2. Scaling Relations and Universal Combinations of Amplitudes: A Short Primer
We assume that the reader is familiar with the notion of critical exponents that describe the singularities of various thermodynamic functions at the approach of a second-order phase transition. Otherwise, we can suggest referring, e.g., to the textbook of Kardar [
1].
Standard scaling relations among the universal critical exponents are the following:
They are very useful, not only to obtain the values of all six fundamental critical exponents within a universality class from the knowledge of two of them, but also because they allow for the definition of other universal quantities, written as specific combinations of critical amplitudes. Let us show how this works. For that purpose, we first define the amplitudes as they enter the expressions of the leading singular behaviors of thermodynamic quantities in the vicinity of a second-order phase transition:
Here, the two arguments of the functions at the l.h.s. are, respectively,
and
, and the indices ± specify the high (
)- and low (
)-temperature phases, meaning that the field is zero, and the index
c, on the contrary implies the field behavior at the critical temperature. The symbol ≃ stands for the leading singularity (i.e., the most singular part since there could be regular contributions to the thermodynamic quantities, power-law corrections to scaling, and multiplicative logarithmic corrections, all these being omitted in Equations (
5)–(
9)).
We can also define the singular part of the free energy density in zero field:
and since the specific heat is the second derivative of
with regard to
t,
is not independent since this requires
. The Lee–Yang edge is another quantity of interest in critical phenomena, and we define
with the so-called gap exponent
.
Universality is the observation that some quantities only depend on very general properties, like space dimensionality. The critical exponents are such universal quantities, but the amplitudes are not, although some combinations among them have the property of universality. To make it clear, let us write Widom’s scaling assumption, i.e., the fact that the singular part of the free energy density is a homogeneous function of the scaling fields
where
is a universal scaling function of its arguments,
and
are the RG dimensions of the relevant fields
t and
h, and
and
are non-universal metric factors that would differ, say, on the square lattice and the triangular lattice in
. The amplitudes defined above depend on these metric factors, and this is why they are not universal, e.g., from
, setting
in the scaling form (
12), one obtains
This identifies the exponent
and the amplitude
.
The other exponents are similarly defined in terms of and by very famous relations that we do not repeat here, and the other amplitudes depend on the metric factors as , , .
Simple ratios are immediately defined from the fact that the approach to criticality from above and from below is described by the same exponent for a given quantity (except for the magnetization, obviously), for example, in the case of the specific heat
and
, where
. It follows that the metric factors cancel in the ratio, and
is thus universal. The limit corresponds to the approach to criticality (
here) since the combination
can be temperature-dependent due to the possible presence of different values for the amplitudes of the corrections to scaling, which has not been taken into account in Equations (
5) to (
9). In the same manner, one defines the universal ratios
The scaling relations are other examples of relations that allow the definition of new combinations. For example, the ratio
eliminates
, and
is then eliminated, thanks to Equation (
1), if we further divide by
. There is still an unwanted
dependence that needs to be simplified, and for that purpose, we consider the quantity
Thanks to Equation (
1), the fact that all metric factors cancel out in this latter quantity makes the combination
universal. Proceeding the same way, Equations (
1) and (
2) suggest to contemplate the expressions
that reach their respective universal values. Eventually, Equation (
4) leads to consider the following combination
as universal also.
3. From the Universal Combinations of Amplitudes to Scaling Laws among Hatted Exponents
Having the universal combinations of amplitudes at hand, we consider now the case where the critical behavior is described, besides the leading singularities, by multiplicative logarithmic corrections. This may happen, for example, for a system at its upper critical dimension
, or in the case of the
four-state Potts model, or the
disordered Ising model as well. Many examples can be found in Refs. [
2,
3,
4].
Let us first remind the standard definitions of some exponent combinations that will occur below:
,
,
,
. The logarithmic corrections can appear either in the approach to the critical temperature when the magnetic field is fixed at zero or, on the other hand, right at
when the magnetic field approaches zero:
We can also define at criticality
the logarithmic correction of the correlation function, defining the exponents
that will play an essential role in the following of this paper:
We mostly use the notations of Refs. [
2,
5], with quantities (amplitudes and exponents) at the critical temperature defined with the subscript
c, except for
in (
29), which is standard according to the terminology fixed by Fisher long ago [
6].
Ralph Kenna and his coworkers, Des Johnston and Wolfhard Janke, have established a series of scaling relations [
2,
3,
4] among “hatted exponents”, as Ralph used to call them. Their approach was based on the zeros of the partition function, either the Lee–Yang zeros (in complex magnetic field) or the Fisher zeros (in complex temperature).
Here, we offer an alternative derivation of most of these scaling laws, probably simpler in its approach. Universality assumes that the previous ratios of amplitudes are still universal when multiplicative logarithmic corrections are present, i.e.,
The fact that this quantity
must tend to
now demands that
This is the first of Ralph and his coworkers’ scaling relations. Using the same method, the second ratio easily leads to a second relation:
The amplitude of the Lee–Yang edge,
, has a non-trivial dependence with the metric factors,
. This can be retrieved from the scaling relation
, and the universality of the ratio
requires that
The scaling relations (
36) and (
37) were first derived in Ref. [
3]. Instead of (
39), Ralph and his coworkers had
, which is recovered here using (
37) and (
39).
In the same paper, they also derived
that we will now consider. This is an analog of the hyperscaling relation for logarithmic relations since it is derived from the same ratio of amplitudes as the ordinary hyperscaling relations, even though the space dimension, fixed at its upper critical value, does not appear explicitly. A new
pseudo-critical exponent [
3,
4,
7] appears there,
, which describes the finite-size scaling (FSS) of the correlation length
This behavior is encoded in the scaling hypothesis for the correlation length, appropriately extended to account for the logarithmic correction:
Like
(respectively,
) is the RG eigenvalue associated with the scaling field
t (respectively,
h), we denote
(respectively,
) the corresponding exponent of the logarithmic correction. For the sake of clarity, we will later denote the rescaled variables as
,
, and
. Equation (
41) follows from the choice
at criticality
in (
42). The same scaling form is used in the thermodynamic limit
, setting
. This requires iterations
Insertion into the expression of the correlation length leads to the leading order
and requires the usual relation
to conform to (
26):
We now show that this agrees with Ralph’s scaling relation (
40). For that purpose, we use the compatibility with the extension of the phenomenological Widom scaling assumption for the free energy density (
12) to the presence of logarithmic corrections, written as far as we know for the first time by Ralph Kenna in Ref. [
8],
The second derivative with regard to
t is the specific heat, and the choice
at
then leads (using
) to
(from now on, we always limit (
43) to leading logarithmic order); hence, from (
25),
which completes the proof.
4. Solving a Disagreement with Our Friends
In Ref. [
2], Ralph Kenna has given a complete account of these and many more scaling relations among hatted exponents. This is not our purpose here to be exhaustive, but rather to show alternative derivations, or to complete what Ralph and his coworkers did not do. With this perspective in mind, Equations (
42) and (
46) and an analogous homogeneity form for the correlation function (discussed later) offer an option to proceed as we show now.
In Ref. [
4], two other scaling relations between hatted exponents were derived:
Concerning the first relation (
49), the second formula is valid in such circumstances where the model has
and an impact angle
for the Fisher zeros in the complex plane (this is the case for the pure two-dimensional Ising model). We will not consider this case, but rather the more general case of the first formula. It can be rederived by careful use of the ratio 4 (Equation (
19)) in
Section 2, and even requires the use of FSS of the correlation length. From
, we first reverse to
. This expression is then incorporated into (
20) to obtain
i.e., a modified version of (
19):
Now, inserting (
41) into (
51) leads to the FSS behavior of the free energy density at criticality
and compatibility with (
46) at
,
then demands
which is Kenna and his coworkers’ relation.
The same derivation can be carried out for the magnetic sector, considering the approach to criticality at
for
, yielding the scaling relation
Concerning Equation (
50), we believe that this relation is incomplete. Applied to the four-state Potts model in two dimensions [
9,
10,
11,
12], which has
,
,
, and
, Equation (
50) is fulfilled. We believe that this is because
, and that an additional term
is missing in the general case. A test is provided in the case of the Ising model in four dimensions, which has
(models at their upper critical dimensions have
[
7,
13,
14,
15]). There, Ralph and his coauthors had anticipated that
for Equation (
50) to work (
,
, and
for the Ising model in four dimensions), but according to Luijten [
16],
instead, a result that is in contradiction with Equation (
50).
Let us examine the problem in more detail. In Ref. [
4], the authors have questioned the relation between the correlation function and the square of the magnetization when the system decorrelates, i.e., for
:
On the contrary, we assume that there is no reason why this would not be valid, so we start from the homogeneity of the (spin–spin) correlation function with logarithmic corrections as
Setting
,
and the thermodynamic limit
leads to the following temperature behavior when
This requires the usual relation
and
The two examples given above are test grounds. For the four-state Potts model in two dimensions, we extract immediately
, which is correct. For the
Ising model, on the other hand, we obtain
, in agreement with Luijten’s result [
16], later verified numerically in Ref. [
17], but we are here in contradiction with the prediction of Refs. [
2,
4].
Since the question is of importance, we want to consider it from other perspectives also. The correlation function is linked to the susceptibility via the fluctuation–dissipation relation:
Setting
, we have
and since the susceptibility obeys, via the second derivative of (
46),
its FSS compared to (
61) demands that
and
Again, this confirms
for the
Ising model.
The fluctuation–dissipation theorem has also been used in Refs. [
2,
4] in the form
from where Equation (
50) follows, so there is still some difficulty hidden to solve our disagreement. Let us set
in (
62):
where the variable
x in the scaling function
is evaluated at
to give
The scaling function must have the behavior
when
to recover the temperature singularity of the susceptibility
. It follows that instead of (
64), one has
and instead of Equation (
50), one has a third form for the exponent
:
again compatible with
for the
Ising model. This suggests to use, instead of the ratio
, the modified version
which, again, is universal. The four standard scaling laws and the corresponding four hatted scaling laws are listed in
Table 1.
So far so good, but the situation is not yet clear since the case of percolation in six dimensions (its upper critical dimension) is maybe a counterexample. With
,
,
, and the values of the logarithmic correction exponents
,
, and the pseudo-critical exponent
, using Equation (
68), we predict
, while Kenna and his coworkers predict
from Equation (
50). This latter result conforms to an analytic prediction from Ref. [
18], but on the other hand, our value is supported by an FSS prediction by Ruiz-Lorenzo [
19],
. This disagreement demands further analysis.
In Ref. [
2], Kenna listed the values of the known hatted critical exponents for a series of models, and when
was not known, he proposed the expected value from the use of Equation (
50). An interesting model is missing from the list, the tricritical Ising model, which has logarithmic corrections at its upper critical dimension
and has non-zero
. We will now analyze this universality class in more detail.
5. The Tricritical Ising Universality Class in the Blume–Capel Model at the Upper Critical Dimension
The spin-1 Blume–Capel model [
20,
21] is a lattice model defined by the Hamiltonian
where the spin variables
,
denotes the ferromagnetic exchange interaction among nearest-neighbor sites (
indicates summation over nearest neighbors), and
is the crystal-field strength that controls the density of vacancies (the
states can be viewed as vacancies in an ordinary
Ising model) [
22]. For
, vacancies are suppressed from the partition function, and the Hamiltonian reduces to that of the Ising ferromagnet. At
the second-order transition is in the pure Ising model universality class. When
increases from 0, a perturbation theory shows that the transition temperature decreases along a line that remains of Ising-like second-order phase transition. On the other hand, in the vicinity of
, the transition is first order and persists first order at small values of
T until it reaches the second-order line. Right at the limit, there is a tricritical point characterized by specific values of
,
(
Figure 1). Tricriticality corresponds to the
Landau expansion [
23], and the upper critical dimension is thus
, the case that we consider now.
Using appropriate linear combinations of the physical parameters, determined by the geometry of the phase diagram and the fact that they have to vanish at the tricritical point, the even scaling fields are
,
, and the odd scaling field is the usual magnetic field
. Lawrie and Sarbach [
24] have shown that the free energy density at the tricritical point in
reads, in terms of these scaling fields, as
where the non-universal metric factors
have been omitted. Here, the subscript “tri” indicates that the expression is valid in the vicinity of the tricritical point where
. The logarithmic corrections are explicitly given in this expression.
The notations in Ref. [
24] necessitate to be adapted to be consistent with those that we have used until now. Leaving aside the logarithmic corrections for a while, let us write
The dominant even scaling field is
g, the usual singularities and critical exponents are therefore defined by their behaviors with regard to
g instead of
, which brings corrections to scaling due to crossover. This means that the
t and
of the three previous sections of this paper will now be replaced by
g and
. At
and
, setting
leads to
. This is compatible with
. The specific heat measures the total energy fluctuations. Its most singular part is defined by
with
. This shows that the exponent
of
is thus equal to the usual value
, and the hyperscaling relation holds.
We can also define less singular exponents with regard to the scaling field
(with tilde notation), e.g.,
. A similar analysis as above shows that
with
with
the crossover exponent. There is a caveat here since
is not equal to , as one can find in the literature [
24]. Indeed,
, hence
. This is important to collect correct expressions, and this is shown in
Table 2.
This being said, we can now incorporate the logarithmic corrections in Equation (
72) to obtain
and the comparison with Equation (
71) simply leads to
We can now deduce the values of the standard critical exponents and the associated logarithmic corrections exponents. They are listed in
Table 3 for three universality classes, which all have non-zero values of the pseudo-critical exponent
, the Ising model in four dimensions, the tricritical Ising model in three dimensions, and the problem of percolation in six dimensions.
In this table, the first six lines are not controversial. The seventh line presents the correlation function correction exponent
, which follows from our scaling law, in any of the forms given in Equations (
59), (
63), or (
68). These three expressions are mutually consistent, but they differ from Equation (
50) used by Kenna and his coauthors. This latter formula would, respectively, predict for the three universality classes the values 0,
, and
. We have seen that the first value, 0, is falsified in the
IM case by Refs. [
16,
17], but the results of Ref. [
18] invalidates our third value
, the last entry of in
Table 3, while Ref. [
19], on the contrary, supports this value.
The case of the tricritical Ising model in three dimensions appears crucial, and we have to provide numerical results in support of our result. The numerical computation of the correlation function is known to be a very delicate problem, and we will approach the value of the exponent
differently, using FSS. Another delicate aspect is also the well-known fact that extracting logarithmic corrections in the vicinity of a critical point can be extremely difficult [
25]. Recently, it was found that very accurate results can be obtained numerically in the Blume–Capel model with relatively small system sizes [
26] via the analysis of the zeros of the partition function, and in particular the Lee–Yang zeros [
27,
28]. The Lee–Yang zeros are connected to the susceptibility [
29] via
where
j labels the zeros in the upper-half complex plane, indexed in order of increasing distance from the critical point. The sum is dominated by the lowest zero, the Lee–Yang edge
, and at the tricritical point, the FSS of the susceptibility is thus linked to that of
:
In the presence of logarithmic corrections, the scaling form of the Lee–Yang edge obeys
compatible with the behavior in terms of the thermal scaling field
g, as it can be shown using the scaling laws of
Table 3,
. If one sits exactly at the tricritical point,
, we can extract the FSS behavior of the zeros by setting
,
and it follows that we expect
which agrees with Equation (
78).
As we said, this form can be checked with good accuracy at the price of relatively light Monte Carlo simulations. The coordinates of the tricritical point of the Blume–Capel model in
are found in Ref. [
30],
,
, but the value of
does not seem to be as accurate as that of the temperature and for example Zierenberg et al. Ref [
31] report instead
. Let us first analyze this problem ourselves. In
Figure 2, we report the FSS of the magnetization at
for several values of
ranging from 2.8440 to 2.8448. The magnetization is expected to follow the FSS behavior
with
and
. The data points are fitted as
with
free parameters. The closest to the expected result (the black dashed line) is at
, where we obtain
. We will thus consider this value of
as our estimate for the coordinate of the tricritical point
.
The analysis of the Lee–Yang edge is presented in
Figure 3 with a larger choice of values of
and, again, the best fit is at
, where the estimate of
is now slightly larger at
.
The reader could still question the sensitivity of the value of
with the choice of tricritical temperature
. Indeed, when one looks at the FSS of the tricritical magnetization, for example, the effective exponent of the log term is either positive and close to the expected value or can differ from the expectation and even be negative, depending on the values of the crystal field
(see
Figure 2). It makes sense to ask whether the role of
may also have a significant influence. We believe that the results presented in this work are reliable and to support the consistency of the numerical data, we show in
Figure 4 that slight variations of
T change the regime from the pure 3d Ising model at
, for which
[
32] is expected, to first order at
, where an effective FSS
is expected [
33].
safely recovers
to a very good accuracy and confirms the tricritical value of
. Note that the transition line in the phase diagram in the vicinity of the tricritical point is almost at a fixed value of
, this is why the three regimes are found at the same crystal-field value of
.