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Molecules 2013, 18(9), 10776-10788; doi:10.3390/molecules180910776

A Highly Efficient Regioselective Addition of Acetylides to Enediones Based on Steric Effects

1
Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan West Road, Beijing 100193, China
2
Department of Chemistry, Ganzhou Teachers College, Ganzhou 341000, China
*
Authors to whom correspondence should be addressed.
Received: 19 July 2013 / Revised: 20 August 2013 / Accepted: 20 August 2013 / Published: 3 September 2013
(This article belongs to the Section Organic Synthesis)
View Full-Text   |   Download PDF [253 KB, 18 June 2014; original version 18 June 2014]   |  

Abstract

A simple and efficient strategy for the synthesis of 1-ethynylcyclohex-2-enol derivatives was developed utilizing regioselective addition of acetylides to enediones based on steric effects. Further investigation of the substrate scope of enediones indicated that all the addition reactions ocurred in good yield. View Full-Text
Keywords: regioselective addition; acetylides; enediones; steric effects; 1-ethynylcyclohex-2-enol derivatives regioselective addition; acetylides; enediones; steric effects; 1-ethynylcyclohex-2-enol derivatives
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

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MDPI and ACS Style

Han, X.; Wan, C.; Yang, D.; Yuan, X.; Du, S.; Xiao, Y.; Qin, Z. A Highly Efficient Regioselective Addition of Acetylides to Enediones Based on Steric Effects. Molecules 2013, 18, 10776-10788.

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