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Materials

Materials is an international peer-reviewed, open access journal on materials science and engineering published semimonthly online by MDPI.
The Spanish Materials Society (SOCIEMAT), Manufacturing Engineering Society (MES) and Chinese Society of Micro-Nano Technology (CSMNT) are affiliated with Materials and their members receive discounts on the article processing charges.
Indexed in PubMed | Quartile Ranking JCR - Q2 (Metallurgy and Metallurgical Engineering | Physics, Applied | Physics, Condensed Matter)

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All Articles (55,172)

Multi-Metal Alloys as Catalysts for Fenton-like Oxidation: A Review

  • Wenjun Sun,
  • Bingbing Li and
  • Qixing Xia
  • + 1 author

The persistent discharge of refractory toxic organic pollutants poses a severe threat to aquatic environmental safety, driving the urgent demand for high-efficiency water treatment technologies in environmental engineering. Fenton and Fenton-like oxidation processes have garnered extensive attention due to their robust oxidizing capacity and environmental benignity; however, traditional Fenton systems are constrained by inherent limitations, including a narrow applicable pH range, potential secondary pollution, and cumbersome catalyst recovery. To address these challenges, Fenton-like catalysts have evolved progressively from single-metal systems to multi-metal alloy configurations. This review systematically elaborates on the fundamental principles and technical bottlenecks of classical Fenton and Fenton-like reactions, while comprehensively summarizing the research progress of multi-metal alloy catalysts—encompassing binary alloys, multi-component alloys, and high-entropy alloys. Special emphasis is placed on dissecting the core mechanisms through which multi-metal alloys optimize redox cycles and enhance structural stability, leveraging intermetallic synergistic effects, unique electronic structures, and lattice distortion. Furthermore, this work synthesizes key performance enhancement strategies for such catalysts, including co-catalyst synergy, external field assistance, and supported composite modification. Ultimately, this review aims to provide a scientific foundation and technical reference for the rational design, development, and engineering application of high-performance Fenton-like catalysts in sustainable wastewater remediation.

19 March 2026

(a) Fe K–edge XANES spectra of ZVI, Fe–10Cu, Fe–25Cu, and Fe foil [78]; (b) Cu K–edge XANES spectra and [78]; (c) EXAFS spectra of 100Cu, Fe–10Cu, Fe–25Cu, and Cu foil [78]; (d) TEM and (e) HRTEM images of Fe–25Cu, along with (e1,e2) FFT patterns corresponding to different regions in the HRTEM image [78]; (f) acceleration of the Fe2+/Fe3+ transformation by copper species [78]; (g) inhibition of the passivation layer formation on the Fe-25Cu surface by independent copper clusters [78].

Today, distributed optical fiber sensors are widely used in structural health monitoring due to their high sensitivity and long-distance applicability. However, when embedded in pavement structures, distributed optical fiber sensors are always installed in a slotted buried fashion, which not only affects current pavement durability but also reduces pavement construction efficiency. In order to design clear requirements of in situ-embedded distributed optical fiber sensors for pavement construction, this study analyzes the micro-mechanical behavior of optical cables under the ultimate pavement compaction state based on a coupled DEM-FDM approach. According to the study results, it is found that when the pavement subbase was compacted, the maximum contact force of 13.2 mm aggregates in the Z-direction exceeds 150 N, which is the main resistance of the external load during pavement construction. The tight-buffered optical cable without reinforcement element and armored layer cannot withstand the vibration load. The inclusion of GFRP strengthening components and an armored layer decreased maximum stress by 38.2% (X), 30.6% (Y), and 30.9% (Z), as well as displacement by 64.6% (X), 45.5% (Y), and 66.7% (Z). Additionally, the thickness of the outer sheath enhanced the ability to withstand tension but not compression. The increase in the thickness of the armored layer can improve the ability to withstand tension and compression.

19 March 2026

Cable model establishment: (a) two-dimensional diagram of optical cable; (b) optical cable division grid; (c) finite element model of optical cable.

This study investigated the effect of CAD-CAM resin composite thickness on the polymerization behavior of dual-cure resin cements used for endocrown restorations. Three commercially available dual-cure resin cements and one light-cure resin cement (for comparison) were polymerized by light irradiation through CAD-CAM resin composite plates of varying thicknesses (1.5, 3.5, 5.5, 7.5, and 9.5 mm). Transmitted light intensity was measured using an optical spectrometer. Polymerization behavior was evaluated immediately after irradiation and after 24 h of aging using Fourier transform infrared spectroscopy to determine the degree of conversion (DC) and Vickers hardness (VH) testing. Transmitted light intensity decreased logarithmically with increasing composite thickness, with less than 1% of incident light reaching the resin cement at thicknesses ≥ 5.5 mm. For the dual-cure resin cements, DC and VH values significantly decreased when the composite thickness exceeded 5.5 mm. Although DC and VH increased after 24 h due to self-curing, values beneath thicker composites remained lower than those beneath 1.5 mm thick composites. The light-cure resin cement failed to polymerize when the composite thickness exceeded 7.5 mm. These results indicate that CAD-CAM resin composite thickness critically influences resin cement polymerization, highlighting the importance of thickness control in endocrown restorations.

19 March 2026

(A) Schematic illustration of the experimental setup for measuring the light intensity transmitted through CAD-CAM resin composite plates of different thicknesses. (B) Schematic illustration of the experimental setup for polymerization of the resin cement under light irradiation through the CAD-CAM resin composite plate of different thicknesses using a dental light-curing unit.

The performance of recycled hot-mix asphalt mixtures (RHAM) is strongly governed by the extent and uniformity of interactions between the aged binder in reclaimed asphalt pavement (RAP) and the virgin binder. However, in current engineering practice, it remains difficult to accurately evaluate the blending degree of aged and virgin asphalt during RHAM production, where the blending degree refers to the extent and uniformity of binder interaction during hot mixing. Moreover, influenced by various construction-related factors, the uniformity of interfacial diffusion between the two asphalt layers is also hard to control, which compromises the durability of RHAM. To address these issues, fluorescence microscopy was used to quantitatively characterize the blending behavior of aged and virgin asphalt, and Fourier transform infrared spectroscopy (FTIR) was employed to investigate the interfacial diffusion process and its evolution under time-temperature coupling conditions from plant production to field paving. The results indicate that, owing to the fluorescent characteristics of the Styrene-butadiene-styrene block copolymer (SBS) modifier in polymer-modified asphalt, the blending behavior during hot mixing can be quantitatively characterized by the fluorescent area and its areal proportion, providing a rapid solution for quantitative evaluation during RHAM production. Increasing the preheating temperature of RAP, extending mixing time, raising mixing temperature, and adopting Mixing Sequence I reduced the proportion of fluorescent area, suggesting improved blending between aged and virgin asphalt. After blending, the interfacial diffusion between aged and virgin asphalt occurs within the RHAM; the uniformity of this diffusion becomes more pronounced as the elapsed duration from production to paving increases. Nevertheless, excessively long duration may induce secondary aging of the blended binder. Accordingly, the duration is recommended to be controlled at approximately 90 min and should not exceed 180 min. By elucidating the blending and diffusion behaviors of aged and virgin asphalt, this study provides practical guidance for contractors in controlling production-process parameters for RHAM.

19 March 2026

The gradation test results of RAP particles before and after extraction.

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Materials - ISSN 1996-1944