Impact of Ionic Strength and Charge Density on Donnan Potential in the NaCl-Cation Exchange Membrane System
Abstract
:1. Introduction
2. Theory
2.1. The Donnan Equilibrium Theory
2.2. Effect of Osmotic Pressure on Donnan’s Potential
2.3. The Debye–Huckel Theory
2.4. The Meissner Corresponding State Model
2.5. Numerical Solution Strategy
3. Results and Discussion
3.1. Model Verification
3.2. Effects of Osmotic Pressure, Ionic Adsorption, and Ionic Pairing on Donnan Potential
3.3. Effects of Membrane Fixed Charge Density and Electrolyte Concentration
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Conflicts of Interest
Disclaimer
References
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Al-Sakaji, B.A.K.; Husseini, G.A.; Darwish, N.A. Impact of Ionic Strength and Charge Density on Donnan Potential in the NaCl-Cation Exchange Membrane System. Water 2023, 15, 3830. https://doi.org/10.3390/w15213830
Al-Sakaji BAK, Husseini GA, Darwish NA. Impact of Ionic Strength and Charge Density on Donnan Potential in the NaCl-Cation Exchange Membrane System. Water. 2023; 15(21):3830. https://doi.org/10.3390/w15213830
Chicago/Turabian StyleAl-Sakaji, Baraa A. K., Ghaleb A. Husseini, and Naif A. Darwish. 2023. "Impact of Ionic Strength and Charge Density on Donnan Potential in the NaCl-Cation Exchange Membrane System" Water 15, no. 21: 3830. https://doi.org/10.3390/w15213830