Search Results (6,058)

Carbon-based nanomaterials have emerged as a promising strategy for bitumen modification to enhance the mechanical and thermal performance of pavements. This review evaluates the present advancements in the inclusion of coke and carbon nanomaterials (CNMs) such as carbon nanotubes (CNTs) and graphene into bituminous systems. The findings and limitations of recent experiments in synthesis procedures along with dispersion methods are deeply explored to determine their impact on the rheological properties of bitumen as well as aging resistance and durability characteristics. Petroleum coke enhances bitumen softening points by 10–15 °C and causes up to 30% improvement in rutting resistance while simultaneously prolonging material fatigue life and aging resistance. Bitumen modification through petroleum coke faces challenges in addition to mixing difficulties due to its high viscosity. Moreover, the incorporation of CNTs and graphene as CNMs shows significant enhancements in rutting resistance with improved tensile strength, lower additive requirements, and enhanced dispersion. Both the superior mechanical properties of carbon nanomaterials and processing advancements in nano-enhanced bitumen have the capability to solve technical issues including material costs and specialized mixing processes. Combining coke with CNMs to enhance performance is a future research direction, which could result in economic and scalability considerations. This review comprehensively explores insights into physicochemical interactions, performance outcomes, and processing techniques, crucial for the development of sustainable, high-performance bitumen composites tailored for next-generation infrastructure applications. Full article

During the operation of a solid rocket motor, the nozzle, which is a key component, is subjected to extreme conditions, including high temperatures, high-speed gas flow, and discrete-phase particles. For composite nozzles incorporating a carbon/carbon (C/C) throat liner and a carbon/phenolic expansion section, thermochemical ablation and the formation of ablation steps during the ablation process significantly hinder nozzle performance and engine operational stability. In this study, the fluid and solid domains and the physicochemical interactions between them during nozzle operation were analyzed. An innovative thermochemical ablation model for composite nozzles was developed to account for wall recession. The coupled model covered multi-component gas flow, heterogeneous chemical reactions on the nozzle surface, structural heat transfer, variations in material parameters induced by carbon/phenolic pyrolysis, and the dynamic recession process of the nozzle profile due to ablation. The model achieved coupling between gas flow, heterogeneous reactions, and structural heat transfer through interfacial mass and energy balance relationships. Based on this model, the distribution of the nozzle’s thermochemical ablation rate was analyzed to investigate the mechanisms underlying ablation step formation. Furthermore, detailed calculations and analyses were performed to determine the effects of the gas pressure, temperature, H₂O concentration, and aluminum concentration in the propellant on the ablation rate of the throat liner and the thickness of the ablation steps. This study provides a theoretical foundation for the thermal protection design and performance optimization of composite nozzles, improving the reliability and service life of solid rocket motor nozzles and advancing technological development. Full article

Asphalt pavements face escalating challenges from traffic loading, climate change, and material degradation, necessitating innovative maintenance solutions. Thermally induced self-healing technologies, leveraging the viscoelastic properties of asphalt binders, can autonomously repair microcracks through targeted thermal activation. This review explored thermally induced self-healing in asphalt mixtures, with a focus on leveraging steel slag as a functional aggregate to enhance sustainability and durability. Two thermal-activation methods, electromagnetic induction and microwave heating, were critically analyzed, highlighting their distinct advantages in heating efficiency, depth, and uniformity. Steel slag offers dual benefits: improving mechanical interlock and skid resistance in mixtures while facilitating efficient heat generation via electromagnetic induction or microwave heating. However, challenges such as hydration-induced expansion, heterogeneous slag composition, and energy-intensive heating processes impede widespread adoption. Pretreatment methods, including natural aging, carbonation, and surface modifications, are essential to mitigate volumetric instability and optimize slag performance. Key factors influencing healing efficacy, including binder properties, operational parameters (e.g., microwave power, frequency), and environmental trade-offs, were systematically evaluated. Future research directions emphasized standardized pretreatment protocols, hybrid heating technologies for uniform temperature distribution, and smart-infrastructure integration for predictive maintenance. Full article

In this work, κ-carrageenan (κ-C) and polyethylene oxide (PEO) were utilized to synthesize polymeric films (κ-C-PEO). A 2^k experimental design was employed to optimize the synthesis of κ-C-PEO systems by considering the content of κ-carrageenan, PEO, and glycerin and their influence on the mechanical features of the resultant films. The κ-C-PEO systems were robustly characterized by FTIR spectroscopy, thermogravimetric analyses, and scanning electron microscopy (SEM). Magnesium oxide nanoparticles (MgO-NPs) were utilized to load κ-C-PEO films as an efficient approach to enhance their biological performance. The activity of κ-C-PEO films was studied against Gram-negative bacteria through the Kirby–Bauer assay. Artemia salina nauplii were cultured to assess the possible toxicity of κ-C-PEO films. The results demonstrated that κ-C-PEO films were elongated with the heterogeneous distribution of MgO-NPs. The tensile strength, thickness, and swelling capacity of κ-C-PEO films were 129 kPa, 0.19 mm, and 52.01%, respectively. TGA and DTA analyses revealed that κ-C-PEO films are thermally stable structures presenting significant mass loss patterns at >200 °C. Treatment with κ-C-PEO films did not inhibit the growth of Escherichia coli nor Pseudomonas aeruginosa. Against A. salina nauplii, κ-C-PEO films did not decrease the survival rate nor compromise the morphology of the tested in vivo model. The retrieved data from this study expand the knowledge about integrating inorganic nanomaterials with polysaccharide-based structures and their possible application in treating chronic wounds. Even though this work provides innovative insights into the optimal design of bioactive structures, further approaches are required to improve the biological performance of the synthesized κ-C-PEO films. Full article

Aging underground cables pose a threatening issue in distribution systems. Replacing all cables at once is economically unfeasible, making it crucial to prioritize replacements. Traditionally, age-based strategies have been used, but they are likely to fail to depict the real condition of cables. Insulation faults are influenced by electrical, mechanical, thermal, and chemical stresses, and partial discharges (PDs) often serve as early indicators and accelerators of insulation aging. The trends in PD activity provide valuable information about insulation condition, although they do not directly reveal the cable’s real age. Due to the absence of an established ranking methodology for such condition-based data, this paper proposes a fuzzy logic and fuzzy analytic hierarchy process (FAHP)-based cable vulnerability ranking framework that effectively manages uncertainty and expert-based conditions. The proposed framework requires only basic and readily accessible data inputs, specifically cable age, which utilities commonly maintain, and PD measurements, such as peak values and event counts, which can be acquired through cost-effective, noninvasive sensing methods. To systematically evaluate the method’s performance and robustness, particularly given the inherent uncertainties in cable age and PD characteristics, this study employs Monte Carlo simulations coupled with a Spearman correlation analysis. The effectiveness of the developed framework is demonstrated using real operational cable data from a Danish distribution network, meteorological information from the Danish Meteorological Institute (DMI), and synthetically generated PD data. The results confirm that the FAHP-based ranking approach delivers robust and consistent outcomes under uncertainty, thereby supporting utilities in making more informed and economical maintenance decisions. Full article

This study presents a comprehensive analysis of combustion mechanisms and emission formation in marine diesel engines using biodiesel blends through experimental validation and computational fluid dynamics simulation using Matlab 2024a. Two marine engines were tested—YANMAR 6HAL2-DTN (200 kW, 1200 rpm) and Niigatta Engineering 6L34HX (2471 kW, 600 rpm)—with biodiesel ratios B0, B20, B50, and B100 at loads from 10% to 100%. The methodology combines detailed experimental measurements of exhaust emissions, fuel consumption, and engine performance with three-dimensional CFD simulations employing k-ε RNG turbulence model, Kelvin–Helmholtz–Rayleigh–Taylor droplet breakup model, and extended Zeldovich mechanism for NOx formation modeling. Key findings demonstrate that biodiesel’s oxygen content (10–12% by mass) increases maximum combustion temperature by 25 °C at 50% load, resulting in NOx emissions increase of 5–13% across all loads. Conversely, CO emissions decrease by 7–10% due to enhanced oxidation reactions. CFD analysis reveals that B100 exhibits 12% greater spray penetration depth, 20% larger Sauter Mean Diameter, and 20–25% slower evaporation rate compared to B0. The thermal Zeldovich mechanism dominates NOx formation (>90%), with prompt-NO and fuel-NO contributions increasing from 6.5% and 0.3% for B0 to 7.2% and 1.3% for B100, respectively, at 25% load. Optimal injection timing varies with biodiesel ratio: 13–15° BTDC for B0 reducing to 10–12° BTDC for B100. These quantitative insights enable evidence-based optimization of marine diesel engines for improved environmental performance while maintaining operational efficiency. Full article

This study presents a comprehensive dynamic model of a small-scale, solar-powered hydraulic gas compression energy storage system tailored for renewable energy applications. Addressing the intermittency of renewable energy sources, the model incorporates mass, momentum, and energy conservation principles and is implemented using GT-Suite simulation software v2025.0. The system, based on a liquid piston mechanism, was analyzed under both adiabatic and isothermal compression scenarios. Validation against experimental data showed maximum deviations under 10% for pressure and 5 °C for temperature. Under ideal isothermal conditions, the system stored up to 8 MJ and recovered 6.1 MJ of energy, achieving a round-trip efficiency of 76.3%. In contrast, adiabatic operation yielded 52.6% efficiency due to thermal losses. Sensitivity analyses revealed the importance of heat transfer enhancement, with performance varying by over 15% depending on spray cooling intensity. These findings underscore the potential of thermally integrated hydraulic systems for efficient, scalable, and cost-effective energy storage in distributed renewable energy networks. Full article

This study examines the effect of silicon and manganese addition on the phase composition and electrical properties of Al-Fe alloys using both experimental methods and thermodynamic modeling with the ThermoCalc software package. This research focuses on the Al–Fe–Si–Mn system, which shows potential for developing conductive aluminum alloys with enhanced performance characteristics. It was found that when silicon and manganese are added in amounts up to 0.6%, the formation of intermetallic phases such as Al₈Fe₂Si and Al₁₅Mn₃Si₂ occurs. These phases significantly influence the electrical conductivity and mechanical stability of the alloy. Thermodynamic modeling proved effective in predicting phase formation, guiding the selection of alloy compositions, and optimizing heat treatment parameters. The optimal composition for a conductive aluminum alloy includes up to 0.8% Fe, 0.5% Si, and 0.6% Mn. Heat treatment in the range of 500–550 °C resulted in a favorable combination of strength, electrical conductivity, and thermal resistance. The findings support the use of Al–Fe–Si–Mn alloys in electrical and structural applications and demonstrate the value of combining computational and experimental approaches in alloy design. Full article

This study presents the development and analysis of hybrid polyurea composite materials. Neat polyurea was reinforced with cellulose nanocrystals (CNCs) and isocyanate-modified CNCs (CNC-ISOs) via a two-step prepolymer process. Introducing CNC considerably increased the mechanical strength and stiffness of the polyurea matrix. The tensile strength increased by up to 16.4%, and the Young modulus improved by approximately 29% compared to the pure polyurea. When CNC was functionalized with isocyanate, the interfacial bonding was further improved, and superior dispersion and load transfer were achieved. At 1.5% CNC-ISO loading, the modulus increased by approximately 128% compared to the unmodified matrix. Comprehensive analyses using FT-IR, XPS, DSC, TGA, DMA, tensile testing, and SEM showed that CNC-ISO films not only achieved higher tensile strength and better thermal stability but also formed a denser polymer network as evidenced by the increased crosslinking density. These findings highlight the importance of tailored nanofiller modification to create advanced polyurea composites with enhanced performance suitable for demanding protective and structural applications. Full article

This review article presents a comprehensive analysis of recent advancements in sound insulating materials, focusing on the characterization of material types and their properties from 2015 to 2024. It examined the application of various natural and synthetic materials, including fibrous, porous, composite, polymeric, and advanced materials, in architectural and environmental acoustics. A systematic search in the Scopus database identified relevant articles that were classified according to the material types and their inherent properties. The analysis covered key aspects such as thermal, mechanical, chemical, and physical characteristics, and their impact on sound insulation performance. Unlike previous studies that focused on classic materials or single aspects, this review used analytical and database tools to identify recent research trends. This review highlights the development of advanced and sustainable materials for noise reduction that address challenges in both building acoustics and environmental sound pollution. Full article

Battery thermal runaway (TR) is usually accompanied by a large amount of heat release, as well as a jet of flame. This not only causes harm to the surrounding environment but even exacerbates thermal runaway propagation (TRP). At this stage, many types of materials are used to suppress TRP, and people tend to focus on improving one characteristic of the material while ignoring other properties of the material. This may leave potential pitfalls for TRP suppression, suggesting the need to study multiple properties of multiple materials. In order to better weigh the advantages and disadvantages of different types of materials when suppressing TRP, we compared three typical materials for suppressing TRP behavior in lithium-ion batteries (LIBs). These materials are phase change materials (PCM), ceramic fibers, and glass fibers. They are all available in two different thicknesses, 2 mm and 3 mm. The experiments started with a comparative analysis of the TR experimental phenomena in the presence of the different materials. Then, the temperature and mass loss of the battery module during TR were analyzed separately and comparatively. The 3 mm glass fiber showed the best inhibition effect, which extended the TR interval between cells 1 and 2 to 894 s and successfully inhibited the TR of cell 3. Compared with the blank group, the total mass loss decreased from 194.3 g to 182.2 g, which is a 6.2% reduction. Subsequently, we comprehensively analyzed the performance of the three materials in suppressing TRP by combining their suppressing mechanisms. The experimental results show that glass fiber has the best effect in suppressing TRP due to its excellent thermal insulation and mechanical properties. This study may provide new insights into how to trade-off material properties for TRP suppression in the future. Full article

CO₂-enhanced coalbed methane recovery (CO₂-ECBM) represents a promising pathway within carbon capture, utilization, and storage (CCUS) technologies, offering dual benefits of methane production and long-term CO₂ sequestration. This review provides a comprehensive analysis of CO₂-ECBM from a full-chain perspective (Mechanism, Practices, and Outlook), covering fundamental mechanisms and key engineering practices. It highlights the complex multi-physics processes involved, including competitive adsorption–desorption, diffusion and seepage, thermal effects, stress responses, and geochemical interactions. Recent progress in laboratory experiments, capacity assessments, site evaluations, monitoring techniques, and numerical simulations are systematically reviewed. Field studies indicate that CO₂-ECBM performance is strongly influenced by reservoir pressure, temperature, injection rate, and coal seam properties. Structural conditions and multi-field coupling further affect storage efficiency and long-term security. This work also addresses major technical challenges such as real-time monitoring limitations, environmental risks, injection-induced seismicity, and economic constraints. Future research directions emphasize the need to deepen understanding of coupling mechanisms, improve monitoring frameworks, and advance integrated engineering optimization. By synthesizing recent advances and identifying research priorities, this review aims to provide theoretical support and practical guidance for the scalable deployment of CO₂-ECBM, contributing to global energy transition and carbon neutrality goals. Full article

This study investigates the impact of various nucleating agents on the crystallization behavior, thermal stability, and mechanical properties of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P3HBHHx) with 6 mol% 3-hydroxyhexanoate (3HHx) units. Nucleating agents, including boron nitride (BN), poly(3-hydroxybutyrate) (PHB), talc, ultrafine cellulose (UFC), and an organic potassium salt (LAK), were incorporated to enhance the crystallization performance. Differential scanning calorimetry (DSC) revealed that BN and PHB significantly increased the crystallization temperature and reduced the crystallization time by half, with BN exhibiting the highest nucleation efficiency. Isothermal kinetics modeled using the Avrami and Lauritzen–Hoffman theories confirmed faster crystallization and reduced nucleation barriers in nucleated samples. Polarized optical microscopy (POM) revealed that the nucleating agents altered the spherulite morphology and increased the growth rates. Under fast cooling, only BN induced crystallization, confirming its superior nucleation activity. Thermogravimetric analysis (TGA) indicated minimal changes in thermal stability, while mechanical testing showed a slight reduction in stiffness without compromising the tensile strength. Overall, BN emerged as the most effective nucleating agent for enhancing the P3HBHHx crystallization kinetics, providing a promising strategy for improving processing efficiency and reducing the cycle times in industrial applications. Full article

Corrosion-resistant coatings are essential for prolonging the lifespan of metal structures, yet conventional formulations often lack sufficient mechanical strength and chemical durability. This study focuses on the development of polyurethane/epoxy hybrid coatings (PUAE) with varying epoxy resin content (5%, 10%, and 15% by weight) to enhance performance. The hybrid films demonstrated improved mechanical properties with increasing epoxy content, including a rise in tensile strength from 39.1 MPa (PUA) to 86.3 MPa (PUAE15) and adhesion from 2.5 MPa to 8.3 MPa. Hardness also increased from 69 Shore A to 98 Shore A, while elongation at break decreased from 158% to 95%, indicating a shift toward a stiffer material. The thermal stability, assessed by TGA, showed higher degradation temperatures, with PUAE15 reaching a maximum decomposition temperature of 390 °C, compared to 320 °C for pure polyurethane. Viscosity at 5 rpm increased from 12.300 mPa·s to 18.563 mPa·s, and the contact angle improved from 105° to 149°, highlighting enhanced hydrophobicity. PUAE15 also displayed superior resistance to solvents and acidic environments. These results affirm that epoxy content significantly influences the structural, mechanical, and corrosion-resistant properties of polyurethane-based coatings, making PUAE15 a promising candidate for advanced anticorrosive applications. Full article

Foam stabilization plays a critical role in the production of foamed mortar, a material widely applied in civil construction due to its thermal insulation and lightweight structural benefits. This study investigates the use of magnetite derived from acid mine drainage (AMD) as a sustainable foam-stabilizing agent. Magnetite’s magnetic properties enhance foam stability by improving air bubble distribution within the mortar. A total of 30 different mixtures were produced, varying the sand-to-cement ratio, type of cement and magnetite content. The compressive strength and tensile flexural strength of the foamed mortars ranged from 0.62 ± 0.04 MPa to 7.33 ± 0.30 MPa and from 0.44 ± 0.12 MPa to 2.82 ± 0.16 MPa, respectively; porosity ranged from 31.8% ± 1.86 to 75.6% ± 2.2; dry and wet bulk density ranged from 423 ± 23 kg.m⁻³ to 1576 ± 96 kg.m⁻³ and from 615 ± 9 kg.m⁻³ to 1828 ± 122 kg.m⁻³, respectively; water absorption ranged from 8.9% ± 0.9 to 45.8% ± 10.6; and thermal conductivity ranged from 0.54 ± 0.03 W·m⁻¹·K⁻¹ to 0.17 ± 0.03 W·m⁻¹·K⁻¹. Results demonstrated that increasing magnetite content led to greater foam stability and porosity but decreased mechanical strength and density. The sand-to-cement ratio significantly affected all measured properties, while the type of cement had minimal influence. These findings suggest that AMD-derived magnetite is a promising additive for optimizing the performance of lightweight, sustainable foamed mortars. Full article