A Novel Bisquaternary Ammonium Compound as an Anion Sensor—ESI-MS and Fluorescence Study
Abstract
:1. Introduction
2. Results and Discussion
2.1. Mass Spectrometry Analysis
2.2. Computational Analysis
2.3. UV–Vis Absorption Analysis
2.4. Analysis of Anion Sensor Properties
2.4.1. Analysis of Luminescent Properties
2.4.2. Sensitivity of Anion Sensing
3. Materials and Methods
3.1. Chemicals
3.2. (TPP)2-CYSTAM Synthesis
3.3. TFA, Cl and HSO4 Bisquaternary Ammonium Dication Adduct Preparation
3.4. Mass Spectrometry
3.5. High-Performance Liquid Chromatography
3.6. Computational Analysis
3.7. UV–Vis Measurement
3.8. Emission and Excitation Measurement
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
References
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TFA-(TPP)2-CYSTAM Parent Ion: m/z 847.270 (M1+) | Cl-(TPP)2-CYSTAM Parent Ion: m/z 769.245 (M2+) | HSO4-(TPP)2-CYSTAM Parent Ion: m/z 831.238 (M3+) |
---|---|---|
- | - | |
- |
Amount of TFA in the Analyzed Sample | ||
---|---|---|
Sample | Percent Concentrations [%] | Amount of Mole |
1 | 1 | 1.31 × 10−4 |
2 | 0.1 | 1.31 × 10−5 |
3 | 0.01 | 1.31 × 10−6 |
4 | 0.001 | 1.31 × 10−7 |
5 | 0.0005 | 0.655 × 10−7 |
6 | 0.0001 | 1.31 × 10−8 |
7 | 0.00001 | 1.31 × 10−9 |
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Kowalska, M.; Wieczorek, R.; Gawryszewska, P.; Bąchor, R. A Novel Bisquaternary Ammonium Compound as an Anion Sensor—ESI-MS and Fluorescence Study. Int. J. Mol. Sci. 2024, 25, 3467. https://doi.org/10.3390/ijms25063467
Kowalska M, Wieczorek R, Gawryszewska P, Bąchor R. A Novel Bisquaternary Ammonium Compound as an Anion Sensor—ESI-MS and Fluorescence Study. International Journal of Molecular Sciences. 2024; 25(6):3467. https://doi.org/10.3390/ijms25063467
Chicago/Turabian StyleKowalska, Marta, Robert Wieczorek, Paula Gawryszewska, and Remigiusz Bąchor. 2024. "A Novel Bisquaternary Ammonium Compound as an Anion Sensor—ESI-MS and Fluorescence Study" International Journal of Molecular Sciences 25, no. 6: 3467. https://doi.org/10.3390/ijms25063467