Search Results (985)

The rotor airflow intensity and distribution characteristics of plant protection UAVs vary significantly with spatial positions below the rotor. Consequently, changes in the rotor–nozzle distance directly affect droplet motion and deposition patterns. To optimize the spraying effect of UAVs, this study combined a numerical simulation of rotor airflow and droplet deposition at different vertical distances between rotor and nozzle with field validation tests. The simulation results revealed that airflow intensity initially increases and then decreases with greater rotor–nozzle distance, peaking at 300–400 mm below the rotor with a maximum airflow velocity of 8.1 m/s. At 360 mm, the droplet swarm achieved its highest average velocity, corresponding to optimal deposition effect. Field tests confirmed a non-linear relationship between rotor–nozzle distance and droplet deposition. Droplet deposition first increased but declined sharply beyond the optimal range. When the distance was 360 mm, the target area exhibited the highest droplet deposition of 0.766 μL·cm⁻² and the lowest drift rate of 23.31%. Although a certain deviation existed between numerical simulation results and field test values, both methods consistently identified 360 mm as the ideal distance for balancing deposition efficiency and drift control. These findings provide actionable insights for field trial design and advance precision spraying strategies for plant protection UAVs. Full article

In this study, a McKenna burner made for calibration is used to generate the laminar flame with the equivalence ratio of 0.78~2.0. The effect of the downward water mist spray on the extinction of the methane–air premixed laminar flame is investigated using hydroxide planar laser-induced fluorescence (OH-PLIF). The variation of the water flow rate for flame extinction is analyzed by the hydroxyl radical concentration distribution and the effective water mist flow rate. The required water flow rate for flame extinction is higher in the cases of rich fuel mixtures. The maximum critical extinguishing water flow rate for the methane–air premixed laminar flame is about 9.55 L/min under the conditions of water mist spray with a 45° solid cone spray angle and a 24 μm droplet size. Furthermore, the evolution of OH-PLIF flame behavior revealed that the stability of the hydroxyl radical concentration at the base of the flame mainly contributed to the flame extinction. This study provides a theoretical reference for the critical extinguishing conditions of water mist in the application of an active fire suppression system. Full article

In view of the problems existing in the application of greenhouse pesticides in China, this paper developed a swing-arm sprayer for greenhouse high-stem crops through field research and a literature review. Static and dynamic simulations of the swing-arm mechanism were carried out to verify the rationality of the structure. The average contact angle between the water and tomato leaves was 49.39°, while the contact angle of the auxiliary solution on the tomato leaves decreased to 40.98°. An indoor atomization test platform was designed to accurately test the particle size and spray performance. The relative span (RS) of droplet distribution showed that the RS values of nozzles 015, 02, and 03 were relatively small, while the RS value of nozzle 04 was about 1.734. With the addition of additives, the RS value of nozzle 02 decreased from 1.305 to 1.021. The field tests showed that the deposition of fog droplets on the front of tomato leaves was in the order of middle > lower > ground > upper (3.622 μL/cm², 3.005 μL/cm², 2.977 μL/cm², and 2.931 μL/cm², respectively). The results indicate that adding additives or increasing the swing-arm angle is beneficial for improving the uniformity of canopy droplet deposition. The front fog droplet coverage of the lower canopy of tomatoes was the lowest, with an average of 26.00%, while the middle and upper canopies had the highest, with an average of 50.58% and 50.72%, respectively. The research found that the spray coverage rate on the front and back sides of tomato leaves was relatively uniform, indicating that the swing-arm greenhouse sprayer designed in this paper could meet the spray quality requirements for tomato pest control. Full article

This study addresses the development of advanced anode materials for lithium-ion batteries by investigating the high-entropy perovskite La(Co_0.2Mn_0.2Fe_0.2Ni_0.2Cu_0.2)O₃. The material was synthesized via spray drying of aqueous metal nitrate solutions, followed by calcination at various temperatures (800 °C/1 h, 1000 °C/1 h, 1000 °C/2 h, 1100 °C/1 h) to optimize structural properties. Structural analysis using X-ray diffraction confirmed the formation of a single-phase perovskite in the sample calcined at 1100 °C for 1 h, while SEM/EDS revealed homogeneous elemental distribution. Electrochemical testing of the powders as anode materials in coin-type lithium-ion cells revealed a trend of slightly increasing capacity over 150 cycles, with capacity ultimately reaching 617 mAh g⁻¹, indicating progressive electrochemical activation. Although the samples share the same composition, variations in calcination conditions resulted in differences in capacity and cycling behavior. These results demonstrate that synthesis parameters critically influence the electrochemical performance of high-entropy perovskites. The findings suggest that such materials have potential as stable anodes for next-generation lithium-ion batteries, contributing to improved durability and efficiency in energy-storage technologies. Full article

Orchard air-assisted sprayers have become key equipment for the prevention and control of fruit tree diseases and pests. However, centrifugal fans are rarely used in orchard air-assisted sprayers. To address the issue that the airflow generated by single-duct centrifugal air-assisted sprayers is insufficient to cover the lower canopy, a flow-guiding device for the lower canopy of fruit trees was designed. The Flow Simulation software of SOLIDWORKS 2021 was used to simulate the airflow field, and various structural parameters of the air outlet were analyzed to determine the optimal configuration of the upper edge inclination angle, the position of the upper air outlet, and the length of the upper air outlet. The results showed that the position of the upper air outlet had the most significant impact on the uniformity of the external flow field, followed by the upper edge inclination angle and the length of the upper air outlet. The optimal parameter settings for the air supply guiding device were determined as follows: upper edge inclination angle of 79°, upper air outlet position of 307 mm, and upper air outlet length of 190 mm. The verification test showed that the relative error between the simulated and actual airflow velocity measurements did not exceed 10%, confirming the accuracy of the simulation. The orchard field test showed that the average deposition density in the inner canopy of fruit trees was 78 particles/cm², indicating strong penetration ability; the distribution of spray droplets in the vertical direction of the canopy was uniform, meeting the requirements of fruit tree pesticide application operations. This technology provides a new approach for the application of centrifugal fans in fruit tree pesticide spraying. Full article

Background/Objectives: Inhalable Microparticles (IMPs) are part of a currently invading field of medicine. In fact, the anatomical district of Rhinopharynx represents a bed for many different pathologies and infections, where the dimension of drug aerosol Microparticles (MPs) represents a discriminating factor to success therapy. The aims of the present work are to demonstrate the efficacy of a new device and its aerosol reproducibility in the nebulization of suspensions to be deposited in the retropharynx. Materials and Methods: The Low-Angle Laser Light Scattering (LALLS) method was used to evaluate both the dimension and distribution of MPs. Six different APIs, used usually in Rhinopharynx pathology, were compared in order to investigate the dimension of MP emissions using four different devices. The results of a retrospective study including 74 subjects treated with standard therapy (ST) and the inhalation of nebulized Sobrerol (NS) were performed. Data regarding the persistence of clinical symptoms (i.e., cough and nasal constipation) were acquired. Results: No significant statistical differences among all the products tested (p > 0.05) were found. One device, Rinubes, demonstrated efficacy and robustness in the fine nebulization of all the pharmaceutical products analyzed. Rinubes delivered an aerosol cloud with significantly lower MMD (66.3 µm) than Mad Nasal and Spray-sol (142.1 and 116.0 µm, respectively), which would allow a higher fraction of drugs to be deposited in the retropharynx. The retrospective clinical study revealed that NS treatment showed higher odds of cough resolution (OR 9.18; p < 0.001) with respect to control ST and showed higher odds of nasal symptom resolution (OR 6.7; p = 0.043). Conclusions: Improved techniques for the administration of inhalable MPs (INPAD) represent significant progress in overcoming the biological and the anatomical barriers in controlling drug release at a specific site. The challenges of nasopharyngeal pathologies offer promising opportunities for the development of non-invasive drug delivery. Full article

Conventional spraying often results in poor deposition on the abaxial (lower) leaf surface and within the middle-to-lower canopy, where pest and disease pressures are typically highest. In this study, we evaluated the performance of electrostatic spraying using basil (Ocimum basilicum), cucumber (Cucumis sativus), and chili pepper (Capsicum annuum) leaves as target surfaces. A high-speed imaging system was employed to map droplet distributions on the abaxial surface, while a neighborhood-matching algorithm combined with droplet tracking was used to quantify the motion of individual droplets near the leaf. At the steady-state stage (frame 4500, 2.25 s), the number of charged droplets detected beneath the abaxial surface increased by 112% (basil), 132% (cucumber), and 213% (chili pepper) compared with non-electrostatic spraying. Smaller charged droplets exhibited higher horizontal velocities and smaller deflection angles in their trajectories near the leaf, indicating a stronger tendency to migrate toward the target surface and into the canopy interior. These findings demonstrate that electrostatic forces substantially enhance abaxial deposition and provide practical guidance for optimizing parameters for electrostatic spraying, such as droplet size, to improve spray efficiency in agricultural applications. Full article

In this work, a comparative study of the corrosion resistance and microstructural characteristics of oxide coatings based on TiO₂ and TiO₂ + Cr₂ + Cr₂O₃ both deposited onto and without a tantalum sublayer has been carried out. The coatings were formed through thermal spraying, and their corrosion behaviour was evaluated through potentiodynamic polarisation in 3.5% NaCl solution using a potentiostat–galvanostat in a three-electrode cell. The TiO₂ + Cr₂O₃ composite coating, applied with a tantalum sublayer, had the lowest corrosion current density and the most positive corrosion potential, indicating its high corrosion resistance. The morphology and elemental composition of the coatings were analysed using scanning electron microscopy (SEM) and energy-dispersive analysis (EDX). The microstructural analysis revealed that the coatings with Cr₂O₃ added were characterised by an increased density, a more uniform phase distribution, and improved adhesion to the substrate. The obtained results confirm that combined TiO₂ + Cr₂O₃ coatings with a tantalum sublayer are promising for use in aggressive environments due to their high corrosion resistance and structural stability. Full article

Alumina (Al₂O₃) is a key material in inorganic and hybrid electronics due to its excellent dielectric, chemical, and thermal stability properties. In this work, we present the first results of alumina films deposited by ultrasonic spray pyrolysis (USP) at low temperatures (40–100 °C) using water as the sole solvent, followed by an annealing step at 100 °C. The films were characterized by SEM, XRD, EDS, and UV-Vis spectroscopy to evaluate their morphology, structure, composition, and optical properties. Preliminary results show an average thickness of approximately 8 µm, with surface features consisting of agglomerates (average particle size ≈ 7.252 µm) distributed over the film. XRD patterns revealed the presence of tetragonal and orthorhombic phases, while EDS confirmed the presence of aluminum and oxygen with slight compositional variations depending on deposition and annealing conditions. UV-Vis absorption spectra exhibited characteristic bands between 259 nm and 263 nm. These results provide a comprehensive understanding of the optical, structural, and morphological behavior of Al₂O₃ films processed at low temperatures. The motivation for studying these films is to enable more eco-friendly gate oxides for organic MIS structures, as well as functional layers in photonic devices. This approach represents a sustainable and straightforward route for obtaining Al₂O₃ coatings compatible with temperature-sensitive substrates, paving the way for future applications in hybrid and organic electronics. Full article

Background/Objectives: Enteric coating protects active pharmaceutical ingredients from gastric degradation, but conventional tablets may present swallowing difficulties in geriatric and pediatric patients. Hence, this study intended to develop pH-responsive multiparticulates, formulated into orally disintegrating tablets (ODTs), for targeted intestinal drug delivery in individuals with dysphagia. Methods: Multiparticulates were developed via sequential seal coating, drug layering, sub-coating, and enteric coating on inert cores using a fluidized bed coater (Pam Glatt, India; bottom spray). Selected enteric-coated batches were directly compressed into ODTs using microcrystalline cellulose (Avicel PH102) and mannitol (Pearlitol SD 160) as fillers, with Explotab^®, Ac-Di-Sol^®, or crospovidone M^® as superdisintegrants. Results: Multiparticulates exhibited mean diameters of 197.671–529.511 μm and span values of 0.603–0.838. Span value < 1, indicating a narrow size distribution. Electron microscopy confirmed the spherical morphology of Batches 7a and b. Enteric-coated batches (5b, 6, 7a, 7b) released ≤10% of the drug in 0.1 N HCl at 2 h. Optimized formulation ODT 7b released 7.904% of the drug under gastric conditions and 79.749% in phosphate buffer (pH 6.8) within 2.5 h, following first-order drug release kinetics. ODT 7b demonstrated hardness (2.538 ± 0.144 kg/cm²), wetting time (11.17 ± 1.051 s), friability (0.712%), and drug content (99.81 ± 1.01%) within acceptable limits. Conclusions: The pH-dependent multiparticulates provided sustained intestinal drug release and, when incorporated into ODTs, yielded a dosage form with a rapid wetting time and acceptable mechanical properties. This dosage form can offer a promising approach for improving compliance and therapeutic efficacy in patients with swallowing difficulties (dysphagia). Full article

Acrobeloides nanus is a cosmopolitan, parthenogenetic soil nematode that is widely distributed across various terrestrial environments, including forests, sand dunes, and agricultural lands. In Korea, this nematode was first isolated from soil collected from a potato farm. It has been used as a biological indicator for monitoring contamination caused by divalent metals such as copper and zinc. In this study, A. nanus was isolated from the soil collected from a cucumber farm, and its identity was confirmed using both morphological and molecular markers. Spray-induced gene silencing using double-stranded RNA (dsRNA) represents a promising new strategy for pest control. Here, we tested a spraying dsRNA that would specifically suppress the target genes in A. nanus. Three genes (Pat-10, Unc-87, and vATPase-B) were targeted, and their expression levels were assessed following treatment with their corresponding dsRNAs. The dsRNAs were sprayed onto the nematode diet. As the concentration of dsRNA increased, the expression levels of the target genes were significantly reduced, leading to notable nematode mortality. However, nematicidal activity varied among the three different dsRNAs. To practically assess these dsRNAs under field conditions, the dsRNAs were applied to the soil containing the nematodes by a drenching application. Significant mortality was observed in treatments with dsRNAs targeting vATPase-B or Pat-10, but not with dsRNA targeting Unc-87. To enhance nematicidal activity in soil, the dsRNAs were formulated with chitosan. This formulation significantly improved the stability of dsRNAs under soil conditions and increased their control efficacy against A. nanus. This study suggests that the drenching technique offers an effective strategy to the control of soil-dwelling nematode pests affecting agricultural crops. Full article

This work develops an Updated Lagrangian Smoothed Particle Hydrodynamics (ULSPH) framework to simulate high-speed icebreaking by a hemispherically capped cylinder (HCC). Using a self-programmed C++ code with Drucker–Prager damage criteria, this work systematically analyzes how impact velocity (100–200 m/s), ice thickness (10–40 cm), and impact angle (60–90°) govern structural loads and ice failure modes. The head of the HCC is always the stress concentration area, and the peak value of the impact force increases non-linearly with increasing the initial velocity from 100 m/s to 200 m/s. The increase in ice layer thickness from 10 cm to 40 cm raises the peak value of the impact force by 18.1%. The ice layer deformation shows three-stage characteristics: collision depression, penetration perforation, and through-spray. When the impact angle α is non-vertical, the strain of the ice layer is asymmetrically distributed, and the component of the peak impact force along the y direction increases significantly with the decrease in the impact angle, reaching 129.3 kN at α = 60°. Results reveal velocity-driven nonlinear force amplification, asymmetric strain distribution at oblique angles, and critical stress concentration at the HCC head, providing design insights for polar equipment. Full article

Crop leaves naturally exhibit a curved morphology and primarily display bending deformation and vibrational responses under wind load. The curved surface structure of leaves plays a critical role in the deposition and retention of pesticide droplets. In this study, wind tunnel experiments combined with high-speed photography and digital image analysis were conducted to systematically investigate the curvature and flexibility distributions of three typical crop leaves: walnut, peach, and pepper, across a range of wind speeds. The results indicate that with increasing wind speed, all three types of leaves gradually transition from smooth, uniform bending to a multi-peak pattern of pronounced local curvature, with increasingly prominent nonlinear deformation characteristics. Moreover, once the wind speed exceeds the critical threshold of 6 m/s, the primary deformation region generally shifts from the leaf base to the tip. For example, the maximum curvature of walnut leaves increased from 0.018 mm⁻¹ to 0.047 mm⁻¹, and that of pepper leaves from 0.031 mm⁻¹ to 0.101 mm⁻¹, both more than double their original values. In addition, all three types of leaves demonstrated a distinct structural gradient characterized by strong basal rigidity and high apical flexibility. The tip flexibility values exceeded 1.5 × 10⁻⁵, 4 × 10⁻⁴, and 5.6 × 10⁻⁴ mm⁻²·mN⁻¹ for walnut, peach, and pepper leaves, respectively. These findings elucidate the mechanical response mechanisms of non-uniform flexible crop leaves under wind-induced bending and provide a theoretical basis and data support for the optimization of air-assisted spraying parameters. Full article

In wheat pest and disease control methods, pesticide application occupies a dominant position, and the use of UAVs for precise pesticide application is a key technology in precision agriculture. However, it is difficult for existing UAV spraying systems to accurately achieve variable spraying according to crop growth conditions, resulting in pesticide waste and environmental pollution. To address this issue, this paper proposes a LiDAR-assisted UAV variable-speed spraying system. Firstly, a biomass estimation model based on LiDAR data and RGB data is constructed, LiDAR point cloud data and RGB data are extracted from the target farmland, and, after preprocessing, key parameters including LiDAR feature variables, canopy cover, and visible-light vegetation indices are extracted from the two types of data. Using these key parameters as model inputs, multiple machine learning methods are employed to build a wheat biomass estimation model, and a variable spraying prescription map is generated based on the spatial distribution of biomass. Secondly, the variable-speed spraying system is constructed, which integrates a prescription map interpretation module and a PWM control module. Under the guidance of the variable spraying prescription map, the spraying rate is adjusted to achieve real-time variable spraying. Finally, a comparative experiment is designed, and the results show that the LiDAR-assisted UAV variable spraying system designed in this study performs better than the traditional constant-rate spraying system; while maintaining equivalent spraying effects, the usage of chemical agents is significantly reduced by 30.1%, providing a new technical path for reducing pesticide pollution and lowering grain production costs. Full article

Cerium-doped zinc cobaltite spinel thin films, $\mathrm{Z}\mathrm{n}{\mathrm{C}\mathrm{e}}_{\mathrm{x}}{\mathrm{C}\mathrm{o}}_{2-\mathrm{x}}{\mathrm{O}}_4 (0.00\le \mathrm{x}\le 0.05)$, were synthesized via spray pyrolysis, and their structural, morphological, optical, and electrical properties were analyzed. X-ray diffraction (XRD) confirmed a cubic spinel structure with a predominant (311) orientation across all compositions. Raman spectroscopy further verified this phase, revealing four active vibrational modes at 180 cm⁻¹, 470 cm⁻¹, 515 cm⁻¹, and 682 cm⁻¹. Scanning electron microscopy (SEM) indicated a uniform grain distribution, while energy-dispersive X-ray spectroscopy (EDS) confirmed the presence of Ce, Zn, Co, and O. Optical measurements revealed two distinct bandgaps, decreasing from 2.32 eV to 2.20 eV for the lower-energy transition and from 3.38 eV to 3.18 eV for the higher-energy transition. Hall effect measurements confirmed p-type conductivity in all films. Electrical analysis showed a reduction in resistivity, from 280.3 Ω·cm to 15.4 Ω·cm, along with an increase in carrier concentration from 1.15 × 10¹⁶ cm⁻³ to 8.15 × 10¹⁷ cm⁻³ with higher Ce content. These results demonstrate that spray pyrolysis is a cost-effective and scalable method for producing Ce-doped ZnCo₂O₄ thin films with tunable properties, making them suitable for electronic and optoelectronic applications. Full article