Bis[(2-benzylideneimino)phenyl]amine
Department of Chemistry, Sichuan Normal University, Chengdu, 610066, P. R. China
*
Author to whom correspondence should be addressed.
Molecules 2000, 5(7), M167; https://doi.org/10.3390/M167
Submission received: 13 May 2000
/
Accepted: 10 June 2000
/
Published: 10 July 2000
(This article belongs to the Section Molbank Section of Molecules, 1997-2001)
Imine and amine ligands have been widely used in the field of transition metal catalyzed olefin polymerization [1]. Here we report the synthesis of a tri-dendated imine-amine compound which we plan to use as a ligand. bis(2-Aminophenyl)amine (0.5g, 2.5mmol) [2] and benzaldehyde (0.53ml, 5.2mmol) are added into 10ml of CH2Cl2 and refluxed 4h under N2. The mixture is concentrated in vacuo, washed with cold hexane and dried in vacuo to give a red crystal product, 0.8g (yield 90%).
M. p. 195°C.
1H NMR (400 MHz, CDCl3): 8.23 (s, 1H, NH), 8.55 (s, 2H, N=CH), 6.8-8.0 (m, 18H, Ph).
13C NMR (75 MHz, CDCl3): Ar, 114.4, 119.8, 127.3, 128.6, 128.8, 131.1, 136.3, 137.7, 139.3; C=N, 157.9.
IR (KBr): 3350, 3051, 2873, 1622, 1582.
Anal. Calc. for C26H21N3 (375.50): C 83.16, H 5.65, N 11.19; Found: C 83.04, H 5.67, N 11.29.
References
- Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem. Int. Ed. 1999, 38, 428–447. [CrossRef]
- Black, D. S.; Rothnie, C. N. E. Aust. J. Chem. 1983, 36, 1141–1147.
Sample Availability: available from the authors and from MDPI. |
© 2000 MDPI. All rights reserved. Molecules website www.mdpi.org/molecules/.
Share and Cite
MDPI and ACS Style
Zhao, K.-Q.; Hu, P.; Li, Q.; Xu, H.-B. Bis[(2-benzylideneimino)phenyl]amine. Molecules 2000, 5, M167. https://doi.org/10.3390/M167
AMA Style
Zhao K-Q, Hu P, Li Q, Xu H-B. Bis[(2-benzylideneimino)phenyl]amine. Molecules. 2000; 5(7):M167. https://doi.org/10.3390/M167
Chicago/Turabian StyleZhao, Ke-Qing, Ping Hu, Quan Li, and Hong-Bo Xu. 2000. "Bis[(2-benzylideneimino)phenyl]amine" Molecules 5, no. 7: M167. https://doi.org/10.3390/M167
Display in JSmol Viewer