Phase Transformations and Physical Properties of Alloys

A special issue of Metals (ISSN 2075-4701).

Deadline for manuscript submissions: closed (31 October 2023) | Viewed by 5822

Special Issue Editor


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Guest Editor
Department of Materials Engineering, Ben-Gurion University of the Negev, Beer-Sheva 84105 POB 653, Israel
Interests: intermetallics; high-entropy alloys; light-weight alloys; electron crystallography; characterization; structure solution; X-ray diffraction; transmission electron microscopy
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Special Issue Information

Dear Colleagues,

The concept of classical metallurgy defines alloys as containing additional (to major constituent) elements which allow the attainment of improved physical properties. Using this approach, new steels (as an example) were developed, increasing the work temperature, corrosion resistance, achieving better strength/ductility combination, etc. Lately, the novel concept of high-entropy alloys has revolutionized the field of metallurgy. Instead of one major constituent and minor impurities, equiatomic or near-equiatomic compositions of a minimum of five elements are used, attaining improved physical properties due to local disorder in the formed solid solutions. Regardless of the concept applied for the preparation of the alloy, the existence or lack of phase transformations have always been at the center of researchers’ attention, since this dictates the possibility of application. As a function of composition, pressure, and/or temperature, physical properties may change dramatically due to the occurring phase transformation. The nature of the phase transformation might vary: order–disorder, appearance or dissolution of intermetallics, etc. Regardless of the nature of the phase transformation, they always induce a change of physical properties that may be wanted or unwanted depending on the subsequent usage.

In this Issue we invite articles containing experimental research and/or theoretical calculations, reporting on the phase transformations occurring in alloys (both conventional and high-entropy alloys). The emphasis of this Issue is on the corner-stone of materials science, namely, how phase transformations influence the physical properties of the alloys.

Prof. Dr. Louisa Meshi
Guest Editor

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Keywords

  • alloy
  • characterization
  • phase transformation
  • physical properties
  • high pressure
  • order–disorder
  • intermetallics
  • high temperature
  • stability

Published Papers (2 papers)

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Research

11 pages, 4167 KiB  
Article
Composition-Induced Magnetic Transition in GdMn1-xTixSi Intermetallic Compounds for x = 0–1
by Roman D. Mukhachev and Alexey V. Lukoyanov
Metals 2021, 11(8), 1296; https://doi.org/10.3390/met11081296 - 17 Aug 2021
Cited by 6 | Viewed by 1710
Abstract
Magnetic intermetallic compounds based on rare earth elements and 3d transition metals are widely investigated due to the functionality of their physical properties and their variety of possible applications. In this work, we investigated the features of the electronic structure and magnetic properties [...] Read more.
Magnetic intermetallic compounds based on rare earth elements and 3d transition metals are widely investigated due to the functionality of their physical properties and their variety of possible applications. In this work, we investigated the features of the electronic structure and magnetic properties of ternary intermetallic compounds based on gadolinium GdMn1-xTixSi, in the framework of the DFT + U method. Analysis of the densities of electronic states and magnetic moments of ions in Ti-doped GdMnSi showed a significant change in the magnetic properties depending on the contents of Mn and Ti. Together with the magnetic moment, an increase in the density of electronic states at the Fermi energy was found in almost all GdMn1-xTixSi compositions, which may indicate a significant change in the transport properties of intermetallic compounds. Together with the expected Curie temperatures above 300 K, the revealed changes in the magnetic characteristics and electronic structure make the GdMn1-xTixSi intermetallic system promising for use in microelectronic applications. Full article
(This article belongs to the Special Issue Phase Transformations and Physical Properties of Alloys)
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15 pages, 7222 KiB  
Article
Laboratory X-ray Diffraction Complex for In Situ Investigations of Structural Phase Evolution of Materials under Gaseous Atmosphere
by Maxim Syrtanov, Georgiy Garanin, Egor Kashkarov, Natalia Pushilina, Viktor Kudiiarov and Tatyana Murashkina
Metals 2020, 10(4), 447; https://doi.org/10.3390/met10040447 - 28 Mar 2020
Cited by 14 | Viewed by 3288
Abstract
In this work, a laboratory X-ray diffraction complex for in situ investigations of structural phase evolution of materials under gaseous atmosphere and elevated temperatures was developed. The approbation of the complex was carried out using a commercially pure titanium (CP-Ti) powder, zirconium (Zr-1Nb) [...] Read more.
In this work, a laboratory X-ray diffraction complex for in situ investigations of structural phase evolution of materials under gaseous atmosphere and elevated temperatures was developed. The approbation of the complex was carried out using a commercially pure titanium (CP-Ti) powder, zirconium (Zr-1Nb) alloy and electron beam melted Ti-6Al-4V alloy. It was established that hydrogenation of the CP-Ti powder occurred at a temperature of 500 °C and a hydrogen pressure of 0.5 atm, accompanied by the formation of metastable γ titanium hydride (γ-TiH) phase. The lifetime of the γ-TiH phase was 35–40 min. Decomposition of the γ-TiH occurred after reaching a temperature of 650 °C as a result of the thermally stimulated desorption of hydrogen. The α-Zr → δ-ZrH phase transformation was observed under hydrogenation of the zirconium Zr-1Nb alloy at a temperature of 350 °C and a hydrogen pressure of 0.5 atm. It was revealed that the increase in hydrogenation temperature to 450 °C accelerated this transformation by two times. Hydrogenation of the electron beam melted titanium Ti-6Al-4V alloy at a temperature of 650 °C and hydrogen pressure of 0.5 atm was accompanied by the α → α + β → β + α2 phase transformations. Full article
(This article belongs to the Special Issue Phase Transformations and Physical Properties of Alloys)
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