Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells
Abstract
:1. Introduction
2. Materials and Methods
2.1. CuCrO2 (CCO) and Mg:CCO Preparation
2.1.1. Nanoparticle Synthesis
2.1.2. Suspension Preparation
2.1.3. Film Preparation
2.2. Materials Characterizaton
2.3. Solar Cell Fabrication and Testing
2.3.1. P3HT:PC61BM OSCs
2.3.2. PFBT2Se2Th:PC71BM OSCs
2.3.3. PTB7-Th:ITIC OSCs
2.3.4. MAPbI3 PSCs
3. Results and Discussion
3.1. Structural, Compositional, and Morphological Characterizations
3.2. Optical and Electronic Characterizations
3.3. CCO and Mg:CCO as HTLs in OSCs and PSCs
4. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
References
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Sample | CCO | 5% Mg:CCO | 10% Mg:CCO |
---|---|---|---|
Polytype composition (%) | 3R-CCO = 59.1 ± 3.0 | 3R-CCO = 59.5 ± 2.6 | 3R-CCO = 56.0 ± 2.7 |
2H-CCO = 40.9 ± 3.0 | 2H-CCO = 40.5 ± 2.6 | 2H-CCO = 44.0 ± 2.7 | |
Rwp (%) 1 | 13.3 | 13.7 | 13.4 |
Rexp (%) 2 | 9.0 | 9.0 | 9.1 |
Rp (%) 3 | 9.0 | 10.9 | 10.5 |
Χ2 | 2.2 | 2.3 | 2.2 |
Crystal size (nm) based on (004) | 7.8 ± 0.4 (2H-CCO) | 5.6 ± 0.3 (2H-CCO) | 4.5 ± 0.3 (2H-CCO) |
Crystal size (nm) based on (110) | 9.6 ± 0.9 (3R-CCO) | 9.4 ± 0.9 (3R-CCO) | 8.7 ± 1.0 (3R-CCO) |
10.2 ± 1.0 (2H-CCO) | 12.3 ± 1.3 (2H-CCO) | 13.1 ± 1.5 (2H-CCO) | |
Lattice parameter a 4 and c 5 (Å) for 3R-CCO | a = 2.99 | a = 2.99 | a = 3.00 |
c =17.44 | c =17.44 | c =17.44 | |
Lattice parameter a and c (Å) for 2H-CCO | a = 2.99 | a = 2.99 | a = 3.00 |
c =11.43 | c =11.44 | c =11.46 |
Sample | CCO | 5% Mg:CCO | 10% Mg:CCO |
---|---|---|---|
Mg/(Mg+Cr) (%) 1 | 0 | 4.0 ± 0.2 | 9.8 ± 1.3 |
Nanoparticle size (nm) 2 | 10.3 ± 2.1 | 8.2 ± 2.1 | 9.8 ± 3.0 |
Sample | Thickness (nm) | Direct Eg (eV) 1 | WFmedian – IEmedian (eV) |
---|---|---|---|
CCO | 18 | 3.27 ± 0.02 | 0.08 |
5% Mg:CCO | 18 | 3.25 ± 0.03 | 0.09 |
10% Mg:CCO | 18 | 3.27 ± 0.03 | 0.16 |
Device Type 1 | HTL_Type | Jsc (mA cm−2) | Voc (V) | FF | PCE (%) |
---|---|---|---|---|---|
P3HT:PC61BM | CCO | 6.94± 0.15 | 0.570 ± 0.000 | 0.685 ± 0.008 | 2.71 ± 0.06 |
5% Mg:CCO | 7.04 ± 0.11 | 0.583 ± 0.005 | 0.642 ± 0.022 | 2.63 ± 0.08 | |
10% Mg:CCO | 7.06 ± 0.11 | 0.581 ± 0.007 | 0.666 ± 0.017 | 2.73 ± 0.03 | |
PFBT2Se2Th:PC71BM | CCO | 10.50 ± 0.29 | 0.666 ± 0.007 | 0.684 ± 0.014 | 4.78 ± 0.18 |
5% Mg:CCO | 10.77 ± 0.61 | 0.664 ± 0.007 | 0.689 ± 0.011 | 4.93 ± 0.26 | |
10% Mg:CCO | 10.88 ± 0.50 | 0.665 ± 0.007 | 0.678 ± 0.011 | 4.91 ± 0.27 | |
PTB7-Th:ITIC | CCO | 11.55 ± 0.17 | 0.786 ± 0.007 | 0.548 ± 0.010 | 4.97 ± 0.14 |
5% Mg:CCO | 11.87 ± 0.15 | 0.793 ± 0.005 | 0.559 ± 0.003 | 5.26 ± 0.08 | |
10% Mg:CCO | 12.02 ± 0.27 | 0.785 ± 0.007 | 0.541 ± 0.011 | 5.11 ± 0.22 | |
MAPbI3 PSC (forward scan) | CCO | 18.91± 0.43 | 0.985 ± 0.058 | 0.678 ± 0.025 | 12.64 ± 0.99 |
5% Mg:CCO | 19.26 ± 0.54 | 1.003 ± 0.010 | 0.696 ± 0.023 | 13.45 ± 0.44 | |
10% Mg:CCO | 19.40 ± 0.39 | 1.007 ± 0.014 | 0.703 ± 0.018 | 13.73 ± 0.34 | |
MAPbI3 PSC (reverse scan) | CCO | 18.70± 0.31 | 1.012 ± 0.006 | 0.697 ± 0.031 | 13.19 ± 0.71 |
5% Mg:CCO | 19.20 ± 0.41 | 1.011 ± 0.004 | 0.719 ± 0.012 | 13.96 ± 0.33 | |
10% Mg:CCO | 19.37 ± 0.35 | 1.014 ± 0.006 | 0.719 ± 0.012 | 14.12 ± 0.28 |
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Zhang, B.; Thampy, S.; Dunlap-Shohl, W.A.; Xu, W.; Zheng, Y.; Cao, F.-Y.; Cheng, Y.-J.; Malko, A.V.; Mitzi, D.B.; Hsu, J.W.P. Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells. Nanomaterials 2019, 9, 1311. https://doi.org/10.3390/nano9091311
Zhang B, Thampy S, Dunlap-Shohl WA, Xu W, Zheng Y, Cao F-Y, Cheng Y-J, Malko AV, Mitzi DB, Hsu JWP. Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells. Nanomaterials. 2019; 9(9):1311. https://doi.org/10.3390/nano9091311
Chicago/Turabian StyleZhang, Boya, Sampreetha Thampy, Wiley A. Dunlap-Shohl, Weijie Xu, Yangzi Zheng, Fong-Yi Cao, Yen-Ju Cheng, Anton V. Malko, David B. Mitzi, and Julia W. P. Hsu. 2019. "Mg Doped CuCrO2 as Efficient Hole Transport Layers for Organic and Perovskite Solar Cells" Nanomaterials 9, no. 9: 1311. https://doi.org/10.3390/nano9091311