Polymers

23 pages, 6896 KB

Open AccessArticle

Modeling of Polyolefin–Aluminum Bonding Technology Under Electromagnetic Energy: Using Hot-Melt Adhesives with Metallic Micro-Additives

by Romeo Cristian Ciobanu, Radu Florin Damian, Mihaela Aradoaei, Cristina Mihaela Schreiner, Alina Ruxandra Caramitu and George Ursache

Polymers 2026, 18(8), 930; https://doi.org/10.3390/polym18080930 - 10 Apr 2026

Abstract

Polyolefin bonding technologies with metal foils are extensively employed in various sectors, particularly in automotive, electronics, and aerospace industries. This research examined the innovative electromagnetic joining of polyolefins to aluminum by evaluating the behavior of hot-melt adhesives derived from polyolefins containing metallic particles. [...] Read more.

Polyolefin bonding technologies with metal foils are extensively employed in various sectors, particularly in automotive, electronics, and aerospace industries. This research examined the innovative electromagnetic joining of polyolefins to aluminum by evaluating the behavior of hot-melt adhesives derived from polyolefins containing metallic particles. The study aimed at establishing the specific absorption rate (SAR, expressed in W/kg) via electromagnetic simulation using CST Studio Suite software. It was observed that, regardless of particle size, Al was the most efficient particle, while the distribution of particles has a negligible impact on Total SAR values. The most significant beneficial effect of the inserts on the absorption capacity of the hot-melt material is primarily observed with a particle size of 1 μm. When connecting polyolefins to aluminum, the power loss density and SAR values exceed those for bonding polyolefins to polyolefins by at least 10 times, owing to aluminum’s conductive properties, which influence the absorption of additional energy in the hot melt mass, likely due to the Salisbury screen effect generated by the bonding arrangement. For hot melts made from polyethylene, a higher frequency of 5.8 GHz is suggested, which is a newly approved frequency used in advanced industrial applications. This positively impacts the effectiveness and viability of the bonding process of polyolefins to aluminum, resulting in reduced exposure times and/or decreased microwave exposure power. It was observed that the hot melts derived from HDPE and PP yielded greater SAR values. Conversely, the SAR values increase when aluminum is attached to HDPE. As a result, the strongest bond of polyolefins to Al occurs when connecting HDPE to Al using HDPE-based hot melts. The proposed simulation methodology may offer considerable improvement in evaluating the efficacy of bonding technology for dissimilar materials subjected to electromagnetic energy Full article

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30 pages, 6016 KB

Open AccessReview

Macromolecular Design Principles Governing Electrospinning of Polymer Nanofibers

by Lan Yi and Christian Dreyer

Polymers 2026, 18(8), 929; https://doi.org/10.3390/polym18080929 - 10 Apr 2026

Abstract

Electrospinning is a versatile technique for producing polymer nanofibers with high ratios of surface area to volume and tunable porosity. Conventional approach to the optimization of processing parameters such as voltage and flow rate frequently encounters limitations in reproducibility and scalability. This review [...] Read more.

Electrospinning is a versatile technique for producing polymer nanofibers with high ratios of surface area to volume and tunable porosity. Conventional approach to the optimization of processing parameters such as voltage and flow rate frequently encounters limitations in reproducibility and scalability. This review proposes a comprehensive framework that integrates macromolecular design principles with established electrohydrodynamic theories. We analyze how intrinsic molecular traits, specifically chain entanglement density, molecular weight distribution (MWD), topological architecture, and polymer–solvent thermodynamic interactions, define the boundaries of jet stability and solidification. Key findings highlight that while molecular weight establishes a baseline for spinnability, the MWD dictates the dynamic response under extreme deformation. Notably, high-molecular-weight fractions act as elastic load-bearers that suppress capillary breakup. Furthermore, we discuss here how molecular architecture and solvent-mediated segmental mobility determine whether molecular orientation is kinetically trapped or relaxed during the nanosecond timescales of jet flight. By establishing a hierarchical design logic prioritizing molecular and formulation variables over processing parameters, this framework provides a robust strategy to overcome challenges in scalability and reproducibility, positioning electrospinning as a sensitive probe for macromolecular dynamics under extreme elongation. Full article

(This article belongs to the Section Polymer Processing and Engineering)

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32 pages, 5044 KB

Open AccessArticle

Chitosan-Based Active Packaging Films Incorporating Terminalia catappa Leaf Extract and Zinc Oxide Precursors for Sustainable Food Packaging

by Prem Thongchai, Paitoon Wannapasit and Kulyada Teerasirida

Polymers 2026, 18(8), 928; https://doi.org/10.3390/polym18080928 - 10 Apr 2026

Abstract

Chitosan-based active films containing microwave-extracted Terminalia catappa leaf extract (TE) and hydrothermally synthesised zinc oxide were developed and characterised. The selected extraction condition (440 W, 20 min, followed by freeze drying) gave 29.5% extract recovery and a total phenolic content of 639.5 mg [...] Read more.

Chitosan-based active films containing microwave-extracted Terminalia catappa leaf extract (TE) and hydrothermally synthesised zinc oxide were developed and characterised. The selected extraction condition (440 W, 20 min, followed by freeze drying) gave 29.5% extract recovery and a total phenolic content of 639.5 mg GAE/g extract. Structural analyses showed that the original crystalline ZnO phase was no longer detectable after film formation under acidic casting conditions, whereas zinc remained present in the film matrix, indicating acid-mediated dissolution and/or structural transformation during casting. Zinc-containing films exhibited higher tensile strength (up to 36.0 MPa), increased glass transition temperature (up to 122.9 °C), and reduced moisture content and water vapour transmission. TE contributed antioxidant activity and light-shielding properties, with antioxidant capacity reaching 22.1 mg Trolox/g film. Films containing ≥0.2% initial ZnO also showed disc-diffusion antimicrobial activity against Escherichia coli (up to 22.7 mm) and Staphylococcus aureus (up to 20.7 mm). A preliminary 7-day banana-wrapping study further suggested that intermediate formulations containing 0.1–0.2% TE and 0.2–0.3% initial ZnO provided a useful balance among mechanical performance, optical properties, antimicrobial activity, and visual preservation. Overall, zinc–polyphenol–chitosan interactions played an important role in governing film structure and functionality. Full article

(This article belongs to the Special Issue Advances in Bio-Based Polymers for Sustainable Packaging)

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Graphical abstract

12 pages, 1100 KB

Open AccessArticle

Assessment of Flexible Pavement Containing Rubberized Asphalt

by Noorance Al-Mukaram, Tariq Al-Mansoori, Ali M. Lafta, Karzan Ismael and Pooyan Ayar

Polymers 2026, 18(8), 927; https://doi.org/10.3390/polym18080927 - 10 Apr 2026

Abstract

This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is [...] Read more.

This work deals with a practical method of using crumb rubber resulting from waste tires to produce modified bitumen via a wet mixing method for road construction in Iraq. Due to wide variation in temperatures and over-loading traffic in Iraq, rutting deformation is the most observed structural pavement problem. Also, tire wear and tear are higher in Iraq than in other countries due to high temperature and dry weather most of the year, which makes considerable amounts of waste tire piles easily accessible. Utilizing this waste material could be crucial to the environment and economy of the country, as well as to the sustainability of resources. Using waste tire materials as bitumen modifiers in the production of hot mix asphalt is a widely practiced experiment, although it is applied differently depending on the weather, type of bitumen used, and its availability. In the methodology of this research, it is suggested to modify asphalt grades 60/70 by a certain amount of crumb rubber (5–20%). The modified asphalt and asphalt grade 40/50 were used in preparing two types of asphalt concretes to examine their volumetric properties and evaluate their rutting behavior. The results for both mixtures were compared to the Iraqi General Specifications for Roads and Bridges (SORB/R9). The findings showed significant improvements in Marshall stability and flow, as well as in the percentages of voids satisfied in the modified mixture. After using rubberized asphalt in the mixture, the rutting depth was recorded below 20 mm and decreased by 30% and 26% at temperatures of 40 °C and 60 °C, respectively, compared to the controlled mixture. Full article

(This article belongs to the Special Issue Polymer Materials in Road Engineering: Performance Evolution and Mechanisms)

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13 pages, 2138 KB

Open AccessArticle

The Influence of Molecular Weight and Comonomer on the Shear Creep of Polyethylene

by Jingwen Li, Zhilan Jin, Yanshu Wang, Shicheng Zhao and Chunlin Ye

Polymers 2026, 18(8), 926; https://doi.org/10.3390/polym18080926 - 10 Apr 2026

Abstract

The occurrence of shear creep in polyethylene under applied stress results in deformation, which restricts the service life of the final product. However, the factors influencing shear creep and its underlying mechanisms remain unclear. This article investigates the effects of average molecular weight [...] Read more.

The occurrence of shear creep in polyethylene under applied stress results in deformation, which restricts the service life of the final product. However, the factors influencing shear creep and its underlying mechanisms remain unclear. This article investigates the effects of average molecular weight and comonomer on the shear creep behavior and underlying mechanisms of high-density polyethylene (HDPE). The materials chosen were HDPE with weight-average molecular weights (Mw) of 148,100, 191,800, 226,500, 252,700 and 325,100 g/mol, as well as copolymers incorporating propylene or octene as comonomers. The results indicate that creep deformation decreases with increasing Mw, and that polyethylene copolymers incorporating propylene and octene cause increased creep deformation compared to homopolymers. Dynamic mechanical analysis (DMA) and rheological testing were used to investigate the influence of Mw and comonomer on shear creep behavior. The experimental results demonstrate that increasing the weight-average molecular weight enhances molecular chain entanglement, thereby improving creep resistance. The incorporation of comonomers introduces branches into the polyethylene structure, reducing entanglement density and leading to diminished creep resistance. This study provides valuable insights and references for the development of polyethylene materials that resist shear creep. Full article

(This article belongs to the Section Polymer Chemistry)

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14 pages, 2882 KB

Open AccessArticle

Eco-Functional PVDF Mixed Matrix Membranes: Characterization and Regeneration in Natural Rubber Skim Latex Purification

by Rianyza Gayatri, Rendy Muhamad Iqbal, Wirach Taweepreda, Muzafar Zulkifli and Ahmad Naim Ahmad Yahaya

Polymers 2026, 18(8), 925; https://doi.org/10.3390/polym18080925 - 10 Apr 2026

Abstract

Concentrated natural rubber skim latex is a sustainable, value-added product derived from natural rubber latex processing, offering high rubber content, fine particle size, and shorter polymer chains compared to pure latex, making it suitable for diverse industrial applications. This study employed an environmentally [...] Read more.

Concentrated natural rubber skim latex is a sustainable, value-added product derived from natural rubber latex processing, offering high rubber content, fine particle size, and shorter polymer chains compared to pure latex, making it suitable for diverse industrial applications. This study employed an environmentally friendly ultrafiltration method using composite membranes composed of polyvinylidene fluoride (PVDF), titanium dioxide (TiO₂), and polyvinylpyrrolidone (PVP) to concentrate skim latex without hazardous chemicals. The process generated two fractions: concentrated skim latex and skim serum. Membrane performance and fouling behavior were evaluated using FESEM-EDX and FTIR. Post-filtration analysis revealed significant latex particle deposition on the membrane surface, with elemental mapping confirming the presence of organic and inorganic residues. FTIR spectra indicated interaction between latex components and membrane functional groups, though the membrane’s structural integrity remained intact. Sodium dodecyl sulfate (SDS) was assessed as a cleaning agent and demonstrated the effective partial restoration of membrane performance, as confirmed by flux recovery (PVDF-PVP-TiO₂ membrane recovered to a slightly higher flux of 7.35 L/m²h). These results highlight the membrane’s durability, fouling characteristics, and cleaning potential, supporting its reusability in latex processing. This study contributes to the development of sustainable separation technologies in the rubber industry, promoting circular economy and zero-discharge practices. Full article

(This article belongs to the Special Issue Advances in Polymeric Membrane Materials for Separation and Purification)

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23 pages, 12574 KB

Open AccessArticle

Self-Assembly of Curved Photonic Heterostructures by the Hanging Drop Method

by Ion Sandu, Claudiu Teodor Fleaca, Florian Dumitrache, Iuliana Urzica, Iulia Antohe and Marius Dumitru

Polymers 2026, 18(8), 924; https://doi.org/10.3390/polym18080924 - 9 Apr 2026

Abstract

By combining hanging-drop self-assembly with melt infiltration and selective inversion, we fabricate millimetric and free-standing curved photonic heterostructures that integrate infiltrated-opal, inverse-opal, embossed, and white-scattering 2.5D metasurface domains within a single continuous body. These architectures enable configurations inaccessible to planar fabrication, including naturally [...] Read more.

By combining hanging-drop self-assembly with melt infiltration and selective inversion, we fabricate millimetric and free-standing curved photonic heterostructures that integrate infiltrated-opal, inverse-opal, embossed, and white-scattering 2.5D metasurface domains within a single continuous body. These architectures enable configurations inaccessible to planar fabrication, including naturally formed concavities within convex inverse-opal films and alternating ordered/single-layer regions that preserve local coherence while introducing disorder at larger scales. Across these heterogeneous curved landscapes, we observe optical phenomena absent in flat photonic structures—spectrally selected lateral collimation, geometry-shifted ghost images, and transmission-derived valleys shaped by curvature-mediated Bragg extraction. Their origin lies in the geometric constraints inherent to curved assemblies, where spatially varying normals, non-parallel lattice orientations, and topologically required defects couple order and disorder into a distributed-coherence regime. This coupling expands the accessible photonic state space, establishing curvature as an active functional degree of freedom rather than a geometric constraint, positioning the self-assembled photonic heterostructures as a scalable route toward multifunctional 3D metasurfaces and new regimes of light–matter interaction. Full article

(This article belongs to the Special Issue Advances in Polymer Materials for Sensors and Flexible Electronics)

13 pages, 2646 KB

Open AccessArticle

Preparation and Properties of Electro-Blown Spinning Erythritol-Based Coaxial Phase Change Fibers

by Jiaxi Yang, Bingnan Chen, Yanxiong Qiao, Zhiguo Ma, Chuanxi Qiao, Zehao Wang, Heqiang Zheng, Zhiqiang Bian, Na Huang, Chunguang Wei, Jun Liu and Ding Nan

Polymers 2026, 18(8), 923; https://doi.org/10.3390/polym18080923 - 9 Apr 2026

Abstract

Phase change thermal storage fibers with high latent heat have attracted significant attention in thermal management and heat storage. Through fiber encapsulation, shape-stable phase change materials can be prepared, thereby expanding their applications. In this study, electro-blown spinning was utilized to prepare phase [...] Read more.

Phase change thermal storage fibers with high latent heat have attracted significant attention in thermal management and heat storage. Through fiber encapsulation, shape-stable phase change materials can be prepared, thereby expanding their applications. In this study, electro-blown spinning was utilized to prepare phase change materials (PCM) using erythritol, with polyethylene oxide (PEO) as the carrier material. Coaxial thermal storage fibers encapsulating the phase change materials were prepared using polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP). The results indicate that the composite fibers have a smooth surface, uniform and smooth morphology, a maximum latent heat of 223.01 J/g, as well as excellent thermal stability. The coaxial fibers exhibit a distinct core–shell structure, with the coaxial fibers encapsulated with PVA as the shell material, demonstrating a high latent heat of 118.62 J/g, a residual rate of 93.81% after heating, and excellent thermal performance. The encapsulation efficiency is 53%, effectively addressing the issue of erythritol leakage. The research results provide valuable guidance for the efficient preparation of erythritol coaxial thermal storage fibers. Full article

(This article belongs to the Section Polymer Fibers)

20 pages, 4718 KB

Open AccessArticle

Effective Deconstruction of Lignocellulose Through Oxidative Catalytic Fractionation Under Additive-Free Non-Alkaline System via Co-LDO Catalyst

by Haozhi Zhang, Wei Yan, Ying Wang, Cheng-Ye Ma and Changfu Zhuang

Polymers 2026, 18(8), 922; https://doi.org/10.3390/polym18080922 - 9 Apr 2026

Abstract

Oxidative catalytic fractionation (OCF) under the lignin-first strategy has emerged as a critical technological approach for biomass refining. To address the inevitable carbohydrate degradation and lignin condensation in conventional OCF, this study designed a cobalt-doped layered double hydroxide oxide (Co-LDO) catalyst compatible with [...] Read more.

Oxidative catalytic fractionation (OCF) under the lignin-first strategy has emerged as a critical technological approach for biomass refining. To address the inevitable carbohydrate degradation and lignin condensation in conventional OCF, this study designed a cobalt-doped layered double hydroxide oxide (Co-LDO) catalyst compatible with non-alkaline (without Brønsted bases) organic systems, which exhibits excellent performance in poplar biomass OCF. With a straightforward preparation process, the Co-LDO catalyst yields high-content oxidized lignin oligomers while efficiently retaining carbohydrates, providing feedstock rich in carbohydrates (cellulose and hemicellulose) for the subsequent production of bioenergy and biomass-based chemicals. Under optimized conditions screened via systematic reaction condition investigation and metal-doped LDO catalyst evaluation, the process achieved a 94.01 wt% delignification rate, with 72.19 wt% of lignin converted into lignin oligomer oil, supported by detailed product composition and structural characterization. Meanwhile, 74.14 wt% hemicellulose and 98.23 wt% cellulose were recovered in solid residues, with structurally intact hemicellulose retention being 2.3 times higher than in traditional OCF. Mass balance calculation confirmed a total poplar refining yield of 81.58 wt%. In summary, this Co-LDO-catalyzed OCF strategy provides a high-activity non-precious metal system, effectively suppressing lignin condensation while preserving high-yield carbohydrates, realizing the efficient full-component refining of poplar biomass. Full article

(This article belongs to the Topic Biomass for Energy, Chemicals and Materials)

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28 pages, 5415 KB

Open AccessArticle

Evaluation of Shear Performance of Integrated GFRP Stirrup Systems in Reinforced Concrete Beams

by Saruhan Kartal, Uğur Gündoğan, İlker Kalkan, Turki S. Alahmari, Abderrahim Lakhouit and Akin Duvan

Polymers 2026, 18(8), 921; https://doi.org/10.3390/polym18080921 - 9 Apr 2026

Abstract

This study investigates the shear behavior of glass fiber-reinforced polymer (GFRP)-reinforced concrete (RC) beams to address challenges associated with their low elastic modulus, absence of yielding, and reduced stirrup efficiency in bending regions. GFRP bars are increasingly adopted as an alternative to steel [...] Read more.

This study investigates the shear behavior of glass fiber-reinforced polymer (GFRP)-reinforced concrete (RC) beams to address challenges associated with their low elastic modulus, absence of yielding, and reduced stirrup efficiency in bending regions. GFRP bars are increasingly adopted as an alternative to steel due to their superior corrosion resistance, durability, and cost-effectiveness. This study focuses on the effects of stirrup type, stirrup spacing, and shear span-to-effective depth ratio on the structural performance of GFRP RC beams. Twelve full-scale beams were tested under four-point bending, incorporating three GFRP shear reinforcement configurations: fabricated closed stirrups, integrated straight bar systems, and discrete vertical bars. Experimental observations were analyzed in terms of failure modes, load-carrying capacity, energy absorption, and deformation characteristics. Results indicate that fabricated F-type stirrups provide the highest shear performance, though their effectiveness is limited by premature rupture at bending points. Site-integrated S- and T-type configurations offer practical alternatives, maintaining structural integrity while mitigating bend-related stress concentrations, but with slightly lower energy absorption and load capacity. Increasing stirrup spacing significantly reduces shear resistance and shifts failure from flexural to shear-dominated modes. Comparisons with widely used design codes and analytical models show that CSA S806-12 provisions offer the most reliable predictions, while other guidelines tend to over- or underestimate shear capacity depending on configuration and a/d ratio. The study highlights the importance of optimizing stirrup type and spacing to enhance the shear performance of GFRP RC beams. Findings provide valuable insights for improving current design methodologies, offering guidance for engineers seeking durable, corrosion-resistant alternatives to steel reinforcement in aggressive environments. This research demonstrates that innovative site-integrated stirrup configurations can bridge practical fabrication constraints without compromising overall shear performance, promoting more efficient and resilient GFRP RC structures. Full article

(This article belongs to the Special Issue Advances in Fiber-Reinforced Polymers for Construction: Properties and Application)

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28 pages, 5037 KB

Open AccessArticle

Sustained Delivery of Paliperidone Palmitate via Encapsulation in Bio-Based NIPU Nanoparticles

by Maria Angeliki Ntrivala, Evangelia Balla, Ermis P. Christodoulou, Margaritis Kostoglou, Panagiotis Klonos, Apostolos Kyritsis and Dimitrios N. Bikiaris

Polymers 2026, 18(8), 920; https://doi.org/10.3390/polym18080920 - 9 Apr 2026

Abstract

In this study, Paliperidone Palmitate (PP), a second-generation antipsychotic, commonly used for the treatment of schizophrenia, was encapsulated in bio-based non-isocyanate polyurethane (NIPU) nanoemulsions. NIPU was synthesized via an isocyanate-free polyaddition route, addressing safety and environmental concerns associated with conventional polyurethanes. The drug-loaded [...] Read more.

In this study, Paliperidone Palmitate (PP), a second-generation antipsychotic, commonly used for the treatment of schizophrenia, was encapsulated in bio-based non-isocyanate polyurethane (NIPU) nanoemulsions. NIPU was synthesized via an isocyanate-free polyaddition route, addressing safety and environmental concerns associated with conventional polyurethanes. The drug-loaded nanoparticles were produced utilizing oil-in-water (O/W) emulsions followed by solvent evaporation and lyophilization. NIPU concentrations of 0.3% and 0.5% w/v, as well as 0.5% w/v PVA were employed, while PP was incorporated at 0.2%, 0.5% and 1% w/v. The formulations were characterized by FTIR, DSC and XRD analyses, and the mechanical strength of neat sponges was evaluated. The nanoparticle formation and size were assessed by DLS and SEM analyses. The water contact angle, porosity measurements and aquatic and enzymatic hydrolysis were additionally performed. The resulting nanocarriers exhibited controlled particle size, increased drug-loading values, structural stability and biodegradability. Lastly, the in vitro dissolution studies revealed a system-specific burst release behavior, and a controlled and sustained overall drug-release profile for majority of the formulations, thereby indicating the potential of NIPU nanocarriers for drug delivery applications, particularly where sustained therapeutic effects are required. Full article

(This article belongs to the Special Issue Polymers and Their Role in Drug Delivery, 3rd Edition)

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27 pages, 2187 KB

Open AccessArticle

A Process Systems Engineering Approach to Model and Optimize Cr⁶⁺-Free and Pd-Free Plating on Plastics Technologies

by Konstantinos A. Pyrgakis, Eleni Poupaki, Michalis Kartsinis, Melina Psycha, Alexios Grigoropoulos, Dimitrios Zoikis-Karathanasis and Alexandros Zoikis-Karathanasis

Polymers 2026, 18(8), 919; https://doi.org/10.3390/polym18080919 - 9 Apr 2026

Abstract

Plating on Plastics (PoP) requires specific surface pre-treatment steps to enable metallization. The conventional PoP industry utilizes hexavalent chromium (toxic, carcinogenic) and palladium (critical raw material) for surface etching and activation, respectively, raising significant health, environmental, and economic concerns. This work is based [...] Read more.

Plating on Plastics (PoP) requires specific surface pre-treatment steps to enable metallization. The conventional PoP industry utilizes hexavalent chromium (toxic, carcinogenic) and palladium (critical raw material) for surface etching and activation, respectively, raising significant health, environmental, and economic concerns. This work is based on a new Cr⁶⁺-free and Pd-free PoP technology that uses piranha (H₂O₂-H₂SO₄) solutions for surface etching, nickel salts for activation, and NaBH₄ for reduction, ultimately forming metallic nucleation sites for downstream electroless plating and electroplating. A comprehensive modeling approach was developed to simulate and predict unit operation performance (reaction kinetics and yields) and material properties (contact angle and adhesion) across processing stages of the new technology. State-of-the-art and data-driven modeling revealed the combinatorial relationships among process performance, the achieved properties and the different settings of process operating conditions. The results also highlighted capabilities for tuning all processes over a range of conditions, reaching desired product specifications (adhesion and thickness). The models were constructed as a Decision Support Tool (DST) serving economic, environmental, safety and Safe and Sustainable by Design (SSbD) objectives. The DST can be used through a user-friendly interface that enables the insertion of user-defined inputs and monitoring of optimization results. Full article

(This article belongs to the Section Polymer Processing and Engineering)

36 pages, 5263 KB

Open AccessReview

Advances in Polymer Film and Coating Technologies for Enhanced Surface Functionality

by Rashid Dallaev

Polymers 2026, 18(8), 918; https://doi.org/10.3390/polym18080918 - 9 Apr 2026

Abstract

Polymer films and coatings play an increasingly critical role in extending material functionality across industrial, biomedical, and environmental applications. Recent advances in surface engineering have enabled precise control of interfacial properties, leading to enhanced durability, cleanliness, and protection. This review summarizes state-of-the-art strategies [...] Read more.

Polymer films and coatings play an increasingly critical role in extending material functionality across industrial, biomedical, and environmental applications. Recent advances in surface engineering have enabled precise control of interfacial properties, leading to enhanced durability, cleanliness, and protection. This review summarizes state-of-the-art strategies for modifying polymer surfaces, with an emphasis on plasma-based surface modification and plasma-induced polymerization as versatile, solvent-free methods for tailoring wettability, chemical functionality, and adhesion. Furthermore, it examines emerging classes of self-cleaning and self-sterilizing coatings that leverage photocatalytic, hydrophobic, or antimicrobial mechanisms to mitigate contamination, biofouling, and pathogen transmission. Additionally, developments in high-performance barrier films designed to protect food products and electronic devices through improved resistance to gases, moisture, and chemical agents are highlighted. By integrating insights from materials chemistry, surface physics, and nanostructured coating design, this review provides a comprehensive overview of current achievements and future directions in functional polymer films and coatings aimed at anti-pollution, antibacterial, and anti-corrosion performance. Full article

(This article belongs to the Special Issue Bio-Based Polymeric Materials for Biomedical Applications)

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23 pages, 12002 KB

Open AccessArticle

Mechanical Modeling of Whisker-Filled Dispersed Isotactic Polypropylene: Matrix-Dominated Yielding and Fracture Mechanisms

by Tetsuo Takayama and Daisuke Shimizu

Polymers 2026, 18(8), 917; https://doi.org/10.3390/polym18080917 - 9 Apr 2026

Abstract

This study investigated mechanical properties of composite materials consisting of an isotactic polypropylene (iPP) matrix reinforced with whisker-like fillers: carbon nanofibers (CBNF) and wollastonite (WN). We strove to develop mechanical models specifically for predicting yield stress and fracture toughness. Experimentally obtained results validated [...] Read more.

This study investigated mechanical properties of composite materials consisting of an isotactic polypropylene (iPP) matrix reinforced with whisker-like fillers: carbon nanofibers (CBNF) and wollastonite (WN). We strove to develop mechanical models specifically for predicting yield stress and fracture toughness. Experimentally obtained results validated findings obtained using the proposed models. Regarding the elastic modulus, data suggest that conventional rules of mixture, typically used for glass fiber-reinforced polymers, remain applicable, indicating that filler addition enhances stiffness in a predictable manner. However, yield stress and fracture toughness exhibited distinct behaviors. Results revealed that these properties are governed predominantly by shear yielding of the iPP matrix rather than reinforcement effect of the fillers. Despite the presence of whiskers, the overall yield and fracture mechanisms depend heavily on the matrix’s plastic deformation and energy dissipation. The constructed models consistently explain these findings, supporting quantitative evaluation of the matrix’s contribution. These results emphasize that developing high-performance iPP composites requires knowledge of the intrinsic ductile properties of the matrix alongside filler selection and dispersion. Full article

(This article belongs to the Section Polymer Physics and Theory)

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23 pages, 3570 KB

Open AccessArticle

Development and Performance Evaluation of a Novel Epoxy-Modified Bitumen for Large-Void Porous Asphalt Concrete (LV-PAC)

by Xing Huang, Dongwei Cao, Qian Zhou, Changjing Xu, Hongmei Wei, Wentao Yang and Mingming Zhang

Polymers 2026, 18(8), 916; https://doi.org/10.3390/polym18080916 - 9 Apr 2026

Abstract

To address the limited drainage capacity of conventional porous asphalt pavements under high-intensity rainfall, this study proposes the use of epoxy-modified bitumen to develop a large-void porous asphalt concrete (LV-PAC) with a target air void content of 25%. This approach represents a novel [...] Read more.

To address the limited drainage capacity of conventional porous asphalt pavements under high-intensity rainfall, this study proposes the use of epoxy-modified bitumen to develop a large-void porous asphalt concrete (LV-PAC) with a target air void content of 25%. This approach represents a novel application of epoxy-modified bitumen to enhance permeability in porous pavement systems. The LV-PAC exhibited improved high-temperature stability, permeability, and clogging recovery capability compared with a conventional high-viscosity porous asphalt concrete (HV-PAC), though its low-temperature deformation capacity was relatively lower. All evaluated performance indicators met the required specifications, highlighting the potential of epoxy-modified bitumen for use in large-void porous pavements pending further field validation. Full article

(This article belongs to the Section Innovation of Polymer Science and Technology)

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25 pages, 8514 KB

Open AccessArticle

Fatigue Life Evaluation and Structural Optimization of Rubber Damping Components in Metro Resilient Wheels

by Qiang Zhang, Zhiming Liu, Yiliang Shu, Guangxue Yang and Wenhan Deng

Polymers 2026, 18(8), 915; https://doi.org/10.3390/polym18080915 - 9 Apr 2026

Abstract

Resilient wheels are widely employed in metro vehicles to mitigate vibration and noise, in which rubber damping components play a critical role in load transmission and fatigue resistance. However, stress concentration and cyclic loading can significantly compromise their durability and service life. In [...] Read more.

Resilient wheels are widely employed in metro vehicles to mitigate vibration and noise, in which rubber damping components play a critical role in load transmission and fatigue resistance. However, stress concentration and cyclic loading can significantly compromise their durability and service life. In this study, the structural optimization and fatigue life of rubber damping components in resilient wheels are systematically investigated based on finite element analysis and in-service metro operational data. A three-dimensional finite element model incorporating hyperelastic material behavior is developed to evaluate stress distributions under three representative conditions: press-fit assembly, straight-line operation, and curved-track operation. Based on the resulting stress fields, critical high-stress regions within the rubber component are identified and selected as targets for structural optimization. The Design of Experiments (DOE) methodology, integrated with the Isight 2022 optimization platform, is employed to determine the optimal geometric parameters that minimize the von Mises equivalent stress. Furthermore, a fatigue life prediction framework is established using actual metro service mileage data. Fatigue performance is assessed using Fe-safe 2022 software in conjunction with rubber fatigue crack propagation theory, and the results before and after optimization are systematically compared. This study demonstrates that stress concentrations in resilient wheel rubber damping components predominantly occur at fillet transition regions, governed by load transfer characteristics under press-fitting and service conditions. Through DOE-based structural optimization, the critical geometric parameters are effectively refined, leading to a significant reduction in stress levels in key regions. As a result, the proposed approach markedly improves fatigue performance, extending the minimum fatigue life from 1300 days to 24,322 days, thereby substantially enhancing the durability and reliability of the resilient wheel system. Full article

(This article belongs to the Section Polymer Processing and Engineering)

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21 pages, 2745 KB

Open AccessArticle

Geopolymer-Based Solution for the Stabilization of Iron Ore Tailings Byproduct

by Gabriella Melo de Deus Vieira, Roberto Aguiar dos Santos, Matheus Navarra Satuf Muniz, Átila Geraldo Rochido dos Santos, José Wilson dos Santos Ferreira and Michéle Dal Toé Casagrande

Polymers 2026, 18(8), 914; https://doi.org/10.3390/polym18080914 - 9 Apr 2026

Abstract

This study investigated the development of a perlite waste-based geopolymer for stabilizing iron ore tailings byproduct (IOTB) for geotechnical applications. Mixtures containing 70/30 and 80/20 proportions of byproduct and geopolymer were produced using perlite waste as the precursor and NaOH as the alkaline [...] Read more.

This study investigated the development of a perlite waste-based geopolymer for stabilizing iron ore tailings byproduct (IOTB) for geotechnical applications. Mixtures containing 70/30 and 80/20 proportions of byproduct and geopolymer were produced using perlite waste as the precursor and NaOH as the alkaline activator through the one-part method. Raw and geopolymer-stabilized IOTB, air-cured for 7, 14, and 28 days, were evaluated by ICP-OES, XRF, pH, geotechnical characterization, compaction, permeability, SEM, and consolidated drained triaxial tests under confining stresses ranging from 250 to 2000 kPa. The selected mixture presented a maximum dry density of 1.8 g/cm³ and optimum moisture content of approximately 14%. XRD results indicated sodium aluminosilicate phases associated with geopolymerization, with mechanical characteristics comparable to feldspar-type structures, while the pH increased from 6.5 to 12.5. Triaxial tests indicated that elastoplastic behavior persisted regardless of the geopolymer addition; however, SEM images confirmed matrix–particle bonding at grain contacts without significant pore filling. The cohesive intercept increased from 0 kPa in the IOTB to 89.1 kPa and 179.2 kPa after 14 and 28 days of curing, respectively, while the friction angle showed a slight increase of up to 7.7%. Deviatoric stress at failure and energy absorption capacity also increased with curing time. Hydraulically, the permeability coefficient remained within the same order of magnitude (10⁻⁴ cm/s), varying from raw IOTB of 2.73 × 10⁻⁴ cm/s to 3.28 × 10⁻⁴ cm/s after 28 days. These results demonstrated that geopolymer stabilization enhanced mechanical performance without compromising drainage capacity, representing a technically viable and socio-environmentally sustainable solution. Full article

(This article belongs to the Section Polymer Applications)

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19 pages, 3777 KB

Open AccessArticle

Structure–Property Relationships in PHB-Based Copolymers and PHB/PLA Biocomposites Modified with Hydroxyapatite and Chitosan

by Yang Liu, Handuo Niu, Dongwei Li, Wei Nie, Ihor Semeniuk and Nataliia Koretska

Polymers 2026, 18(8), 913; https://doi.org/10.3390/polym18080913 - 9 Apr 2026

Abstract

The challenge of substituting bone defects necessitates the search for effective biomaterials based on biopolymer composites with biocompatible fillers. A promising approach in bone tissue engineering is the use of regenerative scaffolds based on polyhydroxyalkanoates (PHAs), specifically poly(3-hydroxybutyrate)—P(3HB), which are characterized by high [...] Read more.

The challenge of substituting bone defects necessitates the search for effective biomaterials based on biopolymer composites with biocompatible fillers. A promising approach in bone tissue engineering is the use of regenerative scaffolds based on polyhydroxyalkanoates (PHAs), specifically poly(3-hydroxybutyrate)—P(3HB), which are characterized by high biocompatibility and osteoinductive potential. In this study, we evaluate the changes in the mechanical, thermal, and morphological properties of P(3HB) within P(3HB)-copolymers/HA, P(3HB)/CS, P(3HB)/PLA/CS, and P(3HB)/PLA/HA composites. These materials, containing various filler contents (up to 70 wt.% of HA–hydroxyapatite or CS–chitosan), were obtained using melt extrusion compounding. It is shown that the modification of biopolymer matrices promotes a decrease in melting temperature, improvement of mechanical characteristics, and an increase in material elasticity. At high filler concentrations, nanoparticle agglomeration and a deterioration of physical-mechanical properties were observed. It was established that a content of 10–20 wt.% of nano-hydroxyapatite and chitosan is optimal, as these composites most closely match the mechanical properties of bone tissue. The results obtained indicate the high potential of the developed nanocomposites for the creation of biodegradable implants in reconstructive orthopedics. Full article

(This article belongs to the Special Issue Processing, Property and Application of Degradable Polymers and Polymeric Composites)

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22 pages, 2681 KB

Open AccessArticle

Fracture and Fatigue Assessment of Bonded Composite Patch Repairs in Notched and Cracked Plates

by Bertan Beylergil, Hasan Ulus, Mehmet Emin Çetin, Halil Burak Kaybal, Sefa Yildirim, Abdulrahman Al-Nadhari and Mehmet Yildiz

Polymers 2026, 18(8), 912; https://doi.org/10.3390/polym18080912 - 8 Apr 2026

Abstract

This study presents a unified mechanics-based framework for evaluating bonded composite patch repairs. Discrete fracture, fatigue, and adhesive responses are transformed into continuous master equations over the design space. Low-order polynomial surfaces model stress intensity and concentration responses, enabling continuous prediction of repair [...] Read more.

This study presents a unified mechanics-based framework for evaluating bonded composite patch repairs. Discrete fracture, fatigue, and adhesive responses are transformed into continuous master equations over the design space. Low-order polynomial surfaces model stress intensity and concentration responses, enabling continuous prediction of repair performance without repeated finite-element analyses. A fracture-based repair efficiency index is derived from the analytical master surface. This index quantifies the average reduction in crack-driving force across the domain. Combined with adhesive stiffness and strength, it defines an adhesive-based repair efficiency index (A-REI), providing a direct link between structural response and material properties. The results show that repair effectiveness is strongly influenced by both geometric severity and adhesive properties. Fatigue performance decreases significantly with increasing notch ratio in single-sided repairs. Double-sided configurations maintain consistently higher efficiency. Symmetric reinforcement more effectively reduces stress concentration, with improvements exceeding 40% at intermediate notch ratios. Adhesive selection is governed by stiffness and strength. Structural adhesives achieve significantly higher A-REI values, whereas compliant adhesives contribute negligibly. Overall, repair symmetry controls the magnitude of improvement, while adhesive properties determine performance ranking. This framework provides a clear, practical basis for design and material selection. Full article

(This article belongs to the Special Issue Advanced Polymer Composites with High Mechanical Properties)

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Polymers

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