Quantum Mechanics and Its Evolving Formulations
Abstract
:1. Introduction: The Pioneers
One morning about the 10 July 1925 I suddenly saw light: Heisenberg’s symbolic manipulation was nothing but the matrix calculus well-known to me since my student days [2].
2. Von Neumann’s Axiomatics
- 1.
- The space of states of a system is a Hilbert space .In particular, the requirement that be complete offers a certain mathematical “comfort”—that is, powerful theorems that do not hold without it.
- 2.
- A state is represented by a ray (“pure state”: ) or a density operator , i.e., a trace class operator with Tr = 1; in particular, defines a pure state if and only if one has , i.e., is a projection.
- 3.
- A physical observable is represented by a self-adjoint operator in . Therefore, one may use
- .
- The spectral theorem for self-adjoint operators.
- .
- Stone’s theorem: is unitary if and only if ; this is the key of the time evolution.
- 4.
- Given a physical observable represented by the self-adjoint operator A, its expectation value in the state is given byFor a pure state , this becomes
- 5.
- Given two states , the transition probability is given by
- Not all vectors in may represent states.First, some states cannot be prepared experimentally, e.g., a state of “infinite energy”, i.e., , if the Hamiltonian H is unbounded. Worse, some vectors cannot make sense as states. For instance, there might be superselection rules; what meaning can be given to ? More basically, there is no plane wave in .
- Which self-adjoint operators in can possibly represent an observable?Certainly not all of them (Pauli was the first to note this). For instance, what could represent the operator if A and B do not commute? Wigner kept asking: what does the operator represent for a hydrogen atom?More generally, the question is how to select the “good” operators. This asks for a precise definition of the concept of observable, containing two aspects: the physical definition—that is, how the quantity can be measured experimentally—and the mathematical definition of the representative operator.
- There are problems with unbounded operators: one has to make their domain precise; they cannot be added freely. Similarly, operators with a continuous spectrum have the problem that there are no eigenvectors corresponding to points of the continuous spectrum. Another difficulty is that the transition between the Schrödinger picture and the Heisenberg picture may be problematic if the Hamiltonian is unbounded.
3. Dirac’s Axiomatics
3.1. The “Bra-Ket” Formalism
- 1.
- The states of a quantum system constitute a vector space , equipped with a Hermitian inner product , which manifests the superposition principle, and there is a bijective correspondence
- 2.
- Given two states , the transition probability is given by
- 3.
- Each physical observable is represented by a linear Hermitian operator on , and these operators form a (non-Abelian) algebra: and are well defined.
- 4.
- Each physical system has a complete system of commuting observables (CSCO), and the eigenvectors of the elements of this CSCO constitute a basis of . Thus, every state may be expanded into that basis.
3.2. Spectral Analysis
- Orthogonality relations
- Closure relation:
- Expansion of an arbitrary state :
- Example: take the CSCO H (rotation invariant Hamiltonian), , (angular momentum), with common eigenvectors :
- Probabilistic interpretation, like von Neumann’s:
3.3. What about a Rigorous Dirac Formalism?
4. The RHS Approach
4.1. Building a Rigged Hilbert Space
- Stage #1: Select a family of labeled observables that in fact define the system, i.e., (i) observables with a precise physical interpretation, e.g. in terms of measurement (position, energy, …) and (ii) represented by self-adjoint operators that possess a common invariant dense domain : . Thus, is an algebra.
- Stage #2: Equip with a suitable topology that makes all operators continuous. In this way, one obtains a topological vector space dense in , with continuous embedding (such a topology may be defined by the family itself).
- Stage #3: By (anti)duality, one obtains the triplet (RHS):
4.2. More about the RHS
- .
- represents those states that are physically preparable.
- .
- is von Neumann’s Hilbert space.
- .
- contains generalized states associated with measurement operations.
- .
- complete, i.e., every Cauchy sequence converges to an element of ; otherwise, its completion might fail to be contained in .
- .
- reflexive: , so that no other space than and has to be considered, which would ruin the interpretation above.
- .
- nuclear, which allows to apply the generalized spectral theorem of Gel’fand–Maurin.
5. The Generalized Spectral Theorem of Gel’fand–Maurin
5.1. Eigenvectors
5.2. The Generalized Spectral Theorem
- .
- A has a self-adjoint extension in ; thus, is an extension of A et (collectively, )
- .
- is nuclear and complete.
5.3. Spectral Projections
- .
- one may identify every vector with a functional
- .
- is a nuclear operator from into ; projection on the eigenspace corresponding to the eigenvalue .
6. Conclusions
- .
- acting in (active point of view)
- .
- acting in (passive point of view)
Funding
Acknowledgments
Conflicts of Interest
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Antoine, J.-P. Quantum Mechanics and Its Evolving Formulations. Entropy 2021, 23, 124. https://doi.org/10.3390/e23010124
Antoine J-P. Quantum Mechanics and Its Evolving Formulations. Entropy. 2021; 23(1):124. https://doi.org/10.3390/e23010124
Chicago/Turabian StyleAntoine, Jean-Pierre. 2021. "Quantum Mechanics and Its Evolving Formulations" Entropy 23, no. 1: 124. https://doi.org/10.3390/e23010124
APA StyleAntoine, J. -P. (2021). Quantum Mechanics and Its Evolving Formulations. Entropy, 23(1), 124. https://doi.org/10.3390/e23010124