Surfactant-Assisted Fabrication of Alumina-Doped Amorphous Silica Nanofiltration Membranes with Enhanced Water Purification Performances
Abstract
:1. Introduction
2. Experimental
2.1. Sol-Synthesis and Membrane Fabrication
2.2. Membrane Characterization
2.3. Filtration Tests
3. Results and Discussion
3.1. Impact of CTAB Concentration on Membrane Porosity
3.2. Concentration of the Coating Sol
3.3. Optimization of the S/O Ratio
3.4. Filtration of A Wastewater Treatment Plant Effluent
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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S/O # | Reaction Time (h) | TEOS:Ethanol (mol:mol) | Al2O3:SiO2 (mol%) | Al2O3 + SiO2 Concentration § (g·L−1) |
---|---|---|---|---|
Membrane samples with different sol dilutions | ||||
0.25 | 15 | 1:4 | 5% | 11.8 |
0.25 | 15 | 1:4 | 5% | 8.7 |
0.25 | 10 | 1:4 | 5% | 6.5 |
Membrane samples with different CTAB concentrations | ||||
0.25 | 10 | 1:4 | 5% | 6.5 |
0.5 | 10 | 1:4 | 5% | 6.5 |
1 | 10 | 1:8 * | 5% | 6.5 |
2 | 20 | 1:12 * | 5% | 6.5 |
4 | 40 | 1:32 * | 5% | 6.5 |
Wastewater Treatment Plan Effluent (ppm) | Permeate S/O = 0.5 (ppm) | Permeate S/O = 2 (ppm) | |
---|---|---|---|
Cl− | 92.1 | 67.5 | 56.5 |
NO3− | 20.2 | 12.0 | 14.4 |
SO42− | 40.9 | 15.7 | 13.0 |
Na+ | 103 | 16.0 | 14.4 |
K+ | 27.2 | 2.95 | 3.53 |
Mg2+ | 7.1 | 0.11 | 0.11 |
Ca2+ | 92 | 0.77 | 0.82 |
TOC (total organic carbon) | 8.51 | 1.26 | 1.31 |
TC (total carbon) | 69.0 | 6.59 | 6.97 |
IMI | 3 × 10−5 | - | - |
CBZ | 8.4 × 10−4 | 2.3 × 10−5 | 3.4 × 10−5 |
BZT | 1.7 × 10−4 | - | - |
MBZT | 1.7 × 10−3 | 1.5 × 10−5 | 2.0 × 10−5 |
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Ma, X.; Janowska, K.; Boffa, V.; Fabbri, D.; Magnacca, G.; Calza, P.; Yue, Y. Surfactant-Assisted Fabrication of Alumina-Doped Amorphous Silica Nanofiltration Membranes with Enhanced Water Purification Performances. Nanomaterials 2019, 9, 1368. https://doi.org/10.3390/nano9101368
Ma X, Janowska K, Boffa V, Fabbri D, Magnacca G, Calza P, Yue Y. Surfactant-Assisted Fabrication of Alumina-Doped Amorphous Silica Nanofiltration Membranes with Enhanced Water Purification Performances. Nanomaterials. 2019; 9(10):1368. https://doi.org/10.3390/nano9101368
Chicago/Turabian StyleMa, Xianzheng, Katarzyna Janowska, Vittorio Boffa, Debora Fabbri, Giuliana Magnacca, Paola Calza, and Yuanzheng Yue. 2019. "Surfactant-Assisted Fabrication of Alumina-Doped Amorphous Silica Nanofiltration Membranes with Enhanced Water Purification Performances" Nanomaterials 9, no. 10: 1368. https://doi.org/10.3390/nano9101368
APA StyleMa, X., Janowska, K., Boffa, V., Fabbri, D., Magnacca, G., Calza, P., & Yue, Y. (2019). Surfactant-Assisted Fabrication of Alumina-Doped Amorphous Silica Nanofiltration Membranes with Enhanced Water Purification Performances. Nanomaterials, 9(10), 1368. https://doi.org/10.3390/nano9101368