Search Results (54)

This paper reviews various emerging alternative SCMs derived from minerals and biomass sources, industrial byproducts, and underutilized waste streams. The paper compiles and evaluates physicochemical properties, reaction mechanisms in cementitious systems, resource availability, supply chain dynamics, technology readiness, the impact on concrete performance, and environmental and cost factors for each candidate SCM. Specifically, the review examines wood ash from bioenergy plants, volcanic and sedimentary natural pozzolans, and construction and demolition waste. This includes recycled concrete fines, asphalt plants’ rock dust (baghouse fines), aggregate production fines, and post-consumer waste, particularly municipal solid waste incinerator ash and wastewater sludge ash. Additionally, the paper explores innovative additives such as cellulose and chitin nanomaterials and calcium–silicate–hydrate nanoseeds to address challenges of slower strength development and rheological changes. The key contribution of this review is a multifactor framework for assessing alternative SCMs, emphasizing availability, supply chain, market readiness, and environmental performance, combined with an engineering performance review. Full article

The present study explores the sustainable potential of volcanic ash sourced from the active Sakurajima volcano (Japan) as an eco-friendly alternative to Portland cement—a binder known for its high carbon emissions—in concrete and mortar production. The abundant pyroclastic material, currently a waste burden for the residents of Sakurajima and the Kagoshima Bay region, presents a unique opportunity for valorization in line with circular economy principles. Rather than treating this ash as a disposal problem, the research investigates its transformation into a valuable supplementary cementitious material (SCM), contributing to more sustainable construction practices. The investigation focused on the material characterization of the ash (including chemical composition, morphology, and PSD) and its pozzolanic activity index, which is a key indicator of its suitability as a cement replacement. Mortars were prepared with 25% of the commercial binder replaced by volcanic ash—both in its raw form and after mechanical activation—and tested for compressive strength after 28 and 90 days of water curing. Additional assessments included workability of the fresh mix (flow table test), apparent density, and flexural strength of the hardened composites. Tests results showed that the applied volcanic ash did not influence the workability of the mix and showed negligible effect on the apparent density (changes of up to 3.3%), although the mechanical strength was deteriorated (decrease by 15–33% after 7 days, and by 25–26% after 28 days). However, further investigation revealed that the simple mechanical grinding significantly enhances the pozzolanic reactivity of Sakurajima ash. The ground ash achieved a 28-day activity index of 81%, surpassing the 75% threshold set by EN 197-1 and EN 450-1 standards for type II mineral additives. These findings underscore the potential for producing low-carbon mortars and concretes using locally sourced volcanic ash, supporting both emissions reduction and sustainable resource management in construction. Full article

Phosphates are key pollutants involved in the eutrophication of water bodies, creating the need for efficient and low-cost strategies for their removal in order to meet environmental quality standards. This study presents a comparative thermodynamic evaluation of phosphate ion adsorption from aqueous solutions using two sustainable and readily available materials: autoclaved aerated concrete (AAC) and pumice stone (PS). Batch experiments were conducted under acidic (pH 3) and alkaline (pH 9) conditions to determine equilibrium adsorption capacities, and kinetic experiments were carried out for the best-performing adsorbent. Adsorption data were fitted to the Langmuir and the Freundlich isotherm models, while kinetic data were evaluated using pseudo-first-order and pseudo-second-order models. The Freundlich model showed the best correlation (R² = 0.90 − 0.97), indicating the heterogeneous nature of the adsorbent surfaces, whereas the Langmuir parameters suggested monolayer adsorption, with maximum capacities of 1006.69 mg/kg for PS and 859.20 mg/kg for AAC at pH 3. Kinetic results confirmed a pseudo-second-order behavior, indicating chemisorption as the main mechanism and the rate-limiting step in the adsorption process. To the best of our knowledge, this is the first study to compare the thermodynamic performance of AAC and PS for phosphate removal under identical experimental conditions. The findings demonstrate the potential of both materials as efficient, low-cost, and thermodynamically favorable adsorbents. Furthermore, the use of AAC, an industrial by-product, and PS, a naturally abundant volcanic material, supports resource recovery and waste valorization, aligning with the principles of the circular economy and sustainable water management. Full article

Cement is widely used as the primary binder in concrete; however, growing environmental concerns and the rapid expansion of the construction industry have highlighted the need for more sustainable alternatives. Geopolymers have emerged as promising eco-friendly binders due to their lower carbon footprint and potential to utilize industrial byproducts. Geopolymer mortar, like other cementitious substances, exhibits brittleness and tensile weakness. Basalt fibers serve as fracture-bridging reinforcements, enhancing flexural and tensile strength by redistributing loads and postponing crack growth. Basalt fibers enhance the energy absorption capacity of the mortar, rendering it less susceptible to abrupt collapse. Basalt fibers have thermal stability up to about 800–1000 °C, rendering them appropriate for geopolymer mortars designed for fire-resistant or high-temperature applications. They assist in preserving structural integrity during heat exposure. Fibers mitigate early-age microcracks resulting from shrinkage, drying, or heat gradients. This results in a more compact and resilient microstructure. Using basalt fibers improves surface abrasion and impact resistance, which is advantageous for industrial flooring or infrastructure applications. Basalt fibers originate from natural volcanic rock, are non-toxic, and possess a minimal ecological imprint, consistent with the sustainability objectives of geopolymer applications. This study investigates the mechanical and thermal performance of a geopolymer mortar composed of metakaolin and red mud as binders, with basalt powder and limestone powder replacing traditional sand. The primary objective was to evaluate the effect of basalt fiber incorporation at varying contents (0.4%, 0.8%, and 1.2% by weight) on the durability and strength of the mortar. Eight different mortar mixes were activated using sodium hydroxide (NaOH) and sodium silicate (Na₂SiO₃) solutions. Mechanical properties, including compressive strength, flexural strength, and ultrasonic pulse velocity (UPV), were tested 7 and 28 days before and after exposure to elevated temperatures (200, 400, 600, and 800 °C). The results indicated that basalt fiber significantly enhanced the performance of the geopolymer mortar, particularly at a content of 1.2%. Specimens with 1.2% fiber showed up to 20% improvement in compressive strength and 40% in flexural strength after thermal exposure, attributed to the fiber’s role in microcrack bridging and structural densification. Subsequent research should concentrate on refining fiber type, dose, and dispersion techniques to improve mechanical performance and durability. Examinations of microstructural behavior, long-term durability under environmental settings, and performance following high-temperature exposure are crucial. Furthermore, investigations into hybrid fiber systems, extensive structural applications, and life-cycle evaluations will inform the practical and sustainable implementation in the buildings. Full article

This study explores the use of volcanic glass powder (VG) derived from Shirasu volcanic deposits as a substitute for silica fume (SF) in producing high-strength precast concrete piles with a compressive strength of 123 MPa. Initially, mortar specimens with varying VG replacement ratios and curing temperatures were prepared to assess their compressive strength. After identifying the optimal mix ratios and curing conditions for high-strength mortars, concrete specimens incorporating VG were produced. Subsequent testing revealed that a VG replacement ratio of 20% by cement volume and a curing temperature of 70 °C were optimal for achieving the target compressive strength. Although the Young’s modulus of VG-incorporated concrete was slightly lower than that of pure cement and SF concrete, its performance remained satisfactory. These findings suggest that VG is a viable alternative to SF in high-strength concrete applications, providing a sustainable method to enhance concrete properties using locally available volcanic deposits. Full article

Pumice forms when a volcanic explosion ejects highly pressurized, superheated rock, rapidly cooling and depressurizing, resulting in a porous structure. In countries with high volcanic activity, pumice stone is a low-cost natural material that is lightweight, non-toxic, eco-friendly, durable, and heat-resistant. Among other applications, pumice has been used as an aggregate to produce lightweight concrete or cementitious material to produce blended cement or geopolymer. Since pumice stone is highly porous, it could be used as a naturally occurring multiscale porous sound-absorbing material, which may add interesting properties for absorbing sound energy. Normally, a double-porosity granular material presents higher sound absorption at low frequencies than a solid-grain material with the same mesoscopic characteristics at a reduced weight. This study uses theoretical and experimental approaches to investigate the sound absorption characteristics of granular pumice samples. The tests were conducted on crushed pumice stones in granular form. The study suggests that pumice stones can be used as a novel material for sound absorption in room acoustics and noise control applications. Full article

The Falakra geosite is located at the northern shoreline of the island of Limnos, Greece, and exhibits an array of unusual geomorphological features developed in late Cenozoic sandstones. Deposition of the primary clastic sediments was overprinted by later, low-temperature hydrothermal fluid flow and interstitial secondary calcite formation associated with nearby volcanic activity. Associated sandstone cannonballs take center stage in a landscape built by joints, Liesengang rings and iron (hydr)oxide precipitates, constituting an intriguing site of high aesthetic value. The Falakra geosite is situated in an area with dynamic erosion processes occurring under humid weather conditions. These have evidently sculpted and shaped the sandstone landscape through a complex interaction of wave- and wind-induced erosional processes aided by salt spray wetting. This type of geosite captivates scientists and nature enthusiasts due to its unique geological and landscape features, making its sustainable conservation a significant concern and topic of debate. Here, we provide detailed geological and remote sensing mapping of the area to improve the understanding of geological processes and their overall impact. Given the significance of the Falakra geosite as a unique tourist destination, we emphasize the importance of developing it under sustainable management. We propose the segmentation of the geosite into four sectors based on the corresponding geological features observed on site. Sector A, located to the west, is occupied by a lander-like landscape; to the southeast, sector B contains clusters of cannonballs and concretions; sector C is characterized by intense jointing and complex iron (hydr)oxide precipitation patterns, dominated by Liesengang rings, while sector D displays cannonball or concretion casts. Finally, we propose a network of routes and platforms to highlight the geological heritage of the site while reducing the impact of direct human interaction with the outcrops. For constructing the routes and platforms, we propose the use of serrated steel grating. Full article

Rice husk ash is a kind of biomass material. Its main component is silicon dioxide, with a content of up to 80%. It has high pozzolanic activity and can react with hydroxide in cement. When treating rice husks, rice husk ash with high volcanic ash activity and a good microaggregate filling effect can be obtained by selecting a suitable incineration environment. These advantages make rice husk ash an ideal concrete admixture, replacing the traditional admixture such as fly ash and slag in concrete. This paper summarizes the preparation methods and physical and chemical properties of rice husk ash, as well as the physical and chemical properties of rice husk ash concrete, such as mechanical properties, temperature resistance, freezing resistance, permeability resistance and chemical erosion resistance. The results show that using 20% rice husk ash as a substitute material for cement improves the resistance strength, compressive strength, flexural strength, and permeability of concrete. In short, the incorporation of rice husk ash can effectively improve the performance of cement-based materials, which will be conducive to the green development of the building material industry and the implementation of the two-carbon strategy. Full article

Lithium slag (LS), an industrial waste byproduct generated during lithium salt production, is characterized by its harmful trace elements, significant stockpiles and low pozzolanic activity. By 2003, the annual discharge of lithium slag in China surpassed 15 million tons, creating an urgent need for established large-scale disposal technologies. One of the primary strategies for the effective utilization of LS is its application as an auxiliary cementitious material in concrete. However, the low reactivity of LS and challenges associated with its large-scale application impede its effective utilization. Enhancing the pozzolanic activity of LS is pivotal for its substantial incorporation into concrete. This study begins by analyzing the physicochemical properties and volcanic ash reactivity of LS derived from various lithium extraction techniques. It subsequently explores the diverse activation techniques aimed at improving the reactivity of LS within concrete. Ultimately, this paper highlights the significance of synergistic activation strategies, particularly physicochemical co-excitation and multi-exciter composite excitation. These approaches are identified as critical pathways for enhancing the activity of LS. Through this exploration, this study aims to unveil innovative strategies that bolster the resource utilization efficiency of LS, thereby facilitating its effective application in the concrete domain. Full article

Limestone calcined clay cement (LC3), enhanced through reactions with volcanic ash and the interaction between limestone and clay, significantly improves the performance of cementitious materials. It has the potential to cut CO₂ emissions by up to 30% and energy consumption in cement manufacture by 15% to 20%, providing a promising prospect for the large-scale production of low-carbon cement with a lower environmental effect. To effectively manufacture LC3 concrete, this study utilized limestone (15%), calcined clay (30%), and gypsum (5%) as supplementary cementitious materials (SCMs), replacing 50% of ordinary Portland cement (OPC). However, in regions abundant in sulfate, sulfate attack can cause interior cracking of concrete, reducing the longevity of the building. To address this issue, microcapsules containing microcrystalline wax, ceresine wax, and nano-CaCO₃ encapsulated in epoxy resin were prepared and successfully incorporated into LC3 concrete. Sulfate resistance tests were conducted through sulfate dry–wet cycles, comparing samples with and without microcapsules. The findings revealed that the initial mechanical and permeability properties of LC3 concrete did not significantly differ from OPC concrete. LC3 concrete with added microcapsules (SP4) exhibited enhanced resistance to sulfate attack, reducing mass loss and compressive strength degradation. SEM images displayed a mesh-like structure of repair products in SP4. After 14 days of self-repair, SP4 exhibited a 44.2% harmful pore ratio, 98.1% compressive strength retention, 88.7% chloride ion diffusion coefficient retention, 91.12 mV maximum amplitude, and 9.14 mV maximum frequency amplitude. The experimental results indicate that the presence of microcapsules enhances the sulfate attack self-healing performance of LC3 concrete. Full article

This study underscores the potential of utilizing natural volcanic tuffs (NVTs) as supplementary cementitious materials (SCMs) in alignment with global sustainability efforts aimed at mitigating the cement industry’s negative impacts on both the economy and the environment. Experimental investigations were conducted on concrete mixtures containing 10%, 20%, 30%, 40%, and 50% NVT as partial cement replacements to assess their influence on concrete’s mechanical and microstructural properties. Based on the findings, concrete samples with 10% NVT replacements exhibited increased flexural and compressive strengths of 35.6% and 5.6%, respectively, compared with ordinary concrete after 28 days. The depth of water penetration in the concrete samples was significantly reduced by the inclusion of NVT, with a maximum reduction of 56.5%. Microstructural analysis using scanning electron microscopy (SEM) revealed enhanced densification of the concrete microstructures, attributed to the high pozzolanic activity of NVT use in cement-based composites. Analysis of variance (ANOVA) revealed statistically significant relationships between NVT content and both the compressive and flexural strengths of the concrete samples. In conclusion, substituting 10% cement with NVT not only enhances the mechanical properties of concrete but also decreases the energy demand for cement production and reduces carbon dioxide (CO₂) emissions, thus contributing to more sustainable construction practices. Full article

Volcanic eruptions stand as destructive threats to adjacent communities, unleashing multiple hazards such as earthquakes, tsunamis, pyroclastic flows, and toxic gases. The imperative for proactive management of volcanic risks and communities’ adaptation cannot be overstated, particularly in densely populated areas where the potential for widespread devastation looms large. Kolumbo, an active submarine volcano located approximately 7 km northeast of Santorini Island in Greece, serves as a pertinent case. Its historical record is characterised by an eruption in 1650 CE that produced a catastrophic tsunami. The aftermath witnessed havoc on neighbouring islands, coupled with casualties stemming from noxious gases in Santorini. Eyewitness accounts mention maximum water run-up heights of 20 m on the southern coast of Ios, inundation of an area of 240 m inland on Sikinos, and a flooding of up to 2 km² inland on the eastern coast of Santorini. Recent studies suggest that a potential future eruption of Kolumbo poses a substantial hazard to the northern and eastern coasts of Santorini. Unfortunately, the absence of a concrete management protocol leaves these areas vulnerable to an impending threat that demands immediate attention. Therefore, it is recommended that a comprehensive approach be adopted, involving scientific research (active monitoring, hazard maps), community engagement, preparedness planning with government agencies, and the development of timely response strategies to reduce the associated risks, prevent casualties, and mitigate the potential consequences on the region’s economy and infrastructure. Full article

The fracture mechanism and macro-properties of SVSAC were studied using a novel test system combined with numerical simulations, which included three-point bending beam tests, the digital image correlation (DIC) technique, scanning electron microscopy (SEM), and ABAQUS analyses. In total, 9 groups and 36 specimens were fabricated by considering two critical parameters: initial notch-to-depth ratios (a₀/h) and concrete mix components (seawater and volcanic scoria coarse aggregate (VSCA)). Changes in fracture parameters, such as the load-crack mouth opening displacement curve (P-CMOD), load-crack tip opening displacement curve (P-CTOD), and fracture energy (G_f), were obtained. The typical double-K fracture parameters (i.e., initial fracture toughness ($K_{\mathrm{IC}}^{\mathrm{ini}}$) and unstable fracture toughness ($K_{\mathrm{IC}}^{\mathrm{un}}$)) and tension-softening (σ-CTOD) curve were analyzed. The test results showed that the initial cracking load (P_ini), G_f, and characteristic length (L_ch) of the SVSAC increased with decreasing a₀/h. Compared with the ordinary concrete (OC) specimen, the P-CMOD and P-CTOD curves of the specimen changed after using seawater and VSCA. The evolution of the crack propagation length was obtained through the DIC technique, indicating cracks appeared earlier and the fracture properties of specimen decreased after using VSCA. Generally, the $K_{\mathrm{IC}}^{\mathrm{un}}$ and $K_{\mathrm{IC}}^{\mathrm{ini}}$ of SVSAC were 36.17% and 8.55% lower than those of the OC specimen, respectively, whereas the effects of a₀/h were negligible. The reductions in P_ini, G_f, and L_ch of the specimen using VSCA were 10.94%, 32.66%, and 60.39%, respectively; however, seawater efficiently decreased the negative effect of VSCA on the fracture before the cracking width approached 0.1 mm. Furthermore, the effects of specimen characteristics on the fracture mechanism were also studied through numerical simulations, indicating the size of the beam changed the fracture toughness. Finally, theoretical models of the double-K fracture toughness and the σ-CTOD relations were proposed, which could prompt their application in marine structures. Full article

Research into lightweight structural concrete using volcanic tuff is of great importance to the construction industry. These materials have excellent thermal insulation properties, which helps improve the energy efficiency of buildings. A three-factor experimental design was used to build the statistical model. The test methods used were methods for determining the crushability of volcanic tuff, determining the average density, compressive strength and thermal conductivity of lightweight structural concrete. The influence of basalt fiber on the properties of lightweight structural concrete has been determined. The optimal compositions of lightweight structural concrete using tuff have been selected. The compressive strength of lightweight structural concrete reached 32.0 MPa. The average density range is 1754.6–2114.0 kg/m³. Good thermal conductivity values were obtained in the range of 0.653–0.818 W/m·K. The article obtained the optimal compositions of lightweight structural concrete using volcanic tuff as a filler. Full article

When using seawater and sea sand as mixes, the mechanical properties and durability of concrete are adversely affected because the raw materials themselves contain harmful ions. Fly ash is the tailings formed in the process of industrial production, the use of which does not require the burning of clinker, reducing CO₂ emissions. Moreover, it belongs to a new type of cementitious materials with low emissions and high environmental protection. Fly ash enhances the properties of concrete and reduces the effect of harmful ions on concrete. Based on the above considerations, the corresponding specimens were prepared and subjected to cubic compressive strength, flexural strength, and seawater freezing and thawing resistance tests by using fly ash admixture as the main variable. A combination of macro-analysis and micro-analysis was used to investigate the effect of fly ash on the performance of seawater sea sand concrete. The results showed that fly ash significantly enhanced the mechanical properties and resistance to seawater freezing and thawing of seawater sea sand concrete. The best improvement in compressive strength and resistance to seawater freezing and thawing was achieved at a substitution rate of 20%. The maximum increase in compressive strength was 13.22%. The maximum reduction in mass loss rate was 57.26% and the strength loss rate was 43.14% after the specimens were subjected to seawater freezing and thawing 75 times. The maximum enhancement in flexural strength was 17.06% for a substitution rate of 10%. Through microanalysis, it can be seen that the incorporation of coal ash can enhance the compactness of concrete through the microaggregate effect as well as the volcanic ash reaction to promote the secondary hydration reaction, so as to strengthen the seawater freeze–thaw resistance of seawater sea sand concrete. Finally, the damage prediction model established using the mean GM (1, 1) model of gray system theory meets the requirements of the first level of prediction accuracy and can accurately predict the damage of seawater sea sand concrete under seawater freezing and thawing. Full article