CoFe2O4/MoS2@Au: Multifunction Z-Scheme Heterojunction for SERS Monitoring and Photocatalytic Degradation of Fungicides
Abstract
:1. Introduction
2. Experimental
2.1. Reagents and Materials
2.2. Instruments
2.3. Synthesis of CoFe2O4/MoS2@Au
2.4. Photocatalytic Degradation
2.5. The Water Remediation Capability
2.6. Evaluation of SERS Activity and Analysis Procedures for Fungicides
2.7. In Situ Monitoring the Photodegradation Process
2.8. Application to Actual Samples
2.9. Statistical Analysis
3. Results and Discussion
3.1. Characterization of As-Prepared Samples
3.2. Photocatalytic Activities
3.3. Photoelectric Properties of Samples
3.4. Water Remediation and Phytotoxicity Tests of ACMS in Water
3.5. SERS Performance of ACMS
3.6. In Situ Photodegradation Monitoring
3.7. Detection of MG in Crucian Carp Samples
4. Conclusions
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Substrate | Targets/Concentration | Catalytic Conditions | Recovery Time | Ref. |
---|---|---|---|---|
30% In2S3/Bi2WO6 | Tetracycline hydrochloride, 20 mg/L | Visible light | 96.0%, 120 min | [23] |
Bi3O4Cl/Bi2MoO6 | Norfloxacin, 10 mg/L | Visible light | 87.34%, 150 min | [24] |
Bi2S3/SnS2/Bi2O3 | CV, 5 mg/L | Visible light | 90 min, 99.6% | [25] |
Fe2O3/GO/WO3 | CV, 20 mg/L | Solar light | 95.4%, 120 min | [26] |
ACMS | CV, 37.5 mg/L | Solar light | 94.76%, b90 min | This work |
Samples | Average Root Length (cm) | Germination Rate | Germination Index |
---|---|---|---|
Water | 8.7125 | 100 | 1 |
Treated wastewater | 8.4 | 100 | 0.9641 |
CV solution | 2.456 | 93.75 | 0.2819 |
Sample | Added Mount (mg/kg) | Detected a ± SD b (mg/kg) | Recovery (%) |
---|---|---|---|
1 | 0.5 | 0.528 ± 0.039 | 105.60 |
2 | 0.1 | 0.116 ± 0.051 | 116.00 |
3 | 0.05 | 0.048 ± 0.009 | 96.00 |
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Dong, Q.; Wei, Q.; Pu, H. CoFe2O4/MoS2@Au: Multifunction Z-Scheme Heterojunction for SERS Monitoring and Photocatalytic Degradation of Fungicides. Separations 2023, 10, 526. https://doi.org/10.3390/separations10100526
Dong Q, Wei Q, Pu H. CoFe2O4/MoS2@Au: Multifunction Z-Scheme Heterojunction for SERS Monitoring and Photocatalytic Degradation of Fungicides. Separations. 2023; 10(10):526. https://doi.org/10.3390/separations10100526
Chicago/Turabian StyleDong, Qirong, Qingyi Wei, and Hongbin Pu. 2023. "CoFe2O4/MoS2@Au: Multifunction Z-Scheme Heterojunction for SERS Monitoring and Photocatalytic Degradation of Fungicides" Separations 10, no. 10: 526. https://doi.org/10.3390/separations10100526