Search Results (7)

This study analyzes, through remote sensing techniques and innovative clouding services, the recent land use dynamics in the North-Roman littoral zone, an area where the latest development has witnessed an important reconversion of purely rural areas to new residential and commercial services. The survey area includes five municipalities and encompasses important infrastructure, such as the “Leonardo Da Vinci” Airport and the harbor of Civitavecchia. The proximity to the metropolis, supported by an efficient network of connections, has modified the urban and peri-urban structure of these areas, which were formerly exclusively agricultural. Hereby, urban expansion has been quantified by classifying Landsat satellite images using the cloud computing platform “Google Earth Engine” (GEE). Landsat multispectral images from 1985 up to 2020 were used for the diachronic analysis, with a five-yearly interval. In order to achieve a high accuracy of the final result, work was carried out along the temporal dimension of the images, selecting specific time windows for the creation of datasets, which were adjusted by the information related to the NDVI index variation through time. This implementation showed interesting improvements in the model performance for each year, suggesting the importance of the NDVI standard deviation parameter. The results showed an increase in the overall accuracy, being from 90 to 97%, with improvements in distinguishing urban surfaces from impervious surfaces. The final results highlighted a significant increase in the study area of the “Urban” and “Woodland” classes over the 35-year time span that was considered, being 67.4 km² and 70.4 km², respectively. The accurate obtained results have allowed us to quantify and understand the landscape transformations in the area of interest, with particular reference to the dynamics of urban development. Full article

The application of parahydrogen gas to enhance the magnetic resonance signals of a diversity of chemical species has increased substantially in the last decade. Parahydrogen is prepared by lowering the temperature of hydrogen gas in the presence of a catalyst; this enriches the para spin isomer beyond its normal abundance of 25% at thermal equilibrium. Indeed, parahydrogen fractions that approach unity can be attained at sufficiently low temperatures. Once enriched, the gas will revert to its normal isomeric ratio over the course of hours or days, depending on the surface chemistry of the storage container. Although parahydrogen enjoys long lifetimes when stored in aluminum cylinders, the reconversion rate is significantly faster in glass containers due to the prevalence of paramagnetic impurities that are present within the glass. This accelerated reconversion is especially relevant for nuclear magnetic resonance (NMR) applications due to the use of glass sample tubes. The work presented here investigates how the parahydrogen reconversion rate is affected by surfactant coatings on the inside surface of valved borosilicate glass NMR sample tubes. Raman spectroscopy was used to monitor changes to the ratio of the (J: 0 → 2) vs. (J: 1 → 3) transitions that are indicative of the para and ortho spin isomers, respectively. Nine different silane and siloxane-based surfactants of varying size and branching structures were examined, and most increased the parahydrogen reconversion time by 1.5×–2× compared with equivalent sample tubes that were not treated with surfactant. This includes expanding the pH₂ reconversion time from 280 min in a control sample to 625 min when the same tube is coated with (3-Glycidoxypropyl)trimethoxysilane. Full article

The olive tree is an important crop in Portugal, where different levels of intensification coexist. The traditional olive orchards present profitability problems, mainly due to harvesting, so there has been a drastic reconversion towards high-density or super-high-density olive orchards. The latter present major constraints due to very specific needs for their use, being practically destined for new orchards. Consequently, the possibility of using systems based on canopy shakers in high-density olive orchards with local varieties is promising. The objective of this work is to evaluate a prototype canopy shaker for the harvesting of high-density olive orchards of the Portuguese variety ‘Cobrançosa’. The evaluation is based on the study of canopy shaking in order to adapt canopy training and the adaptability of the machine. For this purpose, the vibration of 72 points of the tree canopy was recorded and a qualitative assessment of the harvest was carried out. Differences were found between the different zones according to the direction of the forward movement of the harvester and the distance to the trunk. These differences were associated with the values obtained for fruit detachment, and a greater quantity of fruit was harvested in the areas of the canopy in contact with the rods. Full article

For hundreds of years, water mills have supported the local economies of Piedmont by contributing to the production of flour, textile fibres, timber, and metal agricultural tools. Since the beginning of the last century, and in particular after the 1950s, many artefacts have been abandoned. Nonetheless, hundreds of mills are still present in southern Piedmont, both in the plains and in the mountains, sometimes in an excellent state of conservation. This work presents a hammer forge, the La Pianca mill in Busca, Cuneo, Italy, as a significant, detailed case study. The socio-economic context in which exists is analysed, its history is reconstructed, and the functioning of the machinery, including the water wheels, the motion transmission systems, and the various utilities consisting of tilt hammers, grinding wheels, and drills, is analysed in detail. Beyond the historical interest, concerning both the territory and the architecture, as well as the machines and mechanisms, this work aims to make a contribution to the prefiguration of effective scenarios for the reconversion of similar productive artefacts. Full article

The aim of this study is to analyse the likelihood of agricultural workers in rural areas converting to the tourism sector. Chile is used as a case study, drawing on the CASEN survey of 2017 to analyse differences between the northern, central, and southern regions of the country and construct a satellite account of tourism. A matching process was carried out within the data, and the estimation of a logit model was done to assess the probability of labour reconversion. The results indicate that an agricultural worker has a 12.8% probability of retraining. However, differences emerged when demographic characteristics were analysed; specifically, people with post-secondary education and women have a higher probability of retraining. These and other sociodemographic characteristics are important to explain potential labour reconversion towards tourism in rural areas, although differences arose between areas of the country. Therefore, homogeneous public policies that do not consider the specific characteristics of the territories within a country will be ineffective. Full article

Numerous industrial pits are discarded after their exploitation in every part of the world. Humanity both transforms the original morphology of the landscape, due to industrial activity in the territory, and, at the same time, rejects this "new" situation. This is to the detriment of the landscape, which is witness to this transfiguration, degradation, and abandonment. What is the future of these impersonal and empty areas? In this article, we present a general survey concerning the notion of quarry reuse to highlight the importance of this current and common problem. Our work approached the topic through a combination of the main concepts and a description of selected cases of study of quarry reconversions, sensitive to the environmental issues, climate changes, and sustainability. According to this premise, the research also provides an innovative matrix of schemes to classify the existing fundamental methods of recovery. For this effect, the investigation was proposed to be an instrument to improve the knowledge in the scientific and theoretical sectors, flanking the practical understanding, which has already started to move in this direction of reconversion, as the paper shows. Full article

The idea of a “Hydrogen Economy” is that carbon containing fuels should be replaced by hydrogen, thus eliminating air pollution and growth of CO₂ in the atmosphere. However, storage of a gas, its transport and reconversion to electricity doubles the cost of H₂ from the electrolyzer. Methanol made with CO₂ from the atmosphere is a zero carbon fuel created from inexhaustible components from the atmosphere. Extensive work on the splitting of water by bacteria shows that if wastes are used as the origin of feed for certain bacteria, the cost for hydrogen becomes lower than any yet known. The first creation of hydrogen and electricity from light was carried out in 1976 by Ohashi et al. at Flinders University in Australia. Improvements in knowledge of the structure of the semiconductor-solution system used in a solar breakdown of water has led to the discovery of surface states which take part in giving rise to hydrogen (Khan). Photoelectrocatalysis made a ten times increase in the efficiency of the photo production of hydrogen from water. The use of two electrode cells; p and n semiconductors respectively, was first introduced by Uosaki in 1978. Most photoanodes decompose during the photoelectrolysis. To avoid this, it has been necessary to create a transparent shield between the semiconductor and its electronic properties and the solution. In this way, 8.5% at 25 °C and 9.5% at 50 °C has been reached in the photo dissociation of water (GaP and InAs) by Kainthla and Barbara Zeleney in 1989. A large consortium has been funded by the US government at the California Institute of Technology under the direction of Nathan Lewis. The decomposition of water by light is the main aim of this group. Whether light will be the origin of the post fossil fuel supply of energy may be questionable, but the maximum program in this direction is likely to come from Cal. Tech. Full article