Properties of Materials for Spintronic Applications

A special issue of Magnetochemistry (ISSN 2312-7481). This special issue belongs to the section "Spin Crossover and Spintronics".

Deadline for manuscript submissions: closed (20 October 2022) | Viewed by 1902

Special Issue Editor


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Guest Editor
Argonne National Laboratory & Pritzker School of Molecular Engineering, University of Chicago, Chicago, IL, USA
Interests: spintronics; chiral induced spin selectivity; asymmetric reaction; chiral induction; magneto-electronics; magnetoelectrochemistry
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Special Issue Information

Dear Colleagues,

Spintronics is a new technology used for storing, displaying, and processing information based on changes in the electronic properties of magnetic field materials. The magnetization alignment can influence asymmetric interaction with various biological systems and, furthermore, can be used for spintronic applications by utilizing quantum-mechanical effects.

Recently, parallel efforts to induce spin selective charge imbalance have attracted enormous attention in the interdisciplinary community. There is the belief that electronic spin couples its degree of freedom with one of the most intriguing asymmetries in nature, chirality. Chirality corresponds to handedness, such that chiral objects are mirror replicas but cannot be superimposed over each other. Interestingly, moving electrons with specific spin also follow chiral paths due to their asymmetric momentum. This enables the chiral system to couple with a spin degree of freedom of an electron, and allows specific spin to travel through this chiral system, and vice versa for the opposite spin. In the past, many systems were developed to create spin imbalance, such as spin filtering or spin polarized current. For example, recently, in supramolecular helical structures, 50 to 60% spin polarization has been observed, where one can easily control the helicity in order to enable spin polarization. Beyond the molecular measurement, significant effort has also been taken to make real spin valves using these systems. Magnetoresistance devices have been modified, where the soft ferromagnetic layer of the prototype device is replaced with a helical system, enabling spin filtering up to 10%. Although there are several applications of this effect, it is important to realize that a more basic understanding of the phenomenon is required.

Dr. Suryakant Mishra
Guest Editor

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Keywords

  • spintronics
  • chiral induced spin selectivity
  • asymmetric reaction
  • chiral induction
  • magneto-electronics
  • magnetoelectrochemistry

Published Papers (1 paper)

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Research

15 pages, 3011 KiB  
Article
Binuclear Nickel Complexes of a New Di(hydroxyphenyl)imidazolate
by Igor A. Nikovskiy, Kseniia M. Karnaukh, Dmitry Yu. Aleshin, Kirill A. Spiridonov, Anastasia A. Danshina, Yulia V. Nelyubina, Alexander V. Polezhaev and Valentin V. Novikov
Magnetochemistry 2022, 8(10), 132; https://doi.org/10.3390/magnetochemistry8100132 - 18 Oct 2022
Cited by 2 | Viewed by 1566
Abstract
Here, we report a new di(hydroxyphenyl)imidazolate ligand with an N2O2 donor set synthesized by a modified Debus–Radziszewski procedure. Its binuclear nickel(II) complexes feature a weak antiferromagnetic interaction with J12 = −3.16 cm−1 between the two nickel(II) ions identified [...] Read more.
Here, we report a new di(hydroxyphenyl)imidazolate ligand with an N2O2 donor set synthesized by a modified Debus–Radziszewski procedure. Its binuclear nickel(II) complexes feature a weak antiferromagnetic interaction with J12 = −3.16 cm−1 between the two nickel(II) ions identified by magnetometry measurements. As follows from cyclic voltammetry experiments and DFT calculations, they undergo ligand-centered oxidation via the formation of cation radicals with short lifetimes that can be potentially stabilized by bulkier t-butyl groups in the ortho-positions of the ligand. The reported ligand widens the range of the building blocks available to molecular magnetism community and thus provides new ways to the design of magnetic materials with switchable properties. Full article
(This article belongs to the Special Issue Properties of Materials for Spintronic Applications)
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