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22 pages, 4916 KB  
Article
The Genesis and Geological Significance of the Chaluo Granite in Yidun Magmatic Arc, Western Sichuan, China: Constraints from the Zircon U-Pb Chronology, Elemental Geochemistry and S-Pb-Hf Isotope
by Wenjing Yang, Tianshe Cheng, Xuebin Zhang, Lijun Guo, Xujiang Cheng, Xingfang Duo, Hangyu Fan, Hongsheng Gao, Lipeng Tu, Meng Zhao and Weihong Dong
Minerals 2025, 15(9), 916; https://doi.org/10.3390/min15090916 - 28 Aug 2025
Abstract
The Chaluo granite is situated in the middle section of the Yidun magmatic arc in western Sichuan Province, China. It holds great significance for the study of the geological evolution of the Paleo-Neotethys tectonic belts. The Chaluo granite mainly consists of alkaline feldspar, [...] Read more.
The Chaluo granite is situated in the middle section of the Yidun magmatic arc in western Sichuan Province, China. It holds great significance for the study of the geological evolution of the Paleo-Neotethys tectonic belts. The Chaluo granite mainly consists of alkaline feldspar, quartz, and biotite, with a small amount of apatite. LA-ICP-MS zircon U-Pb dating yielded crystallization ages of (87 ± 3) Ma for the Chaluo granite, indicating its formation in the Late Cretaceous. Elemental geochemical testing results showed that the Chaluo granite exhibits I-type granite characteristics. It has undergone significant fractional crystallization processes, with high SiO2 contents (72.83–76.63 wt%), K (K2O/Na2O = 1.33–1.53), Al2O3 (Al2O3 = 12.24–13.56 wt%, A/CNK = 0.91–1.08), and a high differentiation index (DI = 88.91–92.49). Notably, the MgO contents were low (0.10–0.26 wt%), and there were significant depletions of Nb, Sr, Ti, and Eu, while Rb, Pb, Th, U, Zr, and Hf were significantly enriched. The total rare earth element (REE) contents were relatively low (211–383 ppm), showing significant light REE (LREE) enrichment (LREE/HREE = 4.46–5.57) and a pronounced negative Eu anomaly (δEu = 0.09–0.17). In situ zircon Hf analyses, combined with 206Pb/238U ages, gave εHf(t) values ranging from −3.8 to 1.72 and two-stage Hf ages (tDM2) of 875–1160 Ma. Together with the S and Pb isotope compositions of the Chaluo granite, its magma likely originated from the partial melting of Middle–Neoproterozoic sedimentary rocks enriched in biogenic S. The tectonic-setting analysis indicates that the Chaluo granite formed in a post-orogenic intracontinental extensional environment. This environment was triggered by the northward subduction-collision of the Lhasa block, followed by slab break-off and the upwelling of the asthenosphere in the Neo-Tethys orogenic belt. We propose that the Paleo-Tethys tectonic belt was influenced by the Neo-Tethys tectonic activity, at least in the Yidun magmatic arc region during the Late Cretaceous. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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22 pages, 7924 KB  
Article
Confirmation of Significant Iron Formations During “Boring Billion” in Altyn Region, China: A Case Study of the Dimunalike Iron Deposit
by Wencheng Liu, Fanqi Kong, Haibo Ding, Jing Zhang and Mingtian Zhu
Minerals 2025, 15(9), 905; https://doi.org/10.3390/min15090905 - 26 Aug 2025
Abstract
It is generally believed that the ancient oceans during the “boring billion” (1.85–0.8 Ga) lacked the capacity to form large-scale iron formations (IFs), though localized small-scale IFs deposition persisted. The Altyn region of China hosts abundant IFs, with the Dimunalike IFs being the [...] Read more.
It is generally believed that the ancient oceans during the “boring billion” (1.85–0.8 Ga) lacked the capacity to form large-scale iron formations (IFs), though localized small-scale IFs deposition persisted. The Altyn region of China hosts abundant IFs, with the Dimunalike IFs being the largest and most representative, characterized by typical banded iron–silica layers. Detailed fieldwork identified a tuff layer conformably contacting the IFs at the roof rocks of IFs and a ferruginous mudstone layer at the floor rocks of IFs in drill core ZK4312. Geochemical and zircon U-Pb-Hf isotopic analyses were performed. The tuff has a typical tuff structure, mostly made of quartz, and contains a significant amount of natural sulfur. It also has high SiO2 content (77.90%–80.49%) and sulfur content (0.78%–3.06%). The ferruginous mudstone has a volcanic clastic structure and is mainly composed of quartz and chlorite, with abundant coeval pyrite. It shows lower SiO2 content (53.83%–60.32%) and higher TFe2O3 content (10.29%–16.24%). Both layers share similar rare earth element (REE) distribution patterns and trace element compositions, with light REE enrichment and negative Eu, Nb, and Ti anomalies, consistent with arc volcanic geochemistry. Zircon U-Pb ages indicate crystallization of the tuff at 1102 ± 13 Ma and maximum deposition of the mudstone at 1110 ± 41 Ma. These data suggest formation during different stages of the same volcanic–sedimentary process. The εHf(t) values (3.60–12.35 for tuff, 2.92–8.19 for mudstone) resemble those of Algoma-type IF host rocks, implying derivation from re-melted new crust. The Dimunalike IFs likely formed in a submarine volcanic–sedimentary environment. In conclusion, although the Mesoproterozoic ocean was generally in a low-oxygen state, which was not conducive to large-scale IF deposition, localized submarine volcanic–hydrothermal activity could still lead to IF formation. Full article
(This article belongs to the Special Issue Geochemical, Isotopic, and Biotic Records of Banded Iron Formations)
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15 pages, 7780 KB  
Article
Geochronological Constraints on the Genesis of the Changshitougounao Gold Deposit, Qinling Orogen
by Xian-Fa Xue, Sheng-Xiang Lu, Shou-Xu Wang, Da-Hu Yuan, Zheng-Wang Zeng, Jin-Hong Qiu and Jie Wang
Minerals 2025, 15(9), 903; https://doi.org/10.3390/min15090903 - 26 Aug 2025
Viewed by 234
Abstract
The Western Qinling Orogenic Belt, China’s second-largest Au-metallogenic province, hosts numerous polymetallic deposits, with gold resources particularly concentrated in the northwestern Xiahe–Hezuo area. The Changshitougounao gold deposit, located south of the Xiahe Fault, comprises disseminated ores controlled by near E–W-trending faults and is [...] Read more.
The Western Qinling Orogenic Belt, China’s second-largest Au-metallogenic province, hosts numerous polymetallic deposits, with gold resources particularly concentrated in the northwestern Xiahe–Hezuo area. The Changshitougounao gold deposit, located south of the Xiahe Fault, comprises disseminated ores controlled by near E–W-trending faults and is primarily hosted in quartz diorite and the Lower Triassic Longwuhe Formation. Zircon LA–ICP–MS U–Pb dating of fresh quartz diorite yields an age of 241.8 ± 2.6 Ma. Two generations of monazite were identified: type I magmatic monazite and type II hydrothermal monazite. Type I monazite is intergrown with feldspar, quartz, and biotite, and in situ LA–ICP–MS U–Pb analysis gives an age of 239.2 ± 2.2 Ma. Type II monazite occurs as irregular granular aggregates associated with Au-bearing sulfides and hydrothermal sericite, with an in situ U–Pb age of 230 ± 3.5 Ma. Apatite, also coeval with Au-bearing sulfides and type II monazite, yields an LA–ICP–MS U–Pb age of 230.9 ± 2.5 Ma and 230.7 ± 3.0 Ma. Zircon and type I monazite thus constrain the emplacement of the ore-bearing quartz diorite to ca. 240 Ma, whereas hydrothermal type II monazite and apatite constrain the timing of mineralization to ca. 230 Ma. The ~10 Ma interval between magmatism and mineralization indicates that goldmineralization in the Changshitougounao deposit is decoupled from Early Triassic magmatic activity. Integrating previous studies of the West Qinling geodynamic evolution, we infer that the Changshitougounao deposit formed during collisional orogenesis, in response to the closure of the Paleo-Tethys Ocean. Consequently, the Changshitougounao gold deposit is best classified as an orogenic gold system. Pyrite–arsenopyrite and sericite alteration serve as effective exploration vectors, and the contact zone between quartz diorite veins and slate represents a favorable structural setting for ore prospecting. Full article
(This article belongs to the Special Issue Gold–Polymetallic Deposits in Convergent Margins)
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24 pages, 9686 KB  
Article
The Petrogenesis of Early Permian Granodiorites in the Northern Segment of the Changning-Menglian Suture Zone, Western Yunnan, and Their Tectonic Implications
by Jiajia Liu, Zhen Jia, Jiyuan Wang, Feng Zhao, Junbao Luo, Feiyang Xu and Fuchuan Chen
Minerals 2025, 15(9), 894; https://doi.org/10.3390/min15090894 - 23 Aug 2025
Viewed by 279
Abstract
The Changning-Menglian suture zone, as the remnant of the main Paleo-Tethyan oceanic basin in its southern segment, lacks direct magmatic evidence constraining the timing of subduction initiation in its northern segment. The petrogenesis and tectonic setting of the newly discovered Early Permian (~280 [...] Read more.
The Changning-Menglian suture zone, as the remnant of the main Paleo-Tethyan oceanic basin in its southern segment, lacks direct magmatic evidence constraining the timing of subduction initiation in its northern segment. The petrogenesis and tectonic setting of the newly discovered Early Permian (~280 Ma) Wayao granodiorite in the northern segment remain unclear, hindering our understanding of the timing of subduction initiation and processes of the Paleo-Tethyan Ocean in the Changning-Menglian suture zone. This study presents systematic petrographic, zircon U-Pb geochronological, whole-rock major and trace element geochemical, and Sr-Nd-Hf isotopic analyses on the newly discovered Early Permian granodiorite in the Wayao area, northern segment of the Changning-Menglian suture zone, western Yunnan. Zircon U-Pb dating yields a crystallization age of ca. 280 Ma, confirming its emplacement during the Early Permian. The petrogeochemical characteristics indicate that it belongs to the metaluminous, calc-alkaline series of I-type granite. It is enriched in large-ion lithophile elements (LILEs; e.g., Rb, Th, U, La, Pb) and depleted in high-field-strength elements (HFSEs; e.g., Ba, Nb, Sr, Ti), exhibiting a pronounced negative Eu anomaly. Whole-rock Sr-Nd isotopes (εNd(t) = −5.6–−6.1) and zircon Hf isotopes (εHf(t) = −1.34–−10.01) suggest that the magma was predominantly derived from the partial melting of ancient crustal material (primarily metamorphosed basic rocks, such as amphibolite), with a minor addition of mantle-derived components (magma mixing). Combined with petrogeochemical discriminant diagrams (e.g., Sr/Y vs. Y, Rb vs. Yb + Ta) and the regional geological context, this granodiorite is interpreted to have formed in an active continental margin tectonic setting associated with the eastward subduction of the Paleo-Tethys Ocean (represented by the Changning-Menglian Ocean). This discovery fills the gap in the record of Early Permian subduction-related magmatic rocks in the northern segment of the Changning-Menglian suture zone. It provides crucial petrological evidence constraining that the eastward subduction and consumption of the northern Paleo-Tethys Ocean had already commenced by the Early Permian. Full article
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29 pages, 9860 KB  
Article
The Source and Evolution of Ore-Forming Fluids in the Xiaobaihegou Fluorite Deposit, Altyn-Tagh Orogen, NW China: Constraints from Trace Element, Fluid Inclusion, and Isotope Studies
by Kang Chen, Wenlei Song, Yuanwei Wang, Long Zhang, Yongkang Jing, Yi Zhang, Yongbao Gao, Ming Liu, Nan Deng and Junwei Wu
Minerals 2025, 15(8), 840; https://doi.org/10.3390/min15080840 - 8 Aug 2025
Viewed by 348
Abstract
The Xiaobaihegou fluorite deposit is located in the southwest of the Altyn-Tagh Orogen, NW China. However, the provenance, thermodynamic properties, and enrichment mechanisms of the ore-forming fluids in this deposit remain unclear. Fluorite mineralization primarily occurs in the vicinity of the contact zone [...] Read more.
The Xiaobaihegou fluorite deposit is located in the southwest of the Altyn-Tagh Orogen, NW China. However, the provenance, thermodynamic properties, and enrichment mechanisms of the ore-forming fluids in this deposit remain unclear. Fluorite mineralization primarily occurs in the vicinity of the contact zone between the granite and the wall rocks. The zircon U-Pb age of the alkali-feldspar granite in the Xiaobaihegou fluorite deposit is 482.3 ± 4.1 Ma. The ore-hosting lithologies are mainly calcareous rock series of the Altyn Group. The ore bodies are controlled by NE-trending faults and consist primarily of veined, brecciated, massive, and banded ores. The ore mineral assemblage is primarily composed of calcite and fluorite. The rare earth element (REE) patterns of fluorite and calcite in the Xiaobaihegou deposit exhibit right-dipping LREE enrichment with distinct negative Eu anomalies, which closely resemble those of the alkali-feldspar granite. This similarity suggests that the REE distribution patterns of fluorite and calcite were likely inherited from the pluton. The ore-forming process can be divided into an early stage and a late stage. The massive ores formed in the early stage contain mainly gas-rich two-phase fluid inclusions and CO2-bearing three-phase inclusions, with homogenization temperatures ranging from 235 °C to 426 °C and salinities from 28.59% to 42.40% NaCl equivalent. In the late stage, brecciated and stockwork ores were formed. They host liquid-rich two-phase and gas-rich two-phase fluid inclusions, with homogenization temperatures ranging from 129 °C to 350 °C and salinities from 0.88% to 21.61% NaCl equivalent. The results of hydrogen and oxygen isotope studies indicate that the ore-forming fluids were derived from a mixture of magmatic–hydrothermal and meteoric water. Fluorite precipitation in the early stage was mainly due to the mixing of magmatic–hydrothermal solution and meteoric water, as well as a water–rock reaction. In the late stage, fluid mixing further occurred, resulting in a decrease in temperature and the formation of brecciated and stockwork ores. The 87Sr/86Sr and 143Nd/144Nd ratios of fluorite from the deposit range from 0.71033 to 0.71272 and 0.511946 to 0.512073, respectively, indicating that the ore-forming material originates from the crust. Based on the ore-forming characteristics, it is proposed that Ca may be primarily leached from the strata formation, while F may predominantly originate from magmatic–hydrothermal solutions. The formation of fluorite deposits is closely related to the transition of the Central Altyn-Tagh Block and Qaidam Block from a compressional orogenic environment to an extensional tectonic environment. Full article
(This article belongs to the Section Mineral Deposits)
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19 pages, 3872 KB  
Article
Sr-Nd-Hf Isotopic Characteristics of Ore-Bearing Intrusive Rocks in the Chating Cu-Au Deposit and Magushan Cu-Mo Deposit of Nanling-Xuancheng Ore Concentration Area and Their Geological Significance
by Linsen Jin, Xiaochun Xu, Xinyue Xu, Ruyu Bai, Zhongyang Fu, Qiaoqin Xie and Zhaohui Song
Minerals 2025, 15(8), 837; https://doi.org/10.3390/min15080837 - 7 Aug 2025
Viewed by 308
Abstract
The Chating Cu-Au and Magushan Cu-Mo deposits in Anhui province are two representative deposits within the recently defined Nanling-Xuancheng ore concentration area in the Middle and Lower Yangtze River Metallogenic Belt (MLYB). Magmatism and mineralization for the area are not well known at [...] Read more.
The Chating Cu-Au and Magushan Cu-Mo deposits in Anhui province are two representative deposits within the recently defined Nanling-Xuancheng ore concentration area in the Middle and Lower Yangtze River Metallogenic Belt (MLYB). Magmatism and mineralization for the area are not well known at present due to a lack of in-depth studies on the petrogenesis of ore-bearing intrusive rocks and their relationship with deposits. Here, the ore-bearing intrusive rocks of the two deposits are investigated through analyses of whole-rock geochemistry and Sr-Nd isotopes, zircon U-Pb ages, and zircon Hf isotopes. The results reflect the two intrusions, both formed in the Early Cretaceous (138.9 ± 0.8 Ma and 132.2 ± 1.3 Ma). They belong to the sub-alkaline high-K calc-alkaline series, while trace elements are enriched in LILEs and LREE and depleted in HFSEs. However, the intrusions of the Chating deposit (Isr = 0.7064–0.7068; εNd(t) = −8.5–−7.3; εHf(t) = −11.9–−7.0) have obviously different Sr-Nd-Hf isotopic compositions from the intrusions of the Magushan deposit (Isr = 0.7079–0.7081; εNd(t) = −5.7–−5.4; εHf(t) = −5.4–−3.6). The characteristics indicate that the two intrusions were formed in the same diagenetic ages and tectonic settings and derived from a crust–mantle mixture with predominant mantle-derived materials. But the crust materials of sources are different, which further leads to different metallogenic elements, showing that the Chating deposit is enriched in Cu and Au, while the Magushan deposit is enriched in Mo. Moreover, the characteristics and magma sources of two intrusions and metallogenic elements correspond respectively to the Tongling Cu-Au polymetallic ore concentration area in the MLYB and the southern Anhui Mo polymetallic ore concentration area in the Jiangnan orogen. The correlation implies differences in magmatism and mineralization between the northwestern and southeastern parts of the Nanling-Xuancheng ore concentration area, demarcated by the Jiangnan Deep Fault. These variations were mainly controlled by the Pre-Sinian crustal basement. Full article
(This article belongs to the Section Mineral Deposits)
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23 pages, 7821 KB  
Article
The Multiple Stages of Regional Triassic Crustal Reworking in Eastern Tianshan, NW China: Evidence from the Xigebi Area
by Ming Wei, Haiquan Li, Wenxiao Zhou, Mahemuti Muredili, Ernest Chi Fru and Thomas Sheldrick
Minerals 2025, 15(8), 829; https://doi.org/10.3390/min15080829 - 4 Aug 2025
Viewed by 362
Abstract
The eastern Tianshan region in the Central Asian Orogenic Belt (CAOB) is characterized by multiple complex tectonic activity of uncertain historical contribution to the construction of the CAOB. This study utilizes a multi-proxy geochemical approach to characterize I-type monzogranite pluton rocks and their [...] Read more.
The eastern Tianshan region in the Central Asian Orogenic Belt (CAOB) is characterized by multiple complex tectonic activity of uncertain historical contribution to the construction of the CAOB. This study utilizes a multi-proxy geochemical approach to characterize I-type monzogranite pluton rocks and their associated hornblende-rich dioritic enclaves to decipher the tectonic and magmatic evolution of the Xigebi area, eastern Tianshan. Zircon geochronology indicates a Triassic and Permian crystallization age of ca. 224.2 ± 1.7 Ma and ca. 268.3 ± 3.0 Ma for the host monzogranites and the dioritic enclaves, respectively. Major, trace and rare earth element distribution, together with Hf isotope systematics displaying noticeable positive εHf(t) anomalies for both rock types, point to partial melting of meta-mafic rocks in an intraplate extensional setting. The diorite was formed by the melting of lower crustal meta-igneous rocks mixed with mantle melts, and the monzogranite, predominantly from deep crustal meta-basalts contaminated by shallow metasedimentary rocks, with some degree of mixing with deeply sourced mantle magma. While both the host monzogranites and their dioritic enclaves are the products of upwelling magma, the younger Triassic monzogranites captured and preserved fragments of the dioritic Permian lower continental crust during crystallization. These multiple stages of magmatic underplating and crustal reworking associated with vertical stratification of the juvenile paleo-continental crust suggest the monzogranites and diorites indicate a change from a post-collisional setting to a regional intraplate regime on the southern margin of the CAOB. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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26 pages, 6611 KB  
Article
The Geochronology, Geochemical Characteristics, and Tectonic Settings of the Granites, Yexilinhundi, Southern Great Xing’an Range
by Haixin Yue, Henan Yu, Zhenjun Sun, Yanping He, Mengfan Guan, Yingbo Yu and Xi Chen
Minerals 2025, 15(8), 813; https://doi.org/10.3390/min15080813 - 31 Jul 2025
Viewed by 325
Abstract
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late [...] Read more.
The southern Great Xing’an Range is located in the overlap zone of the Paleo-Asian Ocean metallogenic domain and the Circum-Pacific metallogenic domain. It hosts numerous Sn-polymetallic deposits, such as Weilasituo, Bianjiadayuan, Huanggang, and Dajing, and witnessed multiple episodes of magmatism during the Late Mesozoic. The study area is situated within the Huanggangliang-Ganzhuermiao metallogenic belt in the southern Great Xing’an Range. The region has witnessed extensive magmatism, with Mesozoic magmatic activities being particularly closely linked to regional mineralization. We present petrographic, zircon U-Pb chronological, lithogeochemical, and Lu-Hf isotopic analyses of the Yexilinhundi granites. The results indicate that the granite porphyry and granodiorite were emplaced during the Late Jurassic. Both rocks exhibit high SiO2, K2O + Na2O, differentiation index (DI), and 10,000 Ga/Al ratios, coupled with low MgO contents. They show distinct fractionation between light and heavy rare earth elements (LREEs and HREEs), exhibit Eu anomalies, and have low whole-rock zircon saturation temperatures (Tzr), collectively demonstrating characteristics of highly fractionated I-type granites. The εHf(t) values of the granites range from 0.600 to 9.14, with young two-stage model ages (TDM2 = 616.0~1158 Ma), indicating that the magmatic source originated from partial melting of Mesoproterozoic-Neoproterozoic juvenile crust. This study proposes that the granites formed in a post-collisional/post-orogenic extensional setting associated with the subduction of the Mongol-Okhotsk Ocean, providing a scientific basis for understanding the relationship between the formation of Sn-polymetallic deposits and granitic magmatic evolution in the study area. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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20 pages, 9529 KB  
Article
Geochemistry and Geochronology of the Late Permian Linxi Formation in the Songliao Basin, China: Tectonic Implications for the Paleo-Asian Ocean
by Xin Huang, Haihua Zhang, Liang Qiu, Gongjian Li, Yujin Zhang, Wei Chen, Shuwang Chen and Yuejuan Zheng
Minerals 2025, 15(8), 784; https://doi.org/10.3390/min15080784 - 25 Jul 2025
Viewed by 217
Abstract
The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao [...] Read more.
The Central Asian Orogenic Belt (CAOB) represents a crucial area for understanding the tectonic evolution of the Paleo-Asian Ocean and surrounding orogenic systems. This study investigates the petrology, geochronology, and geochemistry of volcanic and clastic rocks from Well HFD3 in the northern Songliao Basin, which provides key insights into the tectonic development of this region. Zircon U–Pb dating of tuff samples from the Linxi Formation provides an accurate age of 251.1 ± 1.1 Ma, corresponding to the late Permian. Geochemical analyses show that the clastic rocks are rich in SiO2 (63.5%) and Al2O3 (13.7%), with lower K2O/Na2O ratios (0.01–1.55), suggesting low compositional maturity. Additionally, the trace element data reveal enrichment in light rare earth elements (LREEs) and depletion in Nb, Sr, and Ta, with a negative Eu anomaly, which indicates a felsic volcanic arc origin. The Chemical Index of Alteration (CIA) values (53.2–65.8) reflect weak chemical weathering, consistent with cold and dry paleo-climatic conditions. These findings suggest that the Linxi Formation clastic rocks are derived from felsic volcanic arcs in an active continental margin environment, linked to the subduction of the Paleo-Asian Ocean slab. The sedimentary conditions reflect a gradual transition from brackish to freshwater environments, corresponding with the final stages of subduction or the onset of orogeny. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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32 pages, 32586 KB  
Article
Magmatic Evolution at the Saindak Cu-Au Deposit: Implications for the Formation of Giant Porphyry Deposits
by Jun Hong, Yasir Shaheen Khalil, Asad Ali Narejo, Xiaoyong Yang, Tahseenullah Khan, Zhihua Wang, Huan Tang, Haidi Zhang, Bo Yang and Wenyuan Li
Minerals 2025, 15(8), 768; https://doi.org/10.3390/min15080768 - 22 Jul 2025
Viewed by 1724
Abstract
The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these [...] Read more.
The Chagai porphyry copper belt is a major component of the Tethyan metallogenic domain, which spans approximately 300 km and hosts several giant porphyry copper deposits. The tectonic setting, whether subduction-related or post-collisional, and the deep dynamic processes governing the formation of these giant deposits remain poorly understood. Mafic microgranular enclaves (MMEs), mafic dikes, and multiple porphyries have been documented in the Saindak mining area. This work examines both the ore-rich and non-ore intrusions in the Saindak porphyry Cu-Au deposit, using methods like molybdenite Re-Os dating, U-Pb zircon ages, Hf isotopes, and bulk-rock geochemical data. Geochronological results indicate that ore-fertile and barren porphyries yield ages of 22.15 ± 0.22 Ma and 22.21 ± 0.33 Ma, respectively. Both MMEs and mafic dikes have zircons with nearly identical 206Pb/238U weighted mean ages (21.21 ± 0.18 Ma and 21.21 ± 0.16 Ma, respectively), corresponding to the age of the host rock. Geochemical and Sr–Nd–Hf isotopic evidence indicates that the Saindak adakites were generated by the subduction of the Arabian oceanic lithosphere under the Eurasian plate, rather than through continental collision. The adakites were mainly formed by the partial melting of a metasomatized mantle wedge, induced by fluids from the dehydrating subducting slab, with minor input from subducted sediments and later crust–mantle interactions during magma ascent. We conclude that shallow subduction of the Arabian plate during the Oligocene–Miocene may have increased the flow of subducted fluids into the sub-arc mantle source of the Chagai arc. This process may have facilitated the widespread deposition of porphyry copper and copper–gold mineralization in the region. Full article
(This article belongs to the Section Mineral Deposits)
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20 pages, 10834 KB  
Article
Genesis of Basalts of the Raohe Subduction–Accretion Complex in the Wandashan Block, NE China, and Its Inspirations for Evolution of the Paleo-Pacific Ocean
by Qing Liu, Cui Liu, Jixu Liu, Jinfu Deng and Shipan Tian
Appl. Sci. 2025, 15(15), 8139; https://doi.org/10.3390/app15158139 - 22 Jul 2025
Viewed by 277
Abstract
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow [...] Read more.
The Raohe subduction–accretion complex (RSAC) in the Wandashan Block, NE China, comprises ultramafic rocks, gabbro, mafic volcanic rocks, deep-sea and hemipelagic sediments, and trench–slope turbidites. We investigate the basalts within the RSAC to resolve debates on its origin. Zircon U-Pb dating of pillow basalt from Dadingzi Mountain yields a concordant age of 117.5 ± 2.1 Ma (MSWD = 3.6). Integrating previous studies, we identify three distinct basalt phases. The Late Triassic basalt (210 Ma–230 Ma) is characterized as komatites–melilitite, exhibiting features of island arc basalt, as well as some characteristics of E-MORB. It also contains high-magnesium lava, suggesting that it may be a product of a juvenile arc. The Middle Jurassic basalt (around 159 Ma–172 Ma) consists of a combination of basalt and magnesium andesite, displaying features of oceanic island basalt and mid-ocean ridge basalt. Considering the contemporaneous sedimentary rocks as hemipelagic continental slope deposits, it is inferred that these basalts were formed in an arc environment associated with oceanic subduction, likely as a result of subduction of the young oceanic crust. The Early Cretaceous basalt (around 117 Ma) occurs in pillow structures, exhibiting some characteristics of oceanic island basalt but also showing transitional features towards a continental arc. Considering the regional distribution of the rocks, it is inferred that this basalt likely formed in a back-arc basin. Integrating the formation ages, nature, and tectonic attributes of the various structural units within the RSAC, as well as previous research, it is inferred that subduction of the Paleo-Pacific Ocean had already begun during the Late Triassic and continued into the Early Cretaceous without cessation. Full article
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29 pages, 14630 KB  
Article
Tectonic Evolution of the Eastern Central Asian Orogenic Belt: Evidence from Magmatic Activity in the Faku Area, Northern Liaoning, China
by Shaoshan Shi, Yi Shi, Xiaofan Zhou, Nan Ju, Yanfei Zhang and Shan Jiang
Minerals 2025, 15(7), 736; https://doi.org/10.3390/min15070736 - 15 Jul 2025
Viewed by 353
Abstract
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the [...] Read more.
The Permian–Triassic magmatic record in the eastern Central Asian Orogenic Belt (CAOB) provides critical insights into the terminal stages of the Paleo-Asian Ocean (PAO) evolution, including collisional and post-collisional processes following its Late Permian closure. The northeastern China region, tectonically situated within the eastern segment of the CAOB, is traditionally known as the Xingmeng Orogenic Belt (XOR). This study integrates zircon U-Pb geochronology, whole-rock geochemistry, and zircon Hf isotopic analyses of intermediate-acid volcanic rocks and intrusive rocks from the former “Tongjiatun Formation” in the Faku area of northern Liaoning. The main objective is to explore the petrogenesis of these igneous rocks and their implications for the regional tectonic setting. Zircon U-Pb ages of these rocks range from 260.5 to 230.1 Ma, indicating Permian–Triassic magmatism. Specifically, the Gongzhuling rhyolite (260.5 ± 2.2 Ma) and Gongzhuling dacite (260.3 ± 2.4 Ma) formed during the Middle-Late Permian (270–256 Ma); the Wangjiadian dacite (243 ± 3.0 Ma) and Wafangxi rhyolite (243.9 ± 3.0 Ma) were formed in the late Permian-early Middle Triassic (256–242 Ma); the Haoguantun rhyolite (240.9 ± 2.2 Ma) and Sheshangou pluton (230.1 ± 1.7 Ma) were formed during the Late Middle-Late Triassic (241–215 Ma). Geochemical studies, integrated with the geochronological results, reveal distinct tectonic settings during successive stages: (1) Middle-Late Permian (270–256 Ma): Magmatism included peraluminous A-type rhyolite with in calc-alkaline series (e.g., Gongzhuling) formed in an extensional environment linked to a mantle plume, alongside metaluminous, calc-alkaline I-type dacite (e.g., Gongzhuling) associated with the subduction of the PAO plate. (2) Late Permian-Early Middle Triassic (256–242 Ma): Calc-alkaline I-type magmatism dominated, represented by dacite (e.g., Wangjiadian) and rhyolite (e.g., Wafangxi), indicative of a collisional uplift environment. (3) Late Middle-Late Triassic (241–215 Ma): Magmatism transitioned to high-K calc-alkaline with A-type rocks affinities, including rhyolite (e.g., Haoguantun) and plutons (e.g., Sheshangou), formed in a post-collisional extensional environment. This study suggests that the closure of the PAO along the northern margin of the North China Craton (NCC) occurred before the Late Triassic. Late Triassic magmatic rocks in this region record a post-orogenic extensional setting, reflecting tectonic processes following NCC-XOR collision rather than PAO subduction. Combined with previously reported age data, the tectonic evolution of the eastern segment of the CAOB during the Permian-Triassic can be divided into four stages: active continental margin (293–274 Ma), plate disintegration (270–256 Ma), final collision and closure (256–241 Ma), and post-orogenic extension (241–215 Ma). Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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24 pages, 4663 KB  
Article
Neoproterozoic Subduction Zone Fluids and Sediment Melt-Metasomatized Mantle Magmatism on the Northern Yangtze Block: Constraints from the Ca. 880 Ma Taoyuan Syenogranite
by Shilei Liu, Yiduo Li, Han Liu, Peng Wang, Shizhen Zhang and Fenglin Chen
Minerals 2025, 15(7), 730; https://doi.org/10.3390/min15070730 - 12 Jul 2025
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Abstract
The Yangtze Block, with its widespread Neoproterozoic mafic–felsic magmatic rock series and volcanic–sedimentary rock assemblages, is one of the key windows for reconstructing the assembly and fragmentation process of Rodinia. This study focuses on the Taoyuan syenogranite from the Micangshan Massif on the [...] Read more.
The Yangtze Block, with its widespread Neoproterozoic mafic–felsic magmatic rock series and volcanic–sedimentary rock assemblages, is one of the key windows for reconstructing the assembly and fragmentation process of Rodinia. This study focuses on the Taoyuan syenogranite from the Micangshan Massif on the northern Yangtze Block, by conducting systematic chronology, mineralogy, and geochemistry analyses to investigate their source, petrogenesis, and tectonic setting. LA-ICP-MS U–Pb geochronology reveals that the medium- to coarse-grained and medium- to fine-grained syenogranites have crystallization ages of 878 ± 4.2 Ma and 880 ± 6.5 Ma, respectively. These syenogranites have aluminum saturation index (A/CNK) values ranging from 0.79 to 1.06, indicating quasi-aluminous to weakly peraluminous compositions, and are classified as calc-alkaline I-type granites. The geochemical indicators of these rocks, including Mg# (44–48, mean 46), Zr/Hf (40.07), Nb/La (0.4), and zircon εHf(t) values (+9.2 to +10.9), collectively indicate a depleted lithospheric mantle source. The mantle source was metasomatized by subduction-derived fluids and sediment melts prior to partial melting as evidenced by their higher Mg#, elevated Ba content, and distinctive ratios (Rb/Y, Nb/Y, Th/Yb, Th/Sm, Th/Ce, and Ba/La). Integrating regional data, this study confirms crust–mantle interaction along the northern Yangtze during the early Neoproterozoic, supporting a sustained subduction-related tectonic setting. Full article
(This article belongs to the Special Issue Selected Papers from the 7th National Youth Geological Congress)
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18 pages, 3402 KB  
Article
Synergistic Detrital Zircon U-Pb and REE Analysis for Provenance Discrimination of the Beach-Bar System in the Oligocene Dongying Formation, HHK Depression, Bohai Bay Basin, China
by Jing Wang, Youbin He, Hua Li, Tao Guo, Dayong Guan, Xiaobo Huang, Bin Feng, Zhongxiang Zhao and Qinghua Chen
J. Mar. Sci. Eng. 2025, 13(7), 1331; https://doi.org/10.3390/jmse13071331 - 11 Jul 2025
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Abstract
The Oligocene Dongying Formation beach-bar system, widely distributed in the HHK Depression of the Bohai Bay Basin, constitutes a key target for mid-deep hydrocarbon exploration, though its provenance remains controversial due to complex peripheral source terrains. To address this, we developed an integrated [...] Read more.
The Oligocene Dongying Formation beach-bar system, widely distributed in the HHK Depression of the Bohai Bay Basin, constitutes a key target for mid-deep hydrocarbon exploration, though its provenance remains controversial due to complex peripheral source terrains. To address this, we developed an integrated methodology combining LA-ICP-MS zircon U-Pb dating with whole-rock rare earth element (REE) analysis, facilitating provenance studies in areas with limited drilling and heavy mineral data. Analysis of 849 high-concordance zircons (concordance >90%) from 12 samples across 5 wells revealed that Geochemical homogeneity is evidenced by strongly consistent moving-average trendlines of detrital zircon U-Pb ages among the southern/northern provenances and the central uplift zone, complemented by uniform REE patterns characterized by HREE (Gd-Lu) enrichment and LREE depletion; geochemical disparities manifest as dual dominant age peaks (500–1000 Ma and 1800–3100 Ma) in the southern provenance and central uplift samples, contrasting with three distinct peaks (65–135 Ma, 500–1000 Ma, and 1800–3100 Ma) in the northern provenance; spatial quantification via multidimensional scaling (MDS) demonstrates closer affinity between the southern provenance and central uplift (dij = 4.472) than to the northern provenance (dij = 6.708). Collectively, these results confirm a dual (north–south) provenance system for the central uplift beach-bar deposits, with the southern provenance dominant and the northern acting as a subsidiary source. This work establishes a dual-provenance beach-bar model, providing a universal theoretical and technical framework for provenance analysis in hydrocarbon exploration within analogous settings. Full article
(This article belongs to the Section Geological Oceanography)
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26 pages, 9198 KB  
Article
The Exotic Igneous Clasts Attributed to the Cuman Cordillera: Insights into the Makeup of a Cadomian/Pan-African Basement Covered by the Moldavides of the Eastern Carpathians, Romania
by Sarolta Lőrincz, Marian Munteanu, Ştefan Marincea, Relu Dumitru Roban, Valentina Maria Cetean, George Dincă and Mihaela Melinte-Dobrinescu
Geosciences 2025, 15(7), 256; https://doi.org/10.3390/geosciences15070256 - 3 Jul 2025
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Abstract
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock [...] Read more.
The Eastern Carpathians are thrust to the east and north over their Eastern European foreland, tectonically covering it over an area several hundred kilometers across. Information about the nature of the underthrust part of the Carpathian foreland can be obtained from the rock fragments preserved in the sedimentary successions of the Carpathian fold and thrust belt, specifically in the Outer Dacides and the Moldavides. Fragments of felsic rocks occurring within the sedimentary units of the Upper Cretaceous successions of the Moldavides have long been attributed to the Cuman Cordillera—an intrabasinal ridge in the Eastern Outer Carpathians. This work is the first complex geochemical and geochronological study on the exotic igneous clasts of the Cuman Cordillera. Igneous clasts from the southern part of the Moldavides (Variegated clay nappe/formation) are investigated here. They include mainly granites and rhyolites. Phaneritic rocks are composed of cumulus plagioclase, albite, amphibole and biotite, and intercumulus quartz and potassium feldspar, with apatite, magnetite, sphene, and zircon as main accessories, while the porphyritic rocks have a mineral assemblage similar to that mentioned above, displayed in a porphyritic texture with a usually crystallized groundmass. SHRIMP U-Pb zircon dating indicated the 583–597 Ma age interval for magma crystallization. Based on calcareous nannofossils, the depositional age of the investigated igneous clasts is Cenomanian to Maastrichtian, implying that the Cuman Cordillera was an emerged piece of land, herein an active source of sediments in the flysch basin for at least 40 Ma, from the Early Cretaceous (Aptian) to the Late Cretaceous (Maastrichtian). The intrusive and subvolcanic rocks show similar trends for trace and major elements, evincing their comagmatic nature. The enrichment in LILE and LREE relative to HFSE and HREE, as well as the element anomalies (e.g., negative Nb, Ta, and Eu and positive Rb, Ba, K, and Pb) suggest a convergent continental plate margin tectonic setting. Mineral chemistry suggests magma crystallization in relatively oxic conditions (magnetite series), during ascent within a depth of 15 km to 5 km. The igneous rocks attributed to the Cuman ridge display compositional and geochronological features similar to Brno and Thaya batholiths in the Brunovistulian terrane, which could be a piece of the Carpathian foreland not covered by the Tertiary thrusts. Our data confirm the non-Carpathian origin of the igneous clasts, revealing a Neoproterozoic history of the Carpathian foreland units, which include a Cadomian/Pan-African continental arc, exposed mainly during the Late Cretaceous as an intrabasinal island of the Alpine Tethys, traditionally known as the Cuman Cordillera. Full article
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