Composition Design and Damage Mechanism of Crystal Superalloys

A special issue of Metals (ISSN 2075-4701). This special issue belongs to the section "Metal Casting, Forming and Heat Treatment".

Deadline for manuscript submissions: 31 August 2024 | Viewed by 1954

Special Issue Editor


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Guest Editor
School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an 710072, China
Interests: Ni-based single crystal superalloys; laser repair; columnar to equiaxed transition (CET); mechanical properties

Special Issue Information

Dear Colleagues,

Due to their excellent resistance to mechanical and chemical degradation, poly- and single-crystal superalloys are high temperature materials used in gas-turbine engines. The number of alloying elements in these alloys is usually greater than ten, and each element has a specific function for improving properties. Therefore, the composition design, on one hand, is always one critical aspect in developing the promising superalloys, which can perform excellently when serving at elevated temperatures. On the other hand, a long time service under harsh conditions, such as high temperature, high pressure, corrosive environment, and applied stress, could lead to damage in superalloys, which will result in the failure of component. Thus, the damage mechanisms of crystal superalloys is another key aspect.

The composition changes in designing the superalloys could lead to variations in the microstructure characterizations, such as the morphology, element distribution, phase constituents, etc., which will determine the performance and change damage modes of the alloys. Hence, the relationships among “composition design–microstructure characterization–damage mechanism” are interesting for the development of new superalloys with excellent performances.

In this Special Issue, we welcome articles that focus on the composition design and damage mechanism of crystal superalloys. Papers on material preparation methods, alloy and component behaviour, and final products’ performance are also encouraged.

Prof. Dr. Nan Wang
Guest Editor

Manuscript Submission Information

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Keywords

  • superalloys
  • laser cladding
  • laser remelting
  • characterization
  • microstructure
  • CET
  • corrosion
  • creep performance
  • fatigue strength
  • damage

Published Papers (1 paper)

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Research

15 pages, 5943 KiB  
Article
A Survey on the Oxidation Behavior of a Nickel-Based Alloy Used in Natural Gas Engine Exhaust Valve Seats
by José Henrique Alano, Renato Luiz Siqueira, Claudio Beserra Martins Júnior, Rodrigo Silva, Guilherme dos Santos Vacchi and Carlos Alberto Della Rovere
Metals 2023, 13(1), 49; https://doi.org/10.3390/met13010049 - 24 Dec 2022
Cited by 2 | Viewed by 1815
Abstract
This study reports the oxidation behavior of a Ni-based alloy used in the manufacture of valve seats for automotive engine exhaust systems. Isothermal thermogravimetric analyses were carried out at temperatures of 660, 740, 860, and 900 °C under an oxygen atmosphere for up [...] Read more.
This study reports the oxidation behavior of a Ni-based alloy used in the manufacture of valve seats for automotive engine exhaust systems. Isothermal thermogravimetric analyses were carried out at temperatures of 660, 740, 860, and 900 °C under an oxygen atmosphere for up to 1 h. At 660 and 740 °C, only one stage was observed during the whole time studied. At this stage, the oxide layer was formed mainly by NiO + Cr2O3, following a linear oxidation law with a rate constant (Kl) on the order of magnitude of 10−6 kg/m2s and an apparent activation energy (Ea) of ~47 kJ/mol. At 860 and 900 °C, an identical first stage was observed with a transition to a different stage. In the second stage, the oxidation layer was composed of Cr2O3, and a parabolic oxidation law was followed with a rate constant (Kp) on the order of 10−8 kg2/m4s and Ea of ~128 kJ/mol. Moreover, the Ni-based alloy formed a dense and compact oxide layer after oxidation, with no apparent cavities, pores, or microcracks. Characterization techniques such as Scanning Electron Microscopy (SEM), Energy-Dispersive X-ray Spectroscopy (EDS), Fourier Transform Infrared Spectroscopy (FTIR), and Raman Spectroscopy were carried out to characterize the formed oxide layer. Full article
(This article belongs to the Special Issue Composition Design and Damage Mechanism of Crystal Superalloys)
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