Search Results (355)

A review on the structure, properties, sustainability, and life cycle analysis of basalt fiber composites, emerging as a major sustainable alternative to traditional synthetic reinforcements such as glass and carbon fibers. Basalt fibers (BFs) are high-performance mineral fibers derived from volcanic rock with a high silica content. These fibers exhibit superior mechanical strength, excellent chemical resistance, and exceptional thermal stability across a broad temperature range. This review explores the multi-sectoral applications of basalt fibers, particularly within the energy and chemical industries. Specific focus is placed on their role as reinforcing agents in concrete and polymer matrix composites, where they provide enhanced durability and corrosion resistance. Central to this discussion is the environmental profile of basalt fibers. We evaluate recent life cycle assessments (LCAs) that compare the environmental gains of BF-reinforced structures. The analysis extends beyond environmental metrics to include the economic and social pillars of sustainability, highlighting basalt’s cost-effectiveness in corrosive environments and its safety as a non-carcinogenic material. This review concludes that basalt fibers offer a significant “green” advantage, encouraging wider industrial adoption. Full article

Marine anthropogenic particle pollution is a major environmental concern due to its persistence and widespread distribution. Microplastics are widely recognized as a subset of anthropogenic particles originating from synthetic polymers. This study examines the occurrence, characteristics, and biological associations of anthropogenic particles ingested by Atlantic chub mackerel from the Saronikos Gulf. A total of 179 specimens were analyzed for anthropogenic particles in the gastrointestinal tract, while muscle tissue was examined in 51 individuals. Anthropogenic particles were detected in the gastrointestinal tract of 74% of individuals and were also present in muscle tissue in 41% of the analyzed specimens. Fibers were the dominant particle type, representing approximately 60% of the identified particles, followed by fragments at 40%. The majority of particles were micro-sized (<5 mm), although meso- and macro-sized particles were also recorded. Black-colored particles predominated, accounting for approximately 53% of the total. No significant differences in anthropogenic particle abundance were observed between sexes, and no consistent seasonal patterns were detected, except for higher occurrence in early autumn compared to winter, although this result should be interpreted with caution due to uneven sample sizes among sampling periods. No statistically significant correlations were found between anthropogenic particle abundance in the gastrointestinal tract or muscle tissue and fish size, condition factor, or stomach fullness. Overall, the findings highlight this species as a suitable bioindicator for monitoring anthropogenic particle pollution and provide baseline information for future assessments in the Saronikos Gulf. Particle identification was based on visual characterization without spectroscopic confirmation; therefore, the detected particles are considered anthropogenic and their polymer composition could not be definitively confirmed. Full article

Hybrid polymer composites combining natural and synthetic fibers offer a balance between mechanical efficiency and sustainability. This study evaluates epoxy-based jute–glass–carbon hybrid laminates with six stacking configurations under tensile and flexural loading. One-way ANOVA confirmed statistically significant differences among laminates (p < 0.001). An integrated AHP–TOPSIS approach was used for multi-criteria ranking, and Response Surface Methodology enabled desirability-based optimization. The carbon-rich cross-ply laminate achieved the highest overall performance, while jute-containing balanced laminates showed enhanced ductility. The results highlight the critical role of stacking sequence in optimizing hybrid composite mechanical behavior. Full article

Sustainable alternatives to synthetic polymer-based sanitary napkins are essential to reduce the environmental impact and health concerns. This study presents a method for using water hyacinth (Eichhornia crassipes), an invasive aquatic weed, as biomass to produce biodegradable absorbent material for sanitary pads. Water hyacinth fibers were treated with an alkaline solution and incorporated into the absorbent core. Morphological, chemical, structural, functional, microbiological, and biodegradability evaluations were then conducted systematically. Scanning electron microscopy showed that non-cellulosic components were successfully removed, producing a rougher surface topology and enhanced fiber interactions. Fourier-transform infrared spectroscopy confirmed structural changes in cellulose after treatment. Additionally, X-ray diffraction showed that the crystallinity index increased from 53.21% in untreated fibers to 62.56% in treated fibers, indicating improved order and stability. The developed absorbent sanitary pad showed rapid fluid uptake, absorbing 10 mL within three seconds while maintaining a skin-compatible neutral pH of 6.87, as specified in Indian Standard IS 5405:1980. Microbial contamination remained low, with a total bacterial count of 360 CFU/g, no yeast or mold at ≤1 CFU/g, and no presence of Staphylococcus aureus. Soil burial tests showed 70% biodegradability at 40 days and approximately 95% at 60 days, indicating high biodegradability. These findings demonstrate the potential of water hyacinth as an inexpensive and environmentally friendly material for manufacturing hygienic sanitary pads, highlighting the sustainability benefits of valorizing invasive biomass and reducing reliance on synthetic polymers. Full article

Background: Online hemodiafiltration (HDF) represents the most advanced form of kidney replacement therapy, combining diffusive and convective transport to enhance the removal of uremic toxins across a wide molecular spectrum. Achieving high convective volumes is a key determinant of treatment efficacy and has been associated with improved survival. Beyond small solutes, HDF targets middle molecules and protein-bound uremic toxins (PBUTs), including β₂-microglobulin, inflammatory cytokines, and other large uremic compounds implicated in cardiovascular and systemic complications. Aims: This narrative review examines advances in dialysis membrane materials, dialyzer design, and monitoring technologies that optimize mass transfer in HDF. It focuses on the interplay between membrane permeability, hemocompatibility, and convective dose delivery, and discusses how these engineering developments translate into clinical performance. Key mechanisms: Recent progress in synthetic polymer membranes, particularly polysulfone- and polyethersulfone-based systems, and hollow-fiber manufacturing has enabled improved control of pore size distribution, hydraulic permeability, and sieving characteristics. These developments enhance the clearance of middle molecules and selected PBUTs while preserving essential proteins such as albumin. Mechanistic insights into internal filtration, protein polarization, and Donnan effects highlight the complex transport processes occurring within the dialyzer and their interaction with automated HDF systems. Expanded hemodialysis and high-volume HDF approaches further increase the removal of larger solutes but require careful management to limit albumin loss and maintain hemocompatibility. Clinical implications: Optimized membrane design, combined with advanced HDF machine algorithms, allows delivery of high convective volumes under safe and stable conditions, improving removal of β₂-microglobulin, cytokines, and other clinically relevant toxins associated with inflammation and cardiovascular risk. However, treatment must remain individualized, considering electrolyte balance, albumin preservation, and patient-specific factors such as inflammation and nutritional status. Mechanistic modeling supports understanding of transport phenomena but must be interpreted cautiously when translated into clinical practice. Conclusions: Advances in membrane science, dialyzer engineering, and monitoring technologies have strengthened the role of HDF as a precision-based renal replacement therapy. Continued innovation aimed at optimizing middle-molecule and PBUT clearance while preserving albumin and treatment stability is essential to improve patient outcomes and support the broader implementation of HDF as a mainstream dialysis modality. Full article

This research aimed to quantify and investigate the morphology of microplastics in skincare and treatment creams related to their chemical composition and the potential risks to human health associated with exposure to microplastics by dermal contact. A total of 21 skincare and treatment cream samples, indicating the target audience (men, women, and children) for each product, and potential diseases were analyzed in terms of the hidden risk of microplastics. To determine the exact number of microplastics to which adults and children are exposed over the course of a year, in-depth research was conducted on the cosmetic care and treatment products used by over 354 respondents from Romania. This study used a free, self-reported questionnaire method, which took into account consumer habits and preferences, as well as any potential medical conditions that could affect exposure. Optical microscopy and micro-FTIR revealed a total of 109 microplastics, with different sizes, colors, and shapes (i.e., fragments and fibers) and various chemical compositions, including mixtures of polymeric and natural structures, as well as 100% synthetic materials, e.g., polyethylene and polyester. The potential health risk of exposure to microplastics in certain cosmetic formulations for adults was assessed by calculating various risk indices, such as the polymer risk index (H), pollution load index (PLI), dermal plastic absorption (DPA), chronic daily dermal exposure (CDDE), risk to human health from dermal absorption (RHHDA), and estimated annual dermal absorption (EADA). These indices were calculated based on the medical conditions and application areas indicated on the labels of the analyzed creams (i.e., skincare and treatment), for both adult and children’s categories, using the fingertip unit (FTU) method for estimating the cream amount. The plastic toxicity of the analyzed samples was assessed using the H and PLI indices. The risk of microplastics to human health from dermal exposure was assessed using the DPA, CDDE, RHHDA, and EADA indices, which showed concerning results regarding the presence of these particles in cosmetic formulations. Full article

Microplastic (MP) pollution poses a significant and emerging threat to global marine ecosystems; however, regional data for the Caribbean remain limited. This study presents a spatial and temporal characterization of MPs in surface and mid-waters of the Colombian Caribbean (Atlántico and Magdalena departments), which were analyzed as independent compartments due to methodological differences in sampling strategies. Sixteen sampling stations were established across two anthropogenic influence zones: Zone 1 (nearshore/bather zone) and Zone 2 (offshore). MPs were quantified and characterized according to shape, color, size, and polymer composition using attenuated total reflectance Fourier transform infrared microspectroscopy (µATR-FTIR) and multivariate techniques. MPs were detected in 100% of samples. Surface water MP abundance was higher in Magdalena (4.5 MPs m⁻³) than in Atlántico (1.7 MPs m⁻³). Mid-water MP concentrations reached maximum values during the high rainfall season in Atlántico, reflecting localized hydrological and anthropogenic influences rather than vertical gradients. Higher concentrations were generally observed in the nearshore Zone 1 compared to offshore Zone 2, although these differences were not consistently statistically significant. Fibers and fragments were the predominant shapes, and synthetic–natural polymer blends, polyethylene terephthalate (PET), polypropylene (PP), and polyacrylic acid (PAA) were the most prevalent. Generalized Additive Models (GAM) indicated that strong fluvial inputs and proximity to urban and riverine sources were factors driving MP distribution. Additionally, the detection of polymers reported in the literature as rare and high-risk, such as acrylonitrile butadiene styrene (ABS), acrylonitrile styrene acrylate (ASA), styrene–ethylene–butylene–styrene (SEBS), and polyvinyl stearate (PVS), highlights the complexity of MP sources in the region. Overall, these results provide the first spatial and temporal characterization of MPs in the surface and mid-water of the Colombian Caribbean and identify critical contamination hotspots that warrant targeted mitigation strategies. Full article

The rapid and accurate detection of SARS-CoV-2 biomarkers remains a critical requirement for effective outbreak control and decentralized diagnostics. Although RT-PCR is the current gold standard, its reliance on centralized laboratories and long processing times limits its applicability in point-of-care settings. In this context, optical biosensing platforms based on surface plasmon resonance (SPR) offer attractive features, including label-free, real-time, and quantitative detection. This study explores the use of synthetic receptors for the highly sensitive detection of the receptor-binding domain (RBD) of the SARS-CoV-2 spike protein. Specifically, soft molecularly imprinted polymer nanoparticles (nanoMIPs) were employed as synthetic receptors and integrated into a high-sensitivity, portable plasmonic platform based on a D-shaped plastic optical fiber (POF) SPR sensor. The nanoMIPs were selectively imprinted against the RBD, characterized by Dynamic Light Scattering (DLS), Isothermal Titration Calorimetry (ITC), and Scanning Electron Microscopy (SEM) to confirm nanoMIPs size, binding properties, and surface morphology. Next, the nanoMIPs were immobilized onto a gold-coated sensing surface, enabling enhanced specificity, affinity, and signal amplification compared to conventional biological recognition elements. The resulting RBD-SPR-nanoMIPs sensor demonstrated promising analytical performance, exhibiting high selectivity against potentially interfering proteins and an anticipated sensitivity suitable for RBD detection at femtomolar concentrations. The inherent stability of nanoMIPs suggests the potential for reusable SPR sensing platforms, paving the way for next-generation synthetic receptor-based plasmonic biosensors. Full article

Natural-fiber biocomposites are increasingly viewed as promising materials for sustainable engineering. However, their broader adoption remains constrained by coupled challenges related to interfacial compatibility, moisture sensitivity, environmental durability, processing limitations, and end-of-life trade-offs. Rather than treating fiber selection, matrix chemistry, processing routes, durability, and sustainability as independent considerations, this review emphasizes their interdependence through the fiber–matrix interface, which governs stress transfer, moisture transport, and long-term property evolution. It provides a comprehensive and integrative analysis of natural-fiber–reinforced polymer composites, encompassing plant-, animal-, and emerging bio-derived reinforcements combined with bio-based, biodegradable, and selected synthetic matrices. Comparative analysis across the literature demonstrates that interfacial engineering consistently dominates mechanical performance, moisture resistance, and property retention, while mediating trade-offs among stiffness, toughness, recyclability, and biodegradability. Moisture transport and environmental ageing are examined using thermodynamic and diffusion-controlled frameworks that link fiber chemistry, interfacial energetics, swelling, and debonding to performance degradation. Fire behavior and flame-retardant strategies are reviewed with attention to heat-release control and their implications for durability and circularity. Processing routes, including extrusion, injection molding, compression molding, resin transfer molding, and additive manufacturing, are assessed with respect to fiber dispersion, thermal stability, scalability, and compatibility with bio-based systems. By integrating structure–property relationships, processing science, durability mechanisms, and sustainability considerations, this review clarifies how natural-fiber biocomposites can be designed to achieve balanced performance, environmental stability, and circular life-cycle behavior, thereby providing guidance for the development of systems suitable for near-term engineering applications. Full article

Bicycle tires and inner tubes constitute a growing waste stream mainly composed of natural rubber, butyl rubber, synthetic elastomers, carbon black, and reinforcing materials. Their multi-material structure and highly crosslinked networks make their recycling challenging, yet efficient recovery is essential for advanced circular economy practices. This review summarizes the current and emerging strategies for recycling bicycle tires and inner tubes. It first outlines the materials and additives present in tire casings and butyl inner tubes, which determine their recycling behavior. Mechanical pre-processing methods, including shredding, grinding, and fiber/steel separation, are presented as essential feedstock preparation steps. Thermochemical approaches, such as pyrolysis and thermolysis, are discussed with emphasis on producing value-added fractions, including pyrolysis oil, recovered carbon black, and fuels. Solvent-based feedstock recycling and chemical dissolution are highlighted as promising routes for selective recovery of rubber polymers and additives. Physical, chemical, and biological devulcanization methods are also reviewed for their potential to restore partial processability to reuse reclaimed rubber. Finally, current and prospective applications of recycled materials are discussed, and key challenges with future research needs are identified, including improving devulcanization efficiency, expanding collection systems, and increasing the value of recovered products. Full article

Fiber-forming polymers are increasingly used to control blood coagulation, either by accelerating the onset of hemostasis or by limiting thrombogenic events in contact with blood. Despite rapid progress in materials engineering, a unified view linking the molecular mechanisms of the coagulation cascade with specific design strategies of procoagulant and anticoagulant polymeric fibers is still missing. In this review, we summarize current knowledge on how natural and synthetic polymers interact with plasma proteins, platelets, and coagulation factors, emphasizing the role of fiber morphology, surface chemistry, charge distribution, and functionalization. Particular attention was paid to systems based on natural polysaccharides (e.g., chitosan, alginate, and cellulose derivatives), as well as synthetic polymers (e.g., PLA, PCL, polyurethanes, and zwitterionic materials). Two possible courses of action were described: their bioactivity may activate the contact pathway and/or support platelet adhesion or their ability to minimize protein adsorption and inhibit thrombin generation. We discuss how metal–polymer coordination, surface immobilization of heparin or nitric oxide donors, and nanoscale texturing modulate coagulation kinetics in opposite directions. Finally, we highlight emerging fiber-based strategies for achieving either rapid hemostasis or long-term hemocompatibility and propose design principles enabling precise tuning of coagulation responses for wound dressings, vascular grafts, and blood-contacting devices. This general compendium of knowledge on blood–material interactions provides a foundation for further design of biomaterials based on fiber-forming polymers and the development of manufacturing processes. Full article

Microplastic contamination in food systems has emerged as a growing concern for food safety and public health. The presence of microplastics in raw milk may represent a potential exposure pathway for both animals and humans. This study investigated the occurrence and characteristics of microplastics in raw milk collected from smallholder dairy farms in Northeastern Thailand. Hand-milked raw milk and bulk tank milk samples were obtained from ten farms and analyzed for microplastic contamination. Suspected microplastic particles were identified and quantified using stereomicroscopy and characterized according to their shape, color, and size, while polymer composition was confirmed by Fourier Transform Infrared Spectroscopy. Microplastics were detected in both hand-milked and bulk tank milk samples, with fiber-shaped particles being the most frequently observed. The majority of detected particles were 0.05–0.15 mm in size and predominantly yellow in color. Polymer analysis revealed that Polydimethylsiloxane, followed by a semi-synthetic composite of Elastane and Rayon. These findings demonstrate that microplastics can be present in raw milk produced by smallholder dairy farms, highlighting the need for improved farm management and milk-handling practices to reduce contamination risks. From a One Health perspective, reducing plastic use and enhancing hygiene during milking and milk storage may help protect animal health, food safety, and consumer well-being. Full article

Polymer composites reinforced with nanofillers, synthetic fibers, and inorganic fillers have progressed rapidly, yet recent advances remain fragmented across filler-specific studies and often lack unified mechanistic interpretation. This review addresses this gap by presenting an interphase-centric, mechanism-driven framework linking processing routes, dispersion and functionalization requirements, interphase formation, and the resulting structure–property relationships. Representative quantitative datasets and mechanistic schematics are integrated to rationalize nonlinear mechanical reinforcement, percolation-controlled electrical/thermal transport, and thermal stabilization and barrier effects across major filler families. The review highlights how reinforcement efficiency is governed primarily by interfacial adhesion, filler connectivity, and processing-induced microstructural evolution rather than filler loading alone. Key challenges limiting scalability are critically discussed, including dispersion reproducibility, viscosity and processability constraints, interphase durability, and recycling compatibility. Finally, mechanism-based design rules and future outlook directions are provided to guide the development of high-performance, multifunctional, and sustainability-oriented polymer composite systems. Full article

Plastic pollution, particularly in marine environments, has become a major global concern; therefore, monitoring and controlling these contaminants is essential to safeguard ecosystem integrity and human health. This study evaluates the ability of Posidonia oceanica spheroids to incorporate and retain plastic debris, with a particular focus on microplastics (MPs). A total of 1300 spheroids were collected along the Latium coast (Central Italy); among these, 454 (34.9%) contained plastic debris, with an average of 3.1 items per spheroid. Overall, 1415 plastic items were extracted and identified. Based on size classification, 48.7% were microplastics, 29.6% mesoplastics, and 21.9% macroplastics. Plastic items mainly consisted of filaments (40.9 ± 12.6%) and fibers (21.5 ± 5.2%). Eleven different colors were recorded, with white (28.8 ± 9.1%), transparent (13.4 ± 6.0%), and black (11.1 ± 6.8%) being the most frequent. A strong correlation was observed between the number of plastic items contained in the spheroids and proximity to wastewater treatment plants, which are known sources of synthetic fibers. Fourier transform infrared spectroscopy (FTIR) identified a total of 15 polymer materials, with nylon (18.2 ± 11.0%) and polyethylene terephthalate (PET; 17.3 ± 7.2%) being the most abundant. Structural alterations observed in FTIR spectra, together with carbonyl index values, indicate that most MPs are of secondary origin, resulting from prolonged environmental degradation. These results demonstrate that P. oceanica spheroids effectively promote plastic trapping and highlight their potential as a simple and cost-effective monitoring tool for marine plastic pollution. Full article