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Article

Modulating Surface Morphology Related to Crystallization Speed of Perovskite Grain and Semiconductor Properties of Optical Absorber Layer under Controlled Doping of Potassium Ions for Solar Cells

by
Tao Ling
,
Xiaoping Zou
*,
Jin Cheng
,
Ying Yang
,
Haiyan Ren
and
Dan Chen
Research Center for Sensor Technology, Beijing Key Laboratory for Sensor, Ministry of Education Key Laboratory for Modern Measurement and Control Technology, School of Applied Sciences, Beijing Information Science and Technology University, Jianxiangqiao Campus, Beijing 100101, China
*
Author to whom correspondence should be addressed.
Materials 2018, 11(9), 1605; https://doi.org/10.3390/ma11091605
Submission received: 10 July 2018 / Revised: 29 August 2018 / Accepted: 30 August 2018 / Published: 4 September 2018
(This article belongs to the Special Issue Interface Engineering in Organic/Inorganic Hybrid Solar Cells)
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Abstract

:
Perovskite thin films with excellent optical semiconductor and crystallization properties and superior surface morphology are normally considered to be vital to perovskite solar cells (PSCs). In this paper, we systematically survey the process of modulating surface morphology and optical semiconductor and crystallization properties of methylammonium lead iodide film by controlling doping of K+ for PSC prepared in air and propose the mechanism of large K+-doped perovskite grain formation related to crystallization speed. The increase in the crystallization speed leads to the production of large grains without localized-solvent-vapor (LSV) pores via moderate doping of K+, and the exorbitant crystallization speed induces super large grains with LSV pores via excessive doping of K+. Furthermore, the semiconductor properties (absorption band edge wavelength, PL emission peak wavelength, energy band gap) of perovskite film can be significantly tuned by controlled doping of K+. The investigation of the detailed process of modulating surface morphology and semiconductor properties of perovskite thin film by controlled doping of K+ may provide guidance and pave the way for superior component design of absorption materials for cost-efficient PSCs.

Graphical Abstract

1. Introduction

Recently, perovskite solar cells (PSCs) were considered, by the public, as the most promising alternative photovoltaic devices as a result of their simple process and high efficiency [1,2,3,4,5]. Undoubtedly, perovskite thin film with superior surface morphology (such as better flatness, low defect density, and large and dense crystal grains) [6,7,8,9] and excellent semiconductor properties (such as suitable exciton binding energy, long carrier lifetime, and appropriate band gap) [6,10,11,12], is normally considered to be vital for PSCs. In order to optimize some semiconductor properties of perovskite materials (such as the interface energy barrier, contact resistance, and carrier diffusion length), some intended doping has been used in absorbing materials based on photovoltaic devices [6,13,14,15,16,17,18,19,20,21,22].
Previously, there were some published reports, which showed that Cs- and Rb-doped PSCs had better stability and higher power conversion efficiency (PCE) than pure PSCs [3,15,16,17]. In addition, some research groups reported that K- and Na-doped perovskites also had better PCE [5,18,19,20,21,22]. Huang et al. confirmed that Na+ can decrease defect density in perovskite absorbers [22]. In our research group, Bai and Yang demonstrated that Rb+ [11] and Na+ [12] can change carrier concentration and mobility, respectively, in perovskite absorbers.
Specially, Tang et al. found that K+ can eliminate the barrier and reduce the defect of perovskite [5,23]. In addition, Zhao et al. reported the modified surface work function, improved crystallinity, and prolonged carrier lifetime in perovskite film via doping of K+ [20]. Yao et al. demonstrated that K+ prefers to occupy the interstitial site in the lattice of perovskite [24]. Kubicki et al. reported that there are unreacted KI and KPbI3 in K-doped perovskite thin film [25]. Abdi-Jalebi et al. reported the substantial mitigation of both non-radiative losses in perovskite films and interfaces with passivating potassium halide layers [26]. Although there are a few reports on doping of K+ in perovskite materials [5,18,20,23,24,25,26,27], a detailed report on the mechanism of large perovskite grain formation related to crystallization speed (CS) in K+-doped perovskite thin films has not been seen up to now, which is also important for the research of K+-doped perovskite thin film for solar cells.
Although certified PCE > 20% was obtained via tuning of the process and composition of perovskite thin film of PSCs [28,29], these devices have been obtained by various processes, which contains a necessary step of forming counter electrode (CE) by thermal evaporation of metals. Apparently, the costs of these metallic CEs are relatively high. To reduce the costs of PSCs, some researchers have developed carbon CEs [30,31,32]. Yang et al. prepared a 2.6% efficient original perovskite solar cell with a candle soot carbon/FTO CE [30]. In our research group, previously, a spongy carbon/FTO composite structure was adopted as a CE and the corresponding cell achieved 4.24% PCE [33], and recently, a PSC with this kind of composite CE was prepared via sequential deposition route and achieved 10.7% PCE [34].
This time, we systematically survey the process of modulating surface morphology and optical semiconductor and crystallization properties of methylammonium lead iodide (MAPbI3) thin film via controlled doping of K+ for PSC prepared in air. In addition, we propose the mechanism of large perovskite grain formation on CS and doping concentration of K+. The increase in the CS leads to the production of large grains without localized-solvent-vapor (LSV) pores via moderate doping of K+ and the exorbitant crystallization speed induces super large grains with LSV pores via excessive doping of K+. Furthermore, the optical semiconductor and crystallization properties of perovskite film prepared in air could be significantly tuned by doping of K+. We also observed the transition from blue shift to red shift of the absorption band edge wavelength with the increase in the amount of doping of K+, which is consistent with the shift of the PL emission peak wavelength. Although this transition did not exist in the results of most research groups [5,20,23], it has occurred [18]. The PSC was prepared via a one-step solvent process under ambient conditions and also resulted in a promising 8.14% PCE on the area of 0.2 cm2.

2. Materials and Methods

2.1. Materials

Fluorine-doped SnO2 (FTO) substrates were purchased from Dalian HeptaChroma Solar Technology Development Corp (Dalian, China). Dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF) were obtained from Sa’en Chemical Technology Corp (Shanghai, China). 18NR-T TiO2 paste (M-TiO2), isopropyl alcohol (IPA), PbI2, chlorobenzene, and acidic titanium dioxide solution (C-TiO2) were obtained from Shanghai MaterWin New Materials Corp (Shanghai, China). Spiro-OMeTAD solution, Methylammonium iodide (MAI), and KI were obtained from Xi’an Polymer Light Technology Corp (Xi’an, China).

2.2. Device Fabrication

The cleaning method of FTO and deposition processes of C-TiO2 layer, M-TiO2 layer and Spiro-OMeTAD layer are the same as those previously [34]. The preparation method of the perovskite thin film deposit and counter electrode will be introduced next. MAPbI3 solution was prepared by mixing 1.2 M CH3NH3I and 1.3 M PbI2 in a mixed solvent (DMF:DMSO = 4:1). Then, 0.6, 0.9 and 1.2 M KI solution was prepared by dissolving a corresponding amount of KI solid in 200 μL mixed solvent (DMF:DMSO = 4:1). These solutions were added to 1 mL prepared MAPbI3 solution. These precursor solutions were spin coated on the M-TiO2/C-TiO2/FTO substrate through two periods at 1000 rpm for 10 and 3000 rpm for 30 s. During the second period, 20 μL of chlorobenzene was dropped at 15 s prior to the end of the period. Then, a thermal annealing of 100 °C for 15 min was processed to yield perovskite films. Finally, the FTO substrates were used to collect the soot of a burning candle as spongy carbon CEs and these spongy carbon films on FTO glasses were then pressed on the as-prepared uncompleted devices.

2.3. Characterization

The details of scanning electron microscopy (SEM) with energy spectrum analysis, X-ray diffraction (XRD) are the same as those used before [34]; however, the absorption spectra of perovskite films with different doping concentrations of K+ were analyzed by an ultraviolet visible (U-V) absorption spectrometer (Avantes, Apeldoom, The Netherlands) and the PL was examined by a LabRAW HR800 PL testing system (HORIBA JObin Yvon, Paris, France).

3. Results and Discussion

The K+ doping contents of 1.2 mL perovskite precursor solutions with the addition of 200 μL KI solutions of 0 M, 0.6 M, 0.9 M and 1.2 M were named 0M, 0.6M, 0.9M and 1.2M, respectively. The MAPbI3 films with 0 M, 0.6 M, 0.9 M and 1.2 M were named MAPbI3+0M, MAPbI3+0.6M, MAPbI3+0.9M and MAPbI3+1.2M, respectively. Surface and cross-sectional SEM images for perovskite absorber layers with 0 M, 0.6 M, 0.9 M and 1.2 M are presented in Figure 1, where we can see clearly the process of modulating surface morphology of the perovskite thin film via controlled doping of K+. In Figure 1e–h, we can see clearly the perovskite layer, M-/C-TiO2 (Mesoporous-TiO2 and Compact-TiO2) layer and FTO layer from the top to the bottom. Although the surface of MAPbI3+0M (presented in Figure 1a) is relatively flat, there are many pores (presented in yellow circle, Figure 1e) in the interface between MAPbI3+0M and M-/C-TiO2. In addition, the sizes of grains are relatively smaller and there are more vertical grain boundaries in MAPbI3+0M (presented in the white circle, Figure 1e). Relative to MAPbI3+0M, the surface of MAPbI3+0.6M (presented in Figure 1b) is rough, but pores are not present in the interface between perovskite layer and M-/C-TiO2, which means the doping of K+ can passivate the interface between MAPbI3+0M and M-/C-TiO2. Furthermore, the sizes of grains are bigger, and there are fewer transverse grain boundaries (presented in Figure 1b). As for MAPbI3+0.9M (Figure 1c,g), the surface has better flatness and grains are larger than for MAPbI3+0.6M, so that the transverse grain boundaries are greatly reduced and vertical grain boundaries are almost gone, which lead to a great improvement in its efficiency. From Figure 1d, we can find a super large grain (>4 μm in the longest direction), but there are LSV pores (presented in blue circle), boundary gaps (presented in yellow circle) and unidentified square protrusions (presented in red circle) on the surface of MAPbI3+1.2M. It is more important to note that there are also LSV pores (presented in blue circle) inside MAPbI3+1.2M according to Figure 1h, which greatly reduces the efficiency of the device. These LSV pores are caused by the inefficient discharge of the solvent from the interior of crystallizing perovskite due to the exorbitant perovskite CS. Through the comparison of these cross-sectional SEM images (Figure 1e–h), we can find that MAPbI3+1.2M becomes very thick (~900 nm). Furthermore, the perovskite grain sizes increases (~500 nm, ~700 nm, ~2 μm and ~4 μm, on average, corresponding MAPbI3+0M, MAPbI3+0.6M, MAPbI3+0.9M and MAPbI3+1.2M, respectively) with the increase in the doping concentration of K+ according to the comparison of these surface SEM images (Figure 1a–d). The perovskite grain sizes increase with the increase in the doping concentration of K+ so that the number of grain boundaries of perovskite films decreases. In addition, the decomposition of perovskite films begins at the boundaries of perovskite grains, so the stability of devices increases with the increase in the doping concentration of K+.
According to these experimental results, we propose the following mechanism (presented in Figure 2) of large K+-doped perovskite grain formation related to CS. In Figure 2, the red arrow represents the solvent evaporation (SE) direction and the small black spot represents seed crystal, which is the root of the formation of perovskite grain. We assume that the distributions of seed crystals in all samples are the same during the initial stage. Lower CS (corresponding to the absence of doping) leads to relatively more spaces to form seed crystals in the perovskite solution due to smaller crystallizing grains during the intermediate stage, which results in smaller grains and more grain boundaries during the final stage eventually. Suitable CS causes larger crystallizing perovskite grains and less spaces for the formations of new seed crystals during the intermediate stage via moderate doping of K+, and finally, the large grains without LSV pores formed. However, excessive doping can cause exorbitant CS and leads to super large crystallizing grain during the intermediate stage, so that there are almost no spaces to form new seed crystals and the solvent can only be evaporated upwards for filling of the whole space by the transverse crystallizing grains, which cause the solvent to not effectively discharge from the interior of crystallizing perovskite; as a result, LSV pores are formed inside the perovskite thin films and on its surface during the final stage. The crystallization already starts when the seed crystal form and it may be during solvent evaporation when the spin-coating or the process of chlorobenzene addition or thermal annealing occur. Irrespective, the schematic mechanism in Figure 2 is adaptive. In addition, it is worth emphasizing that new seed crystals may form at all times, and once the seed crystals form, the process described by the schematic mechanism takes place.
To back up this theory that the CS of perovskite increases with the increase in the K doping amount, we analyze the results of previous research. Uz Zaman et al. prepared K-doped perovskite thin films on FTO substrates by spin coating [35], which are hydrophobic substrates, and the perovskite solution films must shrink after spin coating, unavoidably so that the final perovskite films cannot completely cover the substrates. We can find that the coverage area of perovskite thin films increases with the increase of the K doping amount according to their SEM results [35]. The coverage rate of perovskite thin film on substrate is mainly determined by the strength of the solution thin film shrinkage and the CS of perovskite, illustrated in Figure 3. In Figure 3, the red arrow marks the shrinkage direction of the perovskite solution thin film and the small black dot represents the perovskite seed crystal. In the process of perovskite solution film shrinking, perovskite crystals are also growing in areas with perovskite precursor solution, so that stronger shrinkage strength leads to a smaller coverage rate and faster crystallization speed leads to a greater coverage rate. The shrinkage strength of the perovskite solution film is mainly determined by the solvent and substrate; however, the solvents of the perovskite precursor solutions with different K content and substrates are exactly the same, so the shrinkage strengths of perovskite solution films are almost the same. Thus, the conclusion can be reached that different crystallization speeds lead to different perovskite film coverage rates, and the crystallization speed of perovskite increases with the increase in the K doping amount. The crystallization speed of perovskite we expect can make the grain grow to a large state without localized-solvent-vapor (LSV) pores or with small number of LSV pores of which the inducing efficiency attenuation is less than the benefit from the increase in grain size. According to SEM diagrams and JV curves, the expected speed is between the speed corresponding 0.9 M and the speed corresponding 1.2 M because MAPbI3+0.9M does not have LSV pores and MAPbI3+0.9M has LSV pores, which induce efficiency attenuation. Exorbitant crystallization speed can make the grain grow to a large state with more LSV pores of which the inducing efficiency attenuation is higher than the benefit from the increase in grain size, so the speed corresponding to 1.2 M is an exorbitant crystallization speed.
Figure 4a shows XRD pattern of perovskite thin films with different doping concentration of K+ and we can find that the peak position of perovskite crystal has not been transferred, which means there is no change in the type of perovskite crystal structure via different concentration doping of K+ [36]. In addition, the perovskite film exhibits pure tetragonal phase according to Figure 4a, which indicates that the K+ enters into the perovskite lattice successfully [20]. From Figure 4b, we noticed that the perovskite crystallization is improved with the increase in the K doping amount, which indicates a longer carrier lifetime [20]. Compared to MAPbI3+0M, almost all other (040) peaks shift to lower degree in Figure 4c, which means K+ mainly occupied interstitial sites in lattices [20].
The Energy dispersive X-ray Spectroscopy (EDX) of K-doped perovskite crystallite films and the specific values of quantifying doping levels are presented in Figure 5 and Table 1, respectively. In the EDXs (Figure 5a–d), we can see that the peaks of K elements (presented in blue circle) increase with the increase in the doping concentration, which is consistent with the values in Table 1. The excess iodine coming from the KI solution can also affect the perovskite film performance, which is carried out by Equation (1) [37] and Equation (2) [37,38].
2 I− → I2 + 2 e−
I− + I2 → I3−
However, I3− can effectively decrease the concentration of defects in organic-inorganic lead halide perovskite films [38].
Figure 6a,b show the absorbance spectra and PL spectra of perovskite thin films with 0 M, 0.6 M, 0.9 M and 1.2 M, respectively. There are blue shifts of the absorption band edge wavelength and PL emission peak wavelength of MAPbI3+0.6M and MAPbI3+0.9M, and the red shift the absorption band edge wavelength and PL emission peak wavelength of MAPbI3+1.2M has taken place, compared to reference MAPbI3+0M, indicating that the energy band gap increases first and then decreases with the increase in the doping concentration of K+ [5].
Schematic illustration for the process of modulating surface morphology related to CS and optical semiconductor properties of perovskite thin films via controlled doping of K+ is shown in Figure 7. It gives a very detailed description of the process of modulating surface morphology (including grain size, surface flatness, transverse and vertical grain boundary quantity, internal LSV pores, surface LSV pores, pores in the interface between perovskite layer and M-/C-TiO2, thickness of perovskite thin film, boundary gap) and optical semiconductor properties (absorption band edge wavelength, PL emission peak wavelength, energy band gap) of perovskite thin film via controlled doping of K+ prepared in air. It is worth emphasizing that the mechanism of large K+-doped perovskite grain formation is related to CS. The doping of K+ leads to an increase in CS of perovskite grains during the intermediate stage, and results the formation of large perovskite grains during the final stage. However, excessive doping of K leads to a rapid perovskite crystallization speed that induces super large crystallizing grains and causes the solvent to not effectively discharge from crystallizing perovskite during the intermediate stage; as a result, LSV pores are formed inside the perovskite thin films and on its surface during the final stage.
The structure of the device is shown in Figure 8a. Figure 8b shows the J-V curves from RS for the devices with different doping concentrations of K+, measured under simulated sunlight (AM 1.5 G), and the detail photovoltaic parameters of PSCs is shown in the Table 2. Voc has increased significantly via controlling doping of K+, as a result of elimination of pores in the interface between the perovskite layer and M-/C-TiO2 layer. Due to larger grains in the MAPbI3+0.9M and MAPbI3+1.2M, the corresponding devices obtain higher Jsc. Although the absorption spectrum of MAPbI3+0.9M is relatively low compared to other perovskite films, its device yielded the best performance (especially the Voc and Jsc) due to prolonged carrier lifetime, improved surface morphology and crystallinity, which means the photovoltaic properties of the devices are improved via appropriate doping of K+. A promising efficiency of 8.14% was achieved for the 0.9 M K+-doped device with the carbon/FTO CE, and these simple and low-cost preparation techniques of high-class perovskite thin films and carbon/FTO CE under ambient conditions are beneficial for promoting commercialization.

4. Conclusions

The LSV-pore-free perovskite grains became significantly larger via moderate doping of K+. The mechanism of large K+-doped perovskite grain formation is related to CS and the theory that the CS of perovskite increases with the increase of K doping amount was suggested and preliminarily confirmed. The detailed description of the process of modulating surface morphology (including grain size, surface flatness, transverse and vertical grain boundary quantity, internal LSV pores, surface LSV pores, pores in the interface between MAPbI3+0M and M-/C-TiO2, thickness of perovskite thin film, boundary gap) and optical semiconductor properties (absorption band edge wavelength, PL emission peak wavelength, energy band gap) of perovskite thin film via controlled doping of K+ prepared in air was presented. A promising efficiency of 8.14% in a size of 0.2 cm2 was achieved for the device with inexpensive carbon/FTO CE under one sun illumination. Obviously, mass production of cost-efficient K+-doped PSCs, with spongy carbon/FTO CEs, under ambient atmosphere, is possible.

Author Contributions

T.L. wrote the paper. Y.Y. designed the experiments. T.L. and J.C. analyzed the data. D.C. prepared the samples. T.L. and H.R. performed all the measurements. X.Z. supervised the project. All authors commented and approved the paper.

Funding

This research was funded by the Project of the Natural Science Foundation of China (61875186), the Project of the Natural Science Foundation of Beijing (Z160002), the Opened Fund of the State Key Laboratory on Integrated Optoelectronics (IOSKL2016KF19) and the Beijing Key Laboratory for Sensors of BISTU (KF20181077203).

Conflicts of Interest

The authors declare no conflict of interest.

References

  1. Park, N.-G. Organometal perovskite light absorbers toward a 20% efficiency low-cost solid-state mesoscopic solar cell. J. Phys. Chem. Lett. 2013, 4, 2423–2429. [Google Scholar] [CrossRef]
  2. Yang, W.S.; Noh, J.H.; Jeon, J.N.; Kim, Y.C.; Ryu, S.C.; Seo, S.J.; Seok, S.I.I. High-performance photovoltaic perovskite layers fabricated through intramolecular exchange. Science 2015, 348, 1234–1237. [Google Scholar] [CrossRef] [PubMed]
  3. Saliba, M.; Matsui, T.; Domanski, K.; Seo, J.-Y.; Ummadisingu, A.; Zakeeruddin, S.M.; Correa-Baena, J.-P.; Tress, W.R.; Abate, A.; Hagfeldt, A.; et al. Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance. Science 2016, 354, 206–209. [Google Scholar] [CrossRef] [PubMed]
  4. Shin, S.S.; Yeom, E.J.; Yang, W.S.; Hur, S.; Kim, M.G.; Im, J.; Seo, J. Colloidally prepared La-doped BaSnO3 electrodes for efficient, photostable perovskite solar cells. Science 2017, 356, 167–171. [Google Scholar] [CrossRef] [PubMed]
  5. Tang, Z.G.; Uchida, S.; Bessho, T.; Kinoshita, T.; Wang, H.B.; Awai, F.; Jono, R.; Maitani, M.M.; Nakazaki, J.; Kubo, T.; et al. Modulations of various alkali metal cations on organometal halide perovskites and their influence on photovoltaic performance. Nano Energy 2018, 45, 184–192. [Google Scholar] [CrossRef]
  6. Stranks, S.D.; Eperon, G.E.; Grancini, G.; Menelaou, C.; Alcocer, M.J.P.; Leijtens, T.; Herz, L.M.; Petrozza, A.; Snaith, H.J. Electron-Solvent-vapor-pore Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber. Science 2013, 342, 341–344. [Google Scholar] [CrossRef] [PubMed]
  7. Eperon, G.E.; Burlakov, V.M.; Docampo, P.; Goriely, A.; Snaith, H.J. Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells. Adv. Funct. Mater. 2014, 24, 151–157. [Google Scholar] [CrossRef]
  8. Chen, Z.; Li, H.; Tang, Y.; Huang, X.; Ho, D.; Lee, C.-S. Shape-Controlled Synthesis of Organolead Halide Perovskite Nanocrystals and Their Tunable Optical Absorption. Mater. Res. Express 2014, 1, 015034. [Google Scholar] [CrossRef]
  9. Yin, W.J.; Shi, T.; Yan, Y. Unique Properties of Halide Perovskites as Possible Origins of the Superior Solar Cell Performance. Adv. Mater. 2014, 26, 4653–4658. [Google Scholar] [CrossRef] [PubMed]
  10. Brenner, T.M.; Egger, D.A.; Kronik, L.; Hodes, G.; Cahen, D. Hybrid organic–inorganic perovskites: Low-cost semiconductors with intriguing charge-transport properties. Nat. Rev. Mater. 2016, 1, 15007. [Google Scholar] [CrossRef]
  11. Bai, X.; Zou, X.; Zhu, J.; Pei, Y.; Yang, Y.; Jin, W.; Chen, D. Effect of Rb doping on modulating grain shape and semiconductor properties of MAPbI3 perovskite layer. Mater. Lett. 2018, 211, 328–330. [Google Scholar] [CrossRef]
  12. Yang, Y.; Zou, X.; Pei, Y.; Bai, X.; Jin, W.; Chen, D. Effect of doping of NaI monovalent cation halide on the structural, morphological, optical and optoelectronic properties of MAPbI3 perovskite. J. Mater. Sci. Mater. Electron. 2018, 29, 205–210. [Google Scholar] [CrossRef]
  13. Zhu, F.; Zhang, P.; Wu, X.; Fu, L.; Zhang, J.; Xu, D. The origin of higher open-circuit voltage in Zn-doped TiO2 nanoparticle-based dye-sensitized solar cells. ChemPhysChem 2012, 13, 3731. [Google Scholar] [CrossRef] [PubMed]
  14. Gao, Y.; Yip, H.L.; Chen, K.S.; O’malley, K.M.; Acton, O.; Sun, Y.; Ting, G.; Chen, H.; Jen, A.K.Y. Surface Doping of Conjugated Polymers by Graphene Oxide and Its Application for Organic Electronic Devices. Adv. Mater. 2011, 23, 1903. [Google Scholar] [CrossRef] [PubMed]
  15. Li, Z.; Yang, M.; Park, J.S.; Wei, S.H.; Berry, J.J.; Zhu, K. Stabilizing Perovskite Structures by Tuning Tolerance Factor: Formation of Formamidinium and Cesium Lead Iodide Solid-State Alloys. Chem. Mater. 2016, 28, 284–292. [Google Scholar] [CrossRef]
  16. Saliba, M.; Matsui, T.; Seo, J.-Y.; Domanski, K.; Correa-Baena, J.-P.; Nazeeruddin, M.K.; Zakeeruddin, S.M.; Tress, W.; Abate, A.; Hagfeldt, A.; et al. Cesium-containing triple cation perovskite solar cells: Improved stability, reproducibility and high efficiency. Energy Environ. Sci. 2016, 9, 1989–1997. [Google Scholar] [CrossRef] [PubMed]
  17. Syzgantseva, O.A.; Saliba, M.; Grätzel, M.; Rothlisberger, U. Stabilization of the Perovskite Phase of Formamidinium Lead Triiodide by Methylammonium, Cs, and/or Rb Doping. J. Phys. Chem. Lett. 2017, 8, 1191–1196. [Google Scholar] [CrossRef] [PubMed]
  18. Nam, J.K.; Chai, S.U.; Cha, W.; Choi, Y.J.; Kim, W.; Jung, M.S.; Kwon, J.; Kim, D.; Park, J.H. Potassium Incorporation for Enhanced Performance and Stability of Fully Inorganic Cesium Lead Halide Perovskite Solar Cells. Nano Lett. 2017, 17, 2028–2033. [Google Scholar] [CrossRef] [PubMed]
  19. Chang, J.; Lin, Z.; Zhu, H.; Isikgor, F.H.; Xu, Q.-H.; Zhang, C.; Hao, Y.; Ouyang, J. Enhancing the photovoltaic performance of planar heterojunction perovskite solar cells by doping the perovskite layer with alkali metal ions. J. Mater. Chem. A 2016, 4, 16546–16552. [Google Scholar] [CrossRef]
  20. Zhao, P.; Yin, W.; Kim, M.; Han, M.; Song, J. Improved carriers injection capacity in perovskite solar cells by introducing A-site interstitial defects. J. Mater. Chem. A 2017, 5, 7905–7911. [Google Scholar] [CrossRef]
  21. Bag, S.; Durstock, M.F. Large Perovskite Grain Growth in Low-Temperature Solution-Processed Planar p-i-n Solar Cells by Sodium Addition. ACS Appl. Mater. Interfaces 2016, 8, 5053–5057. [Google Scholar] [CrossRef] [PubMed]
  22. Bi, C.; Zheng, X.; Chen, B.; Wei, H.; Huang, J. Spontaneous Passivation of Hybrid Perovskite by Sodium Ions from Glass Substrates: Mysterious Enhancement of Device Efficiency Revealed. ACS Energy Lett. 2017, 2, 1400–1406. [Google Scholar] [CrossRef]
  23. Tang, Z.G.; Bessho, T.; Awai, F.; Kinoshita, T.; Maitani, M.M.; Jono, R.; Murakami, T.N.; Wang, H.B.; Kubo, T.; Uchida, S.; et al. Hysteresis-free perovskite solar cells made of potassium-doped organometal halide perovskite. Sci. Rep. 2017, 7, 12183. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  24. Yao, D.S.; Zhang, C.M.; Pham, N.D.; Zhang, Y.H.; Tiong, V.T.; Du, A.J.; Shen, Q.; Wilson, G.J.; Wang, H.X. Hindered Formation of Photo-Inactive δ-FAPbI3 Phase and Hysteresis-Free Mixed-Cation Planar Heterojunction Perovskite Solar Cells with Enhanced Efficiency via Potassium Incorporation. J. Phys. Chem. Lett. 2018, 9, 2113–2120. [Google Scholar] [CrossRef] [PubMed]
  25. Kubicki, D.J.; Prochowicz, D.; Hofstetter, A.; Zakeeruddin, S.M.; Gratzel, M.; Emsley, L. Phase Segregation in Potassium-Doped Lead Halide Perovskites from K-39 Solid-State NMR at 21.1 T. J. Am. Chem. Soc. 2018, 140, 7232–7238. [Google Scholar] [CrossRef] [PubMed]
  26. Abdi-Jalebi, M.; Andaji-Garmaroudi, Z.; Cacovich, S.; Stavrakas, C.; Philippe, B.; Richter, J.M.; Alsari, M.; Booker, E.P.; Hutter, E.M.; Pearson, A.J.; et al. Maximizing and stabilizing luminescence from halide perovskites with potassium passivation. Nature 2018, 555, 497–501. [Google Scholar] [CrossRef] [PubMed]
  27. Kubicki, D.J.; Prochowicz, D.; Hofstetter, A.; Zakeeruddin, S.M.; Gratzel, M.; Emsley, L. Phase Segregation in Cs-, Rb- and K-Doped Mixed-Cation (MA)x(FA)1−xPbI3 Hybrid Perovskites from Solid-State NMR. J. Am. Chem. Soc. 2017, 139, 14173–14180. [Google Scholar] [CrossRef] [PubMed]
  28. Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc. 2009, 131, 6050–6051. [Google Scholar] [CrossRef] [PubMed]
  29. Yang, W.S.; Park, B.-W.; Jung, E.H.; Jeon, N.J.; Kim, Y.C.; Lee, D.U.; Shin, S.S.; Seo, J.; Kim, E.K.; Noh, J.H.; et al. Iodide management in formamidinium-lead-halide-based perovskite layers for efficient solar cells. Science 2017, 356, 1376–1379. [Google Scholar] [CrossRef] [PubMed]
  30. Mei, A.; Li, X.; Liu, L.; Ku, Z.; Liu, T.; Rong, Y.G.; Xu, M.; Hu, M.; Chen, J.; Yang, Y.; et al. A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability. Science 2014, 345, 295–298. [Google Scholar] [CrossRef] [PubMed]
  31. Habisreutinger, S.N.; Leijtens, T.; Eperon, G.E.; Stranks, S.D.; Nicholas, R.J.; Snaith, H.J. Carbon nanotube/polymer composites as a highly stable hole collection layer in perovskite solar cells. Nano Lett. 2014, 14, 5561–5568. [Google Scholar] [CrossRef] [PubMed]
  32. Wei, Z.; Yan, K.; Chen, H.; Yi, Y.; Zhang, T.; Long, X.; Li, J.; Zhang, L.; Wang, J.; Yang, S. Cost-efficient clamping solar cells using candle soot for hole extraction from ambipolar perovskites. Energy Environ. Sci. 2014, 7, 3326–3333. [Google Scholar] [CrossRef]
  33. Zhang, N.; Guo, Y.; Yin, X.; He, M.; Zou, X. Spongy carbon film deposited on a separated substrate as counter electrode for perovskite-based solar cell. Mater. Lett. 2016, 182, 248–252. [Google Scholar] [CrossRef]
  34. Ling, T.; Zou, X.; Cheng, J.; Bai, X.; Ren, H.; Chen, D. Modified Sequential Deposition Route through Localized-Liquid-Liquid-Diffusion for Improved Perovskite Multi-Crystalline Thin Films with Micrometer-Scaled Grains for Solar Cells. Nanomaterials 2018, 8, 416. [Google Scholar] [CrossRef] [PubMed]
  35. Uz Zaman, M.M.; Imran, M.; Saleem, A.; Kamboh, A.H.; Arshad, M.; Khan, N.A.; Akhter, P. Potassium doped methylammonium lead iodide (MAPbI3) thin films as a potential absorber for perovskite solar cells; structural, morphological, electronic and optoelectric properties. Phys. B Condens. Matter 2017, 522, 57–65. [Google Scholar] [CrossRef]
  36. Luo, D.; Yu, L.; Wang, H.; Zou, T.; Luo, L.; Liu, Z.; Lu, Z. Cubic structure of the mixed halide perovskite CH3NH3PbI3−xClx via thermal annealing. RSC Adv. 2015, 5, 85480–85485. [Google Scholar] [CrossRef]
  37. Li, C.; Guerrero, A.; Zhong, Y.; Graser, A.; Luna, C.A.M.; Kohler, J.; Bisquert, J.; Hildner, R.; Huettner, S. Real-Time Observation of Iodide Ion Migration in Methylammonium Lead Halide Perovskites. Small 2017, 13, 1701711. [Google Scholar] [CrossRef] [PubMed] [Green Version]
  38. Sun, Q.; Gong, X.; Li, H.; Liu, S.; Zhao, X.; Shen, Y.; Wang, M. Direct formation of I3− ions in organic cation solution for efficient perovskite solar cells. Sol. Energy Mater. Sol. Cells 2018, 185, 111–116. [Google Scholar] [CrossRef]
Materials 11 01605 g001 550
Figure 1. Surface and cross-sectional SEM images for (a,e) MAPbI3+0M; (b,f) MAPbI3+0.6M; (c,g) MAPbI3+0.9M; (d,h) MAPbI3+1.2M.
Figure 1. Surface and cross-sectional SEM images for (a,e) MAPbI3+0M; (b,f) MAPbI3+0.6M; (c,g) MAPbI3+0.9M; (d,h) MAPbI3+1.2M.
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Materials 11 01605 g002 550
Figure 2. Schematic illustration for the mechanism of large K+-doped perovskite grain formation related to crystallization speed.
Figure 2. Schematic illustration for the mechanism of large K+-doped perovskite grain formation related to crystallization speed.
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Materials 11 01605 g003 550
Figure 3. Schematic illustration for the formation of different coverage rates on the hydrophobic substrate due to different solution thin film shrinkage strength and the crystallization speed of perovskite.
Figure 3. Schematic illustration for the formation of different coverage rates on the hydrophobic substrate due to different solution thin film shrinkage strength and the crystallization speed of perovskite.
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Materials 11 01605 g004 550
Figure 4. XRD patterns of perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M: (a) whole patterns; (b) enlargement of (110) crystal plane; (c) enlargement of (040) plane.
Figure 4. XRD patterns of perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M: (a) whole patterns; (b) enlargement of (110) crystal plane; (c) enlargement of (040) plane.
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Figure 5. The Energy dispersive X-ray Spectroscopy (EDX) of perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M.
Figure 5. The Energy dispersive X-ray Spectroscopy (EDX) of perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M.
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Figure 6. (a) Absorbance spectra and (b) PL spectra of perovskite thin films with 0 M, 0.6 M, 0.9 M and 1.2 M.
Figure 6. (a) Absorbance spectra and (b) PL spectra of perovskite thin films with 0 M, 0.6 M, 0.9 M and 1.2 M.
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Figure 7. Schematic illustration for the process of modulating surface morphology related to CS and optical semiconductor properties of perovskite thin film via controlled doping of K+ prepared in air.
Figure 7. Schematic illustration for the process of modulating surface morphology related to CS and optical semiconductor properties of perovskite thin film via controlled doping of K+ prepared in air.
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Figure 8. (a) Schematic illustration for the structure of devices; (b) Light current-voltage (J-V) curves from reverse scan (RS) for the devices with 0 M, 0.6 M, 0.9 M and 1.2 M under RS.
Figure 8. (a) Schematic illustration for the structure of devices; (b) Light current-voltage (J-V) curves from reverse scan (RS) for the devices with 0 M, 0.6 M, 0.9 M and 1.2 M under RS.
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Table
Table 1. EDX identified element percentages (weight %) in the perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M.
Table 1. EDX identified element percentages (weight %) in the perovskite films with 0 M, 0.6 M, 0.9 M and 1.2 M.
SampleK KC KN KO KPb MSn LI L
MAPbI3+0M05.102.350.8023.495.8462.42
MAPbI3+0.6M1.444.582.180.4921.775.4064.14
MAPbI3+0.9M1.504.591.730.3822.215.6763.92
MAPbI3+1.2M1.804.502.070.5521.715.2664.11
Table
Table 2. Photovoltaic parameters of PSCs with 0 M, 0.6 M, 0.9 M and 1.2 M under RS.
Table 2. Photovoltaic parameters of PSCs with 0 M, 0.6 M, 0.9 M and 1.2 M under RS.
DC aJsc b (mA/cm−2)Voc c (v)FF dPCE (%)
0 M11.370.750.524.43
0.6 M12.010.900.525.62
0.9 M16.330.980.518.14
1.2 M14.200.950.557.42
a DC: Doping concentration of K+; b Jsc: Short-circuit photocurrent density; c Voc: Open-circuit voltage; d FF: Fill factor.

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Ling, T.; Zou, X.; Cheng, J.; Yang, Y.; Ren, H.; Chen, D. Modulating Surface Morphology Related to Crystallization Speed of Perovskite Grain and Semiconductor Properties of Optical Absorber Layer under Controlled Doping of Potassium Ions for Solar Cells. Materials 2018, 11, 1605. https://doi.org/10.3390/ma11091605

AMA Style

Ling T, Zou X, Cheng J, Yang Y, Ren H, Chen D. Modulating Surface Morphology Related to Crystallization Speed of Perovskite Grain and Semiconductor Properties of Optical Absorber Layer under Controlled Doping of Potassium Ions for Solar Cells. Materials. 2018; 11(9):1605. https://doi.org/10.3390/ma11091605

Chicago/Turabian Style

Ling, Tao, Xiaoping Zou, Jin Cheng, Ying Yang, Haiyan Ren, and Dan Chen. 2018. "Modulating Surface Morphology Related to Crystallization Speed of Perovskite Grain and Semiconductor Properties of Optical Absorber Layer under Controlled Doping of Potassium Ions for Solar Cells" Materials 11, no. 9: 1605. https://doi.org/10.3390/ma11091605

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