Lessons from a “Failed” Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass
Abstract
:1. Introduction
2. Results and Discussion
Tcalc. | Phase 1 | Phase 2 | Phase 3 |
---|---|---|---|
--- | Zn4Si2O7(OH)2*n H2O | Zn2SiO4 | γ-Zn(OH)2 |
300 | Zn4Si2O7(OH)2*n H2O | Zn2SiO4 | ZnO |
400 | Zn4Si2O7(OH)2*n H2O | Zn2SiO4 | ZnO |
500 | Zn4Si2O7(OH)2*n H2O | Zn2SiO4 | ZnO |
600 | Zn2SiO4 | ZnO | |
700 | Zn2SiO4 | ZnO | |
800 | Zn2SiO4 | ZnO | |
1000 | Zn2SiO4 | ZnO |
Crystallization and morphogenesis.
Location of particle nucleation and effect of reaction temperature
Suggested growth mechanism
3. Experimental Section
Mineralization
Characterization
4. Conclusions
Acknowledgements
References and Notes
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Li, Z.; Khimyak, Y.Z.; Taubert, A. Lessons from a “Failed” Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass. Materials 2008, 1, 3-24. https://doi.org/10.3390/ma1010003
Li Z, Khimyak YZ, Taubert A. Lessons from a “Failed” Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass. Materials. 2008; 1(1):3-24. https://doi.org/10.3390/ma1010003
Chicago/Turabian StyleLi, Zhonghao, Yaroslav Z. Khimyak, and Andreas Taubert. 2008. "Lessons from a “Failed” Experiment: Zinc Silicates with Complex Morphology by Reaction of Zinc Acetate, the Ionic Liquid Precursor (ILP) Tetrabutylammonium Hydroxide (TBAH), and Glass" Materials 1, no. 1: 3-24. https://doi.org/10.3390/ma1010003