings highlight that ECBC-2023 is not only a technically viable solution for energy savings but also financially attractive in residential retrofitting. By incorporating localized climate responsiveness into ECBC-compliant building design, the study provides a practical roadmap for achieving Pakistan’s energy efficiency goals. Additionally, the outcomes serve as a basis for informing policy initiatives, supporting building code adaptation, and raising public awareness of sustainable housing practices. Full article
(This article belongs to the Special Issue Building Energy-Saving Technology—3rd Edition)
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25 pages, 4397 KB  
Article
Towards Climate-Resilient Dwellings: A Comparative Analysis of Passive and Active Retrofit Solutions in Aging Central European Housing Stock
by Joanna Ferdyn-Grygierek and Krzysztof Grygierek
Energies 2025, 18(16), 4386; https://doi.org/10.3390/en18164386 - 18 Aug 2025
Viewed by 518
Abstract
This article evaluates the effectiveness of various energy retrofit solutions—both passive and active—for reducing energy demand and improving indoor thermal conditions in apartments of typical multifamily buildings in Central Europe, considering current and future climate conditions. This study combines computer-based co-simulations (EnergyPlus and [...] Read more.
This article evaluates the effectiveness of various energy retrofit solutions—both passive and active—for reducing energy demand and improving indoor thermal conditions in apartments of typical multifamily buildings in Central Europe, considering current and future climate conditions. This study combines computer-based co-simulations (EnergyPlus and CONTAM) with in situ thermal measurements to identify challenges in maintaining indoor thermal conditions and to support model validation. Key indicators include the number of thermal discomfort hours and heating and cooling demand. The evaluated strategies include passive measures (wall insulation, green or reflective roofs, roller blinds, solar protective glazing) and active solutions such as mechanical cooling. The comfort operative temperature range of the adaptive model is adopted as a measure of thermal comfort and the energy demand in individual apartments as a measure of energy efficiency. The simulation results showed that solar protective glazing combined with a reflective roof reduced thermal discomfort hours by up to 95%, while modern windows alone decreased them by 90% and lowered heating demand by 18%. In contrast, typical passive solutions such as internal blinds or balconies were significantly less effective, reducing discomfort hours by only 11–42%. These findings highlight that, while no single retrofit measure is universally optimal, well-selected passive or hybrid strategies can substantially improve summer comfort, maintain winter efficiency, and reduce long-term reliance on energy-intensive cooling systems in aging multifamily housing. Full article
(This article belongs to the Special Issue Building Energy Performance Modelling and Simulation)
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34 pages, 7297 KB  
Article
Passive Design for Residential Buildings in Arid Desert Climates: Insights from the Solar Decathlon Middle East
by Esra Trepci and Edwin Rodriguez-Ubinas
Buildings 2025, 15(15), 2731; https://doi.org/10.3390/buildings15152731 - 2 Aug 2025
Viewed by 2340
Abstract
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, [...] Read more.
This study investigates the effectiveness of passive design in low-rise residential buildings located in arid desert climates, using the Dubai Solar Decathlon Middle East (SDME) competition as a case study. This full-scale experiment offers a unique opportunity to evaluate design solutions under controlled, realistic conditions; prescriptive, modeled performance; and monitored performance assessments. The prescriptive assessment reviews geometry, orientation, envelope thermal properties, and shading. Most houses adopt compact forms, with envelope-to-volume and envelope-to-floor area ratios averaging 1 and 3.7, respectively, and window-to-wall ratios of approximately 17%, favoring north-facing openings to optimize daylight while reducing heat gain. Shading is strategically applied, horizontal on south façades and vertical on east and west. The thermal properties significantly exceed the local code requirements, with wall performance up to 80% better than that mandated. The modeled assessment uses Building Energy Models (BEMs) to simulate the impact of prescriptive measures on energy performance. Three variations are applied: assigning minimum local code requirements to all the houses to isolate the geometry (baseline); removing shading; and applying actual envelope properties. Geometry alone accounts for up to 60% of the variation in cooling intensity; shading reduces loads by 6.5%, and enhanced envelopes lower demand by 14%. The monitored assessment uses contest-period data. Indoor temperatures remain stable (22–25 °C) despite outdoor fluctuations. Energy use confirms that houses with good designs and airtightness have lower cooling loads. Airtightness varies widely (avg. 14.5 m3/h/m2), with some well-designed houses underperforming due to construction flaws. These findings highlight the critical role of passive design as the first layer for improving the energy performance of the built environment and advancing toward net-zero targets, specifically in arid desert climates. Full article
(This article belongs to the Special Issue Climate-Responsive Architectural and Urban Design)
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20 pages, 2071 KB  
Article
Thermal Performance and Energy Efficiency Evaluation of Building Envelopes Incorporating Trombe Walls, PCM, and Multi-Alveolar Structures in Tunisian Climate
by Nour Lajimi, Noureddine Boukadida, Chemseddine Maatki, Bilel Hadrich, Walid Hassen, Lioua Kolsi and Habib Ben Aissia
Buildings 2025, 15(14), 2575; https://doi.org/10.3390/buildings15142575 - 21 Jul 2025
Viewed by 558
Abstract
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar [...] Read more.
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar heat and distribute it evenly throughout the interior. This study evaluated thermal comfort by examining the effects of phase change materials and multi-alveolar structures combined with a Trombe wall on the thermal behavior of a building and improving the thermal inertia of brick walls. Numerical simulations using Visual FORTRAN were conducted to evaluate the thermal properties of different configurations under the climatic conditions recorded in Hammam Sousse, Tunisia. The results show that the integration of the Trombe wall and PCM has a significant impact on interior temperature stability, energy consumption, and overall thermal comfort. The combined effect of the MAS and PCM with the Trombe wall improved heat gain in winter and spring, reaching a low thermal damping factor of 40% in March, reducing heating power, and optimizing thermal comfort for occupants. Full article
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31 pages, 3874 KB  
Review
Vertical-Axis Wind Turbines in Emerging Energy Applications (1979–2025): Global Trends and Technological Gaps Revealed by a Bibliometric Analysis and Review
by Beatriz Salvador-Gutierrez, Lozano Sanchez-Cortez, Monica Hinojosa-Manrique, Adolfo Lozada-Pedraza, Mario Ninaquispe-Soto, Jorge Montaño-Pisfil, Ricardo Gutiérrez-Tirado, Wilmer Chávez-Sánchez, Luis Romero-Goytendia, Julio Díaz-Aliaga and Abner Vigo-Roldán
Energies 2025, 18(14), 3810; https://doi.org/10.3390/en18143810 - 17 Jul 2025
Viewed by 2920
Abstract
This study provides a comprehensive overview of vertical-axis wind turbines (VAWTs) for emerging energy applications by combining a bibliometric analysis and a thematic mini-review. Scopus-indexed publications from 1979 to 2025 were analyzed using PRISMA guidelines and bibliometric tools (Bibliometrix, CiteSpace, and VOSviewer) to [...] Read more.
This study provides a comprehensive overview of vertical-axis wind turbines (VAWTs) for emerging energy applications by combining a bibliometric analysis and a thematic mini-review. Scopus-indexed publications from 1979 to 2025 were analyzed using PRISMA guidelines and bibliometric tools (Bibliometrix, CiteSpace, and VOSviewer) to map global research trends, and a parallel mini-review distilled recent advances into five thematic areas: aerodynamic strategies, advanced materials, urban integration, hybrid systems, and floating offshore platforms. The results reveal that VAWT research output has surged since 2006, led by China with strong contributions from Europe and North America, and is concentrated in leading renewable energy journals. Dominant topics include computational fluid dynamics (CFD) simulations, performance optimization, wind–solar hybrid integration, and adaptation to turbulent urban environments. Technologically, active and passive aerodynamic innovations have boosted performance albeit with added complexity, remaining mostly at moderate technology readiness (TRL 3–5), while advanced composite materials are improving durability and fatigue life. Emerging applications in microgrids, building-integrated systems, and offshore floating platforms leverage VAWTs’ omnidirectional, low-noise operation, although challenges persist in scaling up, control integration, and long-term field validation. Overall, VAWTs are gaining relevance as a complement to conventional turbines in the sustainable energy transition, and this study’s integrated approach identifies critical gaps and high-priority research directions to accelerate VAWT development and help transition these turbines from niche prototypes to mainstream renewable solutions. Full article
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18 pages, 8362 KB  
Article
Thermal Performance of Trombe Walls with Inclined Glazing and Guided Vanes
by Albert Jorddy Valenzuela Inga, Patrick Cuyubamba, Boris Senin Carhuallanqui Parian and Joel Contreras Núñez
Sustainability 2025, 17(11), 4775; https://doi.org/10.3390/su17114775 - 22 May 2025
Viewed by 698
Abstract
The Trombe Wall (TW) has gained recognition for its simplicity, efficiency, and zero operational costs, making it a key contributor to Sustainable Development Goals (SDGs) 7 and 11 by enhancing energy access and providing sustainable heating solutions. This passive solar technology is particularly [...] Read more.
The Trombe Wall (TW) has gained recognition for its simplicity, efficiency, and zero operational costs, making it a key contributor to Sustainable Development Goals (SDGs) 7 and 11 by enhancing energy access and providing sustainable heating solutions. This passive solar technology is particularly beneficial in rural areas, offering cost-effective thermal comfort while minimizing environmental impact. This study evaluates the performance of three TW configurations attached to a room, designed with inclined glazing relative to the vertical air layer and stone layers at the bottom acting as thermal mass, commonly used in rural installations in Peru. Using 2D Computational Fluid Dynamics, the analysis compares an inclined heated wall with guided vanes featuring three or five blades to a configuration without vanes. Results show that the three-blade guided flow configuration achieves the highest temperature rise of 4 °C, with a reference temperature of 20 °C, under an absorber heat flux of 200–400 W/m2, albeit with a slightly lower flow rate of 0.17–0.23 kg/s compared to the configuration without guided flow. The maximum thermal efficiency of 57.90% was observed for the three-blade configuration, which is 2.26% higher than the efficiency of the configuration without guided flow, under an absorber heat flux of 400 W/m2. The obtained path-lines reveals that the three-blade configuration minimizes flow detachment, nearly eliminates recirculation near the bottom corner of the glazing, and reduces the separation bubble at the top corner of the massive wall near the outlet. These findings highlight the potential of guided vanes to enhance the performance of Trombe Walls in rural settings. Full article
(This article belongs to the Section Energy Sustainability)
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15 pages, 2591 KB  
Article
Empirical Modeling of Seasonal Cooling Performance Based on Test Devices Using Zinc Oxide/Low-Density Polyethylene Passive Cooling Membranes
by Yinjia Zhang, Jun Natsuki, Chengwu Weng, Vuong Dinh Trung, Yiwen Wang, Lina Cui and Toshiaki Natsuki
Polymers 2025, 17(10), 1420; https://doi.org/10.3390/polym17101420 - 21 May 2025
Viewed by 702
Abstract
Outdoor structures, such as vehicles, buildings, and outdoor equipment, are prone to overheat due to prolonged exposure to solar irradiation, which could affect their service life or user experience. To address this urgent issue, we developed a climate-adaptive thermal management solution using zinc [...] Read more.
Outdoor structures, such as vehicles, buildings, and outdoor equipment, are prone to overheat due to prolonged exposure to solar irradiation, which could affect their service life or user experience. To address this urgent issue, we developed a climate-adaptive thermal management solution using zinc oxide (ZnO)/low-density polyethylene (LDPE) hybrid membranes. The cooling performance of the membrane was examined across different seasons, achieving maximum temperature reductions (T) of 12.55 °C in summer, 8.02 °C in autumn, and 2.90 °C in winter. Our results demonstrated that the material’s cooling efficiency varied with seasonal solar irradiance, showing quicker responsiveness in summer and reduced in winter, effectively preventing overcooling. Moreover, the enclosed specific volume (SV) was identified as another critical parameter affecting cooling performance. We established an empirical correlation between T and SV to quantify passive cooling performance across different seasons. This standardized method for assessing the cooling effect enables comparison between different materials, which is essential for determining climate-adaptive thermal management. Notably, the ZnO/LDPE membranes exhibited stable and balanced performance year-round, highlighting their potential for substantial energy savings in outdoor applications. This research provided valuable insights for designing climate-adaptive passive cooling materials that optimize thermal management across seasonal variations while contributing to sustainable energy conservation. Full article
(This article belongs to the Section Polymer Membranes and Films)
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10 pages, 2024 KB  
Article
Bifunctional 4,5-Diiodoimidazole Interfacial Engineering Enables Simultaneous Defect Passivation and Crystallization Control for High-Efficiency Inverted Perovskite Solar Cells
by Huaxi Gao, Yu Zhang, Ihtesham Ghani, Min Xin, Danish Khan, Junyu Wang, Di Lu, Tao Cao, Wei Chen, Xin Yang and Zeguo Tang
Nanomaterials 2025, 15(10), 766; https://doi.org/10.3390/nano15100766 - 20 May 2025
Viewed by 691
Abstract
Despite the rapid efficiency advancement of perovskite solar cells (PSCs), non-radiative recombination at the buried interface between self-assembled monolayers (SAMs) and perovskite remains a critical bottleneck, primarily due to interfacial defects and energy level mismatch. In this study, we demonstrate a bifunctional interlayer [...] Read more.
Despite the rapid efficiency advancement of perovskite solar cells (PSCs), non-radiative recombination at the buried interface between self-assembled monolayers (SAMs) and perovskite remains a critical bottleneck, primarily due to interfacial defects and energy level mismatch. In this study, we demonstrate a bifunctional interlayer engineering strategy by introducing 4,5-diiodoimidazole (4,5-Di-I) at the Me-4PACz/perovskite interface. This approach uniquely addresses two fundamental limitations of SAM-based interfaces: the insufficient defect passivation capability of conventional Me-4PACz due to steric hindrance effects and the poor perovskite wettability on hydrophobic SAM surfaces that exacerbates interfacial voids. The imidazole derivatives not only form strong Pb–N coordination bonds with undercoordinated Pb2+ but also modulate the surface energy of Me-4PACz, enabling the growth of pinhole-free perovskite films with preferential crystal orientation. The champion device with 4,5-Di-I modification achieves a power conversion efficiency (PCE) of 24.10%, with a VOC enhancement from 1.12 V to 1.14 V, while maintaining 91% of initial PCE after 1300 h in N₂ atmosphere (25 °C), demonstrating superior stability under ISOS-L-2 protocols. This work establishes a universal strategy for interfacial multifunctionality design, proving that simultaneous defect suppression and crystallization control can break the long-standing trade-off between efficiency and stability in solution-processed photovoltaics. Full article
(This article belongs to the Special Issue Advanced Nanoscale Materials and (Flexible) Devices)
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