Spin Canting and Weak Ferromagnetism in a New 2D Coordination Polymer with the Co(II) Chain Bridged by a Single End-to-End Azide
Abstract
:1. Introduction
2. Results and Discussion
2.1. Syntheses and Characterization of Compound 1
2.2. Description of Structure of {[Co(N3)(bpmb)(H2O)2](NO3)·H2O}n (1)
2.3. Magnetic Properties
3. Experimental
3.1. Materials and Methods
3.2. Synthesis of {[Co(N3)(bpmb)(H2O)2](NO3)·H2O}n (1)
3.3. X-ray Crystallography
3.4. Physical Measurements
4. Conclusions
Supplementary Materials
Author Contributions
Funding
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Formula | C14H16CoN8O6 |
---|---|
Fw | 451.28 |
Crystal system | Monoclinic |
Space group | Cc |
a/Å | 14.0163(4) |
b/Å | 6.0132(2) |
c/Å | 20.9136(6) |
α/° | 90 |
β/° | 91.6740(10) |
γ/° | 90 |
V/Å3 | 1761.90(9) |
Z | 4 |
T/K | 110(2) |
Dc/g cm−3 | 1.701 |
μ/mm−1 | 1.029 |
Rint | 0.0241 |
θmax/° | 34.983 |
Goodness-of-fits on F2 | 1.030 |
R11, wR22 (all data) | 0.0257, 0.0565 |
R11, wR22 (I > 2σ (I)) | 0.0260, 0.0566 |
Flack | 0.490(14) |
Compound 1 | |||
---|---|---|---|
Co(1)–O(2) | 2.061(2) | Co(1)–N(7) | 2.111(3) |
Co(1)–O(1) | 2.085(2) | Co(1)–N(1) | 2.152(3) |
Co(1)–N(5) | 2.103(2) | Co(1)–N(4) | 2.162(3) |
O(2)–Co(1)–O(1) | 178.81(10) | N(5)–Co(1)–N(1) | 94.87(10) |
O(2)–Co(1)–N(5) | 87.42(10) | N(7)–Co(1)–N(1) | 87.13(11) |
O(1)–Co(1)–N(5) | 91.46(10) | O(2)–Co(1)–N(4) | 92.35(9) |
O(2)–Co(1)–N(7) | 91.57(11) | O(1)–Co(1)–N(4) | 87.17(10) |
O(1)–Co(1)–N(7) | 89.53(11) | N(5)–Co(1)–N(4) | 86.35(10) |
N(5)–Co(1)–N(7) | 177.75(12) | N(7)–Co(1)–N(4) | 91.69(10) |
O(2)–Co(1)–N(1) | 89.56(10) | N(1)–Co(1)–N(4) | 177.78(12) |
O(1)–Co(1)–N(1) | 90.95(9) | N(6) 1–N(7)–Co(1) | 132.9(3) |
N(6)–N(5)–Co(1) | 129.2(3) |
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Kuo, Y.-L.; Liu, H.-K.; Yang, C.-I. Spin Canting and Weak Ferromagnetism in a New 2D Coordination Polymer with the Co(II) Chain Bridged by a Single End-to-End Azide. Inorganics 2023, 11, 444. https://doi.org/10.3390/inorganics11110444
Kuo Y-L, Liu H-K, Yang C-I. Spin Canting and Weak Ferromagnetism in a New 2D Coordination Polymer with the Co(II) Chain Bridged by a Single End-to-End Azide. Inorganics. 2023; 11(11):444. https://doi.org/10.3390/inorganics11110444
Chicago/Turabian StyleKuo, Yi-Lin, Hsin-Kuan Liu, and Chen-I Yang. 2023. "Spin Canting and Weak Ferromagnetism in a New 2D Coordination Polymer with the Co(II) Chain Bridged by a Single End-to-End Azide" Inorganics 11, no. 11: 444. https://doi.org/10.3390/inorganics11110444