Corrosion Induced on Aluminum by Biodiesel Components in Non-Oxygen Environments
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Mass Loss Assays
2.3. Surface Characterization
2.4. Characterization of Chemical Modifications
2.5. Electrochemical Assays
3. Results and Discussion
3.1. Mass Loss Measurements
3.2. Surface Morphology
3.3. Characterization of Chemical Changes
3.4. Potentiodynamic Polarization
3.5. Linear Polarization Resistance (LPR) Measurements
3.6. Electrochemical Impedance Spectroscopy (EIS)
4. Conclusions
Author Contributions
Funding
Institutional Review Board Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Methyl Stearate (MS) | ||||
---|---|---|---|---|
Temperature | No. | Product | No. | Product |
200 | 1 | Eicosanoic acid, methyl ester | 3 | Hexadecanoic acid, methyl ester |
2 | Octadecanoic acid, methyl ester | |||
280 | 2 | Octadecanoic acid, methyl ester | 5 | Decanedioic acid, dibutyl ester |
4 | Heptadecanoic acid, methyl ester | 6 | n-Heptadecane | |
5% Methyl Oleate in Methyl Stearate (MS-5% MO) | ||||
1 | Eicosanoic acid, methyl ester | 8 | Octadecanoic acid, octyl ester | |
200 | 7 | Nonadecanoic acid, methyl ester | 4 | Heptadecanoic acid, methyl ester |
2 | Octadecanoic acid, methyl ester | 3 | Hexadecanoic acid, methyl ester | |
280 | 9 | n-Hexatriacontane | 13 | n-Nonadecane |
10 | n-Pentatriacontane | 14 | n-Octadecane | |
11 | n-Heneicosane | 15 | Oxiraneoctanoic acid, 9-oxo methyl ester | |
12 | n-Eicosane | |||
5%Methyl Linoleate in Methyl Stearate (MS-5% ML) | ||||
200 | 1 | Eicosanoic acid, methyl ester | 3 | Hexadecanoic acid, methyl ester |
2 | Octadecanoic acid, methyl ester | 6 | n-Heptadecane | |
8 | Octadecanoic acid, octyl ester | 16 | Bis(2-ethylhexyl)phthalate | |
280 | 10 | n-Pentatriacontane | 18 | n-Pentadecane |
14 | n-Octadecane | 2 | Octadecanoic acid, methyl ester | |
6 | n-Heptadecane | 5 | Decanedioic, dibutyl ester | |
17 | n-Hexadecane |
Methyl Ester Mixture | T (°C) | Ecorr (V) | icorr (µA/cm2) | βa (mV/Dec) | βc (mV/Dec) |
---|---|---|---|---|---|
Blank | −1.120 | 0.529 | 443.9 | 737.1 | |
MS | 100 | −1.080 | 0.913 | 304.2 | 738.9 |
200 | −1.050 | 0.566 | 421.4 | 624.7 | |
280 | −1.130 | 0.472 | 285.3 | 397.5 | |
MS-5% MO | 100 | −1.050 | 0.895 | 279.8 | 705.9 |
200 | −1.060 | 0.476 | 270.9 | 524.1 | |
280 | −0.989 | 0.185 | 196.7 | 376.4 | |
MS-5% ML | 100 | −1.003 | 1.260 | 273.5 | 695.8 |
200 | −1.010 | 1.370 | 272.0 | 523.6 | |
280 | −1.100 | 0.544 | 292.0 | 457.7 |
Methyl Ester Mixture | 100 (°C) | 200 (°C) | 280 (°C) | ||||
---|---|---|---|---|---|---|---|
Time (h) | Rct × 106 (Ω·cm2) | Cdl × 10−6 (F·cm2) | Rct × 106 (Ω·cm2) | Cdl × 10−6 (F·cm2) | Rct × 106 (Ω·cm2) | Cdl × 10−6 (F·cm2) | |
Blank | 0 | 0.526 | 16.00 | ||||
25 | 1.010 | 5.110 | |||||
50 | 1.260 | 6.370 | |||||
75 | 1.290 | 9.970 | |||||
100 | 1.340 | 9.320 | |||||
MS | 0 | 0.325 | 2890 | 0.145 | 5.010 | 0.959 | 245 |
25 | 1.680 | 6.260 | 1.640 | 2.980 | 2.290 | 2.010 | |
50 | 2.090 | 4.350 | 3.760 | 2.510 | 4.270 | 1.670 | |
75 | 2.550 | 4.140 | 5.000 | 1.390 | 5.090 | 1.600 | |
100 | 4.430 | 3.520 | 6.250 | 0.883 | 6.090 | 1.620 | |
MS-5% MO | 0 | 0.271 | 15,600 | 0.115 | 240 | 0.951 | 67.20 |
25 | 1.950 | 2800 | 1.690 | 8.220 | 3.210 | 3.35 | |
50 | 2.940 | 3.810 | 2.630 | 0.471 | 4.890 | 0.588 | |
75 | 3.920 | 0.418 | 3.660 | 0.027 | 5.140 | 0.0127 | |
100 | 4.950 | 0.143 | 8.680 | 0.002 | 6.860 | 0.001 | |
MS-5% ML | 0 | 0.561 | 19.400 | 0.137 | 4220 | 0.920 | 136.00 |
25 | 1.940 | 17.300 | 3.920 | 101.000 | 3.960 | 60.000 | |
50 | 3.082 | 7.050 | 5.320 | 94.500 | 5.950 | 4.350 | |
75 | 5.312 | 6.510 | 7.110 | 0.165 | 6.190 | 0.154 | |
100 | 5.442 | 6.500 | 9.090 | 0.004 | 7.980 | 0.005 |
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Vergara-Juarez, F.; Porcayo-Calderon, J.; Perez-Orozco, J.P.; Acevedo-Quiroz, M.E.; Bustos-Terrones, V.; Quinto-Hernandez, A. Corrosion Induced on Aluminum by Biodiesel Components in Non-Oxygen Environments. Materials 2024, 17, 1821. https://doi.org/10.3390/ma17081821
Vergara-Juarez F, Porcayo-Calderon J, Perez-Orozco JP, Acevedo-Quiroz ME, Bustos-Terrones V, Quinto-Hernandez A. Corrosion Induced on Aluminum by Biodiesel Components in Non-Oxygen Environments. Materials. 2024; 17(8):1821. https://doi.org/10.3390/ma17081821
Chicago/Turabian StyleVergara-Juarez, Fabiola, Jesus Porcayo-Calderon, Juan Pablo Perez-Orozco, Macdiel Emilio Acevedo-Quiroz, Victoria Bustos-Terrones, and Alfredo Quinto-Hernandez. 2024. "Corrosion Induced on Aluminum by Biodiesel Components in Non-Oxygen Environments" Materials 17, no. 8: 1821. https://doi.org/10.3390/ma17081821