Search Results (1,434)

For the first time, the kinetics of isothermal curing and thermal degradation of polyethylene glycol maleate (pEGM)–based systems and their composites with mineral fillers were investigated in the presence of a benzoyl peroxide/N,N-Dimethylaniline redox-initiating system. DSC analysis revealed that the curing process at 20 °C can be described by the modified Kamal autocatalytic model; the critical degree of conversion (α_c) decreases with increasing content of the unsaturated polyester pEGM and in the presence of fillers. In particular, for unfilled systems, α_c was 0.77 for pEGM45 and 0.60 for pEGM60. TGA results demonstrated that higher pEGM content and the incorporation of fillers lead to increased thermal stability and residual mass, along with a reduction in the maximum decomposition rate (dTGₘₐₓ). Calculations using the Kissinger–Akahira–Sunose and Friedman methods also confirmed an increase in the activation energy of thermal degradation (E_a): E_KAS was 419 kJ/mol for pEGM45 and 470 kJ/mol for pEGM60, with the highest values observed for pEGM60 systems with fillers (496 kJ/mol for SiO₂ and 514 kJ/mol for CaCO₃). Rheological studies employing three-interval thixotropy tests revealed the onset of thixotropic behavior upon filler addition and an increase in structure recovery after deformation of up to 56%. These findings underscore the potential of pEGM-based systems for low-temperature curing and for the design of composite materials with improved thermal resistance. Full article

Due to its multiple amino groups, triethylenetetramine (TETA) can be used as an effective formaldehyde scavenger contributing to the reduction in formaldehyde emission from plywood. This study aimed to evaluate the effect of small TETA loadings on the properties of urea-formaldehyde (UF) resin and the performance of the resulting plywood. Adhesive mixtures containing 0%, 0.5%, 1.0%, and 1.5% TETA were prepared and characterized in terms of pH, viscosity, solids content, and gel time. The incorporation of TETA significantly increased adhesive pH and gel time, while viscosity and solid content were not significantly affected. The analysis of formaldehyde content and spectroscopic and thermogravimetric analyses of the cured adhesives showed reduced formaldehyde content, changes in chemical structure, and enhanced thermal stability at lower temperatures but accelerated degradation at higher temperatures. Formaldehyde emission from plywood was reduced; however, bonding quality and mechanical performance decreased with higher TETA content. Nevertheless, the wet shear strength of all variants exceeded 1 N/mm². Adhesive formulation containing 0.5% TETA was selected as the optimal variant, providing environmental benefits while maintaining satisfactory plywood performance. Full article

Ensuring optimal adhesive curing during plywood and LVL (Layered Veneer Lumber) hot pressing requires accurate knowledge of internal temperature distribution, which is often difficult to assess using conventional surface-based measurements. This study introduces a custom-developed multi-layer smart sensor network capable of in situ, real-time temperature profiling across LVL layers during industrial hot pressing. The system integrates miniature embedded sensors and proprietary data acquisition software, enabling the simultaneous multi-point monitoring of thermal dynamics with a high temporal resolution. Experiments were performed on LVL panels of varying thicknesses, applying industry-standard pressing schedules derived from conventional calculation rules. Despite adherence to prescribed pressing times, results reveal significant core temperature deficits in thicker panels, potentially compromising adhesive gelation and overall bonding quality. These findings underline the need to revisit the pressing time determination for thicker products and demonstrate the potential of advanced sensing technologies to support adaptive process control. The proposed approach contributes to smart manufacturing and the remote-like monitoring of internal thermal states, providing valuable insights for enhancing product performance and industrial process efficiency. Full article

The epoxy monomer N,1-bis(4-(2-oxiranemethoxy)phenyl)methylamine (HBAP-EP) was synthesized through the Schiff base reaction and epichlorohydrin method, and the HBAP-EP monomer was cured using p-aminobenzene sulfonamide (SAA). Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and polarizing optical microscopy (POM) demonstrated that the epoxy monomer exhibits reversible liquid crystal properties, and the liquid crystal fraction of the monomer can reach 14.4% after curing at 120 °C. The fracture toughness of the resin cured at 120 °C can reach 0.93 KJ·m⁻², and its thermal conductivity is 0.3229 W·(m·K)⁻¹, both of which are higher than those of ordinary epoxy resin. Full article

This work examines the colloidal properties of clays sampled from two different locations in Ventzia basin processed as low-density solid additives for water-based drilling fluid applications. The obtained samples were mechanically processed to reach a size less than 2 cm. The material was then activated with 3 wt% soda ash without oven drying, keeping the moisture in environmental conditions to simulate industrial activation conditions. After laying for one month curing time, samples were oven dried at 60 °C and further ground to <120 μm. Two groups of samples were created mixing clays from Ventzia basin and additives. The first group contained clay, xanthan gum and sodium polyacrylate (PAA), while the second group contained clay, xanthan gum and sodium hexametaphosphate (SHMP). Standard tests were performed for the rheological behavior and filtration properties prior to and after dynamic thermal aging. Results obtained were compared with commercial clays from Milos and Wyoming used in drilling fluid systems, after thermally deteriorating also their properties. The obtained results revealed that the enhanced clays under study maintain excellent thermal stability. Notably, the top-performing formulation met the critical American Petroleum Institute (API) benchmark for filtrate loss (<15 mL) and exhibited a robust rheological profile at temperatures up to 105 °C, demonstrating its suitability for water-based fluid (WBF) applications. Full article

Epoxy resins are valuable in aerospace, electronics, and high-performance industries; however, their inherently low thermal conductivity (TC) limits applications requiring effective heat dissipation. Recent reports suggest that certain liquid crystalline or partially crystalline epoxy formulations can achieve higher TC, even exceeding 1 W/(m·K). To investigate this, 17 epoxy formulations were prepared, including the commonly used diglycidyl ether of bisphenol A (DGEBA) and two custom-synthesized diepoxides: TME4, which contains rigid aromatic ester linkages with a C4 aliphatic spacer, and LCE-DP, featuring rigid imine bonds. Thermal conductivity was measured using four techniques: laser flash analysis (LFA), modified transient plane source (MTPS), time-domain thermoreflectance (TDTR), and displacement thermo-optic phase spectroscopy (D-TOPS). Additionally, small-angle and wide-angle X-ray scattering (SAXS/WAXS) were performed to detect crystalline or liquid crystalline domains. All formulations exhibited TC values ranging from 0.13 to 0.32 W/(m·K). The TME4–DDS systems, previously reported to be near 1 W/(m·K), consistently measured between 0.26 and 0.30 W/(m·K). Thus, under our synthesis and curing conditions, the elevated TC reported in prior studies was not reproduced, and no strong evidence of crystallinity was observed; indications of local ordering did not translate into higher conductivity. Variations in TC among methods often matched or exceeded the gains attributed to mesophase formation. More broadly, evidence for crystallinity in epoxy thermosets appears weak, consistent with the notion that crosslinking suppresses long-range ordering. Full article

This study presents a novel strategy for designing photocurable resins tailored for the additive manufacturing of smart thermoset materials. A quaternary formulation was developed by integrating bis(2-methacryloyl)oxyethyl disulfide (DADS) with an epoxy/thiol-ene system (ETES) composed of diglycidyl ether of bisphenol A (EP), pentaerythritol tetrakis(3-mercaptopropionate) (PTMP), and 4,4′-methylenebis(N,N-diallylaniline) (ACA4). This unique combination enables the simultaneous activation of four polymerization mechanisms: radical photopolymerization, thiol-ene coupling, thiol-Michael addition, and anionic ring-opening, within a single resin matrix. A key innovation lies in the exothermic nature of DADS photopolymerization, which initiates and sustains ETES curing at room temperature, enabling 3D printing without thermal assistance. This represents a significant advancement over conventional systems that require elevated temperatures or post-curing steps. The resulting hybrid poly(acrylate–co-ether–co-thioether) network exhibits enhanced mechanical integrity, shape memory behavior, and intrinsic self-healing capabilities. Dynamic Mechanical Analysis revealed a shape fixity and recovery of 93%, while self-healing tests demonstrated a 94% recovery of viscoelastic properties, as evidenced by near-overlapping storage modulus curves compared to a reference sample. This integrated approach broadens the design space for multifunctional photopolymers and establishes a versatile platform for advanced applications in soft robotics, biomedical devices, and sustainable manufacturing. Full article

Crumb rubber, obtained from discarded tires, presents a sustainable alternative in the construction industry, particularly in rubberized concrete. Treated crumb rubber offers improved mechanical performance; however, limited reports are available on its behavior at elevated temperatures. This study investigates the performance of rubberized concrete containing treated and untreated crumb rubber when exposed to elevated temperatures. The treatments employed are chemical (sodium hydroxide (NaOH)) and physical (cement coating) methods. M30-grade concrete was used as a control mix, and crumb rubber (CR) was added by replacing a portion of the fine aggregate. In order to mitigate the strength reduction, silica fume and polypropylene fibers were added. An optimal mix was determined using Taguchi’s L9 orthogonal array, by varying proportions of crumb rubber, silica fume (SF), and polypropylene (PP) fiber. The ideal mix contained 10% CR, 5% SF, and 0.2% PP fiber based on compressive strength. Specimens were cured for 28 days and exposed to temperatures of 200 °C, 400 °C, 600 °C, and 800 °C for 1 h. Mechanical properties such as compressive strength, split tensile strength, and modulus of elasticity were evaluated, along with an ultrasonic pulse velocity test. The results indicate that treated crumb rubber enhances bonding, improving the mechanical and thermal performance of rubberized concrete under high temperature. Full article

Although hempcrete is a more sustainable alternative to most conventional thermal insulation materials, it still requires virgin hemp for its production. In this context, lignocellulosic industrial waste emerges as an attractive alternative to replace the virgin hemp. Accordingly, this work analyzed the use of eucalyptus pinchips and hemp waste as a replacement for virgin hemp in the production of hempcrete. For this, an integral methodology is applied to evaluate not only the technical properties of the mixtures but also to assess the corresponding environmental impacts. In particular, the mechanical properties of the mixtures were analyzed with percentages of replacement between 40% and 100% of virgin hemp by eucalyptus pinchips and/or hemp waste. The density of the mixtures was measured in a time frame between 0 and 28 days, and their compressive strength at 28 days of curing. Finally, life cycle assessments were performed for each mixture. As all mixes reached higher values of compressive strength than the ones with virgin hemp, basically, the differences are concentrated in the environmental impacts. From that perspective, the lime-based mixture with 100% hemp waste reduces the environmental impacts, particularly the emissions for respiratory and carcinogenic/non-carcinogenic effects, which are 10% and 20%, respectively. Full article

This study evaluates adhesive bolts (chemical anchors) bonded with epoxy and vinyl ester resins for surface and tunnel excavations in tropical mining environments under static and dynamic loading. Over 300 pull-out tests in concrete and hard rock examined the effects of bolt length, curing time, and substrate condition on load capacity, failure mode, and bond–slip response. Epoxy anchors exhibited higher bond strength, including under early-age and thermally active conditions, while vinyl ester showed improved ductility and post-peak behaviour in fractured rock. Numerical modelling with Rocscience RS2 (Phase 2) and Unwedge simulated excavation responses for bolt lengths of 190–250 mm and spacings of 0.5–2.0 m. Tensile failure dominated at wider spacings, whereas closely spaced anchors enhanced confinement and redistributed stresses. The combined experimental–numerical evidence quantifies chemical-anchor performance in complex subsurface settings and supports their use for early-age support and long-term stability. Findings motivate integration of resin-grouted bolts into modern support designs, particularly in seismically sensitive or hydrothermally variable mines. Full article

Ground granulated blast furnace slag (GBFS)-based geopolymers represent a viable binder system that combines mechanical efficiency with a significantly lower carbon footprint when compared to conventional Portland cement. This work examines how thermal curing between 20 °C and 80 °C affects setting time, mechanical performance, shrinkage, and porosity of GBFS-based geopolymers. Curing at 40 °C accelerated gel formation, yielding compressive strengths up to 71.9 MPa. This regime also reduced shrinkage and porosity. In contrast, curing at ≥60 °C caused structural degradation and reduced long-term performance. Statistical analysis (ANOVA and Tukey post hoc) confirmed significant effects of curing regime and age on performance. These findings provide key insights for optimizing thermal curing of slag-based geopolymers, supporting their deployment in environmentally responsible construction practices. Full article

This study examines the prestress transmission behavior in near-surface-mounted (NSM) carbon fiber-reinforced polymer (CFRP)-strengthened reinforced concrete structures, with particular emphasis on the effects of temperature. Experimental tests were conducted to evaluate the tensile and shear properties of epoxy adhesives under a range of curing temperatures (20–100 °C) and ambient service temperatures (0–80 °C). The results reveal an inverse exponential relationship between curing time and temperature. Notably, adhesive strength declines significantly above 60 °C and the adhesive loses functionality at 80 °C. Building on these findings, an analytical model was developed to predict prestress transfer length, CFRP strain distribution, and interfacial shear stress. The model incorporates effective bond stiffness and a prestress reduction coefficient to account for varying prestress levels (10–50%). Parametric analyses identify the CFRP elastic modulus, cross-sectional geometry, adhesive thickness, and degree of curing as critical factors influencing prestress transmission. The model’s predictions were validated against experimental data, demonstrating its reliability. Overall, this work provides a theoretical foundation for optimizing the design of NSM CFRP-strengthened structures under complex thermal conditions. Full article

The objective of this study was to evaluate the technical properties and assess the durability of a novel high-performance concrete with aggregates composed entirely of reactive powders derived from chalcedonite—a mineral previously not utilized in HPC technology. Since there is insufficient information on chalcedonite-based concretes in the scientific literature, the presented research aims to address these knowledge gaps. The characterization of the chalcedonite powder involved the determination of specific gravity, particle size distribution, specific surface area, and particle morphology through microscopic analysis. The hardened chalcedonite-based and reference quartz-based high-performance concretes were subjected to a comprehensive suite of tests to determine their physical properties (bulk density, water absorption, and capillary absorption) and mechanical properties (flexural and compressive strength). Durability was further assessed based on compressive strength criteria, including frost resistance and carbonation resistance. To simulate long-term performance and better evaluate the durability of the high-performance concretes, specimens were tested following standard water curing and after additional maturation processes, including thermal treatment, which in the extreme case resulted in a seven-day compressive strength of 176.9 MPa, a value higher by 56.7 MPa (corresponding to an increase of 47.1%) compared to the strength of the identical concrete not subjected to thermal treatment. To explore the potential for architectural applications, particularly in outdoor environments, capillary absorption testing was of particular importance, as it provided insight into the material’s resistance to eventual pigment leaching from the mineral matrix. Full article

The environmental impact of traditional construction materials has led to increasing interest in developing more sustainable alternatives. This study addresses the development of low-carbon autoclaved aerated concrete (AAC) through the complete replacement of ordinary Portland cement (OPC) with ground granulated blast furnace slag (BFS), activated with lime and, in some formulations, supplemented with calcium carbide slag (CCS). Five different AAC mixtures were prepared and evaluated in terms of workability, foaming behavior, compressive strength, phase composition, density, thermal conductivity, and life cycle assessment (LCA). The BFS-based mixtures activated with lime exhibited good workability and foaming stability. After pre-curing, the addition of CCS significantly improved the formation of tobermorite during autoclaving. As a result, the BFS–CCS formulations achieved compressive strengths comparable to the reference OPC-based mix while maintaining low densities (420–441 kg/m³) and thermal conductivities in the range of 0.111–0.119 W/(m·K). These results confirm the technical feasibility of producing structural-grade AAC with a lower environmental footprint. Full article

This work investigates the influence of CaO as a partial substitute for fly ash in alkali-activated fly ash mortars (AAFM), aiming to reduce reliance on conventional thermal curing. Mortars containing 0%, 2%, and 4% CaO were prepared and subjected to two curing regimes: thermal curing at 70 °C for 24 h and ambient curing at 21 °C for 24 h. The materials were thoroughly characterised by XRD, XRF, TGA/DTA, SEM, and particle size distribution, while compressive and flexural strength, density, and porosity were evaluated at 7, 14, and 28 days. The results demonstrated that CaO addition improved mechanical performance in both curing environments, particularly at a 4% substitution level, where compressive strength increased by up to 13.8% under thermal curing conditions. These improvements were associated with the formation of C-S-H and C-A-S-H gels, especially margarite, which contributed to accelerated setting and earlier demoulding. Nonetheless, while CaO incorporation improved mechanical performance and allowed earlier demoulding, it could not fully replicate the effects of heat curing at the studied percentages. Ambient-cured mortars exhibited higher porosity and less compact microstructures than thermally cured samples, which displayed denser, layered morphologies. The study confirms that CaO can act as a partial substitute or reducer for conventional curing, but is not sufficient to enable in situ applications without heat treatment. Future research should explore higher CaO contents in combination with set retarders, intermediate curing regimes, or alternative strategies to balance mechanical performance with energy efficiency. Full article