Synthesis and Application of Porous Clay Materials in Heterogeneous Catalysis and Treatment of Hazardous Wastes

A special issue of Minerals (ISSN 2075-163X). This special issue belongs to the section "Clays and Engineered Mineral Materials".

Deadline for manuscript submissions: closed (30 December 2022) | Viewed by 2615

Special Issue Editor


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Guest Editor
Division of Advanced Nuclear Engineering (DANE), Pohang University of Science and Technology (POSTECH), Pohang 790-784, Korea
Interests: synthesis, characterization, and applications of porous materials in heterogeneous catalysts and treatment of hazardous waste/contaminants; sorption/removal of toxic metals/radionuclides from wastewater, the aqueous speciation of metal ions, and immobilization and leaching of radioactive wastes

Special Issue Information

Dear Colleagues,

Clay minerals are hydrous aluminum silicates (bentonite/montmorillonite/kaolinite) and the key constituents of soils containing magnesium, alkali metals, alkaline earths, and other cations. Because of their several valuable properties (ion-exchange capacity, porous structure, large surface area, surface charge, highly crystallinity, and structure stability), clay materials are potentially used in numerous applications, e.g., heterogeneous catalysis (e.g., catalytic conversion in petrochemical industries), removal/sorption of hazardous waste (e.g., toxic metals, radionuclides, and organic contaminants), and as backfill material in nuclear waste disposal. The synthesis of clay materials has an edge over there natural (mineral) counterparts as their properties (ion-exchange capacity, surface area, etc.) could be efficiently altered by controlled synthesis conditions. Moreover, post-synthesis treatment of clay materials (e.g., surface modification) using various organic/inorganic surface modifier can significantly change their potential applications in various fields/sectors.

Over a time span of decades, various promising works have been reported on the application of both natural and synthesized clay minerals/materials in various fields. However, there is still a need for the collection of vast research to solve several unanswered questions. This Special Issue aims to collect quality research papers and review articles focusing on the synthesis and application of clay materials/clay-based materials in various sectors, including catalysis, sequestration of hazardous wastes (toxic metals, radionuclides, and organic pollutants), and in immobilization of radioactive wastes. In this issue, we aim to cover both experimental as well as theoretical approaches/studies in the aforementioned areas. All potential works are highly welcomed.

Dr. Bhupendra Kumar Singh
Guest Editor

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Keywords

  • sorption
  • radioactive wastes
  • toxic metals
  • immobilization
  • desorption
  • leaching

Published Papers (1 paper)

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Review

21 pages, 3515 KiB  
Review
Application of Clay Materials for Sorption of Radionuclides from Waste Solutions
by Bhupendra Kumar Singh and Wooyong Um
Minerals 2023, 13(2), 239; https://doi.org/10.3390/min13020239 - 8 Feb 2023
Cited by 6 | Viewed by 2216
Abstract
The wide application of nuclear resources in various fields has resulted in the production of radioactive waste, which poses a serious threat to lives and the environment. Nuclear waste contains long-lived radionuclides and, due to its mobility in environments, the proper management of [...] Read more.
The wide application of nuclear resources in various fields has resulted in the production of radioactive waste, which poses a serious threat to lives and the environment. Nuclear waste contains long-lived radionuclides and, due to its mobility in environments, the proper management of generated waste is necessary. To impede the mobility of radionuclides in environments, various materials have been tested as suitable sorbents under different experimental conditions. In this review, we thoroughly discuss some key and recent contributions to the application of natural clays (NCs) and modified/functionalized clays (MCs) for the sorption of various radionuclides in their cationic and anion forms from (simulated) waste solutions under different experimental conditions. More specifically, we discuss the key developments toward the use of natural clays for the efficient sorption of various radioactive contaminates. Later, this review targets the modification/functionalization of natural clays using various organic moieties to improve their removal capacities for various radionuclides/hazardous ions present in waste solutions. Finally, we summarize the major aspects and highlight the key challenges to be addressed in future studies to further enhance the application of clays and clay-based materials for selective and effective removal of various radionuclides from waste solutions. Full article
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