Wet Peroxide Oxidation of Paracetamol Using Acid Activated and Fe/Co-Pillared Clay Catalysts Prepared from Natural Clays
Abstract
:1. Introduction
2. Results and Discussion
2.1. Characterization of Materials
2.1.1. Textural Properties
2.1.2. Surface Composition
2.1.3. Acid-Base Characterization
2.2. CWPO of Paracetamol
3. Materials and Methods
3.1. Reactants and Materials
3.2. Preparation of Clay-Based Materials
3.3. Techniques of Characterization
3.4. Oxidation Runs
3.5. Analytical Techniques
4. Conclusions
Author Contributions
Funding
Conflicts of Interest
References
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Sample | SBET (m2 g−1) | VTotal (mm3 g−1) |
---|---|---|
KO-N | 26 | 69.2 |
KO-A | 28 | 94.6 |
KO-C | 24 | 74.0 |
KO-PILC | 19 | 72.3 |
AK-PILC | 13 | 27.8 |
AS-PILC | 11 | 22.1 |
KA-PILC | 13 | 46.6 |
Sample | pHPZC | Acidity (μmol g−1) | Basicity (μmol g−1) |
---|---|---|---|
KO-N | 7.8 | 350 | 245 |
KO-A | 7.2 | 987 | 614 |
KO-C | 8.0 | 338 | 270 |
KO-PILC | 7.4 | 950 | 652 |
AK-PILC | 7.2 | 812 | 538 |
AS-PILC | 7.6 | 475 | 372 |
KA-PILC | 7.4 | 687 | 627 |
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Santos Silva, A.; Seitovna Kalmakhanova, M.; Kabykenovna Massalimova, B.; G. Sgorlon, J.; Jose Luis, D.d.T.; T. Gomes, H. Wet Peroxide Oxidation of Paracetamol Using Acid Activated and Fe/Co-Pillared Clay Catalysts Prepared from Natural Clays. Catalysts 2019, 9, 705. https://doi.org/10.3390/catal9090705
Santos Silva A, Seitovna Kalmakhanova M, Kabykenovna Massalimova B, G. Sgorlon J, Jose Luis DdT, T. Gomes H. Wet Peroxide Oxidation of Paracetamol Using Acid Activated and Fe/Co-Pillared Clay Catalysts Prepared from Natural Clays. Catalysts. 2019; 9(9):705. https://doi.org/10.3390/catal9090705
Chicago/Turabian StyleSantos Silva, Adriano, Marzhan Seitovna Kalmakhanova, Bakytgul Kabykenovna Massalimova, Juliana G. Sgorlon, Diaz de Tuesta Jose Luis, and Helder T. Gomes. 2019. "Wet Peroxide Oxidation of Paracetamol Using Acid Activated and Fe/Co-Pillared Clay Catalysts Prepared from Natural Clays" Catalysts 9, no. 9: 705. https://doi.org/10.3390/catal9090705