Halogen Interactions in 2,4,5-Tribromoimidazolium Salts
AbstractThe crystal structures of 2,4,5-tribromo-1-(prop-2-ynyl)imidazole and seven new 1,3-dialkyl-2,4,5-tribromoimidazolium salts (R1 = propenyl, propynyl, dibromopropenyl; R2 = Me, Et) with halogen-containing anions (tetrafluoroborate, hexafluorophosphate, triflimide) were determined. The structures revealed halogen...halogen and anion...π interactions. Contacts of the type Br...Br, Br...F, Br...O, Br...N, F...F, H...Br, H...F, F...π and O...π were identified. Specific interactions were quantified by Hirshfeld surface analysis. View Full-Text
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Froschauer, C.; Kahlenberg, V.; Laus, G.; Schottenberger, H. Halogen Interactions in 2,4,5-Tribromoimidazolium Salts. Crystals 2012, 2, 1017-1033.
Froschauer C, Kahlenberg V, Laus G, Schottenberger H. Halogen Interactions in 2,4,5-Tribromoimidazolium Salts. Crystals. 2012; 2(3):1017-1033.Chicago/Turabian Style
Froschauer, Carmen; Kahlenberg, Volker; Laus, Gerhard; Schottenberger, Herwig. 2012. "Halogen Interactions in 2,4,5-Tribromoimidazolium Salts." Crystals 2, no. 3: 1017-1033.