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Search Results (296)

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Keywords = space charge measurement

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7 pages, 1890 KiB  
Article
Investigation of Temperature-Dependent Gate Degradation in Normally-Off AlGaN/GaN High-Electron-Mobility Transistor p-GaN
by Jeonghyeok Yoon and Hyungtak Kim
Electronics 2025, 14(9), 1764; https://doi.org/10.3390/electronics14091764 - 26 Apr 2025
Viewed by 182
Abstract
The effect of temperature on gate degradation behavior was analyzed in Schottky-type p-GaN gate HEMTs under a positive gate voltage. TDDB measurements were conducted at various temperatures, revealing an accelerated gate failure rate at lower temperatures. A Weibull distribution analysis was employed to [...] Read more.
The effect of temperature on gate degradation behavior was analyzed in Schottky-type p-GaN gate HEMTs under a positive gate voltage. TDDB measurements were conducted at various temperatures, revealing an accelerated gate failure rate at lower temperatures. A Weibull distribution analysis was employed to predict the 10-year rated gate voltage, showing that the rated voltage at −10 °C is significantly lower than at 60 °C. Furthermore, the derived activation energy of −0.22 eV indicates that gate degradation intensifies in colder environments. Hole accumulation occurring at the p-GaN/AlGaN interface can promote degradation by facilitating electron injection and accelerating defect generation in the presence of strong electric fields. At higher temperatures, hole release mitigates charge accumulation, thereby extending device longevity. These findings highlight the necessity of reliability assessments for p-GaN gate HEMTs suitable for environments with low temperatures, including space and polar environments. Full article
(This article belongs to the Special Issue Recent Advances in GaN Power Devices)
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12 pages, 9444 KiB  
Article
Research on the Vortex States of Partially Coherent Vortex Beams
by Weihong Sun, Xiangyu Meng, Junchao Ren, Huainan Yu and Yong Wang
Photonics 2025, 12(4), 358; https://doi.org/10.3390/photonics12040358 - 10 Apr 2025
Viewed by 177
Abstract
The Mutual Optical Intensity (MOI) model is further developed to simulate the propagation of partially coherent X-ray vortex beams through free space. The intensity, phase, and amplitude distributions of the degree of coherence in the far field zone are numerically calculated using the [...] Read more.
The Mutual Optical Intensity (MOI) model is further developed to simulate the propagation of partially coherent X-ray vortex beams through free space. The intensity, phase, and amplitude distributions of the degree of coherence in the far field zone are numerically calculated using the MOI model. The effects of the coherence property and topological charge on the vortex beam are analyzed. For Gaussian Schell-model vortex beams, a vortex structure appears around the coherence singularity at the amplitude distribution of the degree of coherence relative to the central point. The number and rotation direction of the vortex structure are consistent with the magnitude and sign of the topological charge of the partially coherent vortex beam. As the spatial coherence decreases, the size of the vortex structure for the phase and amplitude distributions of the degree of coherence gradually increase until they disappear. The intensity of the dark hollow region increases with increasing topological charge. In addition, for the Laguerre–Gaussian Schell-model vortex beam, there is no singularity or vortex structure at the amplitude distribution of the degree of coherence relative to the central point. Therefore, the vortex structure around the coherence singularity at the amplitude distributions of the degree of coherence relative to the central point can be used to measure the vortex beam types and topological charge. Full article
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22 pages, 6031 KiB  
Article
Investigation of the Electrical Properties of Polycrystalline Crednerite CuMn1−xMgxO2 (x = 0–0.06)-Type Materials in a Low-Frequency Field
by Iosif Malaescu, Maria Poienar and Catalin N. Marin
Crystals 2025, 15(2), 184; https://doi.org/10.3390/cryst15020184 - 14 Feb 2025
Viewed by 515
Abstract
CuMn1−xMgxO2 (x = 0–0.06) polycrystalline samples were prepared using the hydrothermal method at T = 100 °C for 24 h in Teflon-line stainless steel autoclaves. The samples were crystallized, forming crednerite structures (C2/m space group), and the Mg [...] Read more.
CuMn1−xMgxO2 (x = 0–0.06) polycrystalline samples were prepared using the hydrothermal method at T = 100 °C for 24 h in Teflon-line stainless steel autoclaves. The samples were crystallized, forming crednerite structures (C2/m space group), and the Mg2+ substitution onto the Mn3+ site induced small changes in the unit cell parameters and volume. Based on complex impedance measurements made between 20 Hz and 2 MHz, at different concentrations of Mg ions (x), the electrical conductivity (σ), the electric modulus (M), and the complex dielectric permittivity (ε) were determined. The conductivity spectrum, σ(f, x), follows the Jonscher universal law and enables the determination of the static conductivity (σDC) of the samples. The results showed that, when increasing the concentration x from 0 to 6%, σDC varied from 15.36 × 10−5 S/m to 16.42 × 10−5 S/m, with a minimum of 4.85 × 10−5 S/m found at a concentration of x = 4%. Using variable range hopping (VRH) and correlated barrier hopping (CBH) theoretical models, the electrical mechanism in the samples was explained. The band gap energy (Wm), charge carrier mobility (μ), number density (NC) of effective charge carriers, and hopping frequency (ωh) were evaluated at different concentrations (x) of substitution with Mg. In addition, using measurements of the temperature dependence of σDC(T) between 300 and 400 K, the thermal activation energy (EA) of the samples was evaluated. Additionally, the dielectric behavior of the samples was explained by the interfacial relaxation process. This knowledge of the electrical properties of the CuMn1−xMgxO2 (x = 0–0.06) polycrystalline crednerite is of interest for their use in photocatalytic, electronic, or other applications. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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14 pages, 5253 KiB  
Article
Research on Monitoring Methods for Electrostatic Discharge Pulses in Spacecraft Dielectric Materials
by Hong Yin, Cunhui Li, Chengxuan Zhao, Xiaogang Qin, Xiaojin Lu, Xuan Wen, Liang Shi, Qing Liu, Jun Wang, Hanwu Jia and Shengsheng Yang
Micromachines 2025, 16(2), 180; https://doi.org/10.3390/mi16020180 - 31 Jan 2025
Viewed by 848
Abstract
Space particle radiation induces charging and discharging phenomena in spacecraft dielectric materials, leading to electrostatic discharge (ESD) and electromagnetic pulses (EMP), which pose significant risks to spacecraft electronic systems by causing interference and potential damage. Accurate and timely monitoring of these phenomena, combined [...] Read more.
Space particle radiation induces charging and discharging phenomena in spacecraft dielectric materials, leading to electrostatic discharge (ESD) and electromagnetic pulses (EMP), which pose significant risks to spacecraft electronic systems by causing interference and potential damage. Accurate and timely monitoring of these phenomena, combined with a comprehensive understanding of their underlying mechanisms, is critical for developing effective protection strategies against satellite charging effects. Addressing in-orbit monitoring requirements, this study proposes the design of a compact sleeve monopole antenna. Through simulations, the relationships between the antenna’s design parameters and its voltage standing wave ratio (VSWR) are analyzed alongside its critical performance characteristics, including frequency band, gain, radiation pattern, and matching circuit. The proposed antenna demonstrates operation within a frequency range of (28.73–31.25) MHz (VSWR < 2), with a center frequency of 30 MHz and a relative bandwidth of 8.4%. Performance evaluations and simulation-based experiments reveal that the antenna can measure pulse signals with electric field strengths ranging from (−1000 to −80) V/m and (80 to 1000) V/m, centered at 25.47 MHz. It reliably monitors discharge pulses generated by electron irradiation on spacecraft-grade FR4 (Flame-Retardant 4) dielectric materials, providing technical support for the engineering application of discharge research in space environments. Full article
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81 pages, 17721 KiB  
Review
Interactive Coupling Relaxation of Dipoles and Wagner Charges in the Amorphous State of Polymers Induced by Thermal and Electrical Stimulations: A Dual-Phase Open Dissipative System Perspective
by Jean Pierre Ibar
Polymers 2025, 17(2), 239; https://doi.org/10.3390/polym17020239 - 19 Jan 2025
Viewed by 713
Abstract
This paper addresses the author’s current understanding of the physics of interactions in polymers under a voltage field excitation. The effect of a voltage field coupled with temperature to induce space charges and dipolar activity in dielectric materials can be measured by very [...] Read more.
This paper addresses the author’s current understanding of the physics of interactions in polymers under a voltage field excitation. The effect of a voltage field coupled with temperature to induce space charges and dipolar activity in dielectric materials can be measured by very sensitive electrometers. The resulting characterization methods, thermally stimulated depolarization (TSD) and thermal-windowing deconvolution (TWD), provide a powerful way to study local and cooperative relaxations in the amorphous state of matter that are, arguably, essential to understanding the glass transition, molecular motions in the rubbery and molten states and even the processes leading to crystallization. Specifically, this paper describes and tries to explain ‘interactive coupling’ between molecular motions in polymers by their dielectric relaxation characteristics when polymeric samples have been submitted to thermally induced polarization by a voltage field followed by depolarization at a constant heating rate. Interactive coupling results from the modulation of the local interactions by the collective aspect of those interactions, a recursive process pursuant to the dynamics of the interplay between the free volume and the conformation of dual-conformers, two fundamental basic units of the macromolecules introduced by this author in the “dual-phase” model of interactions. This model reconsiders the fundamentals of the TSD and TWD results in a different way: the origin of the dipoles formation, induced or permanent dipoles; the origin of the Wagner space charges and the Tg,ρ transition; the origin of the TLL manifestation; the origin of the Debye elementary relaxations’ compensation or parallelism in a relaxation map; and finally, the dual-phase origin of their super-compensations. In other words, this paper is an attempt to link the fundamentals of TSD and TWD activation and deactivation of dipoles that produce a current signal with the statistical parameters of the “dual-phase” model of interactions underlying the Grain-Field Statistics. Full article
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17 pages, 13090 KiB  
Article
Dynamic Imaging of Projected Electric Potentials of Operando Semiconductor Devices by Time-Resolved Electron Holography
by Tolga Wagner, Hüseyin Çelik, Simon Gaebel, Dirk Berger, Peng-Han Lu, Ines Häusler, Nina Owschimikow, Michael Lehmann, Rafal E. Dunin-Borkowski, Christoph T. Koch and Fariba Hatami
Electronics 2025, 14(1), 199; https://doi.org/10.3390/electronics14010199 - 5 Jan 2025
Viewed by 1263
Abstract
Interference gating (iGate) has emerged as a groundbreaking technique for ultrafast time-resolved electron holography in transmission electron microscopy, delivering nanometer spatial and nanosecond temporal resolution with minimal technological overhead. This study employs iGate to dynamically observe the local projected electric potential within the [...] Read more.
Interference gating (iGate) has emerged as a groundbreaking technique for ultrafast time-resolved electron holography in transmission electron microscopy, delivering nanometer spatial and nanosecond temporal resolution with minimal technological overhead. This study employs iGate to dynamically observe the local projected electric potential within the space-charge region of a contacted transmission electron microscopy (TEM) lamella manufactured from a silicon diode during switching between unbiased and reverse-biased conditions, achieving a temporal resolution of 25 ns at a repetition rate of 3 MHz. By synchronizing the holographic acquisition with the applied voltage, this approach enables the direct visualization of time-dependent potential distributions with high precision. Complementary static and dynamic experiments reveal a remarkable correspondence between modeled and measured projected potentials, validating the method’s robustness. The observed dynamic phase progressions resolve and allow one to differentiate between localized switching dynamics and preparation-induced effects, such as charge recombination near the sample edges. These results establish iGate as a transformative tool for operando investigations of semiconductor devices, paving the way for advancing the nanoscale imaging of high-speed electronic processes. Full article
(This article belongs to the Section Optoelectronics)
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14 pages, 13798 KiB  
Article
An Unenclosed Quasi-Static Cavity Resonator-Based Ubiquitous 3-D Wireless Power Transfer System Supporting Simultaneous Through-Wall Wireless Communications
by Qiaoli Zhang, Lingao Fan, Fangcheng Ren, Zhen Yue, Deshuang Zhao, Shuai Ding and Bingzhong Wang
Micromachines 2025, 16(1), 13; https://doi.org/10.3390/mi16010013 - 26 Dec 2024
Viewed by 818
Abstract
With the emergence of the Internet of Things (IoT), the demand on the wireless power supply to consumer electronics simultaneously requires much more location freedom, ease of use, and performance with wireless communications. In this paper, an unenclosed quasi-static cavity resonator (QSCR) constructed [...] Read more.
With the emergence of the Internet of Things (IoT), the demand on the wireless power supply to consumer electronics simultaneously requires much more location freedom, ease of use, and performance with wireless communications. In this paper, an unenclosed quasi-static cavity resonator (QSCR) constructed with metallic strips and the design method are proposed and theoretically analyzed. This unenclosed QSCR has a simple structure, which benefits the wireless charging for portable/wearable electronics and smart appliances in the office and home environment. Meanwhile, it can achieve simultaneous ubiquitous 3-dimensional (3-D) wireless power transfer (WPT) inside the cavity and through-wall wireless communications with external electronic devices. Simulation and experimentation are performed to verify the theoretical analysis of the proposed cavity resonator and the WPT system based on it. As demonstrated, at a powering frequency of 6.78 MHz, the unenclosed QSCR can wirelessly transfer power to the receivers with a maximum power transfer efficiency of 90.5%, and an efficiency exceeding 51.5% is obtained at almost any position within the cavity space. The measured through-wall wireless communication channel attenuation introduced by the unenclosed QSCR is below 2.87 dB. By adjusting the inserted lumped capacitor value, the system can work at any desired frequency. Full article
(This article belongs to the Special Issue Self-Assembly Circuits and Systems for Wireless Applications)
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15 pages, 5707 KiB  
Article
Space Environment Monitoring Unit on Wentian Laboratory Cabin Module of China Space Station
by Huanxin Zhang, Guohong Shen, Donghui Hou, Shenyi Zhang, Chunqin Wang, Ying Sun, Liping Wang and Jiajie Liao
Aerospace 2024, 11(12), 1006; https://doi.org/10.3390/aerospace11121006 - 5 Dec 2024
Viewed by 731
Abstract
This article introduces the design and development of a space environment monitoring unit embedded in the versatile experimental assembly for electronic components outside the China space station’s Wentian laboratory cabin module. A newly designed comprehensive detection system is being used for the first [...] Read more.
This article introduces the design and development of a space environment monitoring unit embedded in the versatile experimental assembly for electronic components outside the China space station’s Wentian laboratory cabin module. A newly designed comprehensive detection system is being used for the first time in this kind of detector. The sensor head of the instrument includes a silicon telescope (composed of two silicon semiconductors) for measuring the LET spectrum and radiation dose rate, a typical chip for monitoring a single-event upset, and a CR-39 plastic nuclear track detector for detecting heavy ion tracks. The two silicon sensors stacked up and down are used for measuring the LET spectrum, which ranges from 0.001 to 100 MeV·cm2/mg. A sensor charge allocation method is adopted to divide the detection range into four cascaded levels, each achieving different detection ranges separately and then concatenated together, while traditional detection methods need multiple sets of probes to achieve the same dynamic range. At the same time, using the two sensors mentioned above, the silicon absorption dose rate under two different shielding thicknesses can be obtained through calculation, ranging from 10−5 to 10−1 rad (Si)/h. Multiple calibration methods are applied on the ground. The preliminary in-orbit detection results are provided and compared with the simulation results obtained using the existing space environment model, and we analyze and discuss their differences. Full article
(This article belongs to the Special Issue Deep Space Exploration)
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13 pages, 2544 KiB  
Article
Research on High-Precision and Wide-Range Spacecraft Potential Measurement Method Based on Capacitive Voltage Division
by Hong Yin, Haibo Liu, Xiaogang Qin, Qing Liu, Jun Wang, Xuan Wen, Peng Wang, Zixin Yu and Shengsheng Yang
Sensors 2024, 24(23), 7583; https://doi.org/10.3390/s24237583 - 27 Nov 2024
Cited by 1 | Viewed by 683
Abstract
The charging and discharging of satellite surfaces induced by the space plasma environment constitute a primary cause of spacecraft anomalies, particularly in geosynchronous orbits subject to geomagnetic substorms and hot plasma injections from the magnetotail, where satellites are prone to unequal high-potential charging, [...] Read more.
The charging and discharging of satellite surfaces induced by the space plasma environment constitute a primary cause of spacecraft anomalies, particularly in geosynchronous orbits subject to geomagnetic substorms and hot plasma injections from the magnetotail, where satellites are prone to unequal high-potential charging, significantly impacting the safe and reliable operation of spacecraft. Addressing the need for measuring these unequal charge states, a high-precision, wide-range spacecraft potential measurement method based on capacitive voltage division was investigated. This study analyzed the mechanism of potential measurement and the factors contributing to errors during the measurement process, explored optimal design methodologies, and innovatively developed a fundamental charge zeroing method to resolve output drift issues caused by accumulated errors fundamentally. Consequently, a non-contact potential measurement system was developed, featuring a measurement range of up to −15,000 V, a resolution below 15 V, and a nonlinear error of less than 0.1%. This system provides technical support for monitoring the potential state of spacecraft and ensuring their safety and protection. Full article
(This article belongs to the Section Electronic Sensors)
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19 pages, 2630 KiB  
Article
Enhancing Long-Term Robustness of Inter-Space Laser Links in Space Gravitational Wave Detection: An Adaptive Weight Optimization Method for Multi-Attitude Sensors Data Fusion
by Zhao Cui, Xue Wang, Jinke Yang, Haoqi Shi, Bo Liang, Xingguang Qian, Zongjin Ye, Jianjun Jia, Yikun Wang and Jianyu Wang
Remote Sens. 2024, 16(22), 4179; https://doi.org/10.3390/rs16224179 - 8 Nov 2024
Cited by 1 | Viewed by 638
Abstract
The stable and high-precision acquisition of attitude data is crucial for sustaining the long-term robustness of laser links to detect gravitational waves in space. We introduce an effective method that utilizes an adaptive weight optimization approach for the fusion of attitude data obtained [...] Read more.
The stable and high-precision acquisition of attitude data is crucial for sustaining the long-term robustness of laser links to detect gravitational waves in space. We introduce an effective method that utilizes an adaptive weight optimization approach for the fusion of attitude data obtained from charge-coupled device (CCD) spot-positioning-based attitude measurements, differential power sensing (DPS), and differential wavefront sensing (DWS). This approach aims to obtain more robust and lower-noise-level attitude data. A system is designed based on the Michelson interferometer for link simulations; validation experiments are also conducted. The experimental results demonstrate that the fused data exhibit higher robustness. Even in the case of a single sensor failure, valid attitude data can still be obtained. Additionally, the fused data have lower noise levels, with root mean square errors of 9.5%, 37.4%, and 93.4% for the single CCD, DPS, and DWS noise errors, respectively. Full article
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27 pages, 3935 KiB  
Article
Dynamic Adaptive Charging Network Planning Under Deep Uncertainties
by Ehsan Saqib and Gyozo Gidófalvi
Energies 2024, 17(21), 5378; https://doi.org/10.3390/en17215378 - 29 Oct 2024
Viewed by 914
Abstract
Charging infrastructure is the backbone of electromobility. Due to new charging behaviors and power distribution and charging space constraints, the energy demand and supply patterns of electromobility and the locations of current refueling stations are misaligned. Infrastructure developers (charging point operators, fleet operators, [...] Read more.
Charging infrastructure is the backbone of electromobility. Due to new charging behaviors and power distribution and charging space constraints, the energy demand and supply patterns of electromobility and the locations of current refueling stations are misaligned. Infrastructure developers (charging point operators, fleet operators, grid operators, vehicle manufacturers, and real-estate developers) need new methodologies and tools that help reduce the cost and risk of investments. To this extent we propose a transport-energy-demand-centric, dynamic adaptive planning approach and a data-driven Spatial Decision Support System (SDSS). In the SDSS, with the help of a realistic digital twin of an electrified road transport system, infrastructure developers can quickly and accurately estimate key performance measures (e.g., charging demand, Battery Electric Vehicle (BEV) enablement) of a candidate charging location or a network of locations under user-specified transport electrification scenarios and constraints and interactively and continuously calibrate and/or expand their network plans as facts about the deep uncertainties about the supply side of transport electrification (i.e., access to grid capacity and real-estate and presence of competition) are gradually discovered/observed. This paper describes the components and the planning support of the SDSS and how these can be used in competitive and collaborative settings. Qualitative user evaluations of the SDSS with 33 stakeholder organizations in commercial discussions and pilots have shown that both transport-energy-demand-centric and dynamic adaptive planning of charging infrastructure planning are useful. Full article
(This article belongs to the Section F: Electrical Engineering)
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17 pages, 4895 KiB  
Article
Effect of Temperature and Electric Field Strength on Carrier Mobility of Oil-Impregnated Pressboard Under DC Voltage
by Jun Deng, Zhicheng Xie, Hao Ge, Xiaoqiang Xue, Chunjia Gao, Jianwei Cheng, Haibin Zhou, Zhicheng Pan, Gang Lyu and Heng Wu
Energies 2024, 17(21), 5338; https://doi.org/10.3390/en17215338 - 26 Oct 2024
Viewed by 1131
Abstract
The influence of carrier mobility on the space charge transport behavior inside the oil-impregnated pressboard insulation of converter transformers cannot be neglected. However, at present, current knowledge is usually derived from empirical or theoretical values, lacks experimental studies, and often ignores the effects [...] Read more.
The influence of carrier mobility on the space charge transport behavior inside the oil-impregnated pressboard insulation of converter transformers cannot be neglected. However, at present, current knowledge is usually derived from empirical or theoretical values, lacks experimental studies, and often ignores the effects of temperature and field strength under actual operating conditions. In this paper, based on the variable-temperature surface potential decay (SPD) method, a carrier mobility measurement platform for oil-impregnated pressboard is established, and the carrier mobility values for different combinations of oil and oil-impregnated pressboard are obtained experimentally to analyze and reveal the influence mechanisms of temperature and field strength on the carrier mobility. The results indicate the following: (1) The positive and negative carrier mobilities of oil-impregnated pressboard are in the range of 10−12–10−13 m2·V−1·s−1, and the negative carrier mobility is always higher than the positive carrier mobility. (2) The carrier mobility is positively correlated with the changes of temperature and field strength, and when the temperature increases from 20 °C to 80 °C, the positive and negative carrier mobilities increase by 4.01 times and 4.72 times, respectively; when the field strength increases from 1 kV/mm to 7 kV/mm, the positive and negative carrier mobility increases by 2.53 and 2.72 times, respectively. (3) The carrier mobility of the pressboard with a higher oil absorption rate changes more significantly with temperature; when the field strength is 7 kV/mm and the temperature increases from 20 °C to 80 °C, the positive polarity carrier mobility increases from 3.96 × 10−13 m2·V−1·s−1 to 2.64 × 10−11 m2·V−1·s−1, an increase of 66.67 times, while the increase in the carrier mobility of the pressboard with a lower oil absorption rate is only 1.59 times. (4) The carrier mobility of the naphthenic transformer oil-impregnated pressboard is higher than that of the paraffin-based transformer oil-impregnated pressboard, and the carrier mobility of two kinds of naphthenic transformer oil-impregnated pressboard is 3.16 times and 2.47 times higher than that of the paraffin-based transformer oil-impregnated pressboard, respectively, under the conditions of 60 °C and 7 kV/mm. (5) Utilizing the Darcy model and microscopic scanning results of the pressboard morphology, it was revealed that permeability and fiber structure are key factors influencing the variation in carrier mobility. The research results of this paper can provide theoretical basis for the calibration and optimization of the oil-pressboard insulation structure of converter transformers. Full article
(This article belongs to the Section F: Electrical Engineering)
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10 pages, 1905 KiB  
Article
Unraveling Asymmetric Electrochemical Kinetics in Low-Mass-Loading LiNi1/3Mn1/3Co1/3O2 (NMC111) Li-Metal All-Solid-State Batteries
by Byoung-Nam Park
Materials 2024, 17(20), 5014; https://doi.org/10.3390/ma17205014 - 14 Oct 2024
Cited by 2 | Viewed by 1205
Abstract
In this study, we fabricated a Li-metal all-solid-state battery (ASSB) with a low mass loading of NMC111 cathode electrode, enabling a sensitive evaluation of interfacial electrochemical reactions and their impact on battery performance, using Li1.3Al0.3Ti1.7(PO4) [...] Read more.
In this study, we fabricated a Li-metal all-solid-state battery (ASSB) with a low mass loading of NMC111 cathode electrode, enabling a sensitive evaluation of interfacial electrochemical reactions and their impact on battery performance, using Li1.3Al0.3Ti1.7(PO4)3 (LATP) as the solid electrolyte. The electrochemical behavior of the battery was analyzed to understand how the solid electrolyte influences charge storage mechanisms and Li-ion transport at the electrolyte/electrode interface. Cyclic voltammetry (CV) measurements revealed the b-values of 0.76 and 0.58, indicating asymmetry in the charge storage process. A diffusion coefficient of 1.5 × 10−9 cm2⋅s−1 (oxidation) was significantly lower compared to Li-NMC111 batteries with liquid electrolytes, 1.6 × 10−8cm2⋅s−1 (oxidation), suggesting that the asymmetric charge storage mechanisms are closely linked to reduced ionic transport and increased interfacial resistance in the solid electrolyte. This reduced Li-ion diffusivity, along with the formation of space charge layers at the electrode/electrolyte interface, contributes to the observed asymmetry in charge and discharge processes and limits the rate capability of the solid-state battery, particularly at high charging rates, compared to its liquid electrolyte counterpart. Full article
(This article belongs to the Special Issue Advanced Materials for Battery Applications and Photoelectric Devices)
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16 pages, 1781 KiB  
Article
Data-Driven Modeling and Open-Circuit Voltage Estimation of Lithium-Ion Batteries
by Edgar D. Silva-Vera, Jesus E. Valdez-Resendiz, Gerardo Escobar, Daniel Guillen, Julio C. Rosas-Caro and Jose M. Sosa
Mathematics 2024, 12(18), 2880; https://doi.org/10.3390/math12182880 - 15 Sep 2024
Viewed by 1232
Abstract
This article presents a data-driven methodology for modeling lithium-ion batteries, which includes the estimation of the open-circuit voltage and state of charge. Using the proposed methodology, the dynamics of a battery cell can be captured without the need for explicit theoretical models. This [...] Read more.
This article presents a data-driven methodology for modeling lithium-ion batteries, which includes the estimation of the open-circuit voltage and state of charge. Using the proposed methodology, the dynamics of a battery cell can be captured without the need for explicit theoretical models. This approach only requires the acquisition of two easily measurable variables: the discharge current and the terminal voltage. The acquired data are used to build a linear differential system, which is algebraically manipulated to form a space-state representation of the battery cell. The resulting model was tested and compared against real discharging curves. Preliminary results showed that the battery’s state of charge can be computed with limited precision using a model that considers a constant open-circuit voltage. To improve the accuracy of the identified model, a modified recursive least-squares algorithm is implemented inside the data-driven method to estimate the battery’s open-circuit voltage. These last results showed a very precise tracking of the real battery discharging dynamics, including the terminal voltage and state of charge. The proposed data-driven methodology could simplify the implementation of adaptive control strategies in larger-scale solutions and battery management systems with the interconnection of multiple battery cells. Full article
(This article belongs to the Special Issue System Modeling, Control Theory, and Their Applications)
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48 pages, 7039 KiB  
Review
A Review of Nanocarbon-Based Anode Materials for Lithium-Ion Batteries
by Nagaraj Nandihalli
Crystals 2024, 14(9), 800; https://doi.org/10.3390/cryst14090800 - 10 Sep 2024
Cited by 6 | Viewed by 3993
Abstract
Renewable and non-renewable energy harvesting and its storage are important components of our everyday economic processes. Lithium-ion batteries (LIBs), with their rechargeable features, high open-circuit voltage, and potential large energy capacities, are one of the ideal alternatives for addressing that endeavor. Despite their [...] Read more.
Renewable and non-renewable energy harvesting and its storage are important components of our everyday economic processes. Lithium-ion batteries (LIBs), with their rechargeable features, high open-circuit voltage, and potential large energy capacities, are one of the ideal alternatives for addressing that endeavor. Despite their widespread use, improving LIBs’ performance, such as increasing energy density demand, stability, and safety, remains a significant problem. The anode is an important component in LIBs and determines battery performance. To achieve high-performance batteries, anode subsystems must have a high capacity for ion intercalation/adsorption, high efficiency during charging and discharging operations, minimal reactivity to the electrolyte, excellent cyclability, and non-toxic operation. Group IV elements (Si, Ge, and Sn), transition-metal oxides, nitrides, sulfides, and transition-metal carbonates have all been tested as LIB anode materials. However, these materials have low rate capability due to weak conductivity, dismal cyclability, and fast capacity fading owing to large volume expansion and severe electrode collapse during the cycle operations. Contrarily, carbon nanostructures (1D, 2D, and 3D) have the potential to be employed as anode materials for LIBs due to their large buffer space and Li-ion conductivity. However, their capacity is limited. Blending these two material types to create a conductive and flexible carbon supporting nanocomposite framework as an anode material for LIBs is regarded as one of the most beneficial techniques for improving stability, conductivity, and capacity. This review begins with a quick overview of LIB operations and performance measurement indexes. It then examines the recently reported synthesis methods of carbon-based nanostructured materials and the effects of their properties on high-performance anode materials for LIBs. These include composites made of 1D, 2D, and 3D nanocarbon structures and much higher Li storage-capacity nanostructured compounds (metals, transitional metal oxides, transition-metal sulfides, and other inorganic materials). The strategies employed to improve anode performance by leveraging the intrinsic features of individual constituents and their structural designs are examined. The review concludes with a summary and an outlook for future advancements in this research field. Full article
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