Impact of Endometallofullerene on P84 Copolyimide Transport and Thermomechanical Properties
Abstract
:1. Introduction
2. Materials and Methods
2.1. Materials
2.2. Membrane Preparation
2.3. Sorption Test
2.4. Pervaporation Test
2.5. Membrane Characterization
3. Results
3.1. Mechanical and Thermal Properties
3.2. Transport Properties
3.3. Pervaporation of Methanol—Methyl Acetate Mixture
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Membrane | E, GPa | σy, MPa | σb, MPa | εb, % | Tg, °C |
---|---|---|---|---|---|
P84 | 2.41 ± 0.09 | 113 ± 2 | 113 ± 2 | 7.4 ± 0.4 | 344 |
P84/Fe@C60(0.1%) | 2.40 ± 0.07 | 112 ± 4 | 109 ± 4 | 7.8 ± 0.5 | 345 |
P84/Fe@C60(0.5%) | 2.39 ± 0.13 | 113 ± 7 | 115 ± 4 | 8.9 ± 0.6 | 346 |
P84 P84/Fe@C60(1%) | 2.39 ± 0.11 | 112 ± 4 | 97 ± 2 | 10 ± 1 | 346 |
Membrane | τ1, °C | τ5, °C | τ10, °C |
---|---|---|---|
P84 | 400 | 466 | 507 |
P84/Fe@C60(0.1%) | 406 | 472 | 508 |
P84/Fe@C60(0.5%) | 410 | 476 | 509 |
P84/Fe@C60(1%) | 400 | 463 | 503 |
Liquid | MW | Density, g/cm3 | Molar Volume, m3/mol | Boiling Point, °C | Viscosity, mPa∙s | Solubility Parameter, (J/cm3)1/2 |
---|---|---|---|---|---|---|
Methanol | 32.0 | 0.792 | 40.4 | 64.7 | 0.54 | 29.7 |
Methyl acetate | 74.1 | 0.933 | 79.4 | 57.1 | 0.36 | 19.6 |
Membrane | Sorption Degree, % | |
---|---|---|
Methanol | Methyl Acetate | |
P84 | 7.8 | 17.0 |
P84/Fe@C60(0.1%) | 11.6 | 16.8 |
P84/Fe@C60(0.5%) | 11.8 | 16.7 |
P84/Fe@C60(1%) | 12.8 | 16.0 |
Membrane | Methanol in Feed, wt % | T, °C | Flux, kg/(m2 h) | Methanol in Permeate, wt % | Separation Factor | Reference |
---|---|---|---|---|---|---|
Cuprophane | 19.9 | 45 | 0.453 | 66.3 | 7.9 | [48] |
Cuprophane | 20.8 | 30 | 0.222 | 68.0 | 8.1 | [48] |
Pervap 2255_40 | 21 | 45 | 4.1 | 45.5 | 3.1 | [29] |
Pervap 2255_50 | 16 | 45 | 1.1 | 55.0 | 6.4 | [29] |
Pervap 2255_30 | 20 | 40 | 2.44 | 54.4 | 4.8 | [46] |
PA/ND(3%) | 18 | 25 | 0.22 | 74.0 | 13.0 | [47] |
P84/Fe@C60(0.5%) | 18 | 25 | 0.072 | 64.3 | 8.2 |
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Polotskaya, G.; Putintseva, M.; Pulyalina, A.; Gofman, I.; Toikka, A. Impact of Endometallofullerene on P84 Copolyimide Transport and Thermomechanical Properties. Polymers 2018, 10, 1108. https://doi.org/10.3390/polym10101108
Polotskaya G, Putintseva M, Pulyalina A, Gofman I, Toikka A. Impact of Endometallofullerene on P84 Copolyimide Transport and Thermomechanical Properties. Polymers. 2018; 10(10):1108. https://doi.org/10.3390/polym10101108
Chicago/Turabian StylePolotskaya, Galina, Maia Putintseva, Alexandra Pulyalina, Iosif Gofman, and Alexander Toikka. 2018. "Impact of Endometallofullerene on P84 Copolyimide Transport and Thermomechanical Properties" Polymers 10, no. 10: 1108. https://doi.org/10.3390/polym10101108