Next Article in Journal
Millimeter Wave Radiations Affect Membrane Hydration in Phosphatidylcholine Vesicles
Next Article in Special Issue
Amino Alcohol Oxidation with Gold Catalysts: The Effect of Amino Groups
Previous Article in Journal
Diffusion Study by IR Micro-Imaging of Molecular Uptake and Release on Mesoporous Zeolites of Structure Type CHA and LTA
Previous Article in Special Issue
Cobalt-based Catalysts for Ammonia Decomposition
Materials 2013, 6(7), 2689-2700; doi:10.3390/ma6072689

Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

1,* , 1
1 Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China 2 Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangdong, Guangzhou 510640, China 3 South African Institute for Advanced Materials Chemistry, University of the Western Cape, Cape Town 7535, South Africa
* Authors to whom correspondence should be addressed.
Received: 16 February 2013 / Revised: 7 April 2013 / Accepted: 16 April 2013 / Published: 8 July 2013
(This article belongs to the Special Issue Advances in Catalytic Materials)
View Full-Text   |   Download PDF [1056 KB, uploaded 8 July 2013]   |   Browse Figures


Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and methanol oxidation activity compared using CV and chronoamperometry (CA). While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous)/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.
Keywords: electrocatalysts; amorphous; core-shell structure; fuel cell; methanol oxidation electrocatalysts; amorphous; core-shell structure; fuel cell; methanol oxidation
This is an open access article distributed under the Creative Commons Attribution License (CC BY 3.0).

Share & Cite This Article

Further Mendeley | CiteULike
Export to BibTeX |
EndNote |
MDPI and ACS Style

Kang, J.; Wang, R.; Wang, H.; Liao, S.; Key, J.; Linkov, V.; Ji, S. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation. Materials 2013, 6, 2689-2700.

View more citation formats

Related Articles

Article Metrics

For more information on the journal, click here


[Return to top]
Materials EISSN 1996-1944 Published by MDPI AG, Basel, Switzerland RSS E-Mail Table of Contents Alert