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Search Results (1,061)

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18 pages, 1628 KB  
Patent Summary
Manual Resin Gear Drive for Fine Adjustment of Schlieren Optical Elements
by Emilia Georgiana Prisăcariu and Iulian Vlăducă
Inventions 2025, 10(5), 89; https://doi.org/10.3390/inventions10050089 - 2 Oct 2025
Abstract
High-precision angular positioning mechanisms are essential across diverse scientific and industrial applications, from optical instrumentation to automated mechanical systems. Conventional bronze–steel gear reduction units, while reliable, are often heavy, costly, and unsuitable for chemically aggressive or vacuum environments, limiting their use in advanced [...] Read more.
High-precision angular positioning mechanisms are essential across diverse scientific and industrial applications, from optical instrumentation to automated mechanical systems. Conventional bronze–steel gear reduction units, while reliable, are often heavy, costly, and unsuitable for chemically aggressive or vacuum environments, limiting their use in advanced research setups. This work introduces a novel 1:360 gear reduction system manufactured by resin-based additive manufacturing, designed to overcome these limitations. The compact worm–gear assembly translates a single crank rotation into a precise one-degree indicator displacement, enabling fine and repeatable angular control. A primary application is the alignment of parabolic mirrors in schlieren systems, where accurate tilt adjustment is critical to correct optical alignment; however, the design is broadly adaptable to other precision positioning tasks in laboratory and industrial contexts. Compared with conventional assemblies, the resin-based reducer offers reduced weight, chemical and vacuum compatibility, and lower production cost. Its three-stage reduction design further enhances load-bearing capacity, achieving approximately double the theoretical torque transfer of equivalent commercial systems. These features establish the device as a robust, scalable, and automation-ready solution for high-accuracy angular adjustment, contributing both to specialized optical research and general-purpose precision engineering. Full article
(This article belongs to the Section Inventions and Innovation in Advanced Manufacturing)
16 pages, 1227 KB  
Article
Multimodal Behavioral Sensors for Lie Detection: Integrating Visual, Auditory, and Generative Reasoning Cues
by Daniel Grabowski, Kamila Łuczaj and Khalid Saeed
Sensors 2025, 25(19), 6086; https://doi.org/10.3390/s25196086 - 2 Oct 2025
Abstract
Advances in multimodal artificial intelligence enable new sensor-inspired approaches to lie detection by combining behavioral perception with generative reasoning. This study presents a deception detection framework that integrates deep video and audio processing with large language models guided by chain-of-thought (CoT) prompting. We [...] Read more.
Advances in multimodal artificial intelligence enable new sensor-inspired approaches to lie detection by combining behavioral perception with generative reasoning. This study presents a deception detection framework that integrates deep video and audio processing with large language models guided by chain-of-thought (CoT) prompting. We interpret neural architectures such as ViViT (for video) and HuBERT (for speech) as digital behavioral sensors that extract implicit emotional and cognitive cues, including micro-expressions, vocal stress, and timing irregularities. We further incorporate a GPT-5-based prompt-level fusion approach for video–language–emotion alignment and zero-shot inference. This method jointly processes visual frames, textual transcripts, and emotion recognition outputs, enabling the system to generate interpretable deception hypotheses without any task-specific fine-tuning. Facial expressions are treated as high-resolution affective signals captured via visual sensors, while audio encodes prosodic markers of stress. Our experimental setup is based on the DOLOS dataset, which provides high-quality multimodal recordings of deceptive and truthful behavior. We also evaluate a continual learning setup that transfers emotional understanding to deception classification. Results indicate that multimodal fusion and CoT-based reasoning increase classification accuracy and interpretability. The proposed system bridges the gap between raw behavioral data and semantic inference, laying a foundation for AI-driven lie detection with interpretable sensor analogues. Full article
(This article belongs to the Special Issue Sensor-Based Behavioral Biometrics)
24 pages, 8088 KB  
Article
The Design and Development of a Wearable Cable-Driven Shoulder Exosuit (CDSE) for Multi-DOF Upper Limb Assistance
by Hamed Vatan, Theodoros Theodoridis, Guowu Wei, Zahra Saffari and William Holderbaum
Appl. Sci. 2025, 15(19), 10673; https://doi.org/10.3390/app151910673 - 2 Oct 2025
Abstract
This study presents the design, development, and experimental validation of a novel cable-driven shoulder exosuit (CDSE) for upper limb rehabilitation and assistance. Unlike existing exoskeletons, which are often bulky, limited in degrees of freedom (DOFs), or impractical for home use, the proposed DSE [...] Read more.
This study presents the design, development, and experimental validation of a novel cable-driven shoulder exosuit (CDSE) for upper limb rehabilitation and assistance. Unlike existing exoskeletons, which are often bulky, limited in degrees of freedom (DOFs), or impractical for home use, the proposed DSE offers a lightweight (≈2 kg), portable, and wearable solution capable of supporting three shoulder movements: abduction, flexion, and horizontal adduction. The system employs a bioinspired tendon-driven mechanism using Bowden cables, transferring actuation forces from a backpack to the arm, thereby reducing user load and improving comfort. Mathematical models and inverse kinematics were derived to determine cable length variations for targeted motions, while control strategies were implemented using a PID-based approach in MATLAB Simscape-Multibody simulations. The prototype was fabricated in three iterations using PLA, aluminum, and carbon fiber—culminating in a durable and ergonomic final version. Experimental evaluations on a healthy subject demonstrated high accuracy in position tracking (<5% error) and torque profiles consistent with simulation outcomes, validating system robustness. The CDSE successfully supported loads up to 4 kg during rehabilitation tasks, highlighting its potential for clinical and at-home applications. This research contributes to advancing wearable robotics by addressing portability, biomechanical alignment, and multi-DOF functionality in upper limb exosuits. Full article
(This article belongs to the Special Issue Advances in Cable Driven Robotic Systems)
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19 pages, 427 KB  
Article
Bridging Leadership Competency Gaps and Staff Nurses’ Turnover Intention: Dual-Rater Study in Saudi Tertiary Hospitals
by Hanan A. Alkorashy and Dhuha A. Alsahli
Healthcare 2025, 13(19), 2506; https://doi.org/10.3390/healthcare13192506 - 2 Oct 2025
Abstract
Background: Nurse-manager competencies shape workforce stability, yet role-based perception gaps between managers and staff may influence staff nurses’ turnover cognitions. Objectives: To (1) compare nurse managers’ self-ratings with staff nurses’ ratings of the same managers on the Nurse Manager Competency Inventory [...] Read more.
Background: Nurse-manager competencies shape workforce stability, yet role-based perception gaps between managers and staff may influence staff nurses’ turnover cognitions. Objectives: To (1) compare nurse managers’ self-ratings with staff nurses’ ratings of the same managers on the Nurse Manager Competency Inventory (NMCI); (2) compare both groups’ perceptions of staff nurses’ turnover intention (EMTIS); (3) examine domain-specific links between perceived competencies and perceived turnover intention; and (4) explore demographic influences (age, education, experience) on these perceptions. Methods: Cross-sectional dual-rater study with 225 staff nurses and 171 nurse managers in two tertiary hospitals in Saudi Arabia. Data were collected from August to November 2024. Managers completed NMCI self-ratings, and staff nurses rated their managers on the same NMCI domains; both groups rated staff nurses’ turnover intention using EMTIS. Between-group differences were tested with one-way ANOVA (two-tailed α = 0.05), and associations were examined with Pearson’s r (95% CIs). Findings: Managers consistently rated themselves higher than staff rated them across all nine NMCI domains; the largest descriptive gaps were in Promoting Staff Retention, Recruit Staff, Perform Supervisory Responsibilities, and Facilitate Staff Development (e.g., overall NMCI: managers M = 3.67, SD = 0.61 vs. staff M = 3.04, SD = 0.74; F = 0.114, p = 0.73)with comparatively smaller divergence for Ensure Patient Safety and Quality. Managers and staff did not differ significantly on EMTIS (overall EMTIS: managers M = 3.16, SD = 1.28 vs. staff M = 3.00, SD = 1.15; F = 21.32, p = 0.173). Specific competency domains—retention, supervision, staff development, safety/quality leadership, and quality improvement—showed small inverse correlations with EMTIS facets (typical r ≈ −0.11 to −0.19; p < 0.05), whereas the global NMCI–overall EMTIS correlation was non-significant (r = −0.077, p = 0.124). Effect sizes were modest and should be interpreted cautiously. Conclusions: Actionable signals reside at the domain (micro-competency) level rather than in global leadership composites. Targeted, continuous, unit-embedded development in human- and development-focused competencies—tracked with dual-lens (manager–staff) measurement and linked to retention KPIs—may help nudge turnover cognitions downward. Key limitations include the cross-sectional, perception-based design and two-site setting. Findings nonetheless align with international workforce challenges and may be transferable to similar hospital contexts. Full article
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15 pages, 2241 KB  
Article
Vertically Aligned Carbon Nanotubes Grown on Copper Foil as Electrodes for Electrochemical Double Layer Capacitors
by Chinaza E. Nwanno, Ram Chandra Gotame, John Watt, Winson Kuo and Wenzhi Li
Nanomaterials 2025, 15(19), 1506; https://doi.org/10.3390/nano15191506 - 1 Oct 2025
Abstract
This study reports a binder-free, catalyst-free method for fabricating vertically aligned carbon nanotubes (VACNTs) directly on copper (Cu) foil using plasma-enhanced chemical vapor deposition (PECVD) for electrochemical double-layer capacitor (EDLC) applications. This approach eliminates the need for catalyst layers, polymeric binders, or substrate [...] Read more.
This study reports a binder-free, catalyst-free method for fabricating vertically aligned carbon nanotubes (VACNTs) directly on copper (Cu) foil using plasma-enhanced chemical vapor deposition (PECVD) for electrochemical double-layer capacitor (EDLC) applications. This approach eliminates the need for catalyst layers, polymeric binders, or substrate pre-treatments, simplifying electrode design and enhancing electrical integration. The resulting VACNTs form a dense, uniform, and porous array with strong adhesion to the Cu substrate, minimizing contact resistance and improving conductivity. Electrochemical analysis shows gravimetric specific capacitance (Cgrav) and areal specific capacitance (Careal) of 8 F g−1 and 3.5 mF cm−2 at a scan rate of 5 mV/s, with low equivalent series resistance (3.70 Ω) and charge transfer resistance (0.48 Ω), enabling efficient electron transport and rapid ion diffusion. The electrode demonstrates excellent rate capability and retains 92% of its initial specific capacitance after 3000 charge–discharge cycles, indicating strong cycling stability. These results demonstrate the potential of directly grown VACNT-based electrodes for high-performance EDLCs, particularly in applications requiring rapid charge–discharge cycles and sustained energy delivery. Full article
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19 pages, 2021 KB  
Article
Fate of Tebuconazole and Trifloxystrobin in Edible Rose Petals: Storage Stability and Human Health Risk Assessment
by Xiaotong Qin, Jinwei Zhang, Yan Tao, Li Chen, Pingzhong Yu, Junjie Jing, Ercheng Zhao, Yongquan Zheng and Min He
Molecules 2025, 30(19), 3938; https://doi.org/10.3390/molecules30193938 - 1 Oct 2025
Abstract
This study addresses the absence of maximum residue limits (MRLs) for tebuconazole and trifloxystrobin in edible rose petals in China by systematically evaluating the residue behavior and dietary exposure risks of these fungicides. An analytical method based on QuEChERS sample preparation coupled with [...] Read more.
This study addresses the absence of maximum residue limits (MRLs) for tebuconazole and trifloxystrobin in edible rose petals in China by systematically evaluating the residue behavior and dietary exposure risks of these fungicides. An analytical method based on QuEChERS sample preparation coupled with UPLC–MS/MS was developed for the simultaneous determination of tebuconazole, trifloxystrobin, and its metabolite CGA321113 in fresh and dried rose petals. Field trials under the highest application conditions (184 g a.i./hm2, applied twice) were conducted to investigate residue dissipation dynamics, storage stability, processing concentration effects, and transfer behavior during brewing. Results indicated that the target compounds remained stable in rose petals for 12 months at –20 °C ± 2 °C. The drying process significantly concentrated residues due to the hydrophobic nature of the compounds, with enrichment factors ranging from 3.0 to 3.9. Brewing tests further confirmed low transfer rates of tebuconazole, trifloxystrobin, and CGA321113 into the infusion, consistent with their low water solubility and high log Kow values. Residue dissipation followed first-order kinetics, with half-lives of 1.9–2.9 days for tebuconazole and 1.2–2.7 days for trifloxystrobin. Dietary risk assessment showed an acceptable risk for trifloxystrobin (RQ = 22.7%) but a high risk for tebuconazole (RQ = 175.1%). It is recommended to set the MRL for both tebuconazole and trifloxystrobin in edible roses at 15.0 mg/kg. This standard ensures consumer safety while accommodating agricultural needs and aligns with international regulations. For the high-risk pesticide tebuconazole, measures such as optimizing application strategies and promoting integrated management should be implemented to mitigate residue risks. Full article
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31 pages, 16219 KB  
Article
Design, Simulation, Construction and Experimental Validation of a Dual-Frequency Wireless Power Transfer System Based on Resonant Magnetic Coupling
by Marian-Razvan Gliga, Calin Munteanu, Adina Giurgiuman, Claudia Constantinescu, Sergiu Andreica and Claudia Pacurar
Technologies 2025, 13(10), 442; https://doi.org/10.3390/technologies13100442 - 1 Oct 2025
Abstract
Wireless power transfer (WPT) has emerged as a compelling solution for delivering electrical energy without physical connectors, particularly in applications requiring reliability, mobility, or encapsulation. This work presents the modeling, simulation, construction, and experimental validation of an optimized dual-frequency WPT system using magnetically [...] Read more.
Wireless power transfer (WPT) has emerged as a compelling solution for delivering electrical energy without physical connectors, particularly in applications requiring reliability, mobility, or encapsulation. This work presents the modeling, simulation, construction, and experimental validation of an optimized dual-frequency WPT system using magnetically coupled resonant coils. Unlike conventional single-frequency systems, the proposed architecture introduces two independently controlled excitation frequencies applied to distinct transistors, enabling improved resonance behavior and enhanced power delivery across a range of coupling conditions. The design process integrates numerical circuit simulations in PSpice and three-dimensional electromagnetic analysis in ANSYS Maxwell 3D, allowing accurate evaluation of coupling coefficient variation, mutual inductance, and magnetic flux distribution as functions of coil geometry and alignment. A sixth-degree polynomial model was derived to characterize the coupling coefficient as a function of coil separation, supporting predictive tuning. Experimental measurements were carried out using a physical prototype driven by both sinusoidal and rectangular control signals under varying load conditions. Results confirm the simulation findings, showing that specific signal periods (e.g., 8 µs, 18 µs, 20 µs, 22 µs) yield optimal induced voltage values, with strong sensitivity to the coupling coefficient. Moreover, the presence of a real load influenced system performance, underscoring the need for adaptive control strategies. The proposed approach demonstrates that dual-frequency excitation can significantly enhance system robustness and efficiency, paving the way for future implementations of self-adaptive WPT systems in embedded, mobile, or biomedical environments. Full article
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20 pages, 4998 KB  
Technical Note
Design and Implementation of a Small-Scale Hydroponic Chamber for Sustainable Vegetative Propagation from Cuttings: A Basil (Ocimum basilicum L.)
by Angélica Nohemí Cardona Rodríguez, Carlos Alberto Olvera-Olvera, Santiago Villagrana-Barraza, Ma. Auxiliadora Araiza-Ezquivel, Diana I. Ortíz-Esquivel, Luis Octavio Solís-Sánchez and Germán Díaz-Flórez
Sustainability 2025, 17(19), 8773; https://doi.org/10.3390/su17198773 - 30 Sep 2025
Abstract
Urban agriculture in space-constrained cities requires compact, reproducible propagation systems. Therefore, the aim of this Technical Note is to design, implement, and functionally validate a low-cost, modular hydroponic chamber (SSHG) for early-stage vegetative propagation. This system couples DHT11-based temperature/RH monitoring with rule-based actuation—irrigation [...] Read more.
Urban agriculture in space-constrained cities requires compact, reproducible propagation systems. Therefore, the aim of this Technical Note is to design, implement, and functionally validate a low-cost, modular hydroponic chamber (SSHG) for early-stage vegetative propagation. This system couples DHT11-based temperature/RH monitoring with rule-based actuation—irrigation 4×/day and temperature-triggered ventilation—under the control of an Arduino Uno microcontroller; LED lighting was not controlled nor analyzed. Two 15-day trials with basil (Ocimum basilicum L.) yielded rooting rates of 61.7% (37/60) and 43.3% (26/60) under a deliberate minimal-input configuration without nutrient solutions or rooting hormones. Environmental summaries and spatial survival maps revealed edge-effect patterns and RH variability that inform irrigation layout improvements. The chamber, bill of materials, and protocol are documented to support replication and iteration. Thus, the SSHG provides a transferable baseline for educators and researchers to audit, reproduce, and improve small-footprint, controlled-environment propagation. Beyond its technical feasibility, the SSHG contributes to sustainability by leveraging low-cost, readily available components, enabling decentralized seedling production in space-constrained settings, and operating under a minimal-input configuration. In line with widely reported hydroponic efficiencies (e.g., lower water use relative to soil-based propagation), this open and replicable platform aligns with SDGs 2, 11, 12, and 13. Full article
(This article belongs to the Section Sustainable Agriculture)
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14 pages, 611 KB  
Article
Studies on the Recovery of Wash Water from Swimming Pool Filters and Their Characteristics—A Case Study
by Wojciech Poćwiardowski
Water 2025, 17(19), 2854; https://doi.org/10.3390/w17192854 - 30 Sep 2025
Abstract
Filter wash water (FWW) from public swimming pools is a recoverable resource, yet full-scale evidence on safe on-site reuse with documented economics is scarce. We evaluated a full-scale integrated recovery unit (SOWA) installed at an indoor public pool. The SOWA system—sedimentation, granular filtration [...] Read more.
Filter wash water (FWW) from public swimming pools is a recoverable resource, yet full-scale evidence on safe on-site reuse with documented economics is scarce. We evaluated a full-scale integrated recovery unit (SOWA) installed at an indoor public pool. The SOWA system—sedimentation, granular filtration operated at a hydraulic loading rate (HLR) of 7.5–10 m3 m−2 h−1, ultrafiltration, and chlorine-dioxide (ClO2) disinfection—was monitored for physicochemical and microbiological performance. Turbidity decreased from 23.1 nephelometric turbidity units (NTU) to 0.25 NTU; chemical oxygen demand, reported as the permanganate index (COD_Mn), fell from 10.4 to 1.6 mg O2 L−1; and total microbial count declined from 1.6 × 104 to 30 colony-forming units per millilitre (CFU mL−1). Indicator organisms (Escherichia coli, Intestinal enterococci and Pseudomonas aeruginosa) were not detected, and all quality criteria complied with national standards. At the Olender facility, monthly freshwater use dropped from 1700 to 1000 m3 after 24/7 SOWA operation, while combined chlorine was maintained at 0.12 mg Cl2/L and no issues with chloroform were observed. The unit recovered 4.7 m3 h−1 of FWW for non-potable uses. According to manufacturer catalogue data, the recovery process can reach up to 96%, enabling annual savings up to ~EUR 9000 and a payback of ~2 years under favourable tariffs and loads. Our outcomes are consistent with independent full-scale reuse trains (e.g., ultrafiltration/reverse osmosis) and with disinfection-by-product control strategies reported in the literature, and they align with international guidance for swimming-pool water reuse. This study provides a rare, end-to-end implementation at full scale, documenting continuous operation, verified microbial safety, regulatory compliance, quantified water and cost savings, and site-specific economics for a compact, multi-barrier FBW recovery system that can be directly transferred to similar facilities. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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14 pages, 5130 KB  
Article
Study on the Drying Characteristics of Moist Fine Lignite in a Dense Gas–Solid Separation Fluidized Bed
by Huicheng Lei, Tengfeng Wan, Tingguan Chen, Bingbing Ma, Zongxu Yao, Bao Xu, Qingfei Wang and Xuan Xu
Minerals 2025, 15(10), 1039; https://doi.org/10.3390/min15101039 - 30 Sep 2025
Abstract
Coal serves as a cornerstone and stabilizer for China’s energy security; utilizing it in a clean and efficient manner aligns with the current national energy situation. The moisture content of coal is a crucial factor affecting its calorific value and separation efficiency. Therefore, [...] Read more.
Coal serves as a cornerstone and stabilizer for China’s energy security; utilizing it in a clean and efficient manner aligns with the current national energy situation. The moisture content of coal is a crucial factor affecting its calorific value and separation efficiency. Therefore, enhancing the drying rate while simultaneously reducing the moisture content in coal is essential to improve separation efficiency. This paper primarily investigates the drying and separation characteristics of wet fine coal particles within a gas–solid fluidized bed system. A hot gas–solid fluidized bed was employed to study the particle fluidization behavior, heat–mass transfer, and agglomeration drying properties under varying airflow temperatures. The results indicate that as the airflow temperature increases, the minimum fluidization velocity tends to decrease. Additionally, with an increase in bed height, the particle temperature correspondingly decreases, leading to weakened heat exchange capability in the upper layer of the bed. Faster heating rates facilitate rapid moisture removal while minimizing agglomeration formation. The lower the proportion of moisture and magnetite powder present, the less force is required to break apart particle agglomerates. The coal drying process exhibits distinct stages. Within a temperature range of 75 °C to 100 °C, there is a significant enhancement in drying rate, while issues such as particle fragmentation or pore structure collapse are avoided at elevated temperatures. This research aims to provide foundational insights into effective drying processes for wet coal particles in gas–solid fluidized beds. Full article
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12 pages, 3413 KB  
Article
High-Precision Beam Deflection and Diagnostics System for EUV Synchrotron Radiation Illumination
by Haigang Liu, Bo Zhao, Xiangyu Meng, Jun Zhao, Zhi Guo, Xiangzhi Zhang, Yong Wang, Qiushi Huang, Zhe Zhang, Zhanshan Wang and Renzhong Tai
Photonics 2025, 12(10), 970; https://doi.org/10.3390/photonics12100970 - 30 Sep 2025
Abstract
The EUV light emitted by the synchrotron radiation source exhibits a stable wavelength and pollution-free characteristics, making it highly suitable for technical verification in diverse EUV lithography applications and playing a pivotal role in EUV lithography industry research. To guide the EUV light [...] Read more.
The EUV light emitted by the synchrotron radiation source exhibits a stable wavelength and pollution-free characteristics, making it highly suitable for technical verification in diverse EUV lithography applications and playing a pivotal role in EUV lithography industry research. To guide the EUV light from the beamline into the experimental platform, this paper proposes a deflection system design based on the Shanghai Synchrotron Radiation Facility (SSRF). This system enables beamline diagnostics for EUV light while facilitating precise positioning and performance testing of the Mo/Si multilayer planar deflection mirror. The deflection system achieves accurate installation and alignment through a coordinate transfer protocol. By imaging the EUV incident light spot on a scintillator and analyzing variations in EUV light intensity data before and after the deflection mirror, the system can accurately measure focused light spot parameters from the beamline and achieve submicron alignment accuracy with 10 μrad angular resolution for the deflection mirror. The proposed design provides valuable insights for advancing EUV lithography technology utilizing synchrotron radiation sources. Full article
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28 pages, 819 KB  
Article
An Approach for the Development and Maturation of ICT Products
by Angelica Serna-Herrera, Oscar Mauricio Caicedo Rendón and Wilfred Rivera Martínez
Adm. Sci. 2025, 15(10), 383; https://doi.org/10.3390/admsci15100383 - 30 Sep 2025
Abstract
Product development in academia and its technology transfer are crucial activities for the sustainable development of society. Nevertheless, transferring academic research is a complex process that requires mature research results aligned with market needs. Existing approaches frequently focus on process management and the [...] Read more.
Product development in academia and its technology transfer are crucial activities for the sustainable development of society. Nevertheless, transferring academic research is a complex process that requires mature research results aligned with market needs. Existing approaches frequently focus on process management and the relationships between system participants, disregarding the importance of maturity assessment in the product development cycle. This paper proposes an approach, comprising a Framework and a Method, to guide the progressive maturation of ICT products from universities and to facilitate their transfer to productive and social sectors. The Framework maps the innovation trajectory from research to commercialization by phases, tasks, activities, and stakeholders. The Method articulates agile cycles inspired by Scrum, with a continuous TRL-based maturity assessment and sustained market engagement to align academic product development with market demands. Innovation experts evaluated the approach using content validity indices and qualitative content analysis. The results showed a high level of agreement on the relevance and usefulness of the Framework and the Method, and qualitative feedback informed improvements in presentation and clarity. In summary, the proposed approach provides a practical roadmap for aligning university research with market needs and enhancing the conversion of prototypes into transferable and marketable solutions. Full article
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22 pages, 10170 KB  
Review
Bio-Inspired Photocatalytic Nitrogen Fixation: From Nitrogenase Mimicry to Advanced Artificial Systems
by Wenpin Xia, Kaiyang Zhang, Jiewen Hou, Huaiyu Fu, Mingming Gao, Hui-Zi Huang, Liwei Chen, Suqin Han, Yen Leng Pak, Hongyu Mou, Xing Gao and Zhenbin Guo
Nanomaterials 2025, 15(19), 1485; https://doi.org/10.3390/nano15191485 - 29 Sep 2025
Abstract
Photocatalytic nitrogen fixation under ambient conditions offers a sustainable alternative to the energy-intensive Haber–Bosch process, yet remains limited by the inertness of N≡N bonds and sluggish multi-electron/proton transfer kinetics. Nature’s nitrogenase enzymes, featuring the FeMo cofactor and ATP-driven electron cascades, inspire a new [...] Read more.
Photocatalytic nitrogen fixation under ambient conditions offers a sustainable alternative to the energy-intensive Haber–Bosch process, yet remains limited by the inertness of N≡N bonds and sluggish multi-electron/proton transfer kinetics. Nature’s nitrogenase enzymes, featuring the FeMo cofactor and ATP-driven electron cascades, inspire a new generation of artificial systems capable of mimicking their catalytic precision and selectivity. This review systematically summarizes recent advances in bio-inspired photocatalytic nitrogen reduction, focusing on six key strategies derived from enzymatic mechanisms: Fe–Mo–S active site reconstruction, hierarchical electron relay pathways, ATP-mimicking energy modules, defect-induced microenvironments, interfacial charge modulation, and spatial confinement engineering. While notable progress has been made in enhancing activity and selectivity, challenges remain in dynamic regulation, mechanistic elucidation, and system-level integration. Future efforts should prioritize operando characterization, adaptive interface design, and device-compatible catalyst platforms. By abstracting nature’s catalytic logic into synthetic architectures, biomimetic photocatalysis holds great promise for scalable, green ammonia production aligned with global decarbonization goals. Full article
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26 pages, 703 KB  
Review
Eco-Friendly Biocatalysts: Laccase Applications, Innovations, and Future Directions in Environmental Remediation
by Hina Younus, Masood Alam Khan, Arif Khan and Fahad A. Alhumaydhi
Catalysts 2025, 15(10), 921; https://doi.org/10.3390/catal15100921 - 26 Sep 2025
Abstract
Laccases, a class of multicopper oxidases found in diverse biological sources, have emerged as key green biocatalysts with significant potential for eco-friendly pollutant degradation. Their ability to drive electron transfer reactions using oxygen, converting pollutants into less harmful products, positions laccases as promising [...] Read more.
Laccases, a class of multicopper oxidases found in diverse biological sources, have emerged as key green biocatalysts with significant potential for eco-friendly pollutant degradation. Their ability to drive electron transfer reactions using oxygen, converting pollutants into less harmful products, positions laccases as promising tools for scalable and sustainable treatment of wastewater, soil, and air pollution. This review explores laccase from a translational perspective, tracing its journey from laboratory discovery to real-world applications. Emphasis is placed on recent advances in production optimization, immobilization strategies, and nanotechnology-enabled enhancements that have improved enzyme stability, reusability, and catalytic efficiency under complex field conditions. Applications are critically discussed for both traditional pollutants such as synthetic dyes, phenolics, and pesticides and emerging contaminants, including endocrine-disrupting chemicals, pharmaceuticals, personal care products, microplastic additives, and PFAS. Special attention is given to hybrid systems integrating laccase with advanced oxidation processes, bioelectrochemical systems, and renewable energy-driven reactors to achieve near-complete pollutant mineralization. Challenges such as cost–benefit limitations, limited substrate range without mediators, and regulatory hurdles are evaluated alongside solutions including protein engineering, mediator-free laccase variants, and continuous-flow bioreactors. By consolidating recent mechanistic insights, this study underscores the translational pathways of laccase, highlighting its potential as a cornerstone of next-generation, scalable, and eco-friendly remediation technologies aligned with circular bioeconomy and low-carbon initiatives. Full article
(This article belongs to the Special Issue Advanced Catalysis for Energy and a Sustainable Environment)
10 pages, 4054 KB  
Article
Prevalence, Morphometric Characteristics of the Accessory Abductor Pollicis Longus Muscle and Clinical Implications: A Cadaveric Study
by Jhonatan Duque-Colorado, Victor Hugo Rodriguez-Torrez, Laura García-Orozco, Rubén Daniel Algieri and Nicolás E. Ottone
Diagnostics 2025, 15(19), 2455; https://doi.org/10.3390/diagnostics15192455 - 25 Sep 2025
Abstract
Background/Objectives: The abductor pollicis longus (APL) muscle exhibits a high degree of anatomical variation, particularly in the number and configuration of its tendons. Understanding these variants is crucial in surgical contexts, especially for tendon transfer and reconstruction procedures. This study aimed to determine [...] Read more.
Background/Objectives: The abductor pollicis longus (APL) muscle exhibits a high degree of anatomical variation, particularly in the number and configuration of its tendons. Understanding these variants is crucial in surgical contexts, especially for tendon transfer and reconstruction procedures. This study aimed to determine the prevalence and morphometric characteristics of the accessory abductor pollicis longus (AAPL) muscle in a Bolivian cadaveric population. Methods: A descriptive, cross-sectional study was performed on 16 forearms from eight adult cadavers (six males and two females) preserved in 10% formalin. Cadaveric dissection was conducted following the AQUA guidelines, with measurements obtained for the AAPL proximal tendon length (PTL), distal tendon length (DTL), muscle length (ML), and transverse muscle length (TML) using a digital caliper. Statistical analysis was carried out using SPSS v26. Results: The AAPL muscle was present in 50% of forearms. Most were unilateral, with one bilateral case. The muscle exhibited a fusiform shape, with fibers aligned longitudinally. Morphometric analysis revealed a mean PTL of 1.20 ± 0.08 cm, DTL of 3.91 ± 0.52 cm, ML of 5.30 ± 0.45 cm, and TML of 0.55 ± 0.056 cm. One case (6.25%) exhibited a multicaudal APL with an additional tendon measuring 6.23 cm. No significant correlations were found between muscle and tendon measurements. Conclusions: AAPL muscles are relatively common and demonstrate notable morphometric variation. While the proximal tendon may be inadequate for grafting due to its short length, the distal tendon offers a viable alternative for reconstructive procedures. Recognition of such variants is clinically relevant, as they may contribute to pathologies like De Quervain’s tenosynovitis or serve as graft sources in surgical interventions. Full article
(This article belongs to the Special Issue Advances in Anatomy—Third Edition)
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