Adsorptive Elimination of a Cationic Dye and a Hg (II)-Containing Antiseptic from Simulated Wastewater Using a Metal Organic Framework
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterizations of the Synthesized MOF-5
2.1.1. PXRD Analysis
2.1.2. FT-IR Analysis
2.1.3. FE-SEM Analysis
2.1.4. EDS Analysis
2.2. Effect of pH
2.3. Effect of Adsorbent Dose
2.4. Effect of Contact Time and Adsorption Kinetics
2.5. Effect of Adsorbate Dosage and Isotherm Modeling
2.6. Thermodynamics of Adsorption
2.7. Effect of Natural Ions and Molecules Present in Real Water
2.8. Regeneration of Adsorbent
2.9. Plausible Mechanism of Adsorption
3. Materials and Methods
3.1. Chemicals and Reagents
3.2. Preparation of MOF-5
3.3. Characterization Techniques
3.4. Adsorption Isotherm Model
3.5. Adsorption Thermodynamics
4. Experimental
4.1. Batch Adsorption Experiments
4.2. Regeneration of Adsorbent
5. Conclusions
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Adsorbate | Type of Dye | Qmax (mg/g) | References |
---|---|---|---|
Aniline blue | Cationic | 55.34 | [49] |
Methylene blue | Cationic | 51.81 | [55] |
Malachite green | Cationic | 50.69 | [56] |
Methylene blue | Cationic | 2.632 | [49] |
Safranin O | Cationic | 8.19 | This study |
Congo Red | Anionic | 769.23 | [57] |
Orange II | Anionic | 10.01 | [49] |
Merbromin | Anionic | 22.22 | This study |
Adsorbent | Adsorbate | Qmax (mg/g) | References |
---|---|---|---|
Coconut coir | Methylene blue | 15.59 | [32] |
Egg shell | Methylene blue | 16.43 | [33] |
Activated carbon from waste biomass | Methylene blue | 10.21 | [34] |
ZnO hydrid beads | Basic blue 41 | 1.0–8.0 | [35] |
Polylactide/spent grain | Malachite green | 1.48 | [36] |
ZnO nanoparticles | Methylene blue | 0.3428 | [37] |
Coir pith carbon | Methylene blue | 5.87 | [58] |
ZnO@ananas comosus waste biomass | Celestine blue | 6.52 | [37] |
Ananas comosus waste biomass | Celestine blue | 5.42 | [37] |
Brewery spent grain | Malachite green | 2.55 | [36] |
Poultry feathers | Malachite green | 3.55 | [36] |
Ananas comosus waste biomass | Celestine blue | 5.42 | [37] |
MOF-5 | Merbromin | 22.22 | This study |
MOF-5 | Safranin O | 8.19 | This study |
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Roy, N.; Das, C.; Paul, M.; Im, J.; Biswas, G. Adsorptive Elimination of a Cationic Dye and a Hg (II)-Containing Antiseptic from Simulated Wastewater Using a Metal Organic Framework. Molecules 2024, 29, 886. https://doi.org/10.3390/molecules29040886
Roy N, Das C, Paul M, Im J, Biswas G. Adsorptive Elimination of a Cationic Dye and a Hg (II)-Containing Antiseptic from Simulated Wastewater Using a Metal Organic Framework. Molecules. 2024; 29(4):886. https://doi.org/10.3390/molecules29040886
Chicago/Turabian StyleRoy, Nilanjan, Chanchal Das, Mohuya Paul, Jungkyun Im, and Goutam Biswas. 2024. "Adsorptive Elimination of a Cationic Dye and a Hg (II)-Containing Antiseptic from Simulated Wastewater Using a Metal Organic Framework" Molecules 29, no. 4: 886. https://doi.org/10.3390/molecules29040886