4.1. Alteration Mapping Using ASTER Data
An overview of the lithological units and alteration zones in the Sahlabad mining area was shown using false color composites (FCC) of bands 4 (red), 6 (green), and (blue) 8 of ASTER (
Figure 5). The selected bands of ASTER have corresponded to the reflection (1.60–1.70 µm: band 4) and absorption properties (2.185–2.225 µm: band 6 and 2.295–2365 µm: band 8) related to Al-OH and Mg-Fe-OH mineral assemblages [
20,
46]. The FCC helps to distinguish some of the main lithological units such as ultrabasic rocks and ophiolite mélange (black ton), andesite (grey to brown hue), shale and sandstone (gray to brown shade), tuff (dark grey color) and limestone (whitish pink shade). Moreover, the altered zones might be depicted in pink to magenta color due to high reflectance of OH-bearing minerals in band 4 of ASTER [
20,
46].
The phyllic and argillic alteration zones have strong Al-OH adsorption properties (illite, montmorillonite, kaolinite, alunite, and muscovite) and can be represented as yellowish-pink shade (
Figure 5). The propylitic alteration regions might be mostly manifested in green tone (
Figure 5) due to the absorption properties of Fe-Mg-OH (chlorite and epidote) in band 8 [
47]. In the southeastern part of the study area, Quaternary alluvium appeared in a red to dark color (
Figure 5) attributed to high abundance of clay minerals [
47]. Considering the geological map of the study area, the rocks that have been subjected to phyllic and argillic alteration are generally associated with felsic to moderate igneous units (i.e., granodiorite and andesite) and sedimentary rocks such as sandstone and conglomerate. Altered propylitic rocks in the study area are generally associated with mafic igneous units such as basalt, ultrabasic units, andesite-basalt and andesitic lavas.
For detailed mapping of hydrothermal alteration minerals, band ratios of 4/2 (to detect iron oxide/hydroxides: gossan), 5/6 (kaolinite and alunite: argillic alteration), 7/6 (muscovite and jarosite: phyllic alteration) and 9/8 (chlorite, epidote and calcite: propylitic alteration) [
19,
42,
43] were assigned and implemented (
Figure 6A–D). Subsequently, the alteration zones were mapped in the study area. The results show that moderate to high surface distribution of gossan is typically detected in ophiolite mélange, basalt, shale and sandstone, limestone, schist, and conglomerate (
Figure 6A). Argillic alteration is widespread in the study area, which is mainly associated with shale and sandstone, ophiolite mélange, andesitic, ultrabasic rocks and conglomerate (
Figure 6B). The phyllic alteration zones show moderate to high surface distribution in many parts of the conglomerate, dacitic dyke, limestone and Quaternary sediments (
Figure 6C). Moderate to high surface distribution of propylitic alteration was mapped associated with ultrabasic rocks, basalt, andesite, ophiolite mélange shale and sandstone (
Figure 6D). Moderate to high abundance of the alteration zones, especially propylitic, gossan and argillic zones were found with copper deposits, old mines, and indices (
Figure 6A–D).
Additionally, the selective principal components analysis (SPCA) method was used to detect the spatial distribution of gossan, argillic, phyllic and propylitic alteration regions in this study. Bands 1, 2, 3 and 4 were selected to map gossan. Analyzing the eigenvector matrix of the selected bands shows the PC2 contains strong loading in band 2 (0.586388) and band 4 (−0.908873) with opposite signs (
Table 4). The positive loadings of the eigenvectors in the reflective bands (band 4) show the alterations in the form of bright pixels, while the negative loadings display the alterations in the dark pixels [
36]. Therefore, iron oxides (gossan) can be mapped as dark pixels in the PC2 image. This image is negated by multiplication to −1 to show iron oxides (gossan) in bright pixels.
Figure 7A shows pseudo-color ramp of PC2 image. Moderate to high spatial distribution of iron oxides (gossan) is mapped in andesite, ophiolite mélange, basalt, shale and sandstone, schist, limestone and conglomerate. Results are almost similar to band ratio of 4/2, although some parts of conglomerate and limestone show high surface distribution of iron oxides in the southwestern and northeastern of the study area (
Figure 7A).
Considering the eigenvector matrix of bands 1, 4, 5 and 6 for mapping argillic zone (
Table 5), the PC4 has a strong contribution of band 5 (0.777935) and band 6 (−0.595506) with reverse signs. Argillic alteration zone (kaolinite and alunite) displays absorption in band 5 (2.145–2.185 μm) [
20,
46,
47]. Thus, argillic alteration can be mapped as bright pixels in the PC4 image. A pseudo-color ramp of image PC4 is shown in
Figure 7B. Argillic alteration (strong to moderate) is mainly mapped in the shale and sandstone, ophiolite mélange, ultrabasic, some part andesitic units and conglomerate and Quaternary deposits. The results are almost identical with the band ratio of 5/6 (see
Figure 6B).
Looking at the eigenvector matrix of bands 1, 4, 6 and 7 for identifying the phyllic zone (
Table 6), it seems that the PC4 contains information for mapping this alteration zone. Strong loading in band 6 (−0.752127) with a negative sign and strong positive loading in band 6 (0.652273) is presented for the PC4. Phyllic alteration exhibits absorption in band 7 (2.235–2.285 μm) and reflectance in band 6 (2.185–2.225 μm) [
19]. Accordingly, the phyllic zone will appear as dark pixels in the PC4 image. This image is negated (by multiplication to −1) for converting the dark to bright pixels. Strong spatial distribution of phyllic zone is associated with dacitic dyke, conglomerate, limestone, basalt, tuff, andesite and quaternary sediments (
Figure 7C). The SPCA results for mapping phyllic zone are matched to band ratio of 7/6 (see
Figure 6C).
Analyzing the eigenvector matrix of bands 1, 4, 8 and 9 is considered for detecting propylitic zone (
Table 7). The PC4 has strong loading in band 8 (−0.705894) with a negative sign and strong loading in band 9 (0.707293) with a positive sign. The propylitic zone is characterized by absorption features of Fe, Mg-OH and CO
3 [
48]. The absorption features are situated in band 8 (2.295–2.365 μm) [
47]. Thus, propylitic zone can be mapped as bright pixels in the PC4 image with considering band 9 as reflectance band. Propylitic alteration is detected in ophiolite mélange, shale and sandstone, ultrabasic rocks, basalt, andesite and some parts of conglomerate, limestone, and Quaternary sediments (
Figure 7D). The identified propylitic zone is almost identical with the band ratio (9/8) results, however, SPCA shows strong surface distribution in northwestern and western parts of the study area. Propylitic, gossan and argillic zones are typically mapped in the location of copper deposits, old mines, and indices in the study area (see
Figure 6 and
Figure 7).
4.2. Geological Maps Derived from the Geochronology, Structures and Geochemistry
The host-rock of the known VMS copper deposits in the study area, namely Mesgaran, Chah-Raste and Zahri are documented as andesite, andesite-basalt and basalt units. Ultrabasic unit, ophiolite melange and schist are also related to structurally-controlled copper mineralization in the study area [
20,
31]. The geological ages of the above mentioned lithologies are Upper Cretaceous and Paleogene (see
Table 2 and
Table 3). A geochronological map of the study area was generated (
Figure 8). This map shows the spatial distribution of lithological units for the geological ages of Neogene, Upper Cretaceous, Quaternary and Paleogene. Copper deposits, old mines, and indices in the study area are mostly hosted in Upper Cretaceous and Paleogene units (
Figure 8). The three main copper deposits are placed in Upper Cretaceous units. However, old mines and some of the indices are situated in Paleogene units (see
Figure 8).
In the study area, fault systems and copper mineralization have a close relationship. The fault system controlled the trend of the host lithology of copper mineralization [
31]. Previous research in the study area confirmed that the high intensity areas (LF more than 30) is one of the most important factors in identifying copper mineralization [
31]. Accordingly, the Lineament Factor (LF) map of the study area was adopted herein (
Figure 9). The NW-SE fault systems are controlling the lithology of the host-rock for copper mineralization. The NW-SE fault systems are consistent with the main trend of lithological units related to copper deposits, old mines, and indices in the area (see
Figure 9).
Figure 10 shows the geochemical map for geochemical family of copper (Pb, Zn, Sn, Ag and Mo) in the study area. The elements Pb, Zn, Sn, Ag and Mo were considered as trace elements and predictor composition of copper mineralization in the study area. Hence, the group behavior was investigated to clarify the geochemical relationships of trace elements with the Cu. Copper deposits, old mines, and indices in the study area are mainly associated with moderate to high anomaly zones (
Figure 10).
4.3. Fusion of Information Layers
In the BPNN algorithm, the training data (see
Table 3) should be divided into two categories (30% to 70%). For this purpose, the training data were randomly divided into two groups and 70% of the group entered the artificial neural network. The result of the estimated line of copper mineralization with real points in the training data and test data is presented in
Figure 11A,B and the accuracy of the training data and test data was estimated (
Figure 11C,D). According to the results, the accuracy value for training data and test data is over 99%. This result indicates a high performance of the BPNN algorithm in predicting information about copper mineralization in the Sahlabad mining area. In other words, the information obtained from copper exploration studies in the area is practically 99% reliable and is sufficiently fit to be used in the decision-making process and the integration of information layers.
After determining the main criteria and sub-criteria in the Fuzzy-AHP method (see
Figure 4), their weights were calculated successively. A paired comparison matrix was formed for the main criteria and sub-criteria and based on expert opinions and prioritization table [
45,
46]. The main criteria and sub-criteria weights were calculated by paired comparison. Paired comparison matrices for the main criteria and sub-criteria are presented in
Table 8,
Table 9,
Table 10 and
Table 11, respectively. According to the calculations performed for each of the above paired comparison matrices, the Inconsistency Rate (IR) (%) was obtained for the main criteria and sub-criteria matrices (
Table 12). Given that all Inconsistency Rates (IRs) are less than 10%, it can be said that the consistency of the expert judgment is accepted [
45]. At information layers fuzzification stage, each information layer, which was defined as the main criteria, was fuzzified based on fuzzy logic. Fuzzy maps are shown in
Figure 12.
In the fusion of information layers based on the calculated weights step, the fuzzified information layers were integrated using AHP and based on the calculated weights. Consequently, the final fused map/potential map of copper mineralization for the Sahlabad mining area was generated (
Figure 13). In the potential map of the study area (
Figure 13), copper occurrences in the area, including copper deposits, old mines and mineral indices were plotted to validate the results. The map shows the potential copper mineralization zones (
Figure 13). The areas with the highest potential are shown in the black color spectrum and the areas with the lowest potential or barren areas are shown in the white spectrum. As can be seen in
Figure 13, all copper occurrences in the Sahlabad mining area are located in areas with high potential copper mineralization. This indicates the high validity of the results. Some new copper potential zones are also identified in northwestern and southeastern parts of the study area (
Figure 13). These zones can be considered for subsequent field campaigns and drilling programs in the Sahlabad mining area.