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24 pages, 7969 KB  
Article
Optimizing Acoustic Performance of Semi-Dense Asphalt Mixtures Through Energy Dissipation Characterization
by Huaqing Lv, Gongfeng Xin, Weiwei Lu, Haihui Duan, Jinping Wang, Yi Yang, Chaoyue Rao and Ruiyao Jiang
Materials 2025, 18(17), 4086; https://doi.org/10.3390/ma18174086 (registering DOI) - 1 Sep 2025
Abstract
Traffic-induced noise pollution is a significant environmental issue, driving the development of advanced noise-reducing pavement materials. Semi-dense graded asphalt mixtures (SDAMs) present a promising compromise, offering enhanced acoustic properties compared to conventional dense-graded asphalt mixtures while maintaining superior durability to porous asphalt mixtures. [...] Read more.
Traffic-induced noise pollution is a significant environmental issue, driving the development of advanced noise-reducing pavement materials. Semi-dense graded asphalt mixtures (SDAMs) present a promising compromise, offering enhanced acoustic properties compared to conventional dense-graded asphalt mixtures while maintaining superior durability to porous asphalt mixtures. However, the mechanism underlying the relationship between the energy dissipation characteristics and noise reduction effects of such mixtures remains unclear, which limits further optimization of their noise reduction performance. This study designed and prepared semi-dense graded noise-reducing asphalt mixtures SMA-6 TM, SMA-10 TM, and SMA-13 TM (SMA TM represents noise-reducing SMA mixture) based on traditional dense-graded asphalt mixtures SMA-6, SMA-10, and SMA-13, and conducted tests for water stability, high-temperature performance (60 °C), and low-temperature performance (−10 °C). Subsequently, energy loss parameters such as loss factor and damping ratio were calculated through dynamic modulus tests to characterize their energy dissipation properties. The mechanism linking the energy dissipation characteristics of semi-dense graded asphalt mixtures to noise reduction was investigated. Finally, the noise reduction effect was further verified through a tire free fall test and a close-proximity (CPX) method. The indoor test results indicate that the semi-dense mixtures exhibited a trade-off in performance: their dynamic stability was 11.1–11.3% lower and low-temperature performance decreased by 4.2% (SMA-13 TM) to 14.1% (SMA-6 TM), with moisture stability remaining comparable. Conversely, they demonstrated superior damping, with consistently higher loss factors and damping ratios. All mixtures reached peak damping at 20 °C, and the loss factor showed a strong positive correlation (R2 > 0.91) with energy dissipation. Field results from a test section showed that the optimized SMA-10 TM mixture yielded a significant tire–road noise reduction of 3–5 dB(A) relative to the SMA-13, while concurrently meeting key performance criteria for anti-water ability and durability. This study establishes a link between the energy dissipation in SDAM and their noise reduction efficacy. The findings provide a theoretical framework for optimizing mixture designs and support the wider application of SDAM as a practical noise mitigation solution. Full article
(This article belongs to the Section Construction and Building Materials)
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18 pages, 299 KB  
Article
Maritime Conflicts and Diplomacy in Late Medieval Castile: Genoese Consuls, Vessels, and Merchants (14th–15th Centuries)
by Raúl González Arévalo and Daniel Ríos Toledano
Histories 2025, 5(3), 42; https://doi.org/10.3390/histories5030042 (registering DOI) - 30 Aug 2025
Viewed by 186
Abstract
The strategic position of the coast of the Kingdom of Seville, along the western route between the Mediterranean and the Atlantic, encouraged the presence of numerous fleets and merchant nations in its ports and waters. The proliferation of privateers and armed conflicts, both [...] Read more.
The strategic position of the coast of the Kingdom of Seville, along the western route between the Mediterranean and the Atlantic, encouraged the presence of numerous fleets and merchant nations in its ports and waters. The proliferation of privateers and armed conflicts, both in Andalusian waters and beyond, had a significant impact on navigation and trade. This article examines the diplomatic strategies developed by the Genoese consuls in Seville to protect the interests of their nation in the maritime conflicts that affected them. Full article
(This article belongs to the Special Issue Novel Insights into Naval Warfare and Diplomacy in Medieval Europe)
42 pages, 1513 KB  
Article
Water Usage and Greenhouse Gas Emissions in the Transition from Coal to Natural Gas: A Case Study of San Juan County, New Mexico
by Tahereh Kookhaei, Armin Razmjoo and Mohammad Ahmadi
Sustainability 2025, 17(17), 7789; https://doi.org/10.3390/su17177789 - 29 Aug 2025
Viewed by 97
Abstract
This study evaluates the trade-offs and environmental impacts of transitioning from coal to natural gas (NG) for electricity generation in San Juan County, with a focus on greenhouse gas emissions and water consumption. It addresses key questions, including how water use and emissions [...] Read more.
This study evaluates the trade-offs and environmental impacts of transitioning from coal to natural gas (NG) for electricity generation in San Juan County, with a focus on greenhouse gas emissions and water consumption. It addresses key questions, including how water use and emissions change as the county shifts from coal to natural gas. The research analyzes water usage and emissions of CO2, NOx, and SO2 during both the extraction and combustion phases of coal and natural gas. Specifically, it compares water consumption and direct emissions from coal-fired and natural gas-fired power plants. The analysis utilizes ten years of combustion-phase data from the Four Corners (coal-fired) and Afton (natural gas-fired) power plants in New Mexico. Linear regression was applied to the historical data, and four transition scenarios were modeled: (1) 100% coal-generated electricity, (2) a 20% reduction in coal with a corresponding increase in NG, (3) a 50% reduction in coal with a corresponding increase in NG, and (4) a complete transition to NG. Regression analysis and scenario calculations indicate that switching to NG results in significant water savings and reduced emissions. Water savings in the combustion phase decrease by up to 2750 gallons per MWh, valued at USD 0.743 per MWh when electricity is generated 100% from NG. CO2 emissions are substantially reduced, with the largest decrease being 0.6127 metric tons per MWh, valued at USD 61.26 per MWh. NOx emissions in the combustion phase decline by 0.0018 metric tons per MWh, with an economic valuation of USD 14.61 per MWh, while SO2 emissions decrease by 0.0006 metric tons per MWh, valued at USD 11.91 per MWh when electricity generation is 100% NG-based. The results highlight the environmental and economic advantages of transitioning from coal to NG. The findings underscore the environmental and economic advantages of transitioning from coal to natural gas. Water conservation is particularly vital in San Juan County’s semi-arid climate. Additionally, lower emissions support climate change mitigation, enhance air quality, and improve public health. The economic valuation of emissions reductions further highlights the financial benefits of this transition, positioning natural gas as a more sustainable and economically viable energy source for the region. Ultimately, this study emphasizes the need to adopt cleaner energy sources such as renewable energy to achieve long-term environmental sustainability and economic efficiency. Full article
25 pages, 4197 KB  
Article
Polyacrylamide-Induced Trade-Offs in Soil Stability and Ecological Function: A Multifunctional Assessment in Granite-Derived Sandy Material
by Junkang Xu, Xin Chen, Guanghui Zhang, Weidong Yu, Chongfa Cai and Yujie Wei
Agronomy 2025, 15(9), 2087; https://doi.org/10.3390/agronomy15092087 - 29 Aug 2025
Viewed by 88
Abstract
Soil erosion in granite-derived weathering mantles poses serious threats to slope stability and ecological sustainability in subtropical regions. While polyacrylamide (PAM) is widely used to improve soil structure, its concentration-dependent effects on multiple soil functions remain unclear. This study developed a multifunctional Soil [...] Read more.
Soil erosion in granite-derived weathering mantles poses serious threats to slope stability and ecological sustainability in subtropical regions. While polyacrylamide (PAM) is widely used to improve soil structure, its concentration-dependent effects on multiple soil functions remain unclear. This study developed a multifunctional Soil Function Index (SFI) framework integrating erosion resistance (SFI1), water regulation (SFI2), and ecological function (SFI3) to evaluate the effects of PAM application (0‰, 1‰, 3‰, 5‰, 7‰) on gully-prone sandy material. Herein, SFI1 was quantified through shear strength (τ) and soil erodibility (Kr); SFI2 was assessed using soil hydraulic parameters (saturated hydraulic conductivity and water retention curves) and SFI3 was derived from the grass root system analysis. The results showed that SFI1 and SFI2 increased nonlinearly with PAM concentration, reaching maximum values of 0.983 and 0.980 at 7‰, with Kr reduced by 77.3% and non-capillary porosity (NAP) increased by 8.1%. In contrast, SFI3 peaked at 0.858 under 3‰ and declined sharply to 0.000 at 7‰, due to micropore over-compaction, reduced aeration, and limited plant-available water. The total SFI exhibited a unimodal trend, with a maximum of 0.755 at 3‰, beyond which ecological suppression offset physical improvements. These findings demonstrate that PAM modifies soil multifunctionality through pore-scale restructuring, inducing function-specific thresholds and trade-offs. A PAM concentration of 3‰ is identified as optimal, achieving a balance between erosion control, hydrological performance, and ecological viability in the management of subtropical granite-derived sandy slopes. Full article
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21 pages, 14457 KB  
Article
Autonomous Underwater Vehicle Adaptive Altitude Control Framework to Improve Image Quality
by Simon Litjens, Peter King, Saurabh Garg, Wenli Yang, Muhammad Bilal Amin and Quan Bai
Drones 2025, 9(9), 608; https://doi.org/10.3390/drones9090608 - 29 Aug 2025
Viewed by 77
Abstract
Autonomous underwater vehicles (AUVs) play a pivotal role in the exploration and monitoring of the sea floor. A primary challenge in surveying AUVs is consistently obtaining high-quality optical imagery data. A major cause of quality reduction is turbid water, which both attenuates and [...] Read more.
Autonomous underwater vehicles (AUVs) play a pivotal role in the exploration and monitoring of the sea floor. A primary challenge in surveying AUVs is consistently obtaining high-quality optical imagery data. A major cause of quality reduction is turbid water, which both attenuates and scatters light. The effects of turbidity can be minimized by lowering the operational altitude of the AUV, at the cost of increased survey duration and cost. Consequently, before conducting a survey, a trade-off must be made between the risk of acquiring suboptimal images and the additional time required to cover an area. In this research, we develop a computer-vision-based technique and control system that dynamically adjusts the altitude of an AUV based on real-time estimates of turbidity from collected images. Our testing in a simulated environment demonstrates that this system reliably improves the efficiency and quality of image collection. Full article
(This article belongs to the Section Unmanned Surface and Underwater Drones)
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27 pages, 12829 KB  
Article
Multiscale Approaches to Ecosystem Services in the Urban Agglomeration of the Yangtze River Delta, China: Socio-Ecological Impacts and Support for Urban Sustainability and Precision Management
by Yue Li, Shengyan Wan, Jinglan Liu and Lin Qiu
Land 2025, 14(9), 1748; https://doi.org/10.3390/land14091748 - 29 Aug 2025
Viewed by 151
Abstract
The trade-offs and synergies among ecosystem services can provide clues for understanding the mechanisms of regional ecological evolution. Previous studies have mainly concentrated on administrative divisions to characterize ecosystem services trade-offs and synergies within specific regions. However, ambiguity persists regarding the spatial diversity [...] Read more.
The trade-offs and synergies among ecosystem services can provide clues for understanding the mechanisms of regional ecological evolution. Previous studies have mainly concentrated on administrative divisions to characterize ecosystem services trade-offs and synergies within specific regions. However, ambiguity persists regarding the spatial diversity and scale dependency of regional ecosystem services, along with the degree to which human activity and climatic variation influence the relationships of multiscale ecosystem services. This study focuses on the Yangtze River Delta Urban Agglomeration in China. Based on grid, county-level, and city-level scales, it analyzes five ecosystem services, namely habitat quality, carbon storage, food production, soil conservation, and water yield, from 2000 to 2020. By using correlation analysis and spatial autocorrelation methods, this study explores the intensity of the trade-offs and synergies among ecosystem services and their spatial patterns. Then, combined with the Optimal Parameters-based Geographical Detector, it identifies the dominant driving factors, quantifies their degree of contribution, and reveals the multiscale differentiation of ecosystem service relationships and their causes. The results show that the five ecosystem services all exhibit significant spatiotemporal heterogeneity. At the grid scale, there is a trade-off relationship between food production and the other four services, while a strong synergistic effect exists among the remaining four services. At the county scale, the synergistic association between habitat quality and carbon storage is the most significant, with the highest contributions from the average annual precipitation and average annual temperature (q-values 0.893 and 0.782, respectively). At the prefecture-level city scale, the intensity of the ecosystem services trade-offs and synergies shows an increasing trend, and the impact of interactions between socio-ecological elements is significantly higher than that at the grid and county scales. This research provides an evidence-based foundation for decision makers to devise suitable strategies that support the coordinated advancement of ecology and the economy across various spatial scales. It is crucial for promoting precise ecosystem regulation and the sustainability of the Yangtze River Delta Urban Agglomeration in China. Full article
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19 pages, 532 KB  
Article
Temporal and Spatial Analysis: The Impact of Virtual Water Flows on Agricultural Production Efficiency in China
by Jinqiong Ouyang, Deqiang Wei and Yihang Hu
Water 2025, 17(17), 2541; https://doi.org/10.3390/w17172541 - 27 Aug 2025
Viewed by 242
Abstract
Panel data from 30 provinces in China spanning the years from 2007 to 2022 were selected. Regional virtual water flows were calculated based on the principle of social equity, and agricultural production efficiency was measured using the Super-SBM model, which overcomes the issue [...] Read more.
Panel data from 30 provinces in China spanning the years from 2007 to 2022 were selected. Regional virtual water flows were calculated based on the principle of social equity, and agricultural production efficiency was measured using the Super-SBM model, which overcomes the issue of being unable to measure efficiency values when they exceed 1 for decision-making units. Based on the aforementioned estimation results, methods such as ArcGis and kernel density estimation were employed to illustrate the changing trends of virtual water flows and agricultural production efficiency in key years. Additionally, a fixed-effects model was used to explore the relationship between the two. The following conclusions are drawn: (1) The overall pattern of virtual water trade in grain exhibits a “north-to-south grain transportation” flow, with the volume of transfers increasing annually, which is contrary to the spatial distribution of water resources. Regions with a net outflow of virtual water in grain are mostly concentrated in major grain-producing areas such as the northeast, while provinces with a net inflow are mainly concentrated in economically developed regions such as South China, Southeast China, and the middle and lower reaches of the Yangtze River. (2) The average agricultural production efficiency shows a fluctuating upward trend, with an overall “S”-shaped pattern in a horizontal view, and the overall differences in production efficiency among provinces have widened. (3) Agricultural production efficiency exhibits an inverted “U”-shaped trend with the increase in virtual water flows, a conclusion that remains valid after a series of robustness tests. Therefore, corresponding suggestions are proposed based on the above conclusions, including formulating a scientific virtual water trade strategy and improving agricultural production efficiency. Full article
(This article belongs to the Special Issue Urban Water Resources: Sustainable Management and Policy Needs)
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15 pages, 2130 KB  
Article
Intra-Specific Variation and Correlation of Functional Traits in Cunninghamia lanceolata at Different Stand Ages
by Jiejie Jiao, Chuping Wu, Honggang Sun and Liangjing Yao
Plants 2025, 14(17), 2675; https://doi.org/10.3390/plants14172675 - 27 Aug 2025
Viewed by 291
Abstract
Intra-specific variation in functional traits and their inter-relationships reflect how plants allocate resources, adapt, and evolve in response to environmental changes. This study investigated eight functional traits—leaf area (LA), specific leaf area (SLA), leaf dry matter content (LDMC), chlorophyll content (CHL), leaf nitrogen [...] Read more.
Intra-specific variation in functional traits and their inter-relationships reflect how plants allocate resources, adapt, and evolve in response to environmental changes. This study investigated eight functional traits—leaf area (LA), specific leaf area (SLA), leaf dry matter content (LDMC), chlorophyll content (CHL), leaf nitrogen content (LNC), leaf phosphorus content (LPC), twig tissue density (TTD), and wood density (WD)—in Cunninghamia lanceolata plantations of three stand ages (15, 30, and 50 years), using a space-for-time substitution approach. We examined differences in trait values, intra-specific variation, and trait correlations across forest ages and diameter classes. The results showed that (1) Functional traits exhibited varying degrees of intra-specific variation, with LA having the highest coefficient of variation (21.66%) and LPC is lowest (9.31%). (2) Forest age had a stronger influence on trait variation than diameter class, with all traits differing significantly across ages, while only WD varied significantly among diameter classes. (3) PC1 (25.5%) and PC2 (19.4%) together explained approximately 44.9% of the total variation, with PC1 primarily reflecting functional trait changes driven by forest age. PCA results showed that LA and CHL tended to exhibit higher values in young forests, whereas SLA, LDMC, LPC, and LNC had relatively higher values in mature forests. This pattern suggests a shift in functional trait expression from resource acquisition to resource conservation strategies with increasing forest age. (4) Significant positive correlations between LNC and LPC, and negative correlations between SLA and LDMC, were observed in most groups, except in large-diameter trees at the over-mature stage. C. lanceolata adjusts trait combinations to enhance fitness across developmental stages. Juvenile trees adopt traits favoring efficient light and nutrient use to support rapid growth and competition. Middle-aged trees prioritize balanced water and nutrient use to maintain productivity and resist disturbances. Mature trees focus on sustained resource use and offspring protection to support ecosystem stability and regeneration. These findings reveal age-specific adaptive strategies and provide insights into the coordination and trade-offs among traits in response to environmental conditions. Full article
(This article belongs to the Section Plant Ecology)
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31 pages, 7470 KB  
Article
Evaluation of a Non-Stagnant Water Gap in Hollow-Fiber Membrane Distillation and Multistage Performance Limitations
by Mohamed O. Elbessomy, Kareem W. Farghaly, Osama A. Elsamni, Samy M. Elsherbiny, Ahmed Rezk and Mahmoud B. Elsheniti
Membranes 2025, 15(9), 253; https://doi.org/10.3390/membranes15090253 - 27 Aug 2025
Viewed by 240
Abstract
Hollow-fiber water gap membrane distillation (HF-WGMD) modules are gaining attention for desalination applications due to their compact design and high surface-area-to-volume ratio. This study presents a comprehensive CFD model to analyze and compare the performance of two HF-WGMD module configurations: one with a [...] Read more.
Hollow-fiber water gap membrane distillation (HF-WGMD) modules are gaining attention for desalination applications due to their compact design and high surface-area-to-volume ratio. This study presents a comprehensive CFD model to analyze and compare the performance of two HF-WGMD module configurations: one with a conventional stagnant water gap (WG) and the other incorporating water gap flow circulation. The model was validated against experimental data, showing excellent agreement, and was then used to simulate flow patterns in the feed, water gap, and coolant domains. Results indicate that, at a feed temperature of 80 °C with a stagnant WG, employing a turbulent flow scheme in the feed side increases water flux by 20.7% compared to laminar flow, while increasing coolant flow rate has a minor impact. In contrast, introducing circulation within the water gap significantly enhances performance, boosting water flux by 30.1%. This effect becomes more pronounced with rising feed temperature: increasing from 50 °C to 80 °C leads to a flux increase from 6.74 to 27.89 kg/(m2h) under circulating WG conditions. However, in multistage systems, the energy efficiency trade-off becomes evident. Water gap circulation is more energy-efficient than the stagnant configuration only for systems with fewer than 20 stages. At higher stage counts, the stagnant WG setup proves more efficient. For example, at 80 °C and 50 stages, the stagnant configuration consumes just 793 kWh/m3, representing a 47.3% reduction in energy consumption compared to the circulating WG setup. These findings highlight the performance benefits and energy trade-offs of water gap circulation in HF-WGMD systems, providing valuable guidance for optimization and scalability of high-efficiency desalination module designs. Full article
(This article belongs to the Section Membrane Applications for Water Treatment)
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16 pages, 2024 KB  
Article
Water-Use Efficiency for Post-Weaning Growth Performance of South African Beef Cattle Under Intensive Production Systems
by Ayanda M. Ngxumeshe, Takalani Mpofu, Khathutshelo Nephawe, Motshekwe Ratsaka and Bohani Mtileni
Animals 2025, 15(17), 2505; https://doi.org/10.3390/ani15172505 - 26 Aug 2025
Viewed by 230
Abstract
This study determined the water-use efficiency for post-weaning growth performance of beef cattle of different frame sizes under intensive production systems. A total of 33 beef cattle weaners of three different frame sizes (small, medium, and large) were randomly allocated individually to metabolic [...] Read more.
This study determined the water-use efficiency for post-weaning growth performance of beef cattle of different frame sizes under intensive production systems. A total of 33 beef cattle weaners of three different frame sizes (small, medium, and large) were randomly allocated individually to metabolic pens. Feed and water were provided ad libitum. The water intake (WI), feed intake (FI), and weight were measured across different feeding phases (starter, grower, and finisher). Water consumption (WC) average daily gain (ADG), weight gain (WG), water intake efficiency (WIE), water footprint per animal (WFP/AU), and WFP/kg were computed. General Linear Model of Statical Analysis software (SAS) version 9.4 was used to analyse the data, and the means were separated using Fisher’s LSD test. The results showed that large-frame beef cattle had significantly higher (p < 0.05) WTf. (412.73 ± 27.27 kg) and WI (3394.09 ± 156.3 L), but also the largest WFP/AU (4407 ± 197.22 L). The medium-frame cattle achieved the highest ADG (1.48 ± 0.14 kg/day) and a moderate WIE (20.15 ± 2.18 L/kg gain), indicating an optimal trade-off between productivity and water use. The small-frame beef cattle exhibited the best WCE (0.051 ± 0.005 kg/L) and the lowest WFP/AU (3822 ± 197.22 L), highlighting superior water-use adaptability. Pearson’s correlation revealed that WCE was positively associated with ADG (r = 0.499; p < 0.05) and negatively with WIE (r = −0.987; p < 0.05). These findings suggest that medium-frame beef cattle provided a balanced compromise between growth performance and resource efficiency, making them more suitable for sustainable production in water-limited environments. Full article
(This article belongs to the Section Animal Nutrition)
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15 pages, 1520 KB  
Article
Evaluating How Growth and Diet of Native Freshwater Fishes Change in Response to Salinity and pH in a Semi-Arid Landscape
by Miles Milbrath, Audrey Lindsteadt and Lusha Tronstad
Fishes 2025, 10(9), 423; https://doi.org/10.3390/fishes10090423 - 26 Aug 2025
Viewed by 524
Abstract
Freshwater ecosystems are increasingly stressed by drought and anthropogenic inputs that can increase specific conductivity (SPC) and pH; however, little is known about how harsher conditions affect fish. We evaluated how fish growth and diet composition changed along a natural gradient in SPC [...] Read more.
Freshwater ecosystems are increasingly stressed by drought and anthropogenic inputs that can increase specific conductivity (SPC) and pH; however, little is known about how harsher conditions affect fish. We evaluated how fish growth and diet composition changed along a natural gradient in SPC and pH in Wyoming, USA using Northern plains killifish (Fundulus kansae) and Fathead minnows (Pimephales promelas). We surveyed 201 sites where we measured water chemistry, sampled fish, and assessed invertebrate prey availability from May to September 2024. Northern plains killifish and/or Fathead minnows inhabited 12 sites, which were the focus of our study. We measured otoliths to assess growth and stomach contents to estimate dietary selectivity. Growth decreased at higher SPC (486–23,500 µS/cm) for Fathead minnows and pH (7.2–9.0) for both species, suggesting an energy trade-off with osmoregulation. Dietary analyses revealed variable selection for Chironomidae larvae, while other taxa such as Gammaridae and Coleoptera were avoided at higher SPC and pH. Despite the extreme conditions, these fish maintained some dietary preference, highlighting behavioral plasticity. Our findings suggest that while these species can tolerate harsh environments, sublethal effects on growth and diet may limit long-term fitness. This research offers a framework for assessing the viability of fish populations inhabiting ecosystems with increasing salinity and pH that can inform conservation and management strategies under future environmental change. Full article
(This article belongs to the Section Biology and Ecology)
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31 pages, 9137 KB  
Article
Ecological Zoning in Mountainous Areas Based on Ecosystem Service Trade-Offs and Landscape Ecological Risk: A Case Study of the Hengduan Mountain Region
by Xiaoyu Zhao, Erfu Dai, Kangning Kong, Yuan Tian, Yong Yang, Zhuo Li, Jiachen Liu, Baolei Zhang and Le Yin
Sustainability 2025, 17(17), 7630; https://doi.org/10.3390/su17177630 - 24 Aug 2025
Viewed by 509
Abstract
Ecological zoning is a key approach to promoting regional ecological protection and sustainable development. At present, landscape ecological risk (LER), driven by both natural and anthropogenic factors, continues to intensify, thereby disrupting ecosystem functions and weakening their service capacity. Although ecosystem services (ESs) [...] Read more.
Ecological zoning is a key approach to promoting regional ecological protection and sustainable development. At present, landscape ecological risk (LER), driven by both natural and anthropogenic factors, continues to intensify, thereby disrupting ecosystem functions and weakening their service capacity. Although ecosystem services (ESs) and LER have been increasingly integrated into ecological management and policy-making in recent years, the interactive relationship between them remains insufficiently explored, particularly in the context of ecological zoning based on their coupled characteristics. Therefore, this study focuses on the Hengduan Mountain region from 2000 to 2020, analyzing the relationship between ES trade-offs and LER, constructing ecological zones, and proposing targeted management strategies. The results show that: (1) ESs in the region are primarily characterized by concave trade-offs, with decreasing trade-off intensity over time. The overall LER level has decreased, exhibiting a spatial pattern of higher risk in the south and lower risk in the north. (2) Bivariate spatial autocorrelation analysis reveals that LER is positively correlated with the trade-offs of carbon storage and soil conservation, shifts from a negative to a positive correlation with carbon storage and water yield, and shifts from a positive to a negative correlation with soil conservation and water yield. (3) Based on overlay zoning, the region is divided into protection, warning, and restoration zones, each with corresponding management measures. This study takes ecological zoning as a starting point to deeply analyze the relationship between ES trade-offs and LER, providing a scientific basis for sustainable development of mountain ecosystems. Full article
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22 pages, 2865 KB  
Article
A Three-Dimensional Evaluation Method for the Metabolic Interaction System of Industrial CO2 and Water Pollution
by Yueqing Yang, Liangliang Wu, Xingjie Lin, Xiaosong Yang, Xuegang Gong, Yu Miao, Mengyu Zhai, Yong Niu, Mingke Luo, Xia Jiang and Jia Wang
Water 2025, 17(16), 2473; https://doi.org/10.3390/w17162473 - 20 Aug 2025
Viewed by 511
Abstract
The inherent complexity of modern supply chains obscures significant hidden CO2 and Water Pollution Equivalent (WPE) emissions, presenting mounting challenges for integrated environmental governance. While prior research has largely treated carbon and water pollution metabolic systems in isolation, this study addresses the [...] Read more.
The inherent complexity of modern supply chains obscures significant hidden CO2 and Water Pollution Equivalent (WPE) emissions, presenting mounting challenges for integrated environmental governance. While prior research has largely treated carbon and water pollution metabolic systems in isolation, this study addresses the critical gap in understanding their bidirectional interactions under socioeconomic dynamics. We develop a novel Three-Dimensional Evaluation Method for the Metabolic Interaction System of Industrial CO2 and Water Pollution (TDE-ISCW). This framework integrates Environmental Input–Output Analysis and Ecological Network Analysis to: (1) identify key industrial sectors and utility relationships within individual CO2 and WPE systems; (2) quantify the mutual disturbance responses between the CO2 and WPE metabolic systems through changes in sectoral emissions/output, inter-sectoral relationships, and sector–system linkages; and (3) propose optimized industrial restructuring strategies for synergistic pollution and carbon reduction. Applied to the highly industrialized Yangtze River Economic Belt, key findings reveal: (i) substantial upstream dependency, exemplified by Advanced Equipment Manufacturing’s 95.7% indirect CO2 emissions; (ii) distinct key sectors for CO2 (e.g., MOO, FTO, MNM) and WPE (e.g., MPM, OTH, FTO) reduction based on competitive relationships; and (iii) complex trade-offs, where emission reductions in one system (e.g., CO2 via FTO restructuring) can trigger heterogeneous responses in the other (e.g., altered WPE influence or downstream CO2/economic shifts). The TDE-ISCW framework provides actionable insights for designing coordinated, adaptive emission reduction policies that account for cascading cross-system effects, ultimately supporting regional industrial upgrading and resource efficiency goals. Future research should incorporate temporal dynamics and full industrial–metabolic cycles. Full article
(This article belongs to the Section Water-Energy Nexus)
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16 pages, 1377 KB  
Article
Risk-Informed Multiobjective Optimization of Reservoir Operation
by Rong Tang and Yuntao Wang
Water 2025, 17(16), 2467; https://doi.org/10.3390/w17162467 - 20 Aug 2025
Viewed by 460
Abstract
Droughts present persistent and severe challenges to the security of regional water supplies, particularly in arid and semiarid regions such as northern China. Traditional reservoir operation models that prioritize water supply reliability or economic efficiency often fail to adequately address the risks posed [...] Read more.
Droughts present persistent and severe challenges to the security of regional water supplies, particularly in arid and semiarid regions such as northern China. Traditional reservoir operation models that prioritize water supply reliability or economic efficiency often fail to adequately address the risks posed by extreme drought events. In this study, we develop a novel risk-informed multiobjective reservoir operation model that incorporates three key performance indicators: reliability, resilience, and vulnerability (RRV). This model aims to improve drought response and enhance the overall stability of the water supply system. It is applied to a multisource water supply system composed of the Nierji Reservoir and various water-user sectors. Unlike traditional models, this approach explicitly balances the trade-offs among supply reliability, recovery capability, and water shortage during drought periods. Comparative analyses with conventional strategies (CSs) under both a six-year consecutive dry period and a representative single dry year demonstrate the superior performance of the RRV-based model in drought management. Specifically, the model reduces the average supply disruption duration from 8–10 to 4–6 ten-day intervals, increases water supply reliability to 90%, decreases the maximum single-event shortage depth to 22 × 106 m3, and lowers the average water shortage to 221 × 106 m3. Agricultural water shortages are reduced, although slight increases occur in other sectors. The results highlight resilience as the most influential objective in the model, and its inclusion or exclusion can be adjusted based on different drought response priorities. This study presents a novel and adaptive framework for reservoir operation under drought conditions, offering practical implications for improving the resilience and efficiency of regional water resource systems in the context of climate change. Full article
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14 pages, 2036 KB  
Article
Advancing Sustainable PVC Polymerization: Direct Water Recycling, Circularity, and Inherent Safety Optimization
by Rolando Manuel Guardo-Ruiz, Linda Mychell Puello-Castellón and Ángel Darío González-Delgado
Sustainability 2025, 17(16), 7508; https://doi.org/10.3390/su17167508 - 20 Aug 2025
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Abstract
Polyvinyl chloride (PVC) remains one of the most widely used synthetic polymers worldwide, primarily due to its versatility, cost-effectiveness, and broad applicability across construction, healthcare, automotive, and consumer goods industries. However, its production involves hazardous chemicals, particularly vinyl chloride monomer (VCM), which requires [...] Read more.
Polyvinyl chloride (PVC) remains one of the most widely used synthetic polymers worldwide, primarily due to its versatility, cost-effectiveness, and broad applicability across construction, healthcare, automotive, and consumer goods industries. However, its production involves hazardous chemicals, particularly vinyl chloride monomer (VCM), which requires rigorous safety assessments. In this context, the present study applies the Inherent Safety Index (ISI) methodology to evaluate the safety performance of a suspension polymerization process for PVC production that incorporates direct water recycling as a sustainability measure. The integration of water reuse reduces the fractional water consumption index from 2.8 to 2.2 and achieves a recovered water purity of 99.6%, demonstrating clear environmental benefits in terms of resource conservation. Beyond water savings, the core objective is to assess how this integration influences the inherent risks associated with the process. The key operational stages—polymerization, VCM recovery, product purification, and water recirculation—were modeled and analyzed using computer-aided process engineering (CAPE) tools. The ISI analysis yielded a score of 33, surpassing the threshold typically associated with inherently safer designs, with VCM hazards alone contributing a score of 19 due to its high flammability and carcinogenicity. These findings reveal a critical trade-off between environmental performance and inherent safety, underscoring that resource integration measures, while beneficial for sustainability, may require complementary safety improvements. This study highlights the necessity of incorporating inherently safer design principles alongside process integration strategies to achieve balanced progress in operational efficiency, environmental responsibility, and risk minimization in PVC manufacturing. Full article
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